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NO20053127L - Fremgangsmate for a fjerne svovelforbindelser, inklusive hydrogensulfid og merkaptaner, fra gasstrommer. - Google Patents

Fremgangsmate for a fjerne svovelforbindelser, inklusive hydrogensulfid og merkaptaner, fra gasstrommer.

Info

Publication number
NO20053127L
NO20053127L NO20053127A NO20053127A NO20053127L NO 20053127 L NO20053127 L NO 20053127L NO 20053127 A NO20053127 A NO 20053127A NO 20053127 A NO20053127 A NO 20053127A NO 20053127 L NO20053127 L NO 20053127L
Authority
NO
Norway
Prior art keywords
mercaptans
hydrogen sulfide
sulfur compounds
carbon dioxide
weight
Prior art date
Application number
NO20053127A
Other languages
English (en)
Inventor
Jolinde Machteld Van De Graaf
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of NO20053127L publication Critical patent/NO20053127L/no

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30Physical properties of adsorbents
    • B01D2253/302Dimensions
    • B01D2253/308Pore size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/304Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Fremgangsmåte for å fjeme hydrogensulfid, merkaptaner og eventuelt karbondioksid og karbonylsulfid fra en gasstrøm omfattende hydrogensulfid, merkaptaner og eventuelt karbondioksid og karbonylsulfid. I et første trinn fjernes mesteparten av hydrogensulfidet, en del av merkaptanene og eventuelt en del av eller mesteparten av karbondioksidet og karbonylsulfidet ved vasking av gasstrømmen med en vandig vaskeoppløsning omfattende 10-45 vekt% vann, beregnet på den totale oppløsning, 10-40 vekt% av et fysikalsk oppløsningsmiddel, beregnet på den totale oppløsning, og 20-60 vekt% av et amin, beregnet på den totale oppløsning. Det første fjernetrinn etterfølges av et andre fjernetrinn i hvilket merkaptaner fjernes ved hjelp av molekylsiler. Ved fremgangsmåte utgjør mengden av merkaptaner som fjemes med den vandige vaskestrøm, mellom 60 og 96 % (av de fjernede merkaptaner i det første og annet trinn), mens mengden som fjernes ved hjelp av molekylsilene, utgjør mellom 40 og 4 % (av den totale mengde fjernede merkaptaner i det første og annet trinn).
NO20053127A 2002-11-28 2005-06-27 Fremgangsmate for a fjerne svovelforbindelser, inklusive hydrogensulfid og merkaptaner, fra gasstrommer. NO20053127L (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02258200 2002-11-28
PCT/EP2003/050908 WO2004047955A1 (en) 2002-11-28 2003-11-28 Process for removing sulphur compounds including hydrogen sulphide and mercaptans from gas streams

Publications (1)

Publication Number Publication Date
NO20053127L true NO20053127L (no) 2005-06-27

Family

ID=32338172

Family Applications (1)

Application Number Title Priority Date Filing Date
NO20053127A NO20053127L (no) 2002-11-28 2005-06-27 Fremgangsmate for a fjerne svovelforbindelser, inklusive hydrogensulfid og merkaptaner, fra gasstrommer.

Country Status (8)

Country Link
US (1) US7425314B2 (no)
EP (1) EP1565248A1 (no)
CN (1) CN1717274A (no)
AU (1) AU2003298333B2 (no)
CA (1) CA2507355C (no)
EA (1) EA009588B1 (no)
NO (1) NO20053127L (no)
WO (1) WO2004047955A1 (no)

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CN109513312A (zh) * 2017-09-18 2019-03-26 中国石化扬子石油化工有限公司 一种利用无水脱硫溶剂脱除混合气中硫化氢的方法
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Also Published As

Publication number Publication date
EP1565248A1 (en) 2005-08-24
CA2507355C (en) 2012-02-21
AU2003298333B2 (en) 2008-05-01
CN1717274A (zh) 2006-01-04
CA2507355A1 (en) 2004-06-10
EA009588B1 (ru) 2008-02-28
US7425314B2 (en) 2008-09-16
EA200500880A1 (ru) 2005-12-29
WO2004047955A1 (en) 2004-06-10
AU2003298333A1 (en) 2004-06-18
US20060110305A1 (en) 2006-05-25

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