MXPA98007639A - Compositions to clean glasses containing immediate diffusion fraud - Google Patents

Abstract

The present invention relates to a composition for cleaning glass comprising: about 0.001% to 3% of an immediate release perfume composition comprising at least about 50% of immediate release perfume ingredients, selected from the group that consists of: ingredients having a boiling point of less than about 260 ° C and a ClogP of at least about 3, and wherein the perfume composition comprises at least 5 different ingredients of immediate release perfume, about 0.001% a 2% of a detergent surfactant system selected from the group consisting of anionic surfactants, amphoteric detergent surfactants including switterionic surfactants, and mixtures thereof, about 0.5% to 30% hydrophobic solvent, the remainder being a solvent system aqueous comprising water and, optionally, a non-aqueous polar solvent, with only minimal cleaning action, sele of the group consisting of methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, glycol ethers having a hydrogen-binding parameter of more than 7.7 and their mixtures, and any minor ingredients. These compositions have good film / streaking characteristics and provide an immediate release perfume effect

Description

COMPOSITIONS TO CLEAN GLASSES CONTAINED »IMMEDIATE RELEASE PERFUME TECHNICAL FIELD This invention relates to compositions for cleaning glass »preferably liquid detergent compositions for use in glass cleaning» especially advantage glasses and »preferably. another hard surfaces. The compositions of the present invention comprise efficient perfumes »of immediate diffusion» a surfactant system detergents »solvents» builders and water. The compositions contain perfumes derived naturally and / or synthetically. that provide a high level of recognition by the consumer »immediately that they are used.

BACKGROUND OF THE INVENTION The use "for example" of solvents and water soluble organic and synthetic surfactants at low levels »to clean glass. It is known. There are several known compositions that provide good film / streaking characteristics "so that the glass is cleaned without leaving objectionable levels of stains and / or films.

The known detergent compositions comprise certain organic solvents, detergent surfactants and builders and / or optional abrasives. However, "the prior art has not been able to teach or recognize the advantages of providing an efficient perfume" of immediate diffusion in glass cleaning formulations "to provide a signal of increased poetic aroma for consumers. The preferred liquid cleaning compositions have the great advantage that they can be applied to hard surfaces in net or concentrated form, so that a relatively high level of, for example, surfactant and / or organic solvent is directly supplied to the dirt. Therefore. The liquid cleaning compositions have the potential to provide superior removal of soap, grease and oily dirt, with respect to the diluted wash solutions prepared from powder cleaning compositions. The most preferred compositions are those that provide good cleaning on tough fabrics and at the same time clean glass without leaving objectionable stain and / or film levels. Liquid compositions and, especially compositions prepared for glass cleaning, require exceptionally good film / grain formation properties. They may also have problems of product form, in particular lack of homogeneity, lack of clarity or excessive odor of "solvent" for use by consumers.

BRIEF DESCRIPTION OF THE INVENTION The present invention relates to a liquid, aqueous detergent composition for hard surfaces, having improved cleaning characteristics and good film / streaking characteristics, comprising »as essential ingredients: (A) about 0.001% to 3% . preferably around 0.01% to 1%. better still »about 0.01% to 0.5%, and most preferably about 0.01% to 0.25% by weight of an immediate diffusion perfume composition» comprising at least about 50%. better still »at least about 60% by weight and most preferably at least about 70% by weight of immediate diffusion perfume ingredients» selected from the group that connects perfume ingredients having a boiling point less than about of 260 ° C and a ClogP of at least about 3, and wherein the perfume composition comprises at least 5 different immediate diffusion perfume ingredients: (B) around 0.001 '/. ß 2%, preferably around 0.02% s 1% and, better yet »about 0.05% to 0.2% detergent surfactant selected from the group consisting of anionic surfactants. amphoteric detergent teneioactive agents "which include the switterionic surfactants; and its mixtures; and (C) about 0.5% to 30%, preferably about 2% to 15%, better still, about 3% to 8% hydrophobic solvent; (D) the balance being an aqueous solvent system comprising water and »optionally» a non-aqueous polar solvent »with only minimal cleaning action, selected from the group consisting of methanol, ethanol, isopropanol, ethylene glycol. propylene glycol »glycol ethers having a hydrogen binding parameter of more than 7.7, and mixtures thereof, and any minor ingredients. All percentages and proportions herein are by weight with respect to the total composition at least as indicated otherwise. All measurements are made at room temperature (25 ° C), unless otherwise stated. The present invention may comprise, consist of. or consist essentially of. the essential components as well as the optional ingredients and the optional components described here.

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to "liquid" aqueous detergent composition for hard surfaces, which has improved cleaning characteristics and good film / grain forming characteristics, especially those which are suitable for cleaning window glassware »comprising» as essential ingredients: (A) about 0.001% to 3% »preferably about 0.01% to 1%» better still »about 0.01% to 0.5%» and most preferably about 0.01% to 0.25% by weight of a perfume composition of immediate diffusion, which comprises at least about 50%. better still, at least about 60% by weight and »very preferable at least about 70% by weight. of immediate diffusion perfume ingredients »selected from the group consisting of perfume ingredients having a boiling point lower than about 260 ° C» preferably less than about 255 ° C and »most preferable» less than about 250 ° C; and a ClogP of at least around 3 »preferably more than around 3.1 and, even better. more than about 3.2: and wherein the perfume composition comprises at least 5% preferably at least. even better. at least 7 y. very preferable, B different perfume ingredients for immediate diffusion; (B) around 0.001% to 2%, preferably around 0.02% to 1% and, better yet. about 0.05% to 0.2% detergent surfactant »selected from the group consisting of anionic surfactants, amphoteric detergent surfactants. which include agents teneioactivoe switteriónicoe; and their mixtures: and (O about 0.5% to 30% »preferably about 2% to 15%» better still, about 3% to 8%, of hydrophobic solvent; (D) the remainder being a seventh aqueous solvent comprising water and »opsionally» non-aqueous polar solvent. with only minimal cleaning action »selected from the group consisting of ethanol» ethanol, isopropanol. ethylene glycol »- propylene glycol» glycol ethers having a hydrogen binding parameter of more than 7.7 and their mixtures, and any minor ingredients. The compositions of the present invention may also include optional ingredients to increase the specific characteristics that are described below.

