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NL1010269C2 - Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat. - Google Patents

Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat. Download PDF

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Publication number
NL1010269C2
NL1010269C2 NL1010269A NL1010269A NL1010269C2 NL 1010269 C2 NL1010269 C2 NL 1010269C2 NL 1010269 A NL1010269 A NL 1010269A NL 1010269 A NL1010269 A NL 1010269A NL 1010269 C2 NL1010269 C2 NL 1010269C2
Authority
NL
Netherlands
Prior art keywords
layer
titanium oxide
support plate
stainless steel
fuel cell
Prior art date
Application number
NL1010269A
Other languages
English (en)
Dutch (nl)
Inventor
Edward Bullock
Robert Christiaan Makkus
Arnoldus Hermanus Hend Janssen
Yves Denos
Michel Cassir
Original Assignee
Stichting Energie
Gemeenschappelijk Ct Voor Onde
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL1010269A priority Critical patent/NL1010269C2/nl
Application filed by Stichting Energie, Gemeenschappelijk Ct Voor Onde filed Critical Stichting Energie
Priority to JP2000575179A priority patent/JP2002527612A/ja
Priority to PCT/NL1999/000624 priority patent/WO2000021152A1/fr
Priority to EP99949465A priority patent/EP1119881B1/fr
Priority to ES99949465T priority patent/ES2211180T3/es
Priority to AT99949465T priority patent/ATE249102T1/de
Priority to DK99949465T priority patent/DK1119881T3/da
Priority to DE69911043T priority patent/DE69911043T2/de
Priority to US09/807,025 priority patent/US6761927B1/en
Priority to CA002346486A priority patent/CA2346486A1/fr
Application granted granted Critical
Publication of NL1010269C2 publication Critical patent/NL1010269C2/nl

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0206Metals or alloys
    • H01M8/0208Alloys
    • H01M8/021Alloys based on iron
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/321Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer
    • C23C28/3215Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal alloy layer at least one MCrAlX layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0215Glass; Ceramic materials
    • H01M8/0217Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0223Composites
    • H01M8/0228Composites in the form of layered or coated products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023Porous and characterised by the material
    • H01M8/0232Metals or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M2008/147Fuel cells with molten carbonates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0048Molten electrolytes used at high temperature
    • H01M2300/0051Carbonates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Sustainable Development (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Fuel Cell (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Inert Electrodes (AREA)
NL1010269A 1998-10-08 1998-10-08 Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat. NL1010269C2 (nl)

Priority Applications (10)

Application Number Priority Date Filing Date Title
NL1010269A NL1010269C2 (nl) 1998-10-08 1998-10-08 Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat.
PCT/NL1999/000624 WO2000021152A1 (fr) 1998-10-08 1999-10-08 Procede de revetement d'une plaque d'appui et pile a combustible munie d'une telle plaque
EP99949465A EP1119881B1 (fr) 1998-10-08 1999-10-08 Procede de revetement d'une plaque d'appui et pile a combustible munie d'une telle plaque
ES99949465T ES2211180T3 (es) 1998-10-08 1999-10-08 Procedimiento para revestir una placa de soporte y celula de combustible provista de dicha placa de soporte.
JP2000575179A JP2002527612A (ja) 1998-10-08 1999-10-08 支持板の被覆方法およびそのような支持板を備える燃料電池
AT99949465T ATE249102T1 (de) 1998-10-08 1999-10-08 Verfahren zum beschichten einer trägerplatte und diese trägerplatte enthaltende brennstoffzelle
DK99949465T DK1119881T3 (da) 1998-10-08 1999-10-08 Fremgangsmåde til at overtrække en understøtningsplade og brændselscelle forsynet med en sådan understøtningsplade
DE69911043T DE69911043T2 (de) 1998-10-08 1999-10-08 Verfahren zum beschichten einer trägerplatte und diese trägerplatte enthaltende brennstoffzelle
US09/807,025 US6761927B1 (en) 1998-10-08 1999-10-08 Method for coating a support plate and fuel cell provided with such a support plate
CA002346486A CA2346486A1 (fr) 1998-10-08 1999-10-08 Procede de revetement d'une plaque d'appui et pile a combustible munie d'une telle plaque

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1010269A NL1010269C2 (nl) 1998-10-08 1998-10-08 Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat.
NL1010269 1998-10-08

Publications (1)

Publication Number Publication Date
NL1010269C2 true NL1010269C2 (nl) 2000-04-11

Family

ID=19767936

Family Applications (1)

Application Number Title Priority Date Filing Date
NL1010269A NL1010269C2 (nl) 1998-10-08 1998-10-08 Werkwijze voor het bekleden van een dragerplaat en MCFC-cel voorzien van een dergelijke dragerplaat.

Country Status (10)

