MXPA03004187A - Produccion de acido 6-aminocaproico. - Google Patents
Produccion de acido 6-aminocaproico.Info
- Publication number
- MXPA03004187A MXPA03004187A MXPA03004187A MXPA03004187A MXPA03004187A MX PA03004187 A MXPA03004187 A MX PA03004187A MX PA03004187 A MXPA03004187 A MX PA03004187A MX PA03004187 A MXPA03004187 A MX PA03004187A MX PA03004187 A MXPA03004187 A MX PA03004187A
- Authority
- MX
- Mexico
- Prior art keywords
- aminocaproic acid
- acid
- produce
- production
- aminocaproic
- Prior art date
Links
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 title abstract 5
- 229960002684 aminocaproic acid Drugs 0.000 title abstract 5
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- UVKXJAUUKPDDNW-NSCUHMNNSA-N (e)-pent-3-enenitrile Chemical compound C\C=C\CC#N UVKXJAUUKPDDNW-NSCUHMNNSA-N 0.000 abstract 1
- MVIPFBVXMASPHV-UHFFFAOYSA-N 3-(azaniumylmethyl)pentanoate Chemical compound CCC(CN)CC(O)=O MVIPFBVXMASPHV-UHFFFAOYSA-N 0.000 abstract 1
- XRUKRHLZDVJJSX-UHFFFAOYSA-N 4-cyanopentanoic acid Chemical compound N#CC(C)CCC(O)=O XRUKRHLZDVJJSX-UHFFFAOYSA-N 0.000 abstract 1
- PSNUVGIVZCOHME-UHFFFAOYSA-N 5-amino-4-methylpentanoic acid Chemical compound NCC(C)CCC(O)=O PSNUVGIVZCOHME-UHFFFAOYSA-N 0.000 abstract 1
- SKUPALMUTWEAPI-UHFFFAOYSA-N 5-cyanopentanoic acid Chemical compound OC(=O)CCCCC#N SKUPALMUTWEAPI-UHFFFAOYSA-N 0.000 abstract 1
- ROLXEZSIIQQWRL-UHFFFAOYSA-N 6-oxohexanenitrile Chemical compound O=CCCCCC#N ROLXEZSIIQQWRL-UHFFFAOYSA-N 0.000 abstract 1
- CFEYBLWMNFZOPB-UHFFFAOYSA-N Allylacetonitrile Natural products C=CCCC#N CFEYBLWMNFZOPB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/12—Formation of amino and carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/04—Formation of amino groups in compounds containing carboxyl groups
- C07C227/06—Formation of amino groups in compounds containing carboxyl groups by addition or substitution reactions, without increasing the number of carbon atoms in the carbon skeleton of the acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyamides (AREA)
Abstract
La presente invencion se refiere a un proceso para elaborar acido 6-aminocaproico mediante hidroformilacion de 3-pentenonitrilo para producir, 3-, 4-, y 5- formilvaleronitrilo (mezcla de FVN), oxidar la mezcla de FVN para producir acido 3-, 4-, y 5-cianovalerico; hidrogenar el producto resultante para producir acido 6-aminocaproico, acido 5-amino-4-metilvalerico y acido 4-amino-3-etilbutirico; y aislar el acido 6-aminocaproico a partir del producto de reaccion. El acido 6-aminocaproico resultante puede ser ciclizado para producir caprolactama.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/713,143 US6372939B1 (en) | 2000-11-16 | 2000-11-16 | Production of 6-aminocaproic acid |
| PCT/US2001/048001 WO2002040440A1 (en) | 2000-11-16 | 2001-10-31 | Production of 6-aminocaproic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA03004187A true MXPA03004187A (es) | 2004-04-20 |
Family
ID=24864918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA03004187A MXPA03004187A (es) | 2000-11-16 | 2001-10-31 | Produccion de acido 6-aminocaproico. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6372939B1 (es) |
| EP (1) | EP1335897A1 (es) |
| JP (1) | JP2004513933A (es) |
| KR (1) | KR20040016821A (es) |
| CN (1) | CN1244545C (es) |
| AU (1) | AU2002235189A1 (es) |
| BR (1) | BR0115957A (es) |
| CA (1) | CA2423319A1 (es) |
| MX (1) | MXPA03004187A (es) |
| TW (1) | TW576828B (es) |
| WO (1) | WO2002040440A1 (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6750362B2 (en) * | 2002-03-12 | 2004-06-15 | E. I. Du Pont De Nemours And Company | Process for making 5-formylvaleronitrile using reactivated catalyst |
| WO2005026106A1 (en) * | 2003-09-11 | 2005-03-24 | Invista Technologies S.A R.L. | Process of hydrocyanation of unsaturated carboxylic acid derivatives |
