MXPA02000469A - Process for the continuous production of epoxy-(meth)acrylic-styrene polymers and their use in coating. - Google Patents
Process for the continuous production of epoxy-(meth)acrylic-styrene polymers and their use in coating.Info
- Publication number
- MXPA02000469A MXPA02000469A MXPA02000469A MXPA02000469A MXPA02000469A MX PA02000469 A MXPA02000469 A MX PA02000469A MX PA02000469 A MXPA02000469 A MX PA02000469A MX PA02000469 A MXPA02000469 A MX PA02000469A MX PA02000469 A MXPA02000469 A MX PA02000469A
- Authority
- MX
- Mexico
- Prior art keywords
- epoxy
- polymeric product
- functional
- coating
- meth
- Prior art date
Links
- 239000011248 coating agent Substances 0.000 title abstract 3
- 238000000576 coating method Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000010924 continuous production Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000007863 gel particle Substances 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Abstract
A process is disclosed for a continuous, high temperature polymerization process for preparing a free radically polymerized epoxy-functional polymeric product. The process comprises continuously charging into a reactor at least one epoxy-functional acrylic monomer, and optionally at least one non-functional free radical polymerizable monomer. An optional free radical polymerization initiator may also be added. The reactor is maintained at an effective temperature for an effective period of time to cause polymerization of the monomers into a polymeric product, such that the polymeric product is formed substantially free of gel particles. A clear coating is also disclosed incorporating polymers of the present invention, such that the clear coating has a low Delta b value at standard conditions.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35435099A | 1999-07-14 | 1999-07-14 | |
| US21933499P | 1999-07-14 | 1999-07-14 | |
| PCT/US2000/018890 WO2001005843A1 (en) | 1999-07-14 | 2000-07-12 | Process for the continuous production of epoxy-(meth)acrylic-styrene polymers and their use in coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MXPA02000469A true MXPA02000469A (en) | 2004-05-21 |
| MX229678B MX229678B (en) | 2005-08-04 |
Family
ID=35965938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA02000469A MXPA02000469A (en) | 1999-07-14 | 2000-07-12 | Process for the continuous production of epoxy-(meth)acrylic-styrene polymers and their use in coating. |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5366347B2 (en) |
| MX (1) | MXPA02000469A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA02000471A (en) * | 1999-07-14 | 2004-07-16 | Johnson Polymer Inc | Process for the continuous production of gel free polymers, and powder and liquid coating applications containing gel free polymers. |
| ATE356842T1 (en) * | 2002-02-01 | 2007-04-15 | Basf Corp | OLIGOMERIC CHAIN EXTENDERS FOR THE TREATMENT, POST-TREATMENT AND RECYCLING OF CONDENSATION POLYMERS, COMPOSITIONS BASED THEREOF AND APPLICATIONS THEREOF |
| JP2008094964A (en) * | 2006-10-12 | 2008-04-24 | Toagosei Co Ltd | Composition for powder coating material |
| CN102844336B (en) * | 2009-07-21 | 2015-07-15 | 巴斯夫公司 | Process for the production of condensation polymers via in-reactor chain extension and products thereof |
| JP2013072050A (en) * | 2011-09-29 | 2013-04-22 | Toagosei Co Ltd | Production method of (meth)acrylic polymer composition having (meth)acryloyl group in side chain |
| JP7757607B2 (en) * | 2020-11-06 | 2025-10-22 | 東亞合成株式会社 | Active energy ray-curable composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5474891A (en) * | 1977-11-29 | 1979-06-15 | Asahi Chem Ind Co Ltd | Continous preparation of copolymer having crosslinkable functional group |
| US4529787A (en) * | 1982-06-15 | 1985-07-16 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
| US4589999A (en) * | 1984-12-28 | 1986-05-20 | E. I. Du Pont De Nemours And Company | Electrically conductive coating composition of a glycidyl acrylic polymer and a reactive polysiloxane |
| JPH03199211A (en) * | 1989-12-27 | 1991-08-30 | Hitachi Chem Co Ltd | Acrylic resin for paint, production thereof and paint composition |
| JP2805389B2 (en) * | 1990-09-28 | 1998-09-30 | 日本ペイント株式会社 | Thermosetting coating composition and method for forming composite coating film using the same |
| CA2088129A1 (en) * | 1992-02-06 | 1993-08-07 | Fritz Erdmann Kempter | Continuous polymerization of vinyl monomers |
| JPH06100605A (en) * | 1992-09-18 | 1994-04-12 | Sanyo Chem Ind Ltd | Production of acrylic resin |
| JPH09188833A (en) * | 1995-11-09 | 1997-07-22 | Nippon Paint Co Ltd | Powder coating composition and coating film forming method |
| JPH1160636A (en) * | 1997-08-08 | 1999-03-02 | Kayaku Akzo Kk | Preparation of acrylic resin |
| DE19752747A1 (en) * | 1997-11-28 | 1999-06-24 | Herberts Gmbh | Process for the preparation of glycidyl (meth) acrylate copolymers |
-
2000
- 2000-07-12 MX MXPA02000469A patent/MXPA02000469A/en active IP Right Grant
- 2000-07-12 JP JP2001511499A patent/JP5366347B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003524683A (en) | 2003-08-19 |
| MX229678B (en) | 2005-08-04 |
| JP5366347B2 (en) | 2013-12-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |