MX2013006884A - Procedimiento para producir acido acetico. - Google Patents
Procedimiento para producir acido