A.- THE COMPOSITION OF THE PERFUME OF IMMEDIATE RELEASE The immediate diffusion perfume ingredients which are described herein, can be formulated into glass cleaning compositions in order to provide a significantly better chance of being noticed by the consumer, than the perfume compositions which are not of immediate diffusion. they do not contain a substantial amount of perfume ingredients that are not immediate diffusion. Additionally, the residual perfume is not convenient on many surfaces. including glass windows, mirrors and lae countertops, where spot / film formation is undesirable. An immediate diffusion perfume ingredient is characterized by its boiling point (.p.e.) and its octanol / water partition coefficient (P). The octanol / water partition coefficient of a perfume ingredient is the ratio between its equilibrium concentrations between octanol and in water. Preferred perfume ingredients »of this invention» have a p.e. determined at normal »ordinary and common pressure» of about 760 mm Hg. from about 260 ° C or less »preferably around 255 ° C and, most preferably» less than about 250 ° C; and a partition coefficient P between octanol / water of about 1000 or more. Since the division coefficients of the preferred perfume ingredients of this invention are highly valued, they are very conveniently given in the form of the base logarithm 10 »logP. Thus, the preferred perfume ingredients of this invention have approximate logP of 3 or more. preferably more than 3.1 and »even better» more than 3.2. The boiling points of muche eetan perfume ingredients. for example, in "Perfume and Flavor Chemicale (Aroma Chemicals)", by Steffen Arctander, published by the author in 1969, which is incorporated herein by reference.The logP of many perfume ingredients has been reported, for example, on the basis of data Pomona92 »obtainable from Daylíght Chemical Information Systems Inc. (Daylight CIS)» Irvine »California, USA, and contains much, along with the original literature, however, logP values are very conveniently calculated through the" CLOGP "program. ", B also obtainable from Daylight CIS. This program also has a list of experimental logP values when they can be obtained in the Pomona92 database. The "calculated logP" (ClogP) is determined by the fragmentary approach of Hansch and Leo (see A. Leo in Comprehensive Medicinal Chemistry »volume 4» C. Hansch »PG Sa mens» JB Taylor and CA Tamsden »editors, page 295» Pergamon Press »1990» incorporated here by reference). The fragmentary approach is based on the chemical structure of each perfume ingredient and takes into account the numbers and types of atoms »atomic connectivity and chemical bonding. The ClogP values that are the most reliable and widely used estimates for these physicochemical properties are preferably used instead of the experimental ClogP values, in the selection of the perfume ingredients that are useful in the present invention. So, when a perfume composition that is composed of ingredients that have a p.e. Approximately 260 ° C or menoe and a ClogP, or an experimental logP of about 3 or more in a glass cleaning composition. The perfume is very effusive and very noticeable when the product is used. Table 1 gives some non-limiting examples of immediate diffusion perfume ingredients useful in the glass cleaning compositions of the present invention. The glass cleaning compositions of the present invention contain about 0.005% to 3% »preferably about 0.01% to 1%, better still» about 0.01% to 0.5% y. very preferable »around 0.01% to 0.25%. of the immediate diffusion perfume composition. The instant diffusion perfume compositions of the present invention contain at least 5, preferably at least 6, better still, at least 7, and even better, at least 8 perfume ingredients of immediate diffusion. Additionally, immediate diffusion perfume compositions of the present invention contain at least about 50% by weight of immediate diffusion perfume ingredients, preferably at least about 55% by weight of immediate diffusion perfume ingredients. still »at least about 60% by weight of perfume ingredients of immediate diffusion, and most preferably, at least about 70% by weight of perfume ingredients of immediate diffusion. Immediate spreading perfume compositions should not contain any individual ingredients at a level of more than about 1% by weight of the composition, preferably not more than about 0.5% by weight of the composition and, better still, no more about 0.25% by weight of the composition. The very common perfume ingredients that are derived from natural sources. they are composed of a multitude of components. For example, orange terpenoe contain about 90% to 95% d-limonene, but they also contain a lot of other minor ingredients. When each of the aforementioned materials is added to the formulation of the instant diffusion perfume compositions of the present invention, it is taken into account as a single ingredient for purposes of the definition of the present invention. The synthetic reproductions of said natural perfume ingredients also consist of a multitude of components and are taken into account as an ingredient for the purposes of defining the invention. Some of the instant dip perfume ingredients of the present invention can be optionally, though less preferably, replaced by "delayed diffusion" perfume ingredients. The delayed diffusion perfume ingredients of this invention, e.g. measured at normal normal »ordinary pressure, of about 260 ° C or less, preferably less than about 255 ° C and, better still, less than about 250 ° C» and a logP or ClogP of around menoe Thus, when a composition of perfume consists of some preferred immediate diffusion ingredients and some delayed diffusion ingredients, the perfume effect is more durable when using the product. Table 2 gives some non-limiting examples of optional delayed diffusion perfume ingredients, useful in the glass cleaning compositions of the present invention. Delayed diffusion perfume ingredients are used primarily in applications where the water will evaporate, thereby releasing the perfume.

When the delayed diffusion perfume ingredients are used in combination with immediate diffusion perfume ingredients in the immediate diffusion perfume compositions of the present invention the weight ratio of immediate diffusion perfume ingredients to diffusion perfume ingredients. retarded is typically at least about 1"preferably at least about 1.3, better yet" about 1.5"and" most preferable "about 2. Immediate diffusion perfume-containing lae co-contain at least about 50% by weight of the immediate diffusion perfume ingredients and delayed diffusion perfume ingredients combined »preferably at least about 55% by weight of the combined perfume ingredients» better still. at least about 60% of the perfume ingredients combined and »very preferable» at least about 70% of the perfume ingredients combined. When some optional delayed diffusion perfume ingredients are used in combination with the immediate diffusion perfume ingredients in the immediate diffusion perfume compositions, the instant diffusion perfume compositions of the present invention contain at least 5 ingredients. of different diffusion perfume and 2 delayed diffusion perfume ingredients »preferably at least 5 different ingredients of immediate diffusion perfume and 3 different ingredients of delayed diffusion perfume» and very preferable, at least 6 different diffusion perfume ingredients immediate and 4 different ingredients of delayed diffusion perfume. The glass cleaner compositions of the present invention contain about 0.005% to 3%, preferably about JO.01% to 1% »even better. about 0. 01% to 0.5% and »very preferable» around 0.01% to 0.25% of the perfume components. In the technique of perfume. some auxiliary materials that are odorless or have little odor are used, for example, as solvents, thinners, extenders or fixatives. The non-limitative examples of this are materials with: ethyl alcohol »carbitol» dipropylene glycol »diethyl phthalate. triethyl citrate »isopropyl myristate and benzyl benzoate. These materials are used "for example" to solubilize or dilute some solid or viscous perfume ingredients, for example, to formulate the handling and / or the formulation. These materials are useful in immediate diffusion perfume compositions, but are not taken into account for the calculation of the limits for the definition / formulation and the immediate diffusion perfume compositions of the present invention. Perfume ingredients that are not immediate diffusion, which should be minimized in the glass cleaning compositions of the present invention, are those having a p.e of more than about 260 ° C. Table 3 gives some non-limiting examples of perfume ingredients that are not immediately available. In some particular compositions for cleaning glass, some perfume ingredients which are not immediate diffusion may be used in small quantities, for example to improve the odor of the product.