| US8119829B2 (en) | 2004-09-08 | 2012-02-21 | Invista North America S.A.R.L. | Process of hydrocyanation of unsaturated carboxylic acid derivatives |
| EP2252698B1 (en) | 2008-03-11 | 2017-11-22 | Genomatica, Inc. | Adipate ester or thioester synthesis |
| PH12013502115A1 (en) | 2011-04-13 | 2014-01-06 | Rennovia Inc | Production of caprolactam from carbohydrate-containing materials |
| CN103732569B (zh) | 2011-06-17 | 2016-06-29 | 英威达技术有限责任公司 | 使用水解酶来增加废物流中的单体含量 |
| US8852899B2 (en) * | 2011-06-17 | 2014-10-07 | Invista North America S.A.R.L. | Methods of making nylon intermediates from glycerol |
| JP2014525741A (ja) | 2011-06-30 | 2014-10-02 | インビスタ テクノロジーズ エス.アー.エール.エル. | ナイロン−7、ナイロン−7,7、およびポリエステルを生産するための生物変換方法 |
| US9102960B2 (en) | 2011-12-16 | 2015-08-11 | Invista North America S.á.r.l. | Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage |
| US9102958B2 (en) | 2011-12-16 | 2015-08-11 | Invista North America S.á.r.l. | Methods of producing 6-carbon chemicals via CoA-dependent carbon chain elongation associated with carbon storage |
| IN2014DN07028A (es) | 2012-02-23 | 2015-04-10 | Rennovia Inc | |
| JP2015515512A (ja) * | 2012-03-13 | 2015-05-28 | インヴィスタ テクノロジーズ エスアエルエル | ナイロンポリマーおよびその製造方法 |
| EP2931907A2 (en) | 2012-12-14 | 2015-10-21 | Invista Technologies S.A R.L. | METHODS OF PRODUCING 7-CARBON CHEMICALS VIA CoA-DEPENDENT CARBON CHAIN ELONGATION ASSOCIATED WITH CARBON STORAGE |
| CN105189764A (zh) | 2012-12-31 | 2015-12-23 | 英威达技术有限责任公司 | 通过与辅酶b合成相关的c1碳链延伸生产7-碳化学物的方法 |
| US9738911B2 (en) | 2012-12-31 | 2017-08-22 | Invista North America S.A.R.L. | Methods of producing 7-carbon chemicals via pyruvate and succinate semialdehyde aldol condensation |
| EP2938730A2 (en) | 2012-12-31 | 2015-11-04 | Invista Technologies S.A R.L. | Methods of producing 6-carbon chemicals via methyl-ester shielded carbon chain elongation |
| EP2938733A2 (en) | 2012-12-31 | 2015-11-04 | Invista North America S.a.r.l. | Methods of producing 7-carbon chemicals via methyl-ester shielded carbon chain elongation |
| WO2014105788A2 (en) | 2012-12-31 | 2014-07-03 | Invista North America S.A.R.L. | Methods of producing 7-carbon chemicals via carbon chain elongation associated with cyclohexane carboxylate synthesis |
| CN105026570A (zh) | 2012-12-31 | 2015-11-04 | 英威达技术有限责任公司 | 通过氧化裂解从长链脂肪酸生产7-碳化学物的方法 |
| EP2938734A2 (en) | 2012-12-31 | 2015-11-04 | Invista Technologies S.A R.L. | Methods of producing 7-carbon chemicals via aromatic compounds |
| US9358526B2 (en) | 2013-11-19 | 2016-06-07 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| US9180436B1 (en) | 2013-11-19 | 2015-11-10 | Emerging Fuels Technology, Inc. | Optimized fischer-tropsch catalyst |
| EP3143152A1 (en) | 2014-05-15 | 2017-03-22 | Invista Technologies S.à r.l. | Methods of producing 6-carbon chemicals using 2,6-diaminopimelate as precursor to 2-aminopimelate |
| EP3155107A1 (en) | 2014-06-16 | 2017-04-19 | Invista Technologies S.à.r.l. | Methods, reagents and cells for biosynthesizing compounds |
| BR112016029471A2 (pt) | 2014-06-16 | 2017-10-24 | Invista Tech Sarl | método para biosintetizar éster de metil glutarato em um hospedeiro recombinante, método para preparar glutarato, célula hospedeira recombinante, hospedeiro recombinante, produto bioderivado, produto de base biológica ou produto derivado de fermentação e método para aumentar a atividade de um polipeptídeo tendo atividade carboxilato reductase sobre um ácido dicarboxílico c4-c8 substituído ou não-substituído |
| US9816117B2 (en) | 2014-06-16 | 2017-11-14 | Invista North America S.A.R.L. | Methods, reagents and cells for biosynthesizing compounds |
| EP3155106A2 (en) | 2014-06-16 | 2017-04-19 | Invista Technologies S.à.r.l. | Methods, reagents and cells for biosynthesizing compound |
