MX2019011600A - Poli(alquilen) guanidinas homogeneas y metodo para la produccion de las mismas. - Google Patents
Poli(alquilen) guanidinas homogeneas y metodo para la produccion de las mismas.Info
- Publication number
- MX2019011600A MX2019011600A MX2019011600A MX2019011600A MX2019011600A MX 2019011600 A MX2019011600 A MX 2019011600A MX 2019011600 A MX2019011600 A MX 2019011600A MX 2019011600 A MX2019011600 A MX 2019011600A MX 2019011600 A MX2019011600 A MX 2019011600A
- Authority
- MX
- Mexico
- Prior art keywords
- alkylene
- poly
- guanidine
- temperature
- guanidines
- Prior art date
Links
- -1 poly(alkylene) Polymers 0.000 title abstract 8
- 229920001484 poly(alkylene) Polymers 0.000 title abstract 8
- 150000002357 guanidines Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical class NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 13
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 6
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 6
- 125000005263 alkylenediamine group Chemical group 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 4
- 125000002947 alkylene group Chemical group 0.000 abstract 3
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La invención se relaciona con un método para la producción de poli(alquilen) guanidinas, que comprende al menos los siguientes pasos: a) proporcionar una alquilen diamina de la formula NH2-(CH2)m-NH2 donde m = un número entero de 4-12, en particular 6-10 en un recipiente de reacción y calentar la alquilen diamina a una temperatura igual o mayor que la temperatura de fusión de la alquilen diamina respectiva, típicamente a una temperatura en el intervalo de 25°C a 115°C, preferiblemente de 55°C a 110°C, como resultado de lo cual se forma una masa fundida de la alquilen diamina; b) agregar por porciones una sal de guanidinio (en forma sólida, en particular de partículadas), en particular HClde guanidinio y hacer reaccionar con la alquilen diamina hasta que concluya la formación de monómeros de alquilen(guanidina); c) hacer reaccionar los monómeros formados en el paso b) a al menos la temperatura mínima a la cual comienza la polimerización hacia la poli(alquilen)guanidina deseada hasta que concluya la formación de la poli(alquilen)guanidina; donde los pasos a) y b) para la formación de monómeros de alquilen(guanidina) son efectuados a una temperatura por debajo de la temperatura mínima de polimerización y todos los pasos del método son llevados a cabo mientras se agita. Un aspecto de la invención se relaciona con las poli(alquilen) guanidinas homogéneas que son obtenidas con el método descrito anteriormente las cuales tienen un contenido de al menos 85% en peso, en particular al menos 90% o 97%, de la poli(alquilen) guanidina lineal deseada con 3-14, preferiblemente 4-10, unidades monoméricas de alquileno en la molécula como el producto principal y un contenido de subproductos, en particular isómeros ramificados de esta poli(alquilen) guanidina, de a lo más 15%, 10%, 5% o 3%.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17000505.2A EP3381967A1 (de) | 2017-03-28 | 2017-03-28 | Homogene poly(alkylen)guanidine und verfahren zu deren herstellung |
| PCT/EP2018/057809 WO2018178093A1 (de) | 2017-03-28 | 2018-03-27 | Homogene poly(alkylen)guanidine und verfahren zu deren herstellung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019011600A true MX2019011600A (es) | 2020-02-17 |
Family
ID=58461031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019011600A MX2019011600A (es) | 2017-03-28 | 2018-03-27 | Poli(alquilen) guanidinas homogeneas y metodo para la produccion de las mismas. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US11926703B2 (es) |
| EP (2) | EP3381967A1 (es) |
| JP (1) | JP7152467B2 (es) |
| CN (1) | CN110662787B (es) |
| AU (1) | AU2018241873B2 (es) |
| BR (1) | BR112019020242B1 (es) |
| CA (1) | CA3058278C (es) |
| EA (1) | EA201992279A1 (es) |
| ES (1) | ES2934253T3 (es) |
| HU (1) | HUE061001T2 (es) |
| MX (1) | MX2019011600A (es) |
| PL (1) | PL3601412T3 (es) |
| PT (1) | PT3601412T (es) |
| SA (1) | SA519410195B1 (es) |
| SG (1) | SG11201909065PA (es) |
| WO (1) | WO2018178093A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109467698B (zh) * | 2018-10-10 | 2019-08-30 | 桂林新先立抗菌材料有限公司 | 一种抗菌聚合物及其制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2325586A (en) * | 1940-03-21 | 1943-08-03 | Du Pont | Polymeric guanidines and process for preparing the same |
| KR100230978B1 (ko) * | 1997-03-07 | 1999-11-15 | 남창우 | 알킬기가 축쇄된 폴리헥사메틸렌구아니딘염과이의 제조방법 및 이의 항균제로서의 용도 |
| AT406163B (de) | 1998-04-22 | 2000-03-27 | P O C Oil Industry Technology | Verfahren zur gewinnung eines desinfektionsmittels |
| JP3636426B2 (ja) * | 1999-03-29 | 2005-04-06 | 日華化学株式会社 | インクジェット記録用被記録材 |
| ITRM20020529A1 (it) * | 2002-10-18 | 2004-04-19 | Franco Staino | Polimeri sterilizzanti, processo di loro preparazione ed uso. |
| AT505102B1 (de) * | 2004-11-05 | 2010-05-15 | Schmidt Oskar | Biozid, insbesondere fungizid wirkendes mittel |
| RU2318803C1 (ru) * | 2006-07-24 | 2008-03-10 | Общество с ограниченной ответственностью "Международный институт эколого-технологических проблем" | Способ получения соли полигуанидина |
| CN101173041A (zh) | 2007-10-19 | 2008-05-07 | 华南理工大学 | 高分子量胍盐和多元胺抗菌型聚合物及其制备方法与应用 |
| DE102009052667A1 (de) | 2009-11-12 | 2011-05-19 | Philipps-Universität Marburg | Polymere oder oligomere Wirkstoffe mit biozider Wirkung, Verfahren zu deren Herstellung und Zusammensetzung umfassend einen polymeren oder oligomeren Wirkstoff |
| DE102009052725A1 (de) * | 2009-11-12 | 2011-05-19 | B. Braun Melsungen Ag | Verwendung von Polyoxyalkylendiamin-basierten Polyguanidinderivaten für medizinische Artikel |
| DE102009060249B4 (de) | 2009-12-23 | 2013-09-12 | Vladimir Lipovich | Verfahren zur Herstellung des Desinfektionsmittels Polyhexamethylenguanidinhydroiodid |
| EP2386589A1 (en) * | 2010-04-23 | 2011-11-16 | Centre National de la Recherche Scientifique (C.N.R.S) | Novel antimicrobial composition, use and preparation thereof |
| US9403944B2 (en) * | 2012-01-12 | 2016-08-02 | John L. Lombardi | Antipathogenic guanidinium copolymer |
| RU2489452C1 (ru) | 2012-04-26 | 2013-08-10 | Общество с ограниченной ответственностью "Компания Вереск" | Способ получения полигексаметиленгуанидин гидрохлорида |
-
2017
- 2017-03-28 EP EP17000505.2A patent/EP3381967A1/de not_active Withdrawn
-
2018
- 2018-03-27 PL PL18713241.0T patent/PL3601412T3/pl unknown
- 2018-03-27 SG SG11201909065P patent/SG11201909065PA/en unknown
- 2018-03-27 EP EP18713241.0A patent/EP3601412B1/de active Active
- 2018-03-27 US US16/499,292 patent/US11926703B2/en active Active
- 2018-03-27 CN CN201880034677.3A patent/CN110662787B/zh active Active
- 2018-03-27 CA CA3058278A patent/CA3058278C/en active Active
- 2018-03-27 WO PCT/EP2018/057809 patent/WO2018178093A1/de not_active Ceased
- 2018-03-27 AU AU2018241873A patent/AU2018241873B2/en active Active
- 2018-03-27 BR BR112019020242-0A patent/BR112019020242B1/pt active IP Right Grant
- 2018-03-27 HU HUE18713241A patent/HUE061001T2/hu unknown
- 2018-03-27 EA EA201992279A patent/EA201992279A1/ru unknown
- 2018-03-27 JP JP2020503087A patent/JP7152467B2/ja active Active
- 2018-03-27 MX MX2019011600A patent/MX2019011600A/es unknown
- 2018-03-27 PT PT187132410T patent/PT3601412T/pt unknown
- 2018-03-27 ES ES18713241T patent/ES2934253T3/es active Active
-
2019
- 2019-09-26 SA SA519410195A patent/SA519410195B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA3058278C (en) | 2024-02-13 |
| PL3601412T3 (pl) | 2023-06-19 |
| US11926703B2 (en) | 2024-03-12 |
| AU2018241873A1 (en) | 2019-11-14 |
| EP3601412B1 (de) | 2022-09-28 |
| HUE061001T2 (hu) | 2023-05-28 |
| WO2018178093A1 (de) | 2018-10-04 |
| SA519410195B1 (ar) | 2022-12-08 |
| EA201992279A1 (ru) | 2020-02-28 |
| BR112019020242A2 (pt) | 2020-04-22 |
| SG11201909065PA (en) | 2019-11-28 |
| JP2020512476A (ja) | 2020-04-23 |
| CA3058278A1 (en) | 2018-10-04 |
| PT3601412T (pt) | 2022-12-27 |
| EP3381967A1 (de) | 2018-10-03 |
| CN110662787A (zh) | 2020-01-07 |
| ES2934253T3 (es) | 2023-02-20 |
| JP7152467B2 (ja) | 2022-10-12 |
| EP3601412A1 (de) | 2020-02-05 |
| CN110662787B (zh) | 2022-05-31 |
| BR112019020242B1 (pt) | 2023-02-23 |
| US20210079159A1 (en) | 2021-03-18 |
| AU2018241873B2 (en) | 2023-07-13 |
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