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MX2015013777A - Montaje de electrodos/electrolito, reactor y metodo para aminacion directa de hidrocarburos. - Google Patents

Montaje de electrodos/electrolito, reactor y metodo para aminacion directa de hidrocarburos.

Info

Publication number
MX2015013777A
MX2015013777A MX2015013777A MX2015013777A MX2015013777A MX 2015013777 A MX2015013777 A MX 2015013777A MX 2015013777 A MX2015013777 A MX 2015013777A MX 2015013777 A MX2015013777 A MX 2015013777A MX 2015013777 A MX2015013777 A MX 2015013777A
Authority
MX
Mexico
Prior art keywords
electrodes
amination
direct
hydrocarbons
electrolyte assembly
Prior art date
Application number
MX2015013777A
Other languages
English (en)
Inventor
Adélio Miguel Magalhães Mendes
Alejandro França Gomes Ribeiro
Margarida Dias Catarino
Ana Sofia Pimentel Félix
Mário Jorge De Oliveira Pinho
Original Assignee
Cuf Químicos Ind S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cuf Químicos Ind S A filed Critical Cuf Químicos Ind S A
Publication of MX2015013777A publication Critical patent/MX2015013777A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/20—Making multilayered or multicoloured articles
    • B29C43/203—Making multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/52—Heating or cooling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061—Metal or alloy
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2029/00—Use of polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals or derivatives thereof as moulding material
    • B29K2029/04—PVOH, i.e. polyvinyl alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2505/00—Use of metals, their alloys or their compounds, as filler
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Catalysts (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Inert Electrodes (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Se describe un montaje de electrodos/electrolito - MEA, reactor de membrana electroquímica - y un método para la aminación directa de hidrocarburos, es decir para la aminación directa de benceno a anilina, y un método para la preparación de tal montaje de electrodos/electrolito. La solución presentada permite el incremento de la conversión de tal aminación por arriba de 60%, aún en bajas temperaturas, esto es, entre 200°C y 450°C; preferiblemente entre 300°C y 400°C. El montaje de electrodos/electrolito para aminación directa de hidrocarburos comprende: • un ánodo (1), conductor de electrones y protones, que incluye una matriz porosa del compuesto, compuesta por una fracción de cerámica y un catalizador para tal aminación a temperaturas inferiores a 450°C; • un cátodo poroso (3), conductor de electrones y protones, y electrocatalizador; • un electrólito (2) , conductor de protones o iones y eléctricamente aislante, ubicado entre el ánodo (1) y el cátodo (3), hecho de un cerámica compuesta impermeable a reactivos y productos de tal aminación.
MX2015013777A 2013-03-28 2014-03-28 Montaje de electrodos/electrolito, reactor y metodo para aminacion directa de hidrocarburos. MX2015013777A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PT106860A PT106860A (pt) 2013-03-28 2013-03-28 Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos
PCT/IB2014/060276 WO2014155360A1 (pt) 2013-03-28 2014-03-28 Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos

Publications (1)

Publication Number Publication Date
MX2015013777A true MX2015013777A (es) 2016-02-16

Family

ID=50687530

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015013777A MX2015013777A (es) 2013-03-28 2014-03-28 Montaje de electrodos/electrolito, reactor y metodo para aminacion directa de hidrocarburos.

Country Status (16)

Country Link
US (2) US10273589B2 (es)
EP (1) EP2980275B1 (es)
JP (1) JP2016519214A (es)
KR (1) KR20160019409A (es)
CN (1) CN105358740B (es)
AU (1) AU2014240787B8 (es)
BR (1) BR112015024853A2 (es)
CA (1) CA2908169A1 (es)
ES (1) ES2723881T3 (es)
MX (1) MX2015013777A (es)
PL (1) PL2980275T3 (es)
PT (2) PT106860A (es)
RU (1) RU2015145278A (es)
SG (2) SG10201707999RA (es)
WO (1) WO2014155360A1 (es)
ZA (1) ZA201507233B (es)

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JP6521830B2 (ja) * 2015-10-20 2019-05-29 東京瓦斯株式会社 高温水蒸気電解セル及び高温水蒸気電解システム
US10392715B2 (en) 2016-08-29 2019-08-27 Wisconsin Alumni Research Foundation Electrochemical reductive amination of furfural-based molecules
KR102621519B1 (ko) * 2018-04-11 2024-01-04 현대자동차주식회사 고분자 전해질막 연료전지용 산화방지제, 이를 포함하는 전해질막, 및 이를 포함하는 운송 수단용 막-전극 접합체
JP2020002397A (ja) * 2018-06-26 2020-01-09 株式会社グラヴィトン 電気分解装置および電極製造方法
WO2020220183A1 (zh) * 2019-04-29 2020-11-05 天津工业大学 多级电催化膜反应器及其在有机电化学反应中的应用和方法
CN111471192B (zh) * 2019-10-15 2021-07-16 中山大学 一种钨酸铋-石墨烯-导电水凝胶的制备方法及其应用
JP6975297B1 (ja) * 2020-08-28 2021-12-01 デノラ・ペルメレック株式会社 アルカリ水電解用アノード
JP7787754B2 (ja) * 2021-03-19 2025-12-17 出光興産株式会社 固体電解質形電解装置並びにそれを用いたポリカーボネート及びポリウレタンの製造方法
CN114725457B (zh) * 2022-03-29 2024-03-12 上海交通大学 一种加快局域氧气传质的膜电极制备方法
CN117418205B (zh) * 2023-10-20 2025-11-14 北京亿华通科技股份有限公司 多孔催化剂气体扩散电极磁控溅射制备方法及电极
WO2025156749A1 (zh) * 2024-01-25 2025-07-31 中国科学技术大学 一种具有对称结构的全固态锂离子膜反应器及其应用

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Also Published As

Publication number Publication date
ZA201507233B (en) 2017-03-29
US10689767B2 (en) 2020-06-23
EP2980275B1 (en) 2019-02-06
AU2014240787B8 (en) 2018-02-08
SG11201508021YA (en) 2015-10-29
JP2016519214A (ja) 2016-06-30
AU2014240787B2 (en) 2018-02-01
PT2980275T (pt) 2019-05-27
AU2014240787A1 (en) 2015-10-22
US20190203366A1 (en) 2019-07-04
PL2980275T3 (pl) 2020-03-31
RU2015145278A (ru) 2017-05-04
CN105358740B (zh) 2018-04-03
WO2014155360A1 (pt) 2014-10-02
PT106860A (pt) 2014-09-29
EP2980275A1 (en) 2016-02-03
US20160032469A1 (en) 2016-02-04
CN105358740A (zh) 2016-02-24
US10273589B2 (en) 2019-04-30
SG10201707999RA (en) 2017-10-30
CA2908169A1 (en) 2014-10-02
ES2723881T3 (es) 2019-09-03
BR112015024853A2 (pt) 2017-07-18
KR20160019409A (ko) 2016-02-19

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