| JP6997175B2 (ja) * | 2016-09-08 | 2022-02-03 | ビーエーエスエフ ソシエタス・ヨーロピア | ZrO2上に担持されたルテニウム触媒の存在下でのニトリル水素化のための方法 |
| CN108546234A (zh) * | 2018-05-15 | 2018-09-18 | 常州兰陵制药有限公司 | 6-氨基己酸的制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1628190A (en) | 1926-05-14 | 1927-05-10 | Raney Murray | Method of producing finely-divided nickel |
| US2870201A (en) * | 1955-04-04 | 1959-01-20 | Maxwell A Pollack | Synthesis of amino acids |
| US2839547A (en) * | 1955-07-30 | 1958-06-17 | Inventa Ag | Process for the production of aminocarboxylic acids |
| US2828337A (en) * | 1956-01-17 | 1958-03-25 | Gulf Research Development Co | Method of oxidizing aldehydes |
| US3496215A (en) | 1965-11-23 | 1970-02-17 | Du Pont | Hydrocyanation of olefins using selected nickel phosphite catalysts |
| US4470928A (en) * | 1981-10-15 | 1984-09-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing cyanovaleric esters and caprolactam |
| DE3602377A1 (de) | 1986-01-28 | 1987-07-30 | Basf Ag | Verfahren zur herstellung von caprolactam |
| DE3643011A1 (de) * | 1986-12-17 | 1988-06-30 | Basf Ag | Verfahren zur herstellung von caprolactam aus 6-aminocapronsaeure, deren estern und amiden |
| DE4421704A1 (de) | 1994-06-21 | 1996-01-04 | Bayer Ag | Verfahren zur Herstellung von hochmolekularem Polyamid 6 |
| US5821378A (en) | 1995-01-27 | 1998-10-13 | E. I. Du Pont De Nemours And Company | Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles |
| FR2738757B1 (fr) | 1995-09-15 | 1997-10-31 | Rhone Poulenc Fibres | Nouveaux composes metalliques utilisables comme catalyseurs |
| US5780623A (en) | 1996-02-23 | 1998-07-14 | Dsm N.V. | Process to prepare ε-caprolactam from 6-aminocaproic acid |
| DE19630788C1 (de) | 1996-07-31 | 1997-09-11 | Basf Ag | Verfahren zur Herstellung von NH¶2¶-Gruppen enthaltenden Verbindungen |
| DE19631521A1 (de) | 1996-08-03 | 1998-02-05 | Basf Ag | Verfahren zur Herstellung von 6-Aminocapronitril |
| FR2755132B1 (fr) | 1996-10-24 | 1998-11-27 | Rhone Poulenc Fibres | Procede de traitement de lactames |
| US5710344A (en) | 1996-11-08 | 1998-01-20 | E. I. Du Pont De Nemours And Company | Process to prepare a linear aldehyde |
| US5840959A (en) | 1997-03-27 | 1998-11-24 | E. I. Du Pont De Nemours And Company | Method of oxidizing alkyl-5-formyl valerate to monoalkyl adipate |
| US5986126A (en) | 1999-01-25 | 1999-11-16 | E. I. Du Pont De Nemours And Company | Process for the production of 6-aminocapronitrile and/or hexamethylenediamine |
-
2000
- 2000-11-16 US US09/713,143 patent/US6372939B1/en not_active Expired - Lifetime
-
2001
- 2001-10-31 KR KR10-2003-7006595A patent/KR20040016821A/ko not_active Withdrawn
- 2001-10-31 MX MXPA03004187A patent/MXPA03004187A/es not_active Application Discontinuation
- 2001-10-31 BR BR0115957-7A patent/BR0115957A/pt not_active IP Right Cessation
- 2001-10-31 EP EP01985545A patent/EP1335897A1/en not_active Withdrawn
- 2001-10-31 AU AU2002235189A patent/AU2002235189A1/en not_active Abandoned
- 2001-10-31 JP JP2002542769A patent/JP2004513933A/ja not_active Withdrawn
- 2001-10-31 WO PCT/US2001/048001 patent/WO2002040440A1/en not_active Ceased
- 2001-10-31 CA CA002423319A patent/CA2423319A1/en not_active Abandoned
- 2001-10-31 CN CNB018189148A patent/CN1244545C/zh not_active Expired - Fee Related
- 2001-11-01 TW TW090127147A patent/TW576828B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1244545C (zh) | 2006-03-08 |
| AU2002235189A1 (en) | 2002-05-27 |
| CA2423319A1 (en) | 2002-05-23 |
| BR0115957A (pt) | 2004-01-06 |
| US6372939B1 (en) | 2002-04-16 |
| KR20040016821A (ko) | 2004-02-25 |
| EP1335897A1 (en) | 2003-08-20 |
| WO2002040440A1 (en) | 2002-05-23 |
| TW576828B (en) | 2004-02-21 |
| JP2004513933A (ja) | 2004-05-13 |
| CN1505606A (zh) | 2004-06-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |