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MX2022003724A - Polimerizacion de alta productividad con catalizador de ligando de ariloxi eter. - Google Patents

Polimerizacion de alta productividad con catalizador de ligando de ariloxi eter.

Info

Publication number
MX2022003724A
MX2022003724A MX2022003724A MX2022003724A MX2022003724A MX 2022003724 A MX2022003724 A MX 2022003724A MX 2022003724 A MX2022003724 A MX 2022003724A MX 2022003724 A MX2022003724 A MX 2022003724A MX 2022003724 A MX2022003724 A MX 2022003724A
Authority
MX
Mexico
Prior art keywords
high productivity
ligand catalyst
ether ligand
ethylene
aryloxy ether
Prior art date
Application number
MX2022003724A
Other languages
English (en)
Inventor
Qinyan Wang
Peter Zoricak
Cheng Fan
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of MX2022003724A publication Critical patent/MX2022003724A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168—Tetra- or multi-dentate ligand
    • C08F4/64186—Dianionic ligand
    • C08F4/64193—OOOO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)

Abstract

La copolimerización de etileno con un comonómero opcional se lleva a cabo en la presencia de un catalizador que tiene una estructura de ligando de ariloxiéter específica. El proceso permite conversiones muy altas de etileno a polietileno con tiempos de residencia muy cortos cuando se lleva a cabo en condiciones de presiones de al menos 10.3 MPa y altas concentraciones de alimentación de etileno de 70 a 150 gramos por litro.
MX2022003724A 2019-10-01 2020-09-28 Polimerizacion de alta productividad con catalizador de ligando de ariloxi eter. MX2022003724A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962908738P 2019-10-01 2019-10-01
PCT/IB2020/059052 WO2021064546A1 (en) 2019-10-01 2020-09-28 High productivity polymerization with aryloxy ether ligand catalyst

Publications (1)

Publication Number Publication Date
MX2022003724A true MX2022003724A (es) 2022-04-26

Family

ID=72840582

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022003724A MX2022003724A (es) 2019-10-01 2020-09-28 Polimerizacion de alta productividad con catalizador de ligando de ariloxi eter.

Country Status (6)

Country Link
US (1) US12297303B2 (es)
EP (1) EP4038118B1 (es)
CA (1) CA3151657A1 (es)
ES (1) ES2967889T3 (es)
MX (1) MX2022003724A (es)
WO (1) WO2021064546A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12338304B2 (en) * 2019-10-01 2025-06-24 Nova Chemicals (International) S.A. Control of unsaturation in polymers produced in solution process

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5589555A (en) 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
EP2024401B1 (en) * 2006-05-17 2015-02-25 Dow Global Technologies LLC High temperature polyethylene solution polymerization process
TW200936619A (en) * 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US8420760B2 (en) * 2007-11-19 2013-04-16 Dow Global Technologies Llc Long chain branched propylene-alpha-olefin copolymers
ES2430540T3 (es) * 2009-06-05 2013-11-21 Dow Global Technologies Llc Procedimiento para fabricar copolímeros ramificados de cadena larga (LCB), de bloque, o interconectados de etileno
US8722817B2 (en) * 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
US8629214B2 (en) * 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
US20110003940A1 (en) * 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
JP5858935B2 (ja) * 2010-03-02 2016-02-10 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマー組成物
KR102251151B1 (ko) * 2012-12-27 2021-05-13 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체를 제조하기 위한 중합 방법
US9527941B2 (en) * 2012-12-27 2016-12-27 Dow Global Technologies Llc Polymerization process for producing ethylene based polymers
BR112015015544A2 (pt) 2012-12-27 2017-07-11 Dow Global Technologies Llc polímero a base de etileno
EP2938644B1 (en) * 2012-12-27 2019-08-28 Dow Global Technologies LLC Process for the polymerization of ethylene and octene
SG11201610690VA (en) * 2014-06-30 2017-01-27 Dow Global Technologies Llc Ethylene-based polymers
JP6985015B2 (ja) * 2014-06-30 2021-12-22 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合用の触媒系
JP6709789B6 (ja) * 2014-12-31 2020-07-22 ダウ グローバル テクノロジーズ エルエルシー ポリオレフィン組成物及びその生成方法
WO2017004456A1 (en) * 2015-06-30 2017-01-05 Dow Global Technologies Llc A polymerization process for producing ethylene based polymers
CN108377649B (zh) * 2015-09-30 2021-04-23 陶氏环球技术有限责任公司 用于产生乙烯类聚合物的聚合方法
BR112019005285B8 (pt) * 2016-09-28 2024-01-09 Dow Global Technologies Llc Filme soprado de múltiplas camadas
US10442920B2 (en) * 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations

Also Published As

Publication number Publication date
CA3151657A1 (en) 2021-04-08
EP4038118A1 (en) 2022-08-10
BR112022005846A2 (pt) 2022-06-21
EP4038118C0 (en) 2023-10-25
EP4038118B1 (en) 2023-10-25
US20220340699A1 (en) 2022-10-27
US12297303B2 (en) 2025-05-13
ES2967889T3 (es) 2024-05-06
WO2021064546A1 (en) 2021-04-08

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