TABLE 1 EXAMPLES OF PERFUME INGREDIENTS OF "IMMEDIATE RELEASE" Perfume ingredients e.g. Approximate ClogP (° C) allo-oci ene 192 4.362 allyl heptoate 210 3.301 anethole 236 3.314 benzyl butyrate 240 3.698 camphene 159 4.192 carvacrol 23B 3.401 beta-caryophyllene 256 6.333 cis-3-hexenyl triglate 101 3.700 Citral (Neral) 228 3,120 citronellol 225 3,193 Citronellyl acetate 229 3,670 citronellyl isobutyrate 249 4,937 citronellil nitrile 225 3,094 cyperlonyl propionate 242 4,628 cyclohexylethyl acetate 187 3,321 decyl aldehyde 209 4,008 dihydromyrcenol 20B 3,030 dihydromyrcenyl acetate 225 3,879 di ethylctanol 213 3,773 diphenyl oxide. 252 4.240 dodecalactone 258 4.359 ethyl ethyl phenylglycidate 260 3.165 phenol acetate 220 3.485 gamma ethylionone 230 4089 gamma-n-methylionone 252 4.309 ga a-nonalactone 243 3.140 geranyl acetate 245 3.715 geranyl formate 216 3.269 geranyl isobutyrate 245 4.393 geranylnitrile 222 3.139 isobutyrate :. hexenyl 182 3,181 hexophene neopentanoate 224 4,374 hexyl thihalate 231 3,800 alpha-ionone 237 3.3B1 beta-ionone 239 3,960 gamma-ionone 240 3,780 alfs-íroña 250 3,820 isobornyl acetate 227 3,485 isobutyl benzoate 242 3,028 isononyl acetate 200 3,984 alcohol iso onyl 194 3.07B isobuty lquinoline 252 4,193 isomentol 219 3,030 para-isopropyl eni lacetaldehyde 243 3,211 isopulegol 212 3,330 lauric aldehyde (dodesanal) 249 5,066 lilial (pt-bucinal) 258 3,858 d-limonene 177 4,232 linalyl acetate 220 3,500 acetate Menthyl 227 3,210 Menthyl Chavicol 216 3,074 Alpha-iso "Gamma" Ethylionone 230 4,209 Ethylnonylacetaldehyde 232 4.B46 Methyloctylacetaldehyde 22B 4,317 Irceno 167 4,272 General 228 3,120 Nitile acetate 231 3,555 Nonyl acetate 212 4,374 Nonylaldehyde 212 3,479 Octylaldehyde 223 3.B45 Terpenoe orange (d-limonene) 177 para-cymene 179 4.06B phenylheptanol 261 3.47B phenylhexanol 25B 3,299 alpha-pinene 157 4,112 beta-pinene 166 4,182 alphaterpinene 176 4.412 gamma-terpinene 183 4.232 terpinolene 1B4 4.232 terpinyl acetate 220 3.475 tetrahydro linalool 191 3. 517 tetrahydro ircenol 208 3.517 tonalid 246 6.247 undedenal 223 4.053 veratrol 206 3. 140 verdox 221 4. 059 vertenex 232 4.060 TABLE 2 EXAMPLES OF INGREDIENTS DD PERFUME OF "DELAYED DIFFUSION" Perfume ingredients e.g. Approximate ClogP approximate allyl caproate 185 2,772 amyl acetate 142 2,258 amyl propionate 161 2,657 anisoic aldehyde 248 1,779 anisole 154 2,061 benzaldehyde 179 1,480 benzyl acetate 215 1,960 benzylacetone 235 1,739 benzyl alcohol 205 1,100 benzyl formate 202 1,414 benzyl isoleylate 246 2,887 benzyl propionate 222 2,489 beta-gam a-hexenol 157 1,337 camphor gum 208 2,117 levo-carveol 227 2,265 d-carvone. 231 2,010 levo-carvone 230 2,203 cinnamic alcohol 25B 1,950 cinnamyl formate 250 1,908 cie-jasmone 248 2,172 cis-3-he- acyl acetate 169 2,243 acetic acid 248 2,531 cumin aldehyde 236 2,780 cyclal C 180 2,301 dimethylbenzylcarbinol 215 1,891 ethyl acetate dimethylbenzylcarbinol 250 2,797 ethyl acetate 77 0.730 ethyl acetoacetate 181 0.333 ethylamyl ketone 167 2.307 ethyl benzoate 212 2,640 ethyl butyrate 121 1,729 ethylhexyl ketone 190 2.916 ethyl phenylacetate 229 2.489 eucalyptol 176 2.756 eugenol 253 2.307 phenolic alcohol 200 2.579 flower acetate (acetate 175 2,357 tricyclodecenyl) Frutene (200,260 tricyclodecenyl propionate) geraniol 230 2,649 hexenol 159 1,397 hexenyl acetate 168 2,343 hexyl acetate 172 2,787 heilyl acetate 155 2,381 hydratropic alcohol 219 1,582 hydroxy citronella 241 1,541 indole 254 2,132 Iodoyl alcohol 132 1,222 isomentone 210 2,831 ieopulegyl acetate 239 2,100 ieoquinoline 243 2,080 liguetral 17 7 2,301 linalool 19B 2,429 linalool oxide 188 1,575 1inalyl formate 202 2,929 menthone 207 2,650 ethylacetophenone 228 2,080 ethylacetolone 152 1.B4B methyl anthranilate 237 2,024 methyl benzoate 200 2,111 methyl benzylacetate 213 2,300 ethyleugenol 249 2,783 methylheptenone 174 1,703 carbonate ethylbeptin 217 2.52B methylheptyl ketone 194 1.B23 methylhexyl ketone 173 2.377 methylphenylcarbinyl acetate 214 2.269 methyl salicylate 223 1.960 methyl N-methylanthranilate 256 2.791 Nerol 227 2,649 octalactone 230 2,203 octyl alcohol (octanol-2) 179 2,719 para-creaol 202 1,000 para-creeyl methyl ether 176 2,560 para-methoxyacetophenone 260 1.B01 para-ethylacetophenone 228 2,080 phenoxyethanol 245 1.1BB phenylacetaldehyde 195 1,780 phenylethyl acetate 232 2.129 phenylethyl alcohol 220 1,183 phenylethyl di ethylcarbmol 238 2,420 phenyl acetate 155 1,684 propyl butyrate 143 2,210 pulegone 224 2,350 rose oxide 182 2,896 safrole 234 1,870 4-terpinenol 212 2,749 alpha-terpineol 219 2,569 viridine 221 1,293 TABLE 3 EXAMPLES OF PERFUME INGREDIENTS THAT ARE NOT DISSEMINATED IMMEDIATE Perfume ingredients _ p.e. Approximate CloqP approximate Allylcyclohexane Propionate 267 3.935 A bretolide 300 6.261 Amyl Benzoate 262 3.417 Amine Cyanate 310 3.771 Amylcinic Aldehyde 285 4.324 Amylcinnamic Aldehyde-Dimethyl 300 4.033 Acetal Isoalyl Salicylate 277 4.601 Auran IOL 450 4.216 Benzophenone 306 3.120 Benzyl Salicylate 300 4.3 B3 Cadinine 275 7,346 Cedrol 291 4,530 Caryl Acetate 303 5.436 Cmamyl iodine 370 5.480 Coumarin 291 1.412 Cichloxyl Salicylate 304 5.265 Dicaldehyde Aldehyde 270 3.680 Dioxide Asmonate +300 3.009 Diphenylmethane 262 4.059 Ethylene Brasilate 332 4.554 Ethyl Dececylenate 264 4. B8B Isoeugenol 266 2.547 Exaltolide 280 5.346 Galaxolide +260 5.482 Geranyl anthranilate 312 4.216 Hexadecanolide 294 6.805 Hexenyl salicylate 271 4,716 Aldehyde hexilciná ico 305 5.473 Hexyl Salicylate 290 5.260 Linalyl Benzoate 263 • * J •? JJ 2-methoxynaphthalene 274 3.235 Methyl cinnamate 263 2,620 Dihydrojae methyl onate +300 2,275 beta-ethylnaphthyl ketone 300 2.275 Indanone moss +250 5.45B Moss ketone p.f. = 137 ° C 3.014 Tibetina de mosgo p.f. = 136 ° C 3.B31 Mérísticina 276 3,200 delta-nonalactone 280 2.760 Oxahexadecanolide-10 +300 4.336 Oxahexadecanolide-11 p.f. = 35 ° C 4.336 Patchouli alcohol 285 4.530 Fantolide 288 5,977 Phenylethyl Benzoate 300 4.058 Phenylethyl phenylacetate 325 3.767 alpha-Santalol 301 3.B00 Tibetolide 280 6.246 delta-Undecalactone 290 3.830 gamma-Undecalactone 297 4.140 Vanillin 285 1.580 Vetiveril acetate 285 4.B82 Yara-Yara 274 3.235 (a) P.f. it is melting point »these ingredients have a p.e above 260 ° C. Perfumes suitable for use in glass cleaning compositions can be formulated from known fragrance ingredients and for the purpose of increasing environmental compatibility, preferably the perfume is free of halogenated fragrance material and nitrous oxide.

