MXPA99000662A - Composiciones de liberacion de molde interna que contiene esteres de fosfato. - Google Patents
Composiciones de liberacion de molde interna que contiene esteres de fosfato.Info
- Publication number
- MXPA99000662A MXPA99000662A MXPA99000662A MX9900662A MXPA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX 9900662 A MX9900662 A MX 9900662A MX PA99000662 A MXPA99000662 A MX PA99000662A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl phosphate
- mono
- alkyl
- mixture
- groups
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 9
- 150000003014 phosphoric acid esters Chemical class 0.000 title 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 13
- 239000010452 phosphate Substances 0.000 abstract 13
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- -1 C2-C6 alkyl phosphate Chemical compound 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 229920002578 polythiourethane polymer Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
- C08G18/3885—Phosphate compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2125/00—Compositions for processes using internal mould release agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
En la presente se describen composiciones de liberacion de molde internas para moldear poliuretano y politiouretano. La composicion incluye una mezcla de (a) un fosfato de monoalquilo de C2-C6; b) un fosfato de dialquilo de C2-C6, en donde los grupos alquilo de fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de fosfato de mono y dialquilo pueden ser iguales o diferentes; y (c) un fosfato de mono y/o dialquilo de C7-C18. Tambien se describe una composicion polimerizable que incluye (a) uno o mas monomeros que contienen dos o mas grupos de isocianato; (b) uno o mas monomeros que contiene dos o mas grupos funcionales seleccionados de un grupo tiol y un grupo hidroxilo; (c) una mezcla de un fosfato de monoalquilo de C2-C6 y un fosfato de dialquilo de C2-C6, en donde los grupos alquilo del fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de la mezcla de fosfato de mono y dialquilo pueden ser iguales o diferentes, en donde el fosfato de monoalquilo de C2-Coest presente en una cantidad de -> 20% en peso, basado en peso total de la mezcla de fosfato de monoalquilo de C2-C6 y el fosfato de dialquilo de C2-C6. La composicion tambien puede incluir opcionalmente el fosfato de mono y/o dialquilo de C7-C18.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68207896A | 1996-07-17 | 1996-07-17 | |
| PCT/EP1997/003801 WO1998003582A1 (en) | 1996-07-17 | 1997-07-16 | Internal mold release compositions containing phosphate esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA99000662A true MXPA99000662A (es) | 2004-11-22 |
Family
ID=24738107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA99000662A MXPA99000662A (es) | 1996-07-17 | 1997-07-16 | Composiciones de liberacion de molde interna que contiene esteres de fosfato. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5962561A (es) |
| EP (1) | EP0912632B1 (es) |
| JP (1) | JP3954108B2 (es) |
| DE (1) | DE69732485T2 (es) |
| MX (1) | MXPA99000662A (es) |
| WO (1) | WO1998003582A1 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6783719B2 (en) | 2001-01-19 | 2004-08-31 | Korry Electronics, Co. | Mold with metal oxide surface compatible with ionic release agents |
| US6852266B2 (en) * | 2001-01-19 | 2005-02-08 | Korry Electronics Co. | Ultrasonic assisted deposition of anti-stick films on metal oxides |
| DK1489117T3 (da) * | 2002-03-18 | 2007-08-13 | Dainippon Printing Co Ltd | Harpikssammensætning og optisk element |
| JP3905409B2 (ja) * | 2002-04-10 | 2007-04-18 | タレックス光学工業株式会社 | 光学レンズ成型用ポリウレタン樹脂組成物および耐衝撃性合成樹脂レンズ |
| FR2860597B1 (fr) * | 2003-10-03 | 2006-01-27 | Essilor Int | Materiau thermodur antiplastifie comportant des atomes de soufre et lentille ophtalmique comprenant un materiau thermodur antiplastifie |
| US20050189677A1 (en) * | 2004-02-26 | 2005-09-01 | Steven Lucka | Method for producing a cast of hydrated thermo-set materials with polyurethane elastomer molds |
| US7309252B2 (en) * | 2005-02-22 | 2007-12-18 | Tyco Electronics Corporation | Low profile surface mount connector |
| US8101107B2 (en) | 2005-11-23 | 2012-01-24 | Milgard Manufacturing Incorporated | Method for producing pultruded components |
| US7875675B2 (en) | 2005-11-23 | 2011-01-25 | Milgard Manufacturing Incorporated | Resin for composite structures |
| US8597016B2 (en) | 2005-11-23 | 2013-12-03 | Milgard Manufacturing Incorporated | System for producing pultruded components |
