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MXPA99000662A - Composiciones de liberacion de molde interna que contiene esteres de fosfato. - Google Patents

Composiciones de liberacion de molde interna que contiene esteres de fosfato.

Info

Publication number
MXPA99000662A
MXPA99000662A MXPA99000662A MX9900662A MXPA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX PA99000662 A MXPA99000662 A MX PA99000662A MX 9900662 A MX9900662 A MX 9900662A MX PA99000662 A MXPA99000662 A MX PA99000662A
Authority
MX
Mexico
Prior art keywords
alkyl phosphate
mono
alkyl
mixture
groups
Prior art date
Application number
MXPA99000662A
Other languages
English (en)
Inventor
Boryslawski Joseph
Original Assignee
Essilor Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essilor Int filed Critical Essilor Int
Publication of MXPA99000662A publication Critical patent/MXPA99000662A/es

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041Lenses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3882Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
    • C08G18/3885Phosphate compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/521Esters of phosphoric acids, e.g. of H3PO4
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2125/00Compositions for processes using internal mould release agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

En la presente se describen composiciones de liberacion de molde internas para moldear poliuretano y politiouretano. La composicion incluye una mezcla de (a) un fosfato de monoalquilo de C2-C6; b) un fosfato de dialquilo de C2-C6, en donde los grupos alquilo de fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de fosfato de mono y dialquilo pueden ser iguales o diferentes; y (c) un fosfato de mono y/o dialquilo de C7-C18. Tambien se describe una composicion polimerizable que incluye (a) uno o mas monomeros que contienen dos o mas grupos de isocianato; (b) uno o mas monomeros que contiene dos o mas grupos funcionales seleccionados de un grupo tiol y un grupo hidroxilo; (c) una mezcla de un fosfato de monoalquilo de C2-C6 y un fosfato de dialquilo de C2-C6, en donde los grupos alquilo del fosfato de dialquilo pueden ser iguales o diferentes y en donde los grupos alquilo de la mezcla de fosfato de mono y dialquilo pueden ser iguales o diferentes, en donde el fosfato de monoalquilo de C2-Coest presente en una cantidad de -> 20% en peso, basado en peso total de la mezcla de fosfato de monoalquilo de C2-C6 y el fosfato de dialquilo de C2-C6. La composicion tambien puede incluir opcionalmente el fosfato de mono y/o dialquilo de C7-C18.
MXPA99000662A 1996-07-17 1997-07-16 Composiciones de liberacion de molde interna que contiene esteres de fosfato. MXPA99000662A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US68207896A 1996-07-17 1996-07-17
PCT/EP1997/003801 WO1998003582A1 (en) 1996-07-17 1997-07-16 Internal mold release compositions containing phosphate esters

Publications (1)

Publication Number Publication Date
MXPA99000662A true MXPA99000662A (es) 2004-11-22

Family

ID=24738107

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA99000662A MXPA99000662A (es) 1996-07-17 1997-07-16 Composiciones de liberacion de molde interna que contiene esteres de fosfato.

Country Status (6)