Country Link
US (1) US6761927B1 (fr)
EP (1) EP1119881B1 (fr)
JP (1) JP2002527612A (fr)
AT (1) ATE249102T1 (fr)
CA (1) CA2346486A1 (fr)
DE (1) DE69911043T2 (fr)
DK (1) DK1119881T3 (fr)
ES (1) ES2211180T3 (fr)
NL (1) NL1010269C2 (fr)
WO (1) WO2000021152A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2298120A1 (fr) * 1999-02-09 2000-08-09 Kazuo Saito Separateur pour pile a combustible et pile a combustible a polymere solide realisee avec ce separateur
US6649031B1 (en) * 1999-10-08 2003-11-18 Hybrid Power Generation Systems, Llc Corrosion resistant coated fuel cell bipolar plate with filled-in fine scale porosities and method of making the same
US7144648B2 (en) 2002-11-22 2006-12-05 The Research Foundation Of State University Of New York Bipolar plate
US20050003261A1 (en) * 2003-07-04 2005-01-06 Ayumi Horiuchi Porous fuel cell separator, method of manufacture thereof, and solid polymer fuel cell
CA2596409C (fr) * 2005-02-01 2013-04-23 Neomax Materials Co., Ltd. Separateur pour pile a combustible et procede de fabrication idoine
US20070003813A1 (en) * 2005-06-30 2007-01-04 General Motors Corporation Stable conductive and hydrophilic fuel cell contact element
US8377607B2 (en) * 2005-06-30 2013-02-19 GM Global Technology Operations LLC Fuel cell contact element including a TiO2 layer and a conductive layer
US20070287057A1 (en) * 2006-06-09 2007-12-13 Elhamid Mahmoud H Abd Method for making a hydrophilic corrosion resistant coating on low grade stainless steel/alloys for bipolar plates
US8603703B2 (en) * 2006-07-26 2013-12-10 GM Global Technology Operations LLC Method for making super-hydrophilic and electrically conducting surfaces for fuel cell bipolar plates
US20080044716A1 (en) * 2006-08-16 2008-02-21 Gm Global Technology Operations, Inc. Durable layer structure and method for making same
JP5312855B2 (ja) * 2008-06-20 2013-10-09 東邦瓦斯株式会社 インターコネクタおよびその製造方法
GB201910455D0 (en) * 2019-07-22 2019-09-04 Teer Coatings Ltd Coating for the surface of an article and process for forming the coating

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2619417A1 (de) * 1976-05-03 1977-11-24 Walter H R Ott Verfahren zur herstellung von festhaftenden auftragungen im thermischen spritzverfahren mit dem spritzzusatzwerkstoff titan ausgefuehrt
JPH0192350A (ja) * 1987-10-01 1989-04-11 Osaka Gas Co Ltd 伝熱面の処理方法
JPH05339748A (ja) * 1992-06-10 1993-12-21 Mitsubishi Heavy Ind Ltd 複合皮膜の製造方法
EP0686706A1 (fr) * 1993-12-28 1995-12-13 Citizen Watch Co. Ltd. Piece decorative blanche et procede pour sa fabrication
DE19523637A1 (de) * 1994-12-27 1996-07-04 Mtu Friedrichshafen Gmbh Korrosionsschutzbeschichtung für Anwendungen in aufkohlender (reduzierender) Atmosphäre bei hohen Temperaturen und Verfahren zur Herstellung einer solchen, sowie mit einer Korrosionsschutzbeschichtung versehenes Anodenblech für eine Schmelzkarbonatbrennstoffzelle
WO1996035825A1 (fr) * 1995-05-08 1996-11-14 Helmut Tannenberger Piece pour utilisation a temperatures elevees et son procede de production

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Publication number Priority date Publication date Assignee Title
US4226897A (en) * 1977-12-05 1980-10-07 Plasma Physics Corporation Method of forming semiconducting materials and barriers
US5805973A (en) * 1991-03-25 1998-09-08 General Electric Company Coated articles and method for the prevention of fuel thermal degradation deposits
US5287730A (en) * 1992-06-18 1994-02-22 Securus, Inc. Plumbing leakage test apparatus and method of use
DE19628823C2 (de) * 1996-07-17 1998-08-20 Mtu Friedrichshafen Gmbh Stromführendes Bauteil für eine Schmelzkarbonatbrennstoffzelle mit Korrosionsschutzbeschichtung
US6335105B1 (en) * 1999-06-21 2002-01-01 General Electric Company Ceramic superalloy articles

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2619417A1 (de) * 1976-05-03 1977-11-24 Walter H R Ott Verfahren zur herstellung von festhaftenden auftragungen im thermischen spritzverfahren mit dem spritzzusatzwerkstoff titan ausgefuehrt
JPH0192350A (ja) * 1987-10-01 1989-04-11 Osaka Gas Co Ltd 伝熱面の処理方法
JPH05339748A (ja) * 1992-06-10 1993-12-21 Mitsubishi Heavy Ind Ltd 複合皮膜の製造方法
EP0686706A1 (fr) * 1993-12-28 1995-12-13 Citizen Watch Co. Ltd. Piece decorative blanche et procede pour sa fabrication
DE19523637A1 (de) * 1994-12-27 1996-07-04 Mtu Friedrichshafen Gmbh Korrosionsschutzbeschichtung für Anwendungen in aufkohlender (reduzierender) Atmosphäre bei hohen Temperaturen und Verfahren zur Herstellung einer solchen, sowie mit einer Korrosionsschutzbeschichtung versehenes Anodenblech für eine Schmelzkarbonatbrennstoffzelle
WO1996035825A1 (fr) * 1995-05-08 1996-11-14 Helmut Tannenberger Piece pour utilisation a temperatures elevees et son procede de production

Non-Patent Citations (2)

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Title
DATABASE WPI Section Ch Week 9404, Derwent World Patents Index; Class F09, AN 94-032177, XP002105853 *
PATENT ABSTRACTS OF JAPAN vol. 013, no. 302 (C - 616) 12 July 1989 (1989-07-12) *

Also Published As

Publication number Publication date
DK1119881T3 (da) 2003-12-08
JP2002527612A (ja) 2002-08-27
EP1119881A1 (fr) 2001-08-01
CA2346486A1 (fr) 2000-04-13
WO2000021152A1 (fr) 2000-04-13
ES2211180T3 (es) 2004-07-01
DE69911043T2 (de) 2004-06-03
US6761927B1 (en) 2004-07-13
EP1119881B1 (fr) 2003-09-03
ATE249102T1 (de) 2003-09-15
DE69911043D1 (de) 2003-10-09

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