[go: up one dir, main page]

NO971109L - Fremgangsmåte for fremstilling av lagdelte nanokompositter av silikat-epoxy, og slike kompositter - Google Patents

Fremgangsmåte for fremstilling av lagdelte nanokompositter av silikat-epoxy, og slike kompositter

Info

Publication number
NO971109L
NO971109L NO971109A NO971109A NO971109L NO 971109 L NO971109 L NO 971109L NO 971109 A NO971109 A NO 971109A NO 971109 A NO971109 A NO 971109A NO 971109 L NO971109 L NO 971109L
Authority
NO
Norway
Prior art keywords
epoxy
silicate
cross
organically modified
layered silicate
Prior art date
Application number
NO971109A
Other languages
English (en)
Other versions
NO971109D0 (no
Inventor
Emmanuel P Giannelis
Phillip B Messersmith
Original Assignee
Cornell Res Foundation Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cornell Res Foundation Inc filed Critical Cornell Res Foundation Inc
Publication of NO971109D0 publication Critical patent/NO971109D0/no
Publication of NO971109L publication Critical patent/NO971109L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40—Compounds of aluminium
    • C09C1/42—Clays
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C01P2006/33—Phase transition temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Epoksy-silikat-nanokompositt fremstilt ved å dispergere en organisk modifisert leire av smektitt-type i en epoksyhar- piks sammen med diglysidyleter av bis- fenol A (DGEBA), herding i nærvær av "nadisk metylanhydrid" (NMA) og/eller benzyldimetylamin (BD^4A), og/eller bor- trifluoridmonoetylamin (BTFA) ved 100-200 °C. Det oppnås molekylær disper- sjon av det lagdelte silikat i den tverrbundne epoksymatriks, med smektitt- lag-åpninger på 100 A eller mer og epok- symatriksen fukter silikatoverflaten godt. Herdereaksjonen omfatter at de funksjonelle grupper av alkylammonium- ionene lokalisert i åpningene i den organisk modifiserte leire deltar i tverrbindingsreaksjonen. Polymernett- verket festes derved direkte til de molekylært dispergerte silikatlag. Nano- kompositten viser en bredere T^ ved svakt høyere temperaturer enn umodifi- serte epoksy. Den dynamiske lagrings- modul for nanokompositten er betydelig høyere i glassområdet og svært mye høyere i gummiplatåområdet enn slik modulus for det umodifiserte epoksy.
NO971109A 1994-09-12 1997-03-11 Fremgangsmåte for fremstilling av lagdelte nanokompositter av silikat-epoxy, og slike kompositter NO971109L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/304,574 US5554670A (en) 1994-09-12 1994-09-12 Method of preparing layered silicate-epoxy nanocomposites
PCT/US1995/010956 WO1996008526A1 (en) 1994-09-12 1995-08-29 Layered silicate-epoxy nanocomposites

Publications (2)

Publication Number Publication Date
NO971109D0 NO971109D0 (no) 1997-03-11
NO971109L true NO971109L (no) 1997-05-07

Family

ID=23177085

Family Applications (1)

Application Number Title Priority Date Filing Date
NO971109A NO971109L (no) 1994-09-12 1997-03-11 Fremgangsmåte for fremstilling av lagdelte nanokompositter av silikat-epoxy, og slike kompositter

Country Status (10)

Country Link
US (1) US5554670A (no)
EP (1) EP0782593A4 (no)
JP (1) JPH10505871A (no)
KR (1) KR970706328A (no)
AU (1) AU3419195A (no)
BR (1) BR9508914A (no)
CA (1) CA2199616A1 (no)
MX (1) MX9701845A (no)
NO (1) NO971109L (no)
WO (1) WO1996008526A1 (no)