B.- THE SURGICAL AGENT SYSTEM The compositions of the present invention contain a detergent surfactant system selected from the group that you have made of anionic surfactants and amphoteric surfactants. which include surface-active agents and their mixtures, as will be described below. The surfactant system: > it is present at a level of about 0.001% to 2%, preferably about 0.02% to 1%, better still, about 0.5% to 0.2% by weight of the composition. d > The Amphocarboxylate Detergent Surfactant The detergent compositions for hard, liquid, aqueous (cleaning) surfaces herein may contain about 0.001% to 2%. preferably around 0.01% to 0.5% »better still» about 0.02% to 0.2% »and very preferable» about 0.03% to 0.08% »of short chain amphocarboxylate detergent surfactant» of 6 to 10 carbon atoms . It has been found that detergents of amphocarboxylate detergents and especially glycinate have been found to give good cleaning, with superior film / vellum formation for detergent compositions which are used to clean both glass and dirt relatively difficult to remove. Despite the short chain, good detergency and short chains provide improved film / grain formation even when compared to the. Most of the detergent agents and detergents are described below. Depending on the level of cleaning desired and / or on the amount of hydrophobic material in the composition that needs to be solubilized, only the amphocarboxylate detergent surfactant can be used or it can be combined with the surfactant coagent, preferably the surfactants. switterionicoe. The "amphocarboxylate" detergent surfactants preferably have the generic formula: RN < A M CH3) nN (Rs) < CHa) "C (O> 0M wherein R is a hydrophobic portion of 6 to 10 carbon atoms» typically a fatty acyl portion containing about 6 to 10 carbon atoms which »in combination with the nitrogen atoms forms a amido group »RA is hydrogen (preferably) or an alkyl group of 1 to 2 carbon atoms, Ra is an alkyl of 1 to 3 carbon atoms or substituted alkyl of 1 to 3 carbon atoms» for example, substituted with hydroxy or substituted with carboxy or methoxy, preferably hydroxyethyl: each is an integer from 1 to 3, each p ee an integer from 1 to 2, preferably i, and each M ee a water-soluble cation, typically a cation of alkali metal »of ammonium and / or of alsanola onium These detergent surfactants are available, for example, from Witco under the tradename Rewoteric AMT: H, which have the formula: C.7Hi5C (0) NH (CHs) ) aN (CHaCHaOH) CH: 2C (O) 0 < - > Na < -, - > from Mona Industries, under the trade name ial Monateric 1000 * R "having the formula: C, H1¡SC (O) MHC CH2) ß (CHaCH ^ OH) CH ^ CH ^ C (O) 0 < - > Na (+).: And from Lonza under the trade name Amphoterge KJ-2 (,, >, which has the formula: c- ..Hiß. IS > C (O) NH (CHa sti (CH ^ CH ^ OCH ^ CÍO) 0 <-> Na <*> -CH5.C (0) 0 <-> Na <->. (2) The surfactant detergent switterionic Lae detergent compositions for hard surfaces »liquid, aqueous (cleaners) of the present may contain from about 0.001% to 2% of suitable switterionic detergent surfactant »containing a cationic group» preferably a quaternary ammonium group »and an ammonium group» preferably the carboxylate »sulfate group and / or sulfonate »better yet», sulfonate. A more preferred scale of inclusion of switterionic detergent surfactant is about 0.02% to 1% surfactant »very preferable in the approximate range of 0.05% to 0.2%. The detergent-surfactant detergent agents as mentioned above, contain both a cationic group and an anionic group and are in a suetancial electrical neutrality, when the number of anionic charges and the cationic charges in the detergent-deodorant agent molecule are substantially the same . Switterionic detergents typically containing both a quaternary ammonium group and an anionic group selected from the group sulfonate and carboalpha are convenient since they maintain their amphoteric nature at the largest pH scale of interest for cleaning hard surfaces. The sulfonate group is the preferred anionic group. The preferred detergent surfactant surfactants have the generic formula: R3CC (O) -N (R- *) - (CR3 ^) nl 3mN (Rß) to «-» - (CRSS5B >; "A-Y < - > wherein each Y ee preferably a carboxylate group (C00 ~) or eulphonate (S03 ~) »better still. eulphonate; wherein each I 3 is a hydrocarbon, eg, an alkyl or alkylene group, containing about 8 to 20 carbon atoms, preferably about 10 to 18, better still about 12 to 16 carbon atoms; wherein each (R- *) is hydrogen or a short chain alkyl "a substituted alkyl containing from one to four carbon atoms" preferably groups selected from the group consisting of methyl »ethyl» propyl »substituted hydroxyethyl or hydropropyl , and its mixtures; preferably methyl; where each (Rs > is selected from the group consisting of hydrogen and hydroxy group with no mae of a hydroxy group in any group (CRS.-.) ,, * •: where (ß) is similar to R- * except that preferably it is not hydrogen, where m is 0 oi, and where each yp * eon an integer of about 1 to 4", preferably 2 to about 3. better still, about 3. Loe grupoe R3 they may be branched or "unsaturated" or both, and said structures may provide film / streaking benefits even when used as part of their mixture with straight-chain alkyl groups R. The groups R- * may also be connected to form ring structures such as imidazoline »pyridine» etc. The preferred hydrocarbylamide alkylene-sulfobetaine detergent (HASB) detergent agents, where m = Y is an eulonate group, provide superior properties of superior greasy dirt removal and / or superior properties. of film formation / veining and / or properties of "anti-fogging" and / or perfume perfumery. Hydroxycarbonylamidoalkerate-eulphobetaine and, to a lesser degree, hydrocarbylamidoalkylenebetaines, are excellent for use in detergent compositions for cleaning hard surfaces, especially those formulated for use in both glass and hard-to-remove soils. They are even better when used with monoethanolamine and / or specific beta-aminoalkanol »as described here. A more preferred specific detergent surfactant is an acyclopethylene (hydroxypropylene) sulphobetaine acylate of 10 to 14 carbon atoms, eg, the detergent surfactant obtainable from the Witco Company as a 40% product of active ingredient under the trademark "REWOTERIC AM CAS Sulfobetaine < »>". The level of detergent surfactant switterio ico. for example. HASB in the composition is typically from about 0.001% to 2.0% »preferably around 0.02% to 1.0%. The level in the composition depends on the eventual level in the dilution to constitute the washing solution. It is an advantage of the switterionic detergent, for example, HASB, that compositions containing it can be more easily diluted by the consumer, since they do not interact with hardness cations, as is easy with conventional surfactant surfactants and ammonia detergents. The switterionic detergents are also extremely effective at very low levels, for example, less than about 1%. Other switterionic detergent surfactants are set forth in column 4 of US Pat. No. 4,287,080"to Siklosi" incorporated herein by reference. A further detailed list of suitable switterionic detergent surfactants for the detergent compositions herein can be found in Collins' U.S. Patent No. 4,557,853, issued December 10, 19B5, incorporated herein by reference. Commercial sources of such surfactants can be found in McCutcheon EMULSIFIERS AND DETERGENTS. North American Edition »1984» McCutcheon Division »MC Publishing Company» also incorporated here by reference. < 3) Optional anionic and nonionic detergent surfactant The detergent compositi preferably the aqueous liquid detergent compositifor hard surfaces, of the present invention. they also contain »as a preferred surfactant coagent», or as the primary detergent surfactant, preferably, about 0.01% to 2.0%, preferably about 0.01% to 1.0%, of suitable anionic detergent surfactant. The agent is anionic surfactants with alkyl or alkylaryl compounds suitably soluble in water, the alkyl having 6 to 20 carbon atoms, and including a sulfate or sulphonate group. Depending on the level of cleaning desired, only an anionic detergent surfactant can be used or the anionic detergent surfactant can be combined with a surfactant coagent, preferably an amphoteric surfactant coagent. The ammonia detergent surfactants herein preferably have the generic formula: R '- (i0 Jo-x-SOa1 -> M < * > where R &bgr; is an alkyl chain of 6 to 20 carbon atoms » preferably an alkyl chain of 8 to 16 carbon atoms, R10"when present, an alkylene chain of 6 to 20 carbon atoms", preferably an alkylene chain of 8 to 16 carbon atoms, "a phenylene group CßH ^ The preferred compositiof the present invention preferably contain about 0.001% to 2% by weight of the composition, better still, about 0.1% to 1%, very preferable about 0.02%. at 0.3% by weight of the composition, of one or more detergent agents of linear alcohol eulfate, of different chain lengths, having the general formula: R-O-S03 M wherein M is any suitable counter ion , preferably sodium, potassium, etc ... and where R is an alkaline group uilo with a chain length of about B to IB carbon atoms, and mixtures thereof; preferably about 12 to IB carbon atoms and their mixtures »better still, about 14 to IB carbon atoms and mixtures thereof; and wherein R ee is more than about 30% of 14 carbon atoms »preferably more than about 35%. better still about 40% by weight of the alkyl sulfate. All of the alkyl sulfate surfactant may contain R of 14 carbon atoms or greater chain length, but more than 30% by weight of the alkyl surfactant preferably must be of a chain length of 14 carbon atoms. Lae compositicomprising only alkyl sulfate surfactant with longer chain lengths, ie from 16 to IB carbon atoms, give good surface lubricity benefit. However, that chain length without the necessary amount of chain lengths of 14 carbon atoms exhibits poor film / grain formation properties. On the other hand, compositicomprising only minor chain alkyl eulfate surfactants, ie alkyl carbamate surfactant of 8 to 12 carbon atoms, give good film / grain formation properties, but show malae propieradadee of lubricidad euperficial. The presence of chain lengths of 14 carbon atoms at levels of more than about 30% in weight of the alkyl eulfate teneoactive agent, compared to other chain lengths. or alone, they provide a product with excellent lubricity properties and excellent film / streaking properties. Particularly preferred compositicontaining about 0.05% to 0.30% by weight of the composition, of a mixture of 12/14 ato oe carbon "wherein the weight ratio of 12 to 14 carbon atoms is about 1:10 at 2: 1, preferably around 1: 5 to 1.5: 1 and »very preferable» around 1: 3 to 1: 1. It has been found that this combination provides sufficient surface lubricity at the same time it avoids the formation of objectionable film / veining. The selected alcohol sulfate detergent raw materials are essentially free of unreacted fatty alcohol "wherein the term" essentially free "is defined as having less than about 2% by weight of the composition. preferably less than about 1.8% and »very preferable» less than about 1.5% by weight of the composition »of unreacted fatty alcohol» in a raw material with nominally 30% active ingredient. A very preferred active sulfate surfactant is a mixture of Stepanol WA-Extra <;? > obtainable from Stepa Company. with extra-alkyl sulphate of 14 carbon atoms added such that the ratio of 12 to 14 carbon atoms is about 1: 1. Concentrated compositions can be used to provide a less expensive product. When a higher concentration is used, ie when the level of alkyl sulfate surfactant used is about 0.10% to 2.0% by weight of the composition, it is preferred to dilute the composition before using it to clean a hard surface. especially glass. The dilution ratios of the concentrate or the alkyl sulfate concentrates with respect to the water may vary, preferably, from about 1: 1 to 1:10 »better yet» about 1: 1.5 to 1: 5 and »that which more preferred »around 1: 2 to 1: 5. Some suitable surfactants for use herein, in small amounts, have one or more of the following: linear sodium alkylbenzenesulfonate "from B to IB carbon atoms in the alkyl (LAS)" in particular LAS of 11 to 12 carbon atoms carbon; the sodium salt of the cocoalkyl ester-sulfate. containing 3 mole of ethylene oxide: the adduct of a random secondary alcohol having a range of alkyl chain length of 11 to 15 carbon atoms and an average of 2 to 10 portion of ethylene oxide; several examples obtainable in the trade from them are Tergitol < ? »> 15-S-3 »Tergitol 'R > 15-S-5, Tergitol 'R 15-S-7 and Tergitol' »> 15-S-9, all obtainable from Union Carbide Corporation; the sodium and potassium salts of coconut fatty acids (coconut fertilizers); the condensation product of a straight chain primary alcohol containing approximately from B to 16 carbon atoms "and having an average carbon chain length of about 10 to 12 carbon atoms" with about 4 to 8 mole of ethylene oxide per mole of alcohol; an amide that has one of the preferred formulas: O E-7-C-N (Ra) 3 wherein R "7 is a straight-chain alkyl group containing from 7 to 15 carbon atoms and having an average carbon chain length of 9 to 13 carbon atoms, approximately, and wherein each R is a hydroxyalkyl group containing from 1 to about 3 carbon atoms, a switterionic surfactant having one of the preferred formulas noted below, or a surfactant of foephine oxide. Suitable surfactant agents are those of fluorocarbon surfactants, examples of which are FC-129 '* "' a fluorinated alkylcarboxylate of potaeium and FC-170-C < : R > A mixture of fluorinated alkylpolyoxyethylene-neonate "available from 3M Corporation" as well as the fluoro-active Zonyl surfactants available from DuPont Corporation It is understood that mixtures of various non-ionic surfactants can be used. Ethoxylated alcohol and / or alkylphenol may also be used as surfactant coagents. (4) Mixtures of amphocarboxylate surfactants can be present in this invention. surfactant agents, switterionic detergents and / or anionic detergent surfactants, as discussed above. The detergent surfactants and detergent detergents can be present at an approximate level of 0.02% to 1.5%. The surfactant agents and amphipcarboxylate detergents can be present at approximate levels of 0.001% to 1.5%. The ratio of switterionic surfactant present to amphocarboxylate detergent surfactant is typically about 3: 1 to 1: 3 »preferably about 2: 1 to 1: 2» better still »about 1: 1. The ratio of primary detergent surfactant to surfactant coagent or surfactant coagents »is typically about 3: 1 to 1: 1.

