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MX377235B - Proceso mejorado para preparar bifenilanilidas y bifenilanilinas cloradas. - Google Patents

Proceso mejorado para preparar bifenilanilidas y bifenilanilinas cloradas.

Info

Publication number
MX377235B
MX377235B MX2016000621A MX2016000621A MX377235B MX 377235 B MX377235 B MX 377235B MX 2016000621 A MX2016000621 A MX 2016000621A MX 2016000621 A MX2016000621 A MX 2016000621A MX 377235 B MX377235 B MX 377235B
Authority
MX
Mexico
Prior art keywords
sup
sub
formula
biphenylanilines
improved process
Prior art date
Application number
MX2016000621A
Other languages
English (en)
Other versions
MX2016000621A (es
Inventor
Jens Dietmar Heinrich
Lars Rodefeld
Michael Dockner
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of MX2016000621A publication Critical patent/MX2016000621A/es
Publication of MX377235B publication Critical patent/MX377235B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/64—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/66—Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5004—Acyclic saturated phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5407—Acyclic saturated phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)

Abstract

La presente invención se relaciona con un proceso para preparar bifenilanilidas sustituidas de la fórmula (I) (Ver Fórmula) en la que R1 se selecciona de un grupo amino protegido, NO2, NH2 y NHR3, en la que un compuesto de la fórmula II (ver Fórmula) se hace reaccionar en presencia de una base y de una sal de paladio, en presencia de un ligando de fosfina de la fórmula (V) como ligando complejo (ver Fórmula) o una sal del mismo, en un solvente, con un compuesto organoboro de la fórmula (III) (ver Fórmula) en la que todos los sustituyentes son como se define en la descripción.
MX2016000621A 2013-07-23 2014-07-18 Proceso mejorado para preparar bifenilanilidas y bifenilanilinas cloradas. MX377235B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13177583 2013-07-23
PCT/EP2014/065463 WO2015011032A1 (de) 2013-07-23 2014-07-18 Verbessertes verfahren zur herstellung von chlorierten biphenylaniliden und biphenylanilinen

Publications (2)

Publication Number Publication Date
MX2016000621A MX2016000621A (es) 2016-05-26
MX377235B true MX377235B (es) 2025-03-07

Family

ID=48808249

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016000621A MX377235B (es) 2013-07-23 2014-07-18 Proceso mejorado para preparar bifenilanilidas y bifenilanilinas cloradas.

Country Status (12)

Country Link
US (2) US9868694B2 (es)
EP (2) EP3418284A1 (es)
JP (2) JP6518242B2 (es)
KR (1) KR102310474B1 (es)
CN (1) CN105392791B (es)
BR (1) BR112016000968B1 (es)
DK (1) DK3024836T3 (es)
ES (1) ES2687950T3 (es)
IL (1) IL243680B (es)
MX (1) MX377235B (es)
TW (1) TWI658031B (es)
WO (1) WO2015011032A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112016000968B1 (pt) * 2013-07-23 2021-05-18 Bayer Cropscience Aktiengesellschaft processo para a preparação de bifenilanilidas halogenadas
EP3500551B1 (en) * 2016-08-22 2021-11-10 Basf Se Process for preparing substituted biphenyls
ES2880323T3 (es) * 2017-02-14 2021-11-24 Basf Se Proceso para la preparación de bifenilos sustituidos
FR3064496A1 (fr) 2017-03-31 2018-10-05 Centre National De La Recherche Scientifique Utilisation de materiaux naturels d'origine vegetale riches en acides phenoliques pour la mise en oeuvre de reaction de chimie organique et le recyclage de catalyseurs
CN107556199A (zh) * 2017-09-24 2018-01-09 杨子辉 一种3,4‑二氯‑2‑氨基‑5‑氟联苯的制备方法
DE102018122708B4 (de) * 2018-09-17 2025-02-20 Novaled Gmbh Organische elektronische Vorrichtung, organisches halbleitendes Material und eine Boranverbindung
CN112955586B (zh) 2018-10-29 2024-10-29 C2Cnt有限责任公司 持续的、容易分离的熔融碳酸盐电解阴极产物
CN114945552A (zh) * 2019-07-19 2022-08-26 阿达玛马克西姆有限公司 制备联苯胺的方法
WO2022031949A1 (en) 2020-08-06 2022-02-10 C2Cnt Llc Sustainable, facile separation of the molten carbonate electrolysis cathode product
JP7591748B2 (ja) * 2020-11-16 2024-11-29 国立研究開発法人産業技術総合研究所 有機生成物の製造方法
US20230159587A1 (en) * 2021-03-22 2023-05-25 L-Base Co., Ltd. Pharmaceutical composition for preventing or treating cancer
WO2022243099A1 (en) 2021-05-19 2022-11-24 Basf Se Process for preparing substituted biphenyls via suzuki coupling of aryl-chlorides

