MX2019002769A - Metodos de preparacion de un catalizador. - Google Patents
Metodos de preparacion de un catalizador.Info
- Publication number
- MX2019002769A MX2019002769A MX2019002769A MX2019002769A MX2019002769A MX 2019002769 A MX2019002769 A MX 2019002769A MX 2019002769 A MX2019002769 A MX 2019002769A MX 2019002769 A MX2019002769 A MX 2019002769A MX 2019002769 A MX2019002769 A MX 2019002769A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- preparing
- aqueous mixture
- contacting
- support
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 4
- 239000012041 precatalyst Substances 0.000 abstract 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- -1 oxotitanium compound Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/025—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Abstract
Un método para preparar un catalizador que comprende a) poner en contacto (i) un soporte de sílice, (ii) un compuesto de oxotitanio, (iii) un compuesto que contiene cromo y (iv) un solvente opcional para formar una primera mezcla acuosa que comprende un precatalizador y un medio de reacción que tiene de 1% en peso a 99% en peso de agua; b) tratar térmicamente el precatalizador con calentamiento a una temperatura de 400°C a 1000°C durante un período de tiempo de 1 minuto a 24 horas para formar el catalizador. Un método para preparar un catalizador que comprende poner en contacto un material de soporte hidratado que comprende sílice con un compuesto que contiene cromo para formar una primera mezcla acuosa que comprende un soporte cromado; poner en contacto la primera mezcla acuosa que comprende un soporte cromado con una solución que comprende (i) un solvente y (ii) un compuesto de oxotitanio para formar una segunda mezcla acuosa que comprende un precatalizador; y tratar térmicamente el precatalizador para formar el catalizador.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/281,538 US9988468B2 (en) | 2016-09-30 | 2016-09-30 | Methods of preparing a catalyst |
| PCT/US2017/053468 WO2018064050A2 (en) | 2016-09-30 | 2017-09-26 | Methods of preparing a catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019002769A true MX2019002769A (es) | 2019-05-09 |
Family
ID=60153432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019002769A MX2019002769A (es) | 2016-09-30 | 2017-09-26 | Metodos de preparacion de un catalizador. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9988468B2 (es) |
| EP (2) | EP3519449A2 (es) |
| KR (2) | KR102637869B1 (es) |
| CN (1) | CN109790236A (es) |
| BR (1) | BR112019005929B1 (es) |
| CA (1) | CA3035255C (es) |
| MX (1) | MX2019002769A (es) |
| RU (2) | RU2762112C2 (es) |
| WO (1) | WO2018064050A2 (es) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9023967B2 (en) | 2011-11-30 | 2015-05-05 | Chevron Phillips Chemical Company Lp | Long chain branched polymers and methods of making same |
| US10213766B2 (en) | 2015-09-18 | 2019-02-26 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US11267914B2 (en) | 2016-12-29 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US10654953B2 (en) | 2016-12-29 | 2020-05-19 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US20200369803A1 (en) | 2016-12-29 | 2020-11-26 | Chevron Phillips Chemical Company Lp | Methods of Preparing a Catalyst |
| US10513570B2 (en) | 2017-11-17 | 2019-12-24 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US10323109B2 (en) | 2017-11-17 | 2019-06-18 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst utilizing hydrated reagents |
| US11266976B2 (en) | 2018-04-16 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst with low HRVOC emissions |
| US10543480B2 (en) * | 2018-04-16 | 2020-01-28 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst utilizing hydrated reagents |
| US10722874B2 (en) | 2018-04-16 | 2020-07-28 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst utilizing hydrated reagents |