Families Citing this family (104)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3402821B2 (ja) * 1995-02-09 2003-05-06 科学技術振興事業団 超微粒子の製造方法と超微粒子配向成長体の製造方法
US6228903B1 (en) 1995-06-07 2001-05-08 Amcol International Corporation Exfoliated layered materials and nanocomposites comprising said exfoliated layered materials having water-insoluble oligomers or polymers adhered thereto
US5760106A (en) * 1995-07-05 1998-06-02 Board Of Trustees Operating Michigan State University Sealant method of epoxy resin-clay composites
DE69629579T2 (de) 1995-11-07 2004-06-24 Southern Clay Products, Inc., Gonzales Organotonzusammensetzungen zum gelieren ungesättigter polyesterharzsysteme
US6287634B1 (en) 1995-12-22 2001-09-11 Amcol International Corporation Intercalates and exfoliates formed with monomeric ethers and esters; composite materials containing same methods of modifying rheology therewith
US6933331B2 (en) 1998-05-22 2005-08-23 Nanoproducts Corporation Nanotechnology for drug delivery, contrast agents and biomedical implants
US5993769A (en) * 1996-11-14 1999-11-30 Board Of Trustees Operating Michigan State University Homostructured mixed organic and inorganic cation exchanged tapered compositions
US5866645A (en) * 1996-11-14 1999-02-02 Board Of Trustees Operating Michigan State University Homostructured mixed organic and inorganic cation exchanged tapered compositions
US6251980B1 (en) 1996-12-06 2001-06-26 Amcol International Corporation Nanocomposites formed by onium ion-intercalated clay and rigid anhydride-cured epoxy resins
US5952095A (en) * 1996-12-06 1999-09-14 Amcol International Corporation Intercalates and exfoliates formed with long chain (C10 +) monomeric organic intercalant compounds; and composite materials containing same
US6071988A (en) * 1996-12-31 2000-06-06 Eastman Chemical Company Polyester composite material and method for its manufacturing
WO1998029491A1 (en) * 1996-12-31 1998-07-09 The Dow Chemical Company Polymer-organoclay-composites and their preparation
US6057035A (en) * 1997-06-06 2000-05-02 Triton Systems, Inc. High-temperature polymer/inorganic nanocomposites
US20090127253A1 (en) * 1997-06-06 2009-05-21 Philip Stark Temperature-controlled induction heating of polymeric materials
US6939477B2 (en) 1997-06-06 2005-09-06 Ashland, Inc. Temperature-controlled induction heating of polymeric materials
US5891611A (en) * 1997-09-29 1999-04-06 Eastman Kodak Company Clay containing antistatic layer for photographic paper
US5981126A (en) * 1997-09-29 1999-11-09 Eastman Kodak Company Clay containing electrically-conductive layer for imaging elements
NL1008003C2 (nl) * 1998-01-09 1999-07-12 Tno Nanocomposiet-materiaal.
US5958311A (en) * 1998-02-09 1999-09-28 Eastman Kodak Company Method of manufacturing a ceramic article
US6017839A (en) * 1998-02-09 2000-01-25 Eastman Kodak Company Ceramic article
US6036765A (en) * 1998-04-01 2000-03-14 Southern Clay Products Organoclay compositions and method of preparation
US6287992B1 (en) 1998-04-20 2001-09-11 The Dow Chemical Company Polymer composite and a method for its preparation
US6232388B1 (en) 1998-08-17 2001-05-15 Amcol International Corporation Intercalates formed by co-intercalation of onium ion spacing/coupling agents and monomer, oligomer or polymer MXD6 nylon intercalants and nanocomposites prepared with the intercalates
AU1837000A (en) 1998-12-07 2000-06-26 Eastman Chemical Company A polymer/clay nanocomposite comprising a clay mixture and process for making same