C- THE SOLVENT HYDROPHON In order to improve the cleanliness in the liquid compositions, a hydrophobic solvent having cleaning activity can be used. The surfactants in the hard surface cleaning compositions of the present invention can be the well known "degreasers", commonly used, for example, in the dry cleaning industry, in the hard surface cleaning industry and in the metal industry. ecánica The useful definition of said solvents can be derived from the solubility parameters that are indicated in "The Today", a Union Carbide publication, incorporated here by reference. The most useful parameter seems to be the hydrogen parameter that is calculated by the formula: where gamma H ee the hydrogen bonding parameter »a is the number of aggregation» (Log a = 3.39066 T ^ / T ^ - 0.15848 - Log M) and gamma T is the solubility parameter that is obtained from the formula: 1/2 (/ \ H ^ W - RRTT)) dd rt M where \ Has the heat of vaporization at 25 ° C »R is the gaseous constant (1.987 cal / mol / degree)» T is the absolute temperature in ° K, Tto is the boiling point in ° K. T0 is the critical temperature in ° K »d is the density in g / ml and M is the molecular weight. For the compositions of the preeent, the hydrogen bonding parameter is preferably less than about 7.7, better still about 2 to 7, or 7.7, and still better about 3 to 6. The solvent with the smaller numbers becomes smaller. increasingly difficult to solubilize in the compositions and have a greater tendency to cause fogging in the glass. Higher numbers require more solvent to provide better cleaning of fatty soils / aceitoeae. The hydrophobic solvents are typically at a level of approximately 0.5% to 30%, preferably around 2% to 15%, better still »around 3% to 8%. Diluted compositions typically have solvents at a level of about 1% to 10%, preferably about 3% to 6%. The concentrated compositions contain about 10% to 30%, preferably about 10% to 20%, solvent. Many of the solvents comprise hydrocarbon or halogenated hydrocarbon moieties of the alkyl or cycloalkyl type, and have a boiling point well above room temperature, that is, above about 20 ° C. The formulator of the compositions of the type herein will be guided in the selection of the coefficient in part by the need to provide good grease-cutting properties and partly by aesthetic considerations. For example, kerosene-type hydrocarbons work quite well to cut the fat in the present compositions, but they may have a bad odor. The kerosene must be excepted to the clean entity before it can be used "even in commercial situations. For domestic use "where the bad colors would not be tolerated" the formulator would most likely select solvents that had a relatively pleasant odor "or odors that could be reasonably modified by the perfume. The alkyl aromatic solvents of 6 to 9 carbon atoms, especially the alkyl radicals of 6 to 9 carbon atoms, preferably octyl benzene, exhibit excellent fat removal properties and have a low pleasant odor. Likewise, olefinic solvents having a boiling point of at least 100 ° C, especially alpha-olefins, preferably 1-decene or 1-dodecene, are excellent solvent and grease scavengers. Generically, the glycolic ethers useful herein have the formula R3- -0- (R aO-) p, H wherein each R "is an alkyl group containing about 3 to 8 carbon atoms" each a is ethylene or propylene and m1 is a number from 1 to 3. The most preferred glycol ethers are selected from the group consisting of monopropylene glycol onopropyl ether, dipropylene glycol monobutyl ether, monopropylene glycol monobutyl ether, ethylene glycol onhexyl ether, ethylene glycol monobutyl ether, monohexyl ether. of diethylene glycol »monoethylene ether of onoethylene glycol» monobutyl ether of onethylene glycol and mixtures thereof A particularly preferred type of solvent for such hard surface compositions comprises diole having from 6 to 16 carbon atoms in its molecular structure. They have an approximate water solubility of 0.1 to 20 g / 100 g of water at 20 ° C.