Country Link
US (1) US5962561A (es)
EP (1) EP0912632B1 (es)
JP (1) JP3954108B2 (es)
DE (1) DE69732485T2 (es)
MX (1) MXPA99000662A (es)
WO (1) WO1998003582A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6783719B2 (en) 2001-01-19 2004-08-31 Korry Electronics, Co. Mold with metal oxide surface compatible with ionic release agents
US6852266B2 (en) * 2001-01-19 2005-02-08 Korry Electronics Co. Ultrasonic assisted deposition of anti-stick films on metal oxides
DK1489117T3 (da) * 2002-03-18 2007-08-13 Dainippon Printing Co Ltd Harpikssammensætning og optisk element
JP3905409B2 (ja) * 2002-04-10 2007-04-18 タレックス光学工業株式会社 光学レンズ成型用ポリウレタン樹脂組成物および耐衝撃性合成樹脂レンズ
FR2860597B1 (fr) * 2003-10-03 2006-01-27 Essilor Int Materiau thermodur antiplastifie comportant des atomes de soufre et lentille ophtalmique comprenant un materiau thermodur antiplastifie
US20050189677A1 (en) * 2004-02-26 2005-09-01 Steven Lucka Method for producing a cast of hydrated thermo-set materials with polyurethane elastomer molds
US7309252B2 (en) * 2005-02-22 2007-12-18 Tyco Electronics Corporation Low profile surface mount connector
US8101107B2 (en) 2005-11-23 2012-01-24 Milgard Manufacturing Incorporated Method for producing pultruded components
US7875675B2 (en) 2005-11-23 2011-01-25 Milgard Manufacturing Incorporated Resin for composite structures
US8597016B2 (en) 2005-11-23 2013-12-03 Milgard Manufacturing Incorporated System for producing pultruded components
US7901762B2 (en) 2005-11-23 2011-03-08 Milgard Manufacturing Incorporated Pultruded component
JP4963497B2 (ja) * 2006-02-23 2012-06-27 三井化学株式会社 ポリチオウレタン系光学材料製造用の内部離型剤
IT1400108B1 (it) * 2010-05-20 2013-05-17 Acomon Ag Catalizzatore di polimerizzazione per politiouretani, composizione liquida polimerizzabile e procedimento per la produzione di vetri organici politiouretanici ad alto indice di rifrazione
US8524134B2 (en) 2010-07-12 2013-09-03 Graham J. Hubbard Method of molding polymeric materials to impart a desired texture thereto
EP2924057B1 (en) * 2012-11-21 2020-10-21 Mitsui Chemicals, Inc. Polymerizable composition for optical material
CN105143349B (zh) * 2013-03-26 2018-08-28 三井化学株式会社 光学材料用聚合性组合物以及由该组合物得到的光学材料及其制造方法
JP2017512883A (ja) * 2014-04-11 2017-05-25 コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag 透明なポリチオウレタン体を製造するための組成物
KR101957082B1 (ko) 2015-03-12 2019-03-11 호야 렌즈 타일랜드 리미티드 이소(티오)시아네이트 조성물 및 그것을 사용한 광학 부재용 수지 조성물
EP3589672B1 (de) * 2017-03-02 2022-01-12 Covestro Intellectual Property GmbH & Co. KG Reaktionsgemische von isocyanaten und polyolen mit verlängerter topfzeit
KR101910131B1 (ko) 2018-02-23 2018-10-19 에스케이씨 주식회사 인계 이형제, 이를 포함하는 광학용 중합성 조성물 및 이의 제조방법
WO2025195909A1 (en) 2024-03-22 2025-09-25 Basf Se Process for the production of a polyurethane prepolymer

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US4500669A (en) * 1977-10-27 1985-02-19 Swedlow, Inc. Transparent, abrasion resistant coating compositions
US4258169A (en) * 1980-03-26 1981-03-24 The Upjohn Company Polyisocyanate compositions containing in-situ formed pyrophosphate mold release agent and process of making
JPS60199016A (ja) * 1984-03-23 1985-10-08 Mitsui Toatsu Chem Inc チオカルバミン酸s―アルキルエステル系レンズ用樹脂の製造方法
US4780522A (en) * 1984-04-11 1988-10-25 Mitsui Toatsu Chemicals, Incorporated Sulfur-containing polyurethane base lens resin
JPS6154331A (ja) * 1984-08-23 1986-03-18 Nippon Denso Co Ltd 車両用冷蔵庫
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JPS6292685A (ja) * 1985-10-18 1987-04-28 Matsushita Electric Ind Co Ltd ビデオ信号処理装置
JPH0777733B2 (ja) * 1986-12-15 1995-08-23 三井東圧化学株式会社 含硫ウレタン樹脂製レンズの注型重合方法
JP2571787B2 (ja) * 1987-05-14 1997-01-16 株式会社クラレ 離型性の改良された成形品の製造方法
US4975328A (en) * 1987-09-22 1990-12-04 Hoya Corporation Process for producing polyurethane lens
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CA1320806C (en) * 1988-02-17 1993-08-03 Teruyuki Nagata Plastic lenses having a high-refracting index and process for the preparation thereof
DE68917171T2 (de) * 1988-02-18 1995-03-30 Mitsui Toatsu Chemicals S-alkylthiocarbamat-Basisharz, dieses Harz enthaltende Kunststofflinse und Verfahren zu ihrer Herstellung.
CA1316315C (en) * 1988-02-22 1993-04-20 Nobuyuki Kajimoto Highly-refractive plastic lens and process for making the lens
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Also Published As

Publication number Publication date
US5962561A (en) 1999-10-05
EP0912632A1 (en) 1999-05-06
WO1998003582A1 (en) 1998-01-29
DE69732485D1 (de) 2005-03-17
EP0912632B1 (en) 2005-02-09
JP3954108B2 (ja) 2007-08-08
DE69732485T2 (de) 2006-01-05
JP2001505232A (ja) 2001-04-17

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Legal Events

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FG Grant or registration