US6376591B1 (en) 1998-12-07 2002-04-23 Amcol International Corporation High barrier amorphous polyamide-clay intercalates, exfoliates, and nanocomposite and a process for preparing same
US6060230A (en) * 1998-12-18 2000-05-09 Eastman Kodak Company Imaging element comprising an electrically-conductive layer containing metal-containing particles and clay particles and a transparent magnetic recording layer
US6093298A (en) * 1999-02-22 2000-07-25 Ppg Industries Ohio, Inc. Electrocoating compositions containing high aspect ratio clays as crater control agents
US6262162B1 (en) 1999-03-19 2001-07-17 Amcol International Corporation Layered compositions with multi-charged onium ions as exchange cations, and their application to prepare monomer, oligomer, and polymer intercalates and nanocomposites prepared with the layered compositions of the intercalates
US6271298B1 (en) 1999-04-28 2001-08-07 Southern Clay Products, Inc. Process for treating smectite clays to facilitate exfoliation
ES2240095T3 (es) 1999-04-30 2005-10-16 Sud-Chemie Ag Composiciones retardantes de llama.
US6491239B2 (en) 1999-05-06 2002-12-10 Eastman Kodak Company Process for milling compounds
US6309749B1 (en) 1999-05-06 2001-10-30 Eastman Kodak Company Ceramic milling media containing tetragonal zirconia
US6225394B1 (en) 1999-06-01 2001-05-01 Amcol International Corporation Intercalates formed by co-intercalation of onium ion spacing/coupling agents and monomer, oligomer or polymer ethylene vinyl alcohol (EVOH) intercalants and nanocomposites prepared with the intercalates
WO2001004205A1 (en) * 1999-07-13 2001-01-18 Vantico Ag Nanocomposites
US6683122B1 (en) 1999-07-13 2004-01-27 Vantico A&T Us Inc. Filler mixtures
US6787592B1 (en) 1999-10-21 2004-09-07 Southern Clay Products, Inc. Organoclay compositions prepared from ester quats and composites based on the compositions
US6713230B2 (en) * 1999-10-25 2004-03-30 Nan Ya Plastics Corporation Photosensitive ink composition
US7279521B2 (en) * 1999-11-10 2007-10-09 Foster Corporation Nylon nanocomposites
US6833392B1 (en) 1999-11-10 2004-12-21 Lawrence A. Acquarulo, Jr. Optimizing nano-filler performance in polymers
US6407155B1 (en) 2000-03-01 2002-06-18 Amcol International Corporation Intercalates formed via coupling agent-reaction and onium ion-intercalation pre-treatment of layered material for polymer intercalation
US6462122B1 (en) 2000-03-01 2002-10-08 Amcol International Corporation Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants
US6632868B2 (en) 2000-03-01 2003-10-14 Amcol International Corporation Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants
US6261640B1 (en) 2000-03-03 2001-07-17 Board Of Trustees Operating Michigan State University Method for the preparation of homostructured mixed proton and organic layered silicates
US6414069B1 (en) * 2000-03-03 2002-07-02 Board Of Trustees Of Michigan University Hybrid mixed ion clay structures for polymer nanocomposite formation
US6403231B1 (en) 2000-05-12 2002-06-11 Pechiney Emballage Flexible Europe Thermoplastic film structures having improved barrier and mechanical properties
US6841211B1 (en) 2000-05-12 2005-01-11 Pechiney Emballage Flexible Europe Containers having improved barrier and mechanical properties
US6447860B1 (en) 2000-05-12 2002-09-10 Pechiney Emballage Flexible Europe Squeezable containers for flowable products having improved barrier and mechanical properties
CA2410429A1 (en) * 2000-05-30 2001-12-06 University Of South Carolina Research Foundation A polymer nanocomposite comprising a matrix polymer and a layered clay material having an improved level of extractable material
