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NO159492C - POLYMER DISPERSIONS WHICH ARE INPOLYMERIZED FINISHED, NITROGEN CONTAINING MONOMERS AND APPLICATION OF THE DISPERSIONS AS PAPER FOR PAPER. - Google Patents

POLYMER DISPERSIONS WHICH ARE INPOLYMERIZED FINISHED, NITROGEN CONTAINING MONOMERS AND APPLICATION OF THE DISPERSIONS AS PAPER FOR PAPER.

Info

Publication number
NO159492C
NO159492C NO813566A NO813566A NO159492C NO 159492 C NO159492 C NO 159492C NO 813566 A NO813566 A NO 813566A NO 813566 A NO813566 A NO 813566A NO 159492 C NO159492 C NO 159492C
Authority
NO
Norway
Prior art keywords
weight
solution
ethylenically unsaturated
monomer
water
Prior art date
Application number
NO813566A
Other languages
Norwegian (no)
Other versions
NO813566L (en
NO159492B (en
Inventor
Fritz Reichel
Konrad Richter
Lothar Hoehr
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of NO813566L publication Critical patent/NO813566L/en
Publication of NO159492B publication Critical patent/NO159492B/en
Publication of NO159492C publication Critical patent/NO159492C/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1. A finely divided polymer dispersion which contains polymerized units of nitrogen-containing monomers, and is obtained by a two-stage polymerization reaction, wherein, in the first polymerization stage, a low molecular weight prepolymer, which has a viscosity of from 1.06 to 1.40 (measured in an Ubbelohde viscometer) in a 1% strength solution of a mixture of 99 parts by weight of dimethyl formamide and 1 part by weight of glacial acetic acid at 20 degrees C, is prepared in a water-miscible solvent, which may contain up to 15% by weight of water, in the manner of a solution copolymerization from a monomer mixture which contains (a) per mole of a nitrogen-containing monomer of the formula see diagramm : EP0051144,P13,F1 or see diagramm : EP0051144,P13,F3 where A is O or NH, B is Cn H2n , n being from 1 to 8, R**1 and R**2 are each Cm H2m+1 , m being from 1 to 4, R**3 is H or CH3 , X4 **- is OH**- , Cl**- , Br**- or CH3 -OSO3 H**- , and R**4 is Cm H2m+1 , m being from 1 to 4, (b) 2.5 to 10 moles of at least one nonionic, hydrophobic, ethylenically unsaturated monomer which, if it is polymerized on its own, forms a hydrophobic polymer, (c) 0.5 to 1.5 moles of an ethylenically unsaturated carboxylic acid or maleic anhydride, and (d) 0 to 7 moles of a nonionic, hydrophilic, ethylenically unsaturated monomer, the solution of the prepolymer is diluted with water in a weight ratio of from 1:3 to 1:50 and, in the second polymerization stage, 1 to 32 parts by weight of at least one nonionic, hydrophobic, ethylenically unsaturated monomer, which is the same as monomer (b) of the prepolymer, are polymerized per part by weight of the solution polymer in this polymer solution in the manner of an emulsion polymerization in the presence of a usual amount of a water-soluble polymerization initiator.
NO813566A 1980-10-23 1981-10-22 POLYMER DISPERSIONS WHICH ARE INPOLYMERIZED FINISHED, NITROGEN CONTAINING MONOMERS AND APPLICATION OF THE DISPERSIONS AS PAPER FOR PAPER. NO159492C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19803039976 DE3039976A1 (en) 1980-10-23 1980-10-23 FINE-PIECE, NITROGEN-CONTAINING MONOMERS, POLYMER DISPERSION CONTAINING POLYMERIZED

Publications (3)

Publication Number Publication Date
NO813566L NO813566L (en) 1982-04-26
NO159492B NO159492B (en) 1988-09-26
NO159492C true NO159492C (en) 1989-01-04

Family

ID=6115005

Family Applications (1)

Application Number Title Priority Date Filing Date
NO813566A NO159492C (en) 1980-10-23 1981-10-22 POLYMER DISPERSIONS WHICH ARE INPOLYMERIZED FINISHED, NITROGEN CONTAINING MONOMERS AND APPLICATION OF THE DISPERSIONS AS PAPER FOR PAPER.

Country Status (5)

Country Link
EP (1) EP0051144B1 (en)
AT (1) ATE6867T1 (en)
DE (2) DE3039976A1 (en)
FI (1) FI69477C (en)
NO (1) NO159492C (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4772518A (en) * 1986-10-21 1988-09-20 Ppg Industries, Inc. Water reducible acrylic polymer for printing of paper and polyvinyl chloride
DE4229142A1 (en) * 1992-09-01 1994-03-03 Basf Ag Paper sizing mixtures
DE19949382A1 (en) 1999-10-13 2001-04-19 Basf Ag Use of finely divided, dye-containing polymers PF as a coloring component in cosmetic products
ATE292643T1 (en) * 2000-08-16 2005-04-15 Bayer Chemicals Ag CATIONIC POLYMER DISPERSIONS FOR PAPER SIZING
DE102004027735A1 (en) * 2004-06-07 2005-12-22 Basf Ag Finely divided, amphoteric, aqueous polymer dispersions, process for their preparation and their use
JP2010513734A (en) * 2006-12-20 2010-04-30 ビーエーエスエフ ソシエタス・ヨーロピア Paper sizing mixture
US8901227B2 (en) 2009-06-04 2014-12-02 Basf Se Fine-particle, cationic, aqueous polymer dispersions, method for the production thereof, and use thereof
JP6805251B2 (en) * 2015-12-01 2020-12-23 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ Fine cationic aqueous polymer dispersion, its production method, and its use
WO2018001885A1 (en) * 2016-06-30 2018-01-04 Basf Se Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and use thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3706722A (en) * 1967-05-29 1972-12-19 Dow Chemical Co Polymers from essentially water-insoluble unsaturated liquid monomers and process for preparing same
DE2452585B2 (en) * 1974-11-06 1981-07-30 Basf Ag, 6700 Ludwigshafen Process for the preparation of shear-stable aqueous copolymer dispersions

Also Published As

Publication number Publication date
FI812751L (en) 1982-04-24
DE3162897D1 (en) 1984-05-03
EP0051144B1 (en) 1984-03-28
FI69477C (en) 1986-02-10
EP0051144A1 (en) 1982-05-12
FI69477B (en) 1985-10-31
ATE6867T1 (en) 1984-04-15
NO813566L (en) 1982-04-26
NO159492B (en) 1988-09-26
DE3039976A1 (en) 1982-06-03

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