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MX2019011258A - Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida. - Google Patents

Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida.

Info

Publication number
MX2019011258A
MX2019011258A MX2019011258A MX2019011258A MX2019011258A MX 2019011258 A MX2019011258 A MX 2019011258A MX 2019011258 A MX2019011258 A MX 2019011258A MX 2019011258 A MX2019011258 A MX 2019011258A MX 2019011258 A MX2019011258 A MX 2019011258A
Authority
MX
Mexico
Prior art keywords
liquid phase
alpha
alcohols
oxidation
preparation
Prior art date
Application number
MX2019011258A
Other languages
English (en)
Inventor
Keller Andreas
Vautravers Nicolas
Henrique Teles Joaquim
Braunsmann Kirsten
Bauer Stefan
Joerg Ufer Andreas
Bosch Marco
Luense Vera
John Zakzeski Joseph
Fenyn Michaela
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2019011258A publication Critical patent/MX2019011258A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/38—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a primary hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C07C45/39—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups being a secondary hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Proceso para la preparación de aldehídos alfa, beta insaturados mediante la oxidación de alcoholes en presencia de una fase líquida, en donde la fase líquida contiene de 0.1 a menos de 25% en peso de agua, y en donde la fase líquida contiene al menos 25% en peso de alcoholes de la Fórmula general (II) y aldehídos alfa, beta insaturados de la Fórmula general (I), y en donde el oxidante es oxigeno y/o peróxido de hidrógeno.
MX2019011258A 2017-03-20 2018-03-12 Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida. MX2019011258A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP17161798 2017-03-20
EP17178052 2017-06-27
EP17209505 2017-12-21
PCT/EP2018/056008 WO2018172110A1 (en) 2017-03-20 2018-03-12 Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase

Publications (1)

Publication Number Publication Date
MX2019011258A true MX2019011258A (es) 2019-12-05

Family

ID=61617035

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019011258A MX2019011258A (es) 2017-03-20 2018-03-12 Proceso para la preparacion de aldehidos alfa, beta insaturados mediante oxidacion de alcoholes en presencia de una fase liquida.

Country Status (6)

Country Link
US (1) US10875821B2 (es)
JP (1) JP7086096B6 (es)
CN (2) CN117603025A (es)
MX (1) MX2019011258A (es)
MY (1) MY194475A (es)
WO (1) WO2018172110A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10532970B2 (en) 2016-06-29 2020-01-14 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
WO2020048852A1 (en) * 2018-09-07 2020-03-12 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
WO2020048855A1 (en) * 2018-09-07 2020-03-12 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
EP3967394A4 (en) * 2020-06-19 2022-04-20 Lg Chem, Ltd. DEHYDROGEN CATALYST, PROCESS FOR ITS PRODUCTION AND PROCESS FOR PRODUCTION OF ALKEN USING THE SAME
CN116997541A (zh) * 2021-03-19 2023-11-03 花王株式会社 氧化物的制造方法、和Pt/Bi复合催化剂的制造方法
US20250340502A1 (en) 2022-05-20 2025-11-06 Basf Se Purification of an ethylenically unsaturated alcohol stream, preparation of an ethylenically unsaturated aldehyde, in particular prenal, and compounds derived therefrom
WO2024246272A1 (en) * 2023-06-02 2024-12-05 Basf Se Processes for the preparation of citral and interrelated products

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2386509A1 (fr) * 1977-04-05 1978-11-03 Basf Ag Procede de preparation de 3-alkyl-butene-1-als
JPS5838226A (ja) * 1981-08-31 1983-03-05 Sagami Chem Res Center 不飽和カルボニル化合物の製造法
DE19722567A1 (de) 1997-05-28 1998-12-03 Basf Ag Verfahren zur kontinuierlichen technischen Herstellung ungesättigter aliphatischer Aldehyde in einem Rohrbündelreaktor
DE19743621C1 (de) 1997-10-02 1999-03-25 Rwe Dea Ag Verfahren zur Herstellung von Aldehyden und Carbonsäuren durch Oxidation primärer Alkohole
AU2003292698A1 (en) * 2003-01-07 2004-07-29 National Institute Of Advanced Industrial Science And Technology PROCESS FOR PRODUCING Alpha,ss-UNSATURATED CARBONYL COMPOUND
WO2008037693A1 (de) 2006-09-26 2008-04-03 Basf Se Kontinuierliches verfahren zur herstellung von citral
US8173838B2 (en) * 2006-10-03 2012-05-08 Mitsubishi Rayon Co., Ltd. Method for producing at least one of α, β-unsaturated aldehyde and α, β-unsaturated carboxylic acid
CN102336619B (zh) * 2010-07-26 2014-01-29 华东师范大学 一种氧气氧化醇制备醛或酮的方法

Also Published As

Publication number Publication date
WO2018172110A1 (en) 2018-09-27
CN117603025A (zh) 2024-02-27
US10875821B2 (en) 2020-12-29
CN110418779A (zh) 2019-11-05
JP7086096B2 (ja) 2022-06-17
JP2020512319A (ja) 2020-04-23
US20200010393A1 (en) 2020-01-09
MY194475A (en) 2022-11-30
EP3601205A1 (en) 2020-02-05
JP7086096B6 (ja) 2022-07-04
BR112019018099A2 (pt) 2020-03-31
CN110418779B (zh) 2023-12-15

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