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9708047A (pt) 1996-03-13 1999-07-27 Basf Ag Processo para a preparação de nitrobifenilas
WO1998035967A2 (en) 1997-02-18 1998-08-20 Neurocrine Biosciences, Inc. Biazacyclic crf antagonists
US6307087B1 (en) 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
FR2801884A1 (fr) 1999-12-06 2001-06-08 Rhodia Chimie Sa Procede de preparation d'un compose polyaromatique
WO2003066643A1 (fr) * 2002-02-04 2003-08-14 Hokko Chemical Industry Co., Ltd. Procede de production de phosphine tertiaire a groupe hydrocarbone volumineux lie
DE10215292A1 (de) 2002-02-19 2003-08-28 Bayer Cropscience Ag Disubstitutierte Pyrazolylcarbocanilide
DE10252273A1 (de) * 2002-11-11 2004-05-27 Bayer Ag Polyhalogenalkylaryle
CN100548948C (zh) * 2002-12-09 2009-10-14 麻省理工学院 金属配体以及以此为基础的改良的金属催化方法
KR20050085473A (ko) * 2002-12-09 2005-08-29 메사추세츠 인스티튜트 오브 테크놀로지 금속에 대한 리간드 및 이를 기초로 하는 금속 촉매작용에의한 방법
CN1886411B (zh) * 2003-11-28 2010-09-08 北兴化学工业株式会社 硼酸磷酯化合物的制造方法,新型硼酸磷酯化合物及其使用方法
AR052930A1 (es) * 2005-03-02 2007-04-11 Basf Ag Procedimiento para la preparacion de bifenilos sustituidos
DE102005022362B4 (de) * 2005-05-10 2016-12-15 Studiengesellschaft Kohle Mbh Verfahren zur decarboxylierenden C-C Verknüpfung von Carbonsäuren mit Kohlenstoffelektrophilen
CN101374799B (zh) * 2006-06-01 2012-05-23 巴斯夫欧洲公司 制备取代联苯的方法
AU2007267055A1 (en) 2006-06-01 2007-12-06 Basf Se Process for preparing substituted biphenyls
EP2008991A1 (de) * 2007-06-29 2008-12-31 Bayer CropScience AG Verfahren zur Herstellung von Biarylen
EP2119697A1 (en) * 2008-05-09 2009-11-18 Bayer CropScience AG Process for preparing substituted biphenylanilides
EP2473476B1 (de) * 2009-08-31 2015-01-14 Bayer Intellectual Property GmbH Tetraarylborat verfahren zur herstellung von substituierten biphenylen
CA2797533A1 (en) * 2010-04-27 2011-11-10 Calcimedica, Inc. Compounds that modulate intracellular calcium
BR112016000968B1 (pt) * 2013-07-23 2021-05-18 Bayer Cropscience Aktiengesellschaft processo para a preparação de bifenilanilidas halogenadas

Also Published As

Publication number Publication date
JP2019108352A (ja) 2019-07-04
KR20160033702A (ko) 2016-03-28
ES2687950T3 (es) 2018-10-30
US9868694B2 (en) 2018-01-16
JP6518242B2 (ja) 2019-05-22
JP2016525526A (ja) 2016-08-25
IL243680A0 (en) 2016-04-21
KR102310474B1 (ko) 2021-10-07
US20180093942A1 (en) 2018-04-05
TW201546031A (zh) 2015-12-16
CN105392791B (zh) 2019-02-22
TWI658031B (zh) 2019-05-01
IL243680B (en) 2020-06-30
BR112016000968B1 (pt) 2021-05-18
BR112016000968A2 (pt) 2017-08-29
US20160280635A1 (en) 2016-09-29
WO2015011032A1 (de) 2015-01-29
EP3418284A1 (de) 2018-12-26
DK3024836T3 (en) 2018-10-08
MX2016000621A (es) 2016-05-26
EP3024836B1 (de) 2018-07-11
EP3024836A1 (de) 2016-06-01
CN105392791A (zh) 2016-03-09

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