US6737464B1 (en) 2000-05-30 2004-05-18 University Of South Carolina Research Foundation Polymer nanocomposite comprising a matrix polymer and a layered clay material having a low quartz content
US6569214B2 (en) * 2000-06-01 2003-05-27 U.S. Technology Corporation Composite polymer blast media
US6680108B1 (en) 2000-07-17 2004-01-20 Eastman Kodak Company Image layer comprising intercalated clay particles
DE60211129T2 (de) * 2001-03-02 2007-05-03 Southern Clay Products, Inc., Gonzales Herstellung von polymernanoverbundmaterialien durch dispersiondestabilisierung
IL142376A0 (en) * 2001-04-02 2002-03-10 Pachmas Metal Plastic & Fibre Nanocomposites, process for making them and products made from them
US6855426B2 (en) 2001-08-08 2005-02-15 Nanoproducts Corporation Methods for producing composite nanoparticles
JP2005505643A (ja) * 2001-08-16 2005-02-24 ヘンケル コーポレイション 吸湿が低減されたエポキシ成形組成物
US20060079623A1 (en) * 2001-08-17 2006-04-13 Chenggang Chen Method of forming nanocomposite materials
JP2005503865A (ja) * 2001-09-28 2005-02-10 ボストン サイエンティフィック リミテッド ナノ材料からなる医療デバイス及びそれを利用した治療方法
US6762233B2 (en) * 2001-10-09 2004-07-13 The University Of Chicago Liquid crystalline composites containing phyllosilicates
US6887931B2 (en) * 2001-10-23 2005-05-03 Ashland Inc. Thermosetting inorganic clay nanodispersions and their use
US6758148B2 (en) 2001-10-26 2004-07-06 Chep International, Inc. Fire blocking method and apparatus
US7588699B2 (en) 2001-11-02 2009-09-15 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof
KR100450232B1 (ko) * 2002-01-24 2004-09-24 주식회사 엘지화학 유기점토 화합물, 및 이를 포함하는 고분자-점토나노복합체 조성물
AU2003206170A1 (en) * 2002-02-04 2003-09-02 Lg Chem, Ltd. Organic-inorganic nanocomposite and preparation thereof
US6822035B2 (en) * 2002-02-20 2004-11-23 The University Of Chicago Process for the preparation of organoclays
US7135508B2 (en) 2002-02-20 2006-11-14 The University Of Chicago Coatings and films derived from clay/wax nanocomposites
US6790896B2 (en) * 2002-03-18 2004-09-14 The University Of Chicago Composite materials with improved phyllosilicate dispersion
US7160942B2 (en) * 2002-07-12 2007-01-09 Uchicago Argonne, Llc Polymer-phyllosilicate nanocomposites and their preparation
US7163973B2 (en) * 2002-08-08 2007-01-16 Henkel Corporation Composition of bulk filler and epoxy-clay nanocomposite
US8501858B2 (en) * 2002-09-12 2013-08-06 Board Of Trustees Of Michigan State University Expanded graphite and products produced therefrom
US20050048291A1 (en) * 2003-08-14 2005-03-03 General Electric Company Nano-filled composite materials with exceptionally high glass transition temperature
US7708974B2 (en) 2002-12-10 2010-05-04 Ppg Industries Ohio, Inc. Tungsten comprising nanomaterials and related nanotechnology
DK1581588T3 (da) * 2003-01-08 2007-04-02 Sued Chemie Ag Sammensætning på basis af præeksfolierede nanoclays og anvendelse heraf
US6667148B1 (en) * 2003-01-14 2003-12-23 Eastman Kodak Company Thermally developable materials having barrier layer with inorganic filler particles
US20040213846A1 (en) * 2003-04-23 2004-10-28 Greenblatt Gary David Polymer-clay nanocomposite for extended release of active ingredient
WO2004111122A1 (de) 2003-06-12 2004-12-23 Süd-Chemie AG Verfahren zur herstellung von nanocomposit-additiven mit verbesserter delaminierung in polymeren
WO2004113429A2 (en) * 2003-06-23 2004-12-29 The University Of Chicago Polyolefin nanocomposites
US20050119371A1 (en) * 2003-10-15 2005-06-02 Board Of Trustees Of Michigan State University Bio-based epoxy, their nanocomposites and methods for making those
US8722160B2 (en) * 2003-10-31 2014-05-13 Aeris Capital Sustainable Ip Ltd. Inorganic/organic hybrid nanolaminate barrier film
JP4799416B2 (ja) * 2003-11-04 2011-10-26 ハンツマン・アドヴァンスト・マテリアルズ・（スイッツランド）・ゲーエムベーハー ２成分系の硬化可能な組成物
US7148282B2 (en) * 2003-12-19 2006-12-12 Cornell Research Foundations, Inc. Composite of high melting polymer and nanoclay with enhanced properties
KR100540048B1 (ko) * 2004-01-30 2005-12-29 재단법인서울대학교산학협력재단 신규한 나노복합재용 유기화제
KR100519560B1 (ko) * 2004-01-30 2005-10-06 재단법인서울대학교산학협력재단 폴리에스테르/점토 나노복합재 및 그의 제조방법
KR100553758B1 (ko) * 2004-02-02 2006-02-20 삼성에스디아이 주식회사 유기 전계 발광 소자
US8642455B2 (en) * 2004-02-19 2014-02-04 Matthew R. Robinson High-throughput printing of semiconductor precursor layer from nanoflake particles
WO2005111184A2 (en) * 2004-04-30 2005-11-24 Michigan State University Compositions of cellulose esters and layered silicates and process for the preparation thereof
DE102004039451A1 (de) * 2004-08-13 2006-03-02 Süd-Chemie AG Polymerblend aus nicht verträglichen Polymeren
US20090032108A1 (en) * 2007-03-30 2009-02-05 Craig Leidholm Formation of photovoltaic absorber layers on foil substrates
CN101048461A (zh) * 2004-10-27 2007-10-03 纳幕尔杜邦公司 自粘合涂料组合物
US7420071B2 (en) * 2005-05-04 2008-09-02 Uchicago Argonne, Llc Thermally stable surfactants and compositions and methods of use thereof
US7300799B2 (en) * 2005-06-24 2007-11-27 Elementis Specialties, Inc. Method to assess organoclay exfoliation and orientation in organoclay/polymer composites
KR100705793B1 (ko) 2005-09-30 2007-04-10 금호타이어 주식회사 개질된 나노층상 실리케이트를 함유하는 타이어 사이드월고무조성물
KR100705794B1 (ko) 2005-09-30 2007-04-09 금호타이어 주식회사 화학적으로 표면처리된 나노클레이를 포함하는 타이어용고무조성물
ES2332474T3 (es) 2006-02-13 2010-02-05 Council Of Scientific And Industrial Research Composiciones de nanocompuesto polimerico de filosilicato exfoliado y un proceso para la preparacion de las mismas.
US8158450B1 (en) * 2006-05-05 2012-04-17 Nanosolar, Inc. Barrier films and high throughput manufacturing processes for photovoltaic devices
EP2865404B1 (en) * 2007-06-01 2019-09-11 Covidien LP Extension tubes for balloon catheters
US8134684B2 (en) * 2008-02-22 2012-03-13 Sematech, Inc. Immersion lithography using hafnium-based nanoparticles
RU2404213C2 (ru) * 2008-10-29 2010-11-20 Федеральное государственное унитарное предприятие "Научно-исследовательский физико-химический институт имени Л.Я. Карпова" Эпоксидная композиция
ITTV20080160A1 (it) * 2008-12-05 2010-06-06 Nanto Srl Vernici e rivestimenti anticorrosione contenenti nanoclay
US8124230B2 (en) * 2009-08-13 2012-02-28 Intel Corporation Non-aggregating nanoparticles and the use thereof
WO2011032120A2 (en) * 2009-09-14 2011-03-17 Namics Corporation Underfill for high density interconnect flip chips
DE102010033029A1 (de) 2010-08-02 2012-02-02 Siemens Aktiengesellschaft Hochtemperaturstabile Schichtsilikate mit erhöhter Schichtaufweitung
WO2012069640A1 (de) * 2010-11-26 2012-05-31 Siemens Aktiengesellschaft Verfahren zur exfolierung organisch modifizierter schichtsilikate durch hochdruckdispergierung
US20130253119A1 (en) * 2010-12-06 2013-09-26 Korea Institute Of Ceramic Engineering And Technology High strength organic/inorganic composite using plate-shaped inorganic particles and method for preparing same
US9334387B2 (en) * 2013-09-10 2016-05-10 King Fahd University Of Petroleum And Minerals Method for preparation of epoxy-clay nanocomposites

Family Cites Families (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2531427A (en) * 1946-05-03 1950-11-28 Ernst A Hauser Modified gel-forming clay and process of producing same
BE582883A (no) * 1958-10-28
NL295858A (no) * 1962-07-27
US3290165A (en) * 1963-04-01 1966-12-06 Huber Corp J M Surface modified pigments
US3227675A (en) * 1963-05-01 1966-01-04 Huber Corp J M Silane-treated clay reinforced resin compositions
US3537994A (en) * 1967-07-25 1970-11-03 Nat Lead Co Organophilic clay greases
US3567680A (en) * 1968-05-03 1971-03-02 Huber Corp J M Surface modified pigments and methods for producing same and elastomers containing same
US3586468A (en) * 1968-09-16 1971-06-22 A E Gosselin Engineering Inc Burner combustion control including ultrasonic pressure waves
GB1313749A (en) * 1969-10-02 1973-04-18 Canadian Patents Dev Polymeric high performance composites
US3671190A (en) * 1970-11-10 1972-06-20 Laporte Industries Ltd Synthetic clay-like minerals of the smectite type and method of preparation
US3666407A (en) * 1971-01-28 1972-05-30 Pfizer Process for producing synthetic hectorite-type clays
US3855147A (en) * 1972-05-26 1974-12-17 Nl Industries Inc Synthetic smectite compositions, their preparation, and their use as thickeners in aqueous systems
US3852405A (en) * 1972-09-22 1974-12-03 Nl Industries Inc Laminar heavy metal aluminosilicates
US3844978A (en) * 1972-12-01 1974-10-29 Chevron Res Layered clay minerals and processes for using
US3844979A (en) * 1972-12-01 1974-10-29 Chevron Res Layered clay minerals, catalysts, and processes for using
US3974125A (en) * 1974-09-27 1976-08-10 Exxon Research And Engineering Company Higher dialkyl dimethyl ammonium clay gelling agents for unsaturated polyester compositions
IL50548A (en) * 1976-09-23 1979-10-31 Yissum Res Dev Co Process for preparation of molecular sieves
US4081496A (en) * 1977-06-27 1978-03-28 N L Industries, Inc. Thixotropic polyester compositions containing an organophilic clay gellant
US4190686A (en) * 1978-08-04 1980-02-26 Muis Louis H Protective composition and method
US4465542A (en) * 1982-02-19 1984-08-14 Mitsui Petrochemical Industries, Ltd. Adhesive composition
US4480060A (en) * 1983-01-27 1984-10-30 Corning Glass Works Mica-resin composite material
US4455382A (en) * 1983-01-27 1984-06-19 Corning Glass Works Organic-inorganic composites of neutralized polyelectrolyte complexes
US4454237A (en) * 1983-01-27 1984-06-12 Corning Glass Works Organic-inorganic composites containing synthetic mica
US4690868A (en) * 1985-02-08 1987-09-01 E.C.C. America Inc. Process for surface treating clay minerals and resultant products
US4789403A (en) * 1986-07-22 1988-12-06 E.C.C. America Inc. Surface modified layered lattice silicate pigments
US4990405A (en) * 1985-03-25 1991-02-05 Armstrong World Industries, Inc. Multi-ply composites and sheets of epoxy and flocced 2:1 layered silicates
US4667158A (en) * 1985-04-01 1987-05-19 Redlich Robert W Linear position transducer and signal processor
US4739007A (en) * 1985-09-30 1988-04-19 Kabushiki Kaisha Toyota Chou Kenkyusho Composite material and process for manufacturing same
DE3806548C2 (de) * 1987-03-04 1996-10-02 Toyoda Chuo Kenkyusho Kk Verbundmaterial und Verfahren zu dessen Herstellung
JPH0778089B2 (ja) * 1987-03-26 1995-08-23 株式会社豊田中央研究所 複合材料の製造方法
CA1338252C (en) * 1989-07-05 1996-04-16 Osamu Ogitani Resist ink composition
US5151155A (en) * 1991-05-09 1992-09-29 Rheox, Inc. Process for deinking wastepaper with organically modified smectite clay