(D) THE AQUEOUS SOLVENT SYSTEM The rest of the formula is typically water and non-aqueous polar solvents with only minimal cleaning action, such as methanol. ethanol, isopropanol, ethylene glycol, glycol ether having a hydrogen bonding parameter of 7.7, propylene glycol and mixtures thereof, preferably ethanol.

The level of non-aqueous polar solvent is usually higher when more concentrated formulas are prepared. Typically the non-aqueous polar solvent level is around 0.5% to 40%, preferably around 1% to 10% »even better. about 2% to 8% (especially for "diluted" compositions) and the water level is about 50% to 99%, preferably about 75% to 95%.

(E) OPTIONAL INGREDIENTS < 1 > Soluble carbonate and / or bicarbonate salts, optional The alkaline metal carbonate and / or bicarbonate saltse. soluble in water »such as sodium bicarbonate, potassium bicarbonate» potassium carbonate »cesium carbonate» sodium carbonate and mixtures thereof are added to the composition of the present invention in order to improve the formation of marbled film when The product is dried on the surface by rubbing, as is typical for cleaning glass. Preferred lae elees are sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, their respective hydrates and dream mixtures. The solubilized water-soluble alkali metal carbonate and bicarbonate are typically present as salts at a level of 0% to about 0.5%, preferably around 0.005% to 0.1%, better still, about 0.01% a 0.1%, and very preferable »about 0.02% to 0.05% by weight of the composition. The pH in the composition "at least initially, in use is about 7 to 11", preferably around 7.5 to 10.5. better yet, around 8 to 10. The pH is typically measured in the product. < 2) Tartaric acid monoethanolamine salt, optional Builders also may be employed in the present invention which are efficient for surface cleaners and have reduced film / streaking characteristics at the critical level. The addition of the tartaric acid specific builder at critical levels in the present composition improves the cleanliness of the film / streaking formation problem, as it usually occurs when builders are added to hard surface cleaners. By means of the present invention there is no longer a need to make a compromise between the improved cleaning and the results that form acceptable film / grain, which is especially important for hard surface cleaners, and which also applies to glass cleaning. These compositions containing the builder of the present, at the levels of the preeente, have exceptionally good cleaning properties. They also have exceptionally good gloss properties. When they are used to clean shiny surfaces without rinsing, they have much less tendency than, for example, the products with carbonate improver to leave a matte finish on the surface and to form film / veining. The tartaric acid detergency builder is present at approximate levels of 0.001% to 0.1% »preferably around 0.01% to 0.1%, better still» from 0.01% to 0.05%. The salts are preferably compatible and include the sodium »ammonium» salts of potassium and / or alkanolammonium. The alkanolammonium salt is preferred. The preferred alkanolammonium salt which is formed by the addition of monoethanolamine (MEA) at a level of about 0.005% to 0.2%, preferably about 0.01% to 0.1%, better still, about 0.02% to 0.1% of the composition. < 3 > The optional substantive ingredients An optional part of this invention is a substantive material that improves the hydrophilicity of the surface being treated. especially glass. This increase in hydrophilicity provides an improved appearance when the surface is re-moistened and then dried. The water "laminates" from the surface and thereby minimizes the formation. for example, of "rain spots" that form when it dries. The substantive materials useful in the present invention include polymers of amine oxide »polycarboxylate. polystyrene sulfonate and polyether based polymers. The level of substantive polymer should normally be around 0.01% to 1%, preferably around 0.05% to 0.5%, better still. about 0.1% to 0.3% by weight of the composition. The use of polycarboxylate, polystyrene sulfonate and polyether-based polymers to provide this hydrophilicity is known in the art. The use of these polymers is described in the pending application of Procter and Gamble Serial No. or a / 378 »205» filed on January 25, 1995. of Masters and co-inventors. which is incorporated herein by this reference. The optional amine oxide polymers of this invention have one or more monomer units that contain at least one N-oxide group. At least around 10%. preferably more than about 50% »better yet» more than about 90% of the newly formed polymer formers contain an amine oxide group. Eoe polymer can be described by the general formula: wherein each P eeta selected from homopolymerizable portions and copyable can be joined to form the polyester skeleton, preferably vinyl portions. for example. C < R) aC (R) a "wherein R ee H" alkyl (ene) of 1 to 12 carbon atoms (preferably 1 to 4 carbon atoms), aryl (ene) of 6 to 12 carbon atoms and / or B; B is a portion selected from alkyl of 1 to 12 carbon atoms "linear and cyclic" substituted and unsubstituted, alkylene of 1 to 12 carbon atoms. heterocyclic of 1 to 12 carbon atoms »aromatic groups of 6 to 12 carbon atoms» and wherein at least one of said portion B has at least one amine oxide group (= N-L >); u ee from 0 to around 2: yt is a number such that the molecular weight of the polymer is around 2,000 to 100,000, preferably around 5,000 to 20,000 and, better still, around 8,000 to 12. 000 Preferred optional polymers of this invention possess the unexpected property of being substantive without leaving a visible residue that would render the glass surface unattractive to consumers. Preferred polymers include polymers of 4-vinylpyridine poly (N-oxide) (PVMO), for example, formed by polymerization of onomers including the following portion: wherein, for the purposes of this invention, t is a number such that the average molecular weight of the polymer is about 2,000 to 100,000, preferably about 5,000 to 20,000, and, better yet, about from 8,000 to 12,000. The convenient scale of molecular weight of the polymers useful in the present invention is in contrast to what has been found in the art with respect to the additives to polycarboxylate bath »polystyrene sulfonate and polyether» which prefer molecular weights in the scale from 400,000 to 1,500,000.