| EP4223803A3 (en) | 2018-09-17 | 2023-11-08 | Chevron Phillips Chemical Company LP | Modified supported chromium catalysts and ethylene-based polymers produced therefrom |
| CA3112425A1 (en) * | 2018-09-24 | 2020-04-02 | Chevron Phillips Chemical Company Lp | Methods for making supported chromium catalysts with increased polymerization activity |
| US10858456B1 (en) | 2019-06-12 | 2020-12-08 | Chevron Phillips Chemical Company Lp | Aqueous titanation of Cr/silica catalysts by the use of acetylacetonate and another ligand |
| US10889664B2 (en) | 2019-06-12 | 2021-01-12 | Chevron Phillips Chemical Company Lp | Surfactant as titanation ligand |
| US11242416B2 (en) | 2019-06-12 | 2022-02-08 | Chevron Phillips Chemical Company Lp | Amino acid chelates of titanium and use thereof in aqueous titanation of polymerization catalysts |
| CN114401788B (zh) | 2019-09-16 | 2024-03-08 | 切弗朗菲利浦化学公司 | 基于铬的催化剂以及将烷烃转化成较高级和较低级脂肪族烃的工艺 |
| US11180435B2 (en) | 2019-09-16 | 2021-11-23 | Chevron Phillips Chemical Company, Lp | Chromium-catalyzed production of alcohols from hydrocarbons |
| CN114409833B (zh) * | 2020-01-28 | 2022-09-27 | 切弗朗菲利浦化学公司 | 利用水合试剂制备催化剂的方法 |
| US11780786B2 (en) | 2020-09-14 | 2023-10-10 | Chevron Phillips Chemical Company Lp | Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons |
| EP4352068B1 (en) | 2021-06-08 | 2025-10-08 | Chevron Phillips Chemical Company Lp | Chromium-catalyzed production of alcohols from hydrocarbons in the presence of oxygen |
| CN119053382A (zh) | 2022-04-26 | 2024-11-29 | 切弗朗菲利浦化学公司 | 具有碱金属或锌的钛酸化铬/二氧化硅催化剂及制备该催化剂的水性方法 |
| US12077627B2 (en) | 2022-04-26 | 2024-09-03 | Chevron Phillips Chemical Company Lp | Aqueous methods for titanating a chromium/silica catalyst with an alkali metal |
| US12134591B2 (en) | 2022-10-31 | 2024-11-05 | Chevron Phillips Chemical Company Lp | Methanol production from methane utilizing a supported chromium catalyst |
| WO2024229004A1 (en) | 2023-05-02 | 2024-11-07 | Chevron Phillips Chemical Company Lp | Methods of chromium catalyst activation to reduce gels and improve melt index potential |
| WO2025101724A1 (en) | 2023-11-09 | 2025-05-15 | Chevron Phillips Chemical Company Lp | Systems and methods for chromium catalyst activation |
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-
2016
- 2016-09-30 US US15/281,538 patent/US9988468B2/en active Active
-
2017
- 2017-09-26 RU RU2019105277A patent/RU2762112C2/ru active
- 2017-09-26 WO PCT/US2017/053468 patent/WO2018064050A2/en not_active Ceased
- 2017-09-26 RU RU2021136501A patent/RU2021136501A/ru unknown
- 2017-09-26 KR KR1020237035946A patent/KR102637869B1/ko active Active
- 2017-09-26 EP EP17787697.6A patent/EP3519449A2/en active Pending
- 2017-09-26 KR KR1020197007564A patent/KR20190059898A/ko not_active Ceased
- 2017-09-26 EP EP24159191.6A patent/EP4372013A3/en active Pending
- 2017-09-26 CA CA3035255A patent/CA3035255C/en active Active
- 2017-09-26 BR BR112019005929-6A patent/BR112019005929B1/pt active IP Right Grant
- 2017-09-26 CN CN201780056786.0A patent/CN109790236A/zh active Pending
- 2017-09-26 MX MX2019002769A patent/MX2019002769A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2019105277A3 (es) | 2021-05-18 |
| RU2762112C2 (ru) | 2021-12-15 |
| EP4372013A3 (en) | 2024-08-28 |
| KR20190059898A (ko) | 2019-05-31 |
| BR112019005929A2 (pt) | 2019-06-11 |
| RU2019105277A (ru) | 2020-10-30 |
| BR112019005929B1 (pt) | 2021-03-30 |
| KR20230151063A (ko) | 2023-10-31 |
| CA3035255A1 (en) | 2018-04-05 |
| KR102637869B1 (ko) | 2024-02-16 |
| US20180094087A1 (en) | 2018-04-05 |
| WO2018064050A3 (en) | 2018-05-17 |
| US9988468B2 (en) | 2018-06-05 |
| RU2021136501A (ru) | 2022-02-17 |
| CA3035255C (en) | 2021-04-06 |
| CN109790236A (zh) | 2019-05-21 |
| EP4372013A2 (en) | 2024-05-22 |
| EP3519449A2 (en) | 2019-08-07 |
| WO2018064050A2 (en) | 2018-04-05 |
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