Also Published As

Publication number Publication date
BR9508914A (pt) 1998-11-03
AU3419195A (en) 1996-03-29
US5554670A (en) 1996-09-10
CA2199616A1 (en) 1996-03-21
JPH10505871A (ja) 1998-06-09
MX9701845A (es) 1998-02-28
EP0782593A1 (en) 1997-07-09
WO1996008526A1 (en) 1996-03-21
KR970706328A (ko) 1997-11-03
EP0782593A4 (en) 1999-05-12
NO971109D0 (no) 1997-03-11

Similar Documents

Publication Publication Date Title
NO971109L (no) Fremgangsmåte for fremstilling av lagdelte nanokompositter av silikat-epoxy, og slike kompositter
Karnati et al. Applications of silica nanoparticles in glass/carbon fiber-reinforced epoxy nanocomposite
US6251980B1 (en) Nanocomposites formed by onium ion-intercalated clay and rigid anhydride-cured epoxy resins
Chow Water absorption of epoxy/glass fiber/organo-montmorillonite nanocomposites
Hsiue et al. Flame‐retardant epoxy resins: An approach from organic–inorganic hybrid nanocomposites
CA1254321A (en) Epoxy composition containing dispersed elastomeric particles
Zhou et al. Nanoclay and long‐fiber‐reinforced composites based on epoxy and phenolic resins
Pol et al. Studies on the mechanical properties of composites reinforced with nanoparticles
CN101368065A (zh) 耐高温消融与透波涂料及其制备方法
CN104004482A (zh) 一种环氧/有机硅/石墨烯杂化高导热胶粘剂及其制备方法
Dorigato et al. Development and thermo‐mechanical behavior of nanocomposite epoxy adhesives
JP3653906B2 (ja) エポキシ樹脂組成物、プリプレグ及び繊維強化複合材料
Norkhairunnisa et al. Effects of organo‐montmorillonite on the mechanical and morphological properties of epoxy/glass fiber composites
Brown et al. Epoxy resin based nanocomposites: 1. Diglycidylether of bisphenol A (DGEBA) with triethylenetetramine (TETA)
Li et al. Synergistic reinforcement of epoxy/basalt fiber composites with dimensionally different nanoparticles
CN114031896A (zh) 一种碳纤维缠绕用环氧树脂组合物及其制备方法
JPH0518323B2 (no)
CN1709664A (zh) 利用等离子体改善农作物秸秆与脲醛树脂界面胶合性能的方法
CN101457011A (zh) 一种复合纳米粒子改性环氧树脂的制备
KR100601756B1 (ko) 유리섬유 강화 폴리아미드 수지조성물
JPH0286616A (ja) 低粘度のエポキシ樹脂組成物
KR930006103A (ko) 에폭시 수지 조성물
JPH02169658A (ja) エポキシ樹脂組成物
JPH01259066A (ja) 熱硬化性樹脂組成物
Hou et al. Morphology and thermal/mechanical properties of alkyl‐imidazolium‐treated rectorite/epoxy nanocomposites