MX2018002311A - Nuevo metodo para la fluoracion de cloroalcanos. - Google Patents
Nuevo metodo para la fluoracion de cloroalcanos.Info
- Publication number
- MX2018002311A MX2018002311A MX2018002311A MX2018002311A MX2018002311A MX 2018002311 A MX2018002311 A MX 2018002311A MX 2018002311 A MX2018002311 A MX 2018002311A MX 2018002311 A MX2018002311 A MX 2018002311A MX 2018002311 A MX2018002311 A MX 2018002311A
- Authority
- MX
- Mexico
- Prior art keywords
- fluorinating
- chloroalkanes
- novel method
- fluorinated
- oxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000001348 alkyl chlorides Chemical class 0.000 title 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000003682 fluorination reaction Methods 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0218—Compounds of Cr, Mo, W
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/26—Fluorinating
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/23—Preparation of halogenated hydrocarbons by dehalogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
- C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/12—Fluorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invención se refiere a un método para fluorar un sustrato de alcano que comprende poner en contacto el sustrato de alcano con un fluoroalcano en presencia de un catalizador de fluoración seleccionado de óxido de cromo, óxido de cromo fluorado, óxido de aluminio y óxido de aluminio fluorado a temperaturas elevadas.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562215788P | 2015-09-09 | 2015-09-09 | |
| PCT/US2016/050912 WO2017044719A1 (en) | 2015-09-09 | 2016-09-09 | Novel method for fluorinating chloroalkanes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2018002311A true MX2018002311A (es) | 2018-04-11 |
Family
ID=58240831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2018002311A MX2018002311A (es) | 2015-09-09 | 2016-09-09 | Nuevo metodo para la fluoracion de cloroalcanos. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20200223772A1 (es) |
| EP (1) | EP3347335A4 (es) |
| JP (1) | JP2018526385A (es) |
| KR (1) | KR20180039665A (es) |
| CN (1) | CN107922296A (es) |
| MX (1) | MX2018002311A (es) |
| WO (1) | WO2017044719A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103553871A (zh) † | 2006-10-31 | 2014-02-05 | 纳幕尔杜邦公司 | 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法 |
| CN110573482B (zh) * | 2017-06-30 | 2022-05-10 | 中央硝子株式会社 | 1-氯-3,3,3-三氟丙烯的制备方法 |
| US20210317055A1 (en) | 2018-07-18 | 2021-10-14 | The Chemours Company Fc, Llc | Production of haloolefins in an adiabatic reaction zone |
| EP3847145A2 (en) | 2018-09-07 | 2021-07-14 | The Chemours Company FC, LLC | Fluorine removal from antimony fluorohalide catalyst using chlorocarbons |
| MY202072A (en) * | 2018-10-26 | 2024-04-02 | Chemours Co Fc Llc | Hfo-1234ze and hfo-1234yf compositions and processes for producing and using the compositions |
| BR112021022059A2 (pt) | 2018-10-26 | 2021-12-28 | Chemours Co Fc Llc | Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante |
| US11209196B2 (en) | 2018-10-26 | 2021-12-28 | The Chemours Company Fc, Llc | HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions |
| WO2020218336A1 (ja) * | 2019-04-25 | 2020-10-29 | Agc株式会社 | ハイドロクロロフルオロカーボンの製造方法、1-クロロ-2,3,3-トリフルオロプロペンの製造方法、1-クロロ-2,3,3,4,4,5,5-ヘプタフルオロ-1-ペンテンの製造方法 |
| KR20250006214A (ko) * | 2022-04-28 | 2025-01-10 | 칸토 덴카 코교 가부시키가이샤 | 1,1,1,3,5,5,5-헵타플루오로-2-펜텐의 제조 방법 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2404706A (en) * | 1943-10-04 | 1946-07-23 | Du Pont | Fluorination |
| EP0203807B1 (en) * | 1985-05-28 | 1988-09-28 | E.I. Du Pont De Nemours And Company | Catalytic fluoroolefin transhalogenations |
| JPS6226239A (ja) * | 1985-05-28 | 1987-02-04 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | フルオロオレフインの接触ハロゲン交換法 |
| US5146020A (en) * | 1986-03-20 | 1992-09-08 | E. I. Du Pont De Nemours And Company | Disproportionation of selected chlorofluoromethanes |
| US5175379A (en) * | 1988-08-27 | 1992-12-29 | Hoechst Ag | Process for the preparation of partly flourinated ethanes |
| GB0806422D0 (en) * | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| GB0806389D0 (en) * | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| EP2172441A1 (en) * | 2008-10-02 | 2010-04-07 | Solvay Fluor GmbH | Process for the manufacture of hydrochlorofluorocarbons using trifluoromethane as fluorinating agent |
| US8203022B2 (en) * | 2008-10-27 | 2012-06-19 | E I Du Pont De Nemours And Company | Conversion of 2-chloro-1,1,1,2-tetrafluoropropane to 2,3,3,3-tetrafluoropropene |
| EP2516367B1 (en) * | 2009-12-23 | 2015-10-07 | Arkema France | Catalytic gas phase fluorination of 243db to 1234yf |
| CN102947257B (zh) * | 2010-06-23 | 2014-07-09 | 旭硝子株式会社 | 1,1-二氯-2,3,3,3-四氟丙烯及2,3,3,3-四氟丙烯的制造方法 |
| MX347872B (es) * | 2010-10-22 | 2017-05-16 | Arkema France | Proceso para la preparacion de 2,3,3,3-tetrafluoropropeno. |
-
2016
- 2016-09-09 WO PCT/US2016/050912 patent/WO2017044719A1/en not_active Ceased
- 2016-09-09 MX MX2018002311A patent/MX2018002311A/es unknown
- 2016-09-09 EP EP16845105.2A patent/EP3347335A4/en not_active Withdrawn
- 2016-09-09 CN CN201680052408.0A patent/CN107922296A/zh active Pending
- 2016-09-09 US US15/759,035 patent/US20200223772A1/en not_active Abandoned
- 2016-09-09 KR KR1020187006409A patent/KR20180039665A/ko not_active Withdrawn
- 2016-09-09 JP JP2018511396A patent/JP2018526385A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2018526385A (ja) | 2018-09-13 |
| WO2017044719A1 (en) | 2017-03-16 |
| CN107922296A (zh) | 2018-04-17 |
| US20200223772A1 (en) | 2020-07-16 |
| EP3347335A1 (en) | 2018-07-18 |
| KR20180039665A (ko) | 2018-04-18 |
| EP3347335A4 (en) | 2019-03-20 |
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