| US7901762B2 (en) | 2005-11-23 | 2011-03-08 | Milgard Manufacturing Incorporated | Pultruded component |
| JP4963497B2 (ja) * | 2006-02-23 | 2012-06-27 | 三井化学株式会社 | ポリチオウレタン系光学材料製造用の内部離型剤 |
| IT1400108B1 (it) * | 2010-05-20 | 2013-05-17 | Acomon Ag | Catalizzatore di polimerizzazione per politiouretani, composizione liquida polimerizzabile e procedimento per la produzione di vetri organici politiouretanici ad alto indice di rifrazione |
| US8524134B2 (en) | 2010-07-12 | 2013-09-03 | Graham J. Hubbard | Method of molding polymeric materials to impart a desired texture thereto |
| EP2924057B1 (en) * | 2012-11-21 | 2020-10-21 | Mitsui Chemicals, Inc. | Polymerizable composition for optical material |
| CN105143349B (zh) * | 2013-03-26 | 2018-08-28 | 三井化学株式会社 | 光学材料用聚合性组合物以及由该组合物得到的光学材料及其制造方法 |
| JP2017512883A (ja) * | 2014-04-11 | 2017-05-25 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | 透明なポリチオウレタン体を製造するための組成物 |
| KR101957082B1 (ko) | 2015-03-12 | 2019-03-11 | 호야 렌즈 타일랜드 리미티드 | 이소(티오)시아네이트 조성물 및 그것을 사용한 광학 부재용 수지 조성물 |
| EP3589672B1 (de) * | 2017-03-02 | 2022-01-12 | Covestro Intellectual Property GmbH & Co. KG | Reaktionsgemische von isocyanaten und polyolen mit verlängerter topfzeit |
| KR101910131B1 (ko) | 2018-02-23 | 2018-10-19 | 에스케이씨 주식회사 | 인계 이형제, 이를 포함하는 광학용 중합성 조성물 및 이의 제조방법 |
| WO2025195909A1 (en) | 2024-03-22 | 2025-09-25 | Basf Se | Process for the production of a polyurethane prepolymer |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4500669A (en) * | 1977-10-27 | 1985-02-19 | Swedlow, Inc. | Transparent, abrasion resistant coating compositions |
| US4258169A (en) * | 1980-03-26 | 1981-03-24 | The Upjohn Company | Polyisocyanate compositions containing in-situ formed pyrophosphate mold release agent and process of making |
| JPS60199016A (ja) * | 1984-03-23 | 1985-10-08 | Mitsui Toatsu Chem Inc | チオカルバミン酸s―アルキルエステル系レンズ用樹脂の製造方法 |
| US4780522A (en) * | 1984-04-11 | 1988-10-25 | Mitsui Toatsu Chemicals, Incorporated | Sulfur-containing polyurethane base lens resin |
| JPS6154331A (ja) * | 1984-08-23 | 1986-03-18 | Nippon Denso Co Ltd | 車両用冷蔵庫 |
| US4622376A (en) * | 1985-06-27 | 1986-11-11 | Ppg Industries, Inc. | Composition of aromatic poly(allylcarbonate), styrene materials, and crosslinker containing three or more ethylenically unsaturated groups for producing polymer of high refractive index and low yellowness |
| JPS6292685A (ja) * | 1985-10-18 | 1987-04-28 | Matsushita Electric Ind Co Ltd | ビデオ信号処理装置 |
| JPH0777733B2 (ja) * | 1986-12-15 | 1995-08-23 | 三井東圧化学株式会社 | 含硫ウレタン樹脂製レンズの注型重合方法 |
| JP2571787B2 (ja) * | 1987-05-14 | 1997-01-16 | 株式会社クラレ | 離型性の改良された成形品の製造方法 |
| US4975328A (en) * | 1987-09-22 | 1990-12-04 | Hoya Corporation | Process for producing polyurethane lens |
| US4929707A (en) * | 1988-02-16 | 1990-05-29 | Mitsui Toatsu Chemicals, Inc. | Polyurethane base lens resin, plastic lens comprising the resin and preparation method of the lens |
| CA1320806C (en) * | 1988-02-17 | 1993-08-03 | Teruyuki Nagata | Plastic lenses having a high-refracting index and process for the preparation thereof |
| DE68917171T2 (de) * | 1988-02-18 | 1995-03-30 | Mitsui Toatsu Chemicals | S-alkylthiocarbamat-Basisharz, dieses Harz enthaltende Kunststofflinse und Verfahren zu ihrer Herstellung. |
| CA1316315C (en) * | 1988-02-22 | 1993-04-20 | Nobuyuki Kajimoto | Highly-refractive plastic lens and process for making the lens |
| US5231195A (en) * | 1991-05-24 | 1993-07-27 | Ppg Industries, Inc. | Ethylenically unsaturated phenolphthaleinic monomers |
| US5693738A (en) * | 1994-04-08 | 1997-12-02 | Mitsui Toatsu Chemicals, Inc. | Composition for urethane-base plastic lens, urethane-base plastic lens obtained from the composition, and process for the production of the plastic lens |
-
1997
- 1997-07-16 EP EP97932831A patent/EP0912632B1/en not_active Expired - Lifetime
- 1997-07-16 JP JP50653698A patent/JP3954108B2/ja not_active Expired - Fee Related
- 1997-07-16 WO PCT/EP1997/003801 patent/WO1998003582A1/en not_active Ceased
- 1997-07-16 DE DE69732485T patent/DE69732485T2/de not_active Expired - Fee Related
- 1997-07-16 MX MXPA99000662A patent/MXPA99000662A/es active IP Right Grant
-
1998
- 1998-12-08 US US09/207,040 patent/US5962561A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5962561A (en) | 1999-10-05 |
| EP0912632A1 (en) | 1999-05-06 |
| WO1998003582A1 (en) | 1998-01-29 |
| DE69732485D1 (de) | 2005-03-17 |
| EP0912632B1 (en) | 2005-02-09 |
| JP3954108B2 (ja) | 2007-08-08 |
| DE69732485T2 (de) | 2006-01-05 |
| JP2001505232A (ja) | 2001-04-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |