MX2019005754A - Composicion de polietileno que tiene indice alto de dilatacion. - Google Patents
Composicion de polietileno que tiene indice alto de dilatacion.Info
- Publication number
- MX2019005754A MX2019005754A MX2019005754A MX2019005754A MX2019005754A MX 2019005754 A MX2019005754 A MX 2019005754A MX 2019005754 A MX2019005754 A MX 2019005754A MX 2019005754 A MX2019005754 A MX 2019005754A MX 2019005754 A MX2019005754 A MX 2019005754A
- Authority
- MX
- Mexico
- Prior art keywords
- polyethylene composition
- expansion
- high index
- lcbi
- mif
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0017—Combinations of extrusion moulding with other shaping operations combined with blow-moulding or thermoforming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Una composición de polietileno particularmente adecuada para producir artículos huecos moldeados por soplado, que tiene las siguientes características: 1) densidad de 0,940 a 0,955 g/cm3, determinada de conformidad con la ISO 1183 a 23°C; 2) relación de MIF/MIP de 12 a 30; 3) Mz de 2.000.000 a 4.500.000 g/mol; 4) ?0.02 de 160.000 a 300.000 Pa.s; 5) índice de ramificación de cadena larga, LCBI, menor o igual a 0,75.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16199338 | 2016-11-17 | ||
| PCT/EP2017/077799 WO2018091261A1 (en) | 2016-11-17 | 2017-10-30 | Polyethylene composition having high swell ratio |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019005754A true MX2019005754A (es) | 2019-11-08 |
Family
ID=57348515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019005754A MX2019005754A (es) | 2016-11-17 | 2017-10-30 | Composicion de polietileno que tiene indice alto de dilatacion. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US11479660B2 (es) |
| EP (1) | EP3541852B1 (es) |
| JP (1) | JP6698948B2 (es) |
| KR (1) | KR102109306B1 (es) |
| CN (2) | CN110023344A (es) |
| BR (1) | BR112019009862B1 (es) |
| CA (1) | CA3043355C (es) |
| ES (1) | ES2978633T3 (es) |
| MX (1) | MX2019005754A (es) |
| PL (1) | PL3541852T3 (es) |
| RU (1) | RU2720803C1 (es) |
| WO (1) | WO2018091261A1 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3112357C (en) * | 2018-09-20 | 2022-11-22 | Basell Polyolefine Gmbh | Polyethylene composition for films |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE363977B (es) | 1968-11-21 | 1974-02-11 | Montedison Spa | |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| JP2879347B2 (ja) | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| BE1009308A3 (fr) | 1995-04-28 | 1997-02-04 | Solvay | Polymere d'ethylene et procedes pour son obtention. |
| JP2000514492A (ja) * | 1996-07-11 | 2000-10-31 | モービル・オイル・コーポレーション | 中間の分子量分布を有するポリエチレンを製造するための高活性触媒 |
| CA2257131C (en) | 1997-03-29 | 2008-01-08 | Montell Technology Company B.V. | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| CA2527357A1 (en) * | 2003-05-29 | 2004-12-09 | Basell Poliolefine Italia S.R.L. | Process for the preparation of a catalyst component and components therefrom obtained |
| ATE347569T1 (de) | 2003-08-20 | 2006-12-15 | Basell Poliolefine Srl | Verfahren und vorrichtung zur polymerisation von ethylen |
| BRPI0621073B1 (pt) * | 2005-12-23 | 2017-12-05 | Basell Poliolefine Italia S.R.L. | Gas phase process and apparatus for polymerization of olefins |
| ATE455149T1 (de) | 2006-04-07 | 2010-01-15 | Dow Global Technologies Inc | Polyolefinverbindungen, daraus hergestellte artikel und herstellungsverfahren dafür |
| ATE511919T1 (de) * | 2007-12-21 | 2011-06-15 | Basell Poliolefine Srl | Verfahren zur gasphasenpolymerisation von olefinen |
| BRPI0923872B1 (pt) * | 2008-12-29 | 2018-04-03 | Basell Poliolefine Italia S.R.L | Processo para alimentar um catalisador em um reator para polimerização. |
| KR101950622B1 (ko) * | 2012-10-22 | 2019-02-20 | 바젤 폴리올레핀 게엠베하 | 높은 스웰비를 가진 폴리에틸렌 조성물 |
| MX366406B (es) * | 2012-10-22 | 2019-07-08 | Basell Polyolefine Gmbh | Composicion de polietileno que tiene una proporcion alta de dilatacion. |
| KR20150068438A (ko) * | 2012-10-22 | 2015-06-19 | 바젤 폴리올레핀 게엠베하 | 우수한 기계적 성질을 가진 폴리에틸렌 조성물 |
| KR101624093B1 (ko) * | 2013-02-27 | 2016-05-24 | 바젤 폴리올레핀 게엠베하 | 폴리에틸렌 공정 및 그 조성물 |
| EP2818508A1 (en) * | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition having high impact and stress cracking resistance |
| EP2818509A1 (en) * | 2013-06-25 | 2014-12-31 | Basell Polyolefine GmbH | Polyethylene composition for blow molding having high stress cracking resistance |
| WO2016075165A1 (en) * | 2014-11-13 | 2016-05-19 | Total Research & Technology Feluy | Rotomolded articles comprising at least one layer comprising a metallocene-catalyzed polyethylene resin |
| PL3221397T3 (pl) | 2014-11-18 | 2020-03-31 | Basell Polyolefine Gmbh | Kompozycja polietylenowa o wysokiej odporności na pękanie naprężeniowe |
| RU2688145C1 (ru) * | 2015-06-26 | 2019-05-20 | Базелл Полиолефин Гмбх | Состав полиэтилена, обладающий высокими механическими свойствами и технологичностью при обработке |
| EP3313932B1 (en) | 2015-06-26 | 2021-11-17 | Basell Polyolefine GmbH | Polyethylene composition having high mechanical properties and processability |
-
2017
- 2017-10-30 WO PCT/EP2017/077799 patent/WO2018091261A1/en not_active Ceased
- 2017-10-30 JP JP2019525989A patent/JP6698948B2/ja active Active
- 2017-10-30 CN CN201780070821.4A patent/CN110023344A/zh active Pending
- 2017-10-30 MX MX2019005754A patent/MX2019005754A/es unknown
- 2017-10-30 RU RU2019115584A patent/RU2720803C1/ru active
- 2017-10-30 ES ES17794302T patent/ES2978633T3/es active Active
- 2017-10-30 CN CN202510258896.1A patent/CN120040856A/zh active Pending
- 2017-10-30 BR BR112019009862-3A patent/BR112019009862B1/pt active IP Right Grant
- 2017-10-30 CA CA3043355A patent/CA3043355C/en active Active
- 2017-10-30 PL PL17794302.4T patent/PL3541852T3/pl unknown
- 2017-10-30 KR KR1020197015277A patent/KR102109306B1/ko active Active
- 2017-10-30 EP EP17794302.4A patent/EP3541852B1/en active Active
- 2017-10-30 US US16/461,862 patent/US11479660B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2019533757A (ja) | 2019-11-21 |
| US20190338108A1 (en) | 2019-11-07 |
| CA3043355A1 (en) | 2018-05-24 |
| KR20190069568A (ko) | 2019-06-19 |
| EP3541852B1 (en) | 2024-04-03 |
| BR112019009862A2 (pt) | 2019-08-27 |
| WO2018091261A1 (en) | 2018-05-24 |
| PL3541852T3 (pl) | 2024-06-10 |
| BR112019009862B1 (pt) | 2022-10-18 |
| EP3541852A1 (en) | 2019-09-25 |
| CA3043355C (en) | 2020-06-30 |
| RU2720803C1 (ru) | 2020-05-13 |
| KR102109306B1 (ko) | 2020-05-12 |
| US11479660B2 (en) | 2022-10-25 |
| CN120040856A (zh) | 2025-05-27 |
| JP6698948B2 (ja) | 2020-05-27 |
| CN110023344A (zh) | 2019-07-16 |
| ES2978633T3 (es) | 2024-09-17 |
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