(F) OPTIONAL MINOR INGREDIENTS The compositions herein also contain various other additives which are known in the art for detergent compositions. They are preferably not used at the level that cause unacceptable film / grain formation. The non-limiting examples of said additives are: Hydrotropes. tale such as eodium tclueneulfonate »eodium cumenesulfonate and potassium xylene sulphate; and Aesthetic enhancing ingredients, such as colorants as long as they do not adversely affect the film / veining formation in the. cleaning the glass. Antibacterial agents may be present, but preferably only at low levels to avoid film / streaking problems. The most hydrophobic antibacterial / germicidal agents are avoided "such as orthobenzyl para-chlorophenol. If present, said materials would remain at levels below 0.1%. Stabilizing ingredients may be present, typically to stabilize more hydrophobic ingredients such as perfume. Stabilizing ingredients include acetic acid and propionic acid and their salts, for example, NH 4 MEA Na. K »etc. »Preferably acetic acid and alkanediole of 2 to 6 carbon atoms, more preferably butanediol. The stabilizing ingredients do not work according to any known principle. However, the combination of the amide-surfactant surfactant with the linear acyl amphocarboxylate detergent surfactant is the anionic detergent surfactant. the nonionic detergent active agent or its mixture and the stabilizing ingredient can create a microemulsion. The amount of stabilizing ingredient is typically about 0.01% to 0.5%, preferably about 0.02% to 0.2%. The proportion of hydrophobic material, eg, perfume, which can be stabilized in the product, is related to the total of the surface-active agent and, typically, is an amount that provides a ratio of the surfactant to hydrophobic material of about 1: 2 to around 2: 1. Other detergent builders that are efficient for hard surface cleaners and have reduced film / streaking characteristics at critical levels may also be present in the compositions of the invention. The optional builders. additional »suitable» _ include the salts of ethylenedia-inotetraacetic acid (hereinafter EDTA) »citric acid, nitrilotriacetic acid (hereinafter NTA) »solid carboxy-ethylsuccinic acid» N- (2-hydroxypropyl) iminodiacetic acid and N-di-ethylene glycol-N-N-diacetic acid in the case of DIDA eduction). Preferred salts are compatible and include the ammonium, sodium, potassium and / or alkanolammonium eleates. The alkanolammonium salt is preferred as described below. A preferred builder is NTA (eg, sodium) a preferred builder is citrate (eg, from eioxide or from orioethanolamine) and a much preferred builder is EDTA (eg, from eioxide). These optional, additional detergency builders. when they are present, they are typically at approximate levels of 0.055 to 0.5%, better still, around 0.05% to 0.3%, very preferable, around 0.05% to 0.15%. The significance of these additional detergency requirements in the wash solution used for glass should be around 0.2%. Therefore, typically, the dilution is highly preferred for cleaning glasses "while the complete concentration is preferred for general purpose cleaning" depending on the concentration of the product. Typically, the best film / streaking results occur mainly when the enhancer is combined with amphoteric and / or switterionic detergent surfactant compositions, although an improvement is also seen with the anionic or anionic / nonionic detergent surfactant compositions, less preferred. In order to make the present invention readily understandable, reference is made to the following examples, which are intended for illustration only and should not be construed as limiting their scope.

PERFUME A.- Floral citrus Perfume ingredients% by weight Immediate diffusion ingredients Citral 4 Citronellol 5 Citronellil nitrile 3 para-cymene 2 Decilaldehyde 1 Dihydro ircenol 15 Geranil nitrile 3 alpha-Ionone 2 Linalinium acetate 5 gamma-Methylionone 3 My dinner 1.5 Orange terpenes 15 be a -pineno 3 Delayed differed ingredients Aldehyde anieic 1 beta-ga ma-hexenol 0.3 Acetic acid cis-3-hexenilo 0.2 cie-Jasmona 1 Linalool 8 Nerol 3 alpha-Terpineol 4 Other Ingredients Amyl Salicylate 1 Hexylcinamic Aldehyde 5 Hexyl 3-Tertiary Salicylate bucinal 5 Patchouli 1 Fenilhexanol 5 Total 100 PERFUME B. ~ - Floral rose Perfume ingredients% by weight Ingredients of immediate diffusion Citronelol 15 Citronelil nitrile 3 Decylaldehyde 1 Dihydromyrcenol. 5 Dimethyloctanol 5 Diphenyl oxide 1 Geranyl Acetate 3 Geranyl formate 3 alpha-ionone 3 Bearbornyl Acetate 4 ga ma-Methylionone 4 P.T. bucinal 10 Geraniol delayed-release ingredient 7 Phenylethyl alcohol 15 Terpineol 5 Other Ingredient Aurantiol 3 Benzophenone 3 Hexyl cinnamic aldehyde 10 Total 100 PERFUME C- Natural lime Perfume ingredients% by weight Immediate diffusion ingredients Canfeno __ 1 Ariofileno 1 para-cymeno 1 Acetate of geranilo 2 d-Limonene 49 Mirceno 2 al a-Pineno 1.5 beta-Pineno 2 Terpinolene 20 Delayed differed ingredients Eucalyptol 1.5 Phenolic alcohol 1 Linelool 3 Terpínen-4-ol 2 Terpineol 10 Other ingredients Bisaboleno 3 Total 100 PERFUME D.- Natural lemon Perfume ingredients% by weight Ingredients of immediate diffusion Citral 4 Fruteno 15 d-Limonene 50 Acetal of linalyl 6 alpha-Pineno 4 beta-Pineno 3 Other Ingredients Methyl Dihydrojasmonate 18 Total 100 PERFUME E.- Citrus lime Perfume ingredients% by weight Immediate diffusion ingredients Citral 3 Citronelil nitrile 2 Decilaldehyde 0.5 Dihydromircinol 10 Frutene 5 Geranil nitrile 3 Linalyl Acetate 5 Octylaldehyde 0.5 Orange terpenes 30 para-ci eno __ 1.5 Phenilhexanol 5 alfa-Pineno 2.5 Terpinyl acetate 2 Tetrahydrolinalool 3 Verdox 1 Delayed Release Ingredients Benzyl Propionate 2 Eucalyptol 2 Alcohol chelic 0.5 Flower acetate 7 beta-gamma-hexenol 0.5 Linalool 7 alpha-terpineol 2 Other ingredients Methyl dihydrojasmonate 5 total 100 EXAMPLE I INGREDIENTE Formula -% by weight% by weight Butoxipropanol 2.B »m S Ethanol 2.8 2.8 Sodium dodecyl sulfate 0.13 0.20 Triodiculide of eodium 0.11 0.08 Eodium bicarbonate 0.02 0 Sodium carbonate 0.02 0 Perfume A 0.05 Perfume B 0.10 Water rest rest EXAMPLE II Formula Component Ieopropanol 2.00 4.00 .00 Ethanol 2.00 5.00 Butoxipropanol 3.00 1.00 4.00 Alkyl sulfate 0.20 of 12 carbon atoms Alkyl sulfate 0.08 0.10 of 14 carbon atoms Cocoamidopro ilbetam 0.20 0.10 Benceneulfonate of alkyl 0.10 linear of Cß_iß Sodium laurethulfate 0.25 Ethoxylate of alcohol (eodol < = * > 91-6 ) 0.04 Sodium bicarbonate 0.02 00..0066 0.04 Monoethanolamine 0. 1 Tartaric acid 0.03 Perfume A 0.20 Perfume B 0.05 Perfume C 0.025 Perfume D 0.05 Perfume E 0.025 PVNO (Molecular weight pro 0.15 0.25 medium around 10,000) Water rest rest rest rest rest

Claims (7)

NOVELTY OF THE INVENTION CLAIMS

1. - A liquid, aqueous detergent composition for hard surfaces »having improved cleaning characteristics and good film / streaking characteristics» characterized in that it comprises: (A) about 0.001% to 3% of an immte diffusion perfume composition » comprising at least about 50% of immte diffusion perfume ingrnts selected from the group consisting of ingrnts having a boiling point lower than about 260 ° C and a ClogP of at least about 3; and wherein the perfume composition comprises at least 5 different perfume ingrnts of immte diffusion; (B) about 0.001% to 2% detergent surfactant system selected from the group consisting of anionic surfactant and surfactant agents and amphoteric detergents, which include the surfactant surfactants; and mixtures; and (C) about 0.5% to 30% hydrophobic solvent; (D) the balance being an aqueous solvent system comprising water and, optionally, a non-aqueous polar solvent, with only minimal cleaning action, selected from the group that connects methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, glycol ether having a hydrogen binding parameter of more than 7.7, and their mixtures, and any minor ingrnts.

2. The composition according to claim 1 »further characterized in that the immte diffusion perfume composition does not contain any individual ingrnt at a level of more than about 60% by weight of the perfume composition.

3. The composition according to claim 2 »further characterized in that component B is selected from the group consisting of: (1) about 0.001% to 2% detergent-containing detergent agent having the generic formula: RN (A) (CHa) "N (a) (CHa)" C or O) 0M wherein R is a hydrophobic portion of 6 to 10 carbon atoms "which includes the fatty acyl portion containing about 6 to 10 carbon atoms which» in combination with the nitrogen atom forms an amido group, R1 is hydrogen or an alkyl group of 1 to 2 carbon atoms; R55 is alkyl of 1 to 3 carbon atoms, carboxyl or ethyl or hydroxyethyl; each n is an integer from 1 to 3; each p is an integer from 1 to 2; and each M is a water soluble cation, selected from alkali metal »ammonium» alkanolammonium and mixture of estoe cationee; (2) about 0.001% to 2% detergent-containing detergent agent having the generic formula: R3CC (O) -N (R- ») - (CR = S)" 1 ^ Re) a »*» - (CRßa ) 1-Y '- »wherein each R3 is an alkyl or alkylene group containing about 10 to IB carbon atoms: each (- *) and (ß) is selected from the group consisting of hydrogen» methyl » ethyl »propyl. ethyl or propyl substituted with hydroxy and mixtures thereof; each (Rs) is selected from the group consisting of hydrogen and hydroxy groups, with no more than about one hydro group in any portion (C * ^) ^!; is 0 or i; each A and is a number from l to around 4; and Y is a carboxylate or sulfonate group; and (3) about 0.001% to 2.0% detergent surfactant having the generic formula: ß- (Rlo) o_1-S03'-, "*" wherein Rβ is an alkyl chain of 6 to 20 carbon atoms; R 10 is an alkylene chain of 6 to 20 carbon atoms; a phenylene group C 1 H 4 O; and M is the same as before; and (4) mixtures of the miemoe.

4. The composition according to claim 3, further characterized in that the ingrnt of immte release perfume is selected from the group that you connected of: halo-osimeno, allyl heptoate, anethole »benzyl butyrate» camphene, carvasrol »beta- caryophyllene »c-3-hexanyl tiglato, citral (Neral), citronellol, cyclohexyl ethylacetate, decylaldehyde» dihydromyrcenol »dihydromyrcenyl acetate, dimethyloctanol, diphenyl oxide» dodecalactone »ethyl? ethyl methylglycate acid» phenyl acetate, gamma-methylionone, gamma-n-rnethionione, ga ma-nonalactone, geranyl acetate, geranyl formate, geranyl butyrate, geranylnitrile, hexanyl isobutyrate, henilopentanopentanoate. hexyl tiglato, alpha-ionone. beta-ionone »gamma-ionone» alpha-irona. isobornyl acetate »isobutyl benzoate» isononyl acetate »isononyl alcohol, isobutylquinoline» iso entol »para-isopropyl phenylacetaldehyde» isopulegol »lauric aldehyde (dodecanal)» lilial (pt-bucinal) »d-liroionene» linalyl acetate »acetate entyl »methylcavicol» alpha-iso- "gamma" -methylionone »methylnonylacetaldehyde. ethyl ethyl acetaldehyde »ircene», neryl acetate, nonyl acetate »nonilaldehyde octylaldehyde» orange terpene (d-limonene) »para-ci ene. phenylheptanol »phenylhexanol, alpha-pinene, beta-pinene» alphaterpinene »gamma-terpinene» terpinolene »terpinyl acetate» tetrahydrolinalool »tetrahydromyrcenol» tonalid »undedenal» veratrol »verdox and vertene ?.

5. The composition according to claim 3, further characterized in that the immediate release perfume composition also includes delayed release perfume ingredients selected from the group consisting of perfume ingredients having a boiling point of less than 260 °. C and a ClogP of less than about 3. wherein the ratio of immediate release perfume ingredients to delayed release perfume ingredients is at least 1: 1,

6. The composition according to claim 5 »further characterized because the delayed release perfume ingredients are selected from the group consisting of: allyl caproate, amyl acetate »amyl propionate» anisic aldehyde, anisole »benzaldehyde» benzyl acetate »benzylacetone» benzyl alcohol »benzyl formate» isoform benzyl valerate »benzyl propionate» beta-gamma-hexenol »camphor gum» levo-carveol »d-carvone levo-sarvone »cinnamic alcohol» cinnamyl formate »cis-jasmone» cis-3-hexenyl acetate, cuminic alcohol »cuminic aldehyde» cyclal C »dimethylbenzylcarbinol, dimethylbenzylcarbinyl acetate» ethyl acetate »ethyl acetoacetate» ethylacetone, benzoate ethyl, ethyl butyrate, ethylhexyl ketone »ethyl phenylacetate» eucalyptol »eugenol» phenolic alcohol. flower acetate (tricyclodecenyl acetate) frutene (tricyclodecenyl propionate), geraniol »hexenol» hexenyl acetate »hexyl acetate» hexyl formate. Hydratropic alcohol »Hydroxycitronella» Indole. isoamyl alcohol. iso -oneone - isopulegyl acetate »isoquinolma. ligustraX linalool. Linalool oxide. linalyl formate »menthone, methylacetophenone. Methyl amyl ketone, methyl anthranilate, methyl benzoate. methyl benzyl acetate, ethyleugenol, ethylheptenone »ethylheptin carbonate, methylheptyl ketone» ine-ethylhexyl ketone »ethylphenylcarbinyl acetate» methyl ealicylate, methyl-N-methyl anthranilate, nerol, octelactone, octyl octanol-2 alcohol), para-creamp, methyl ether of para-creeyl, para-etoxyacetophenone. para-ethylacetate nona, f-noxyethanol, phenylacetaldehyde, phenyl ethylacetate, phenylethyl alcohol, phenylethyldi ethylcarbinol, phenyl acetate. propyl butyrate »pulegone» rose oxide »safrola» 4-terpineol. alpha-terpineol and viridin. 7 - The composition according to claim 1 »further characterized in that the immediate release perfume composition has at least 555 immediate release perfume ingredients. 8. The composition according to claim 7, further characterized in that the immediate release perfume composition has at least 60% immediate release ingredient. 9. The composition according to claim 8, further characterized in that the instant release perfume composition has at least 70% immediate release ingredients. 10. The composition according to claim 1, characterized, in addition, because the level of the immediate release perfume composition is about 0.01% to 1% by weight of the total composition. 11. The composition according to claim 10, further characterized in that the level of the immediate release perfume composition is approximately 0.01% to 0.5%. 12. The composition according to claim 11 »further characterized in that the immediate release perfume composition has at least 70% immediate release perfume ingredients. 13. The method for cleaning glass with an effective amount of the composition of claim 1. RSSJMEH PE TrfA INVEMCoy The present invention relates to a composition for cleaning glass comprising: about 0.001% to 3% of an immediate release perfume composition comprising at least about 50% of immediate release perfume ingredients »selected from the group that consists of: ingredients that have a boiling point of menoe of about 260 ° C and a ClogP of at least about 3; and wherein the perfume composition comprises when less than 5 different ingredients of immediate release perfume; about 0.001% to 2% of a system of detergent surfactant selected from the group consiete of agentee teneioactivoe aniónicoe »detergentee teneioactivos agents anfóteroe including switteriónicoe surfactants and eue mezclae" about 0.5% to 30% of hydrophobic solvent being the remainder an aqueous solvent system comprising water and optionally a non-aqueous polar solvent with only minimal cleaning action. selected from the group you have methanol, ethanol »isopropanol» ethylene glycol, propylene glycol. Glycolic ethers having a hydrogen bonding parameter of 7.7 and more, and any minor ingredients. These compositions have good film / streaking characteristics and provide an immediate release perfume effect. CR / cgt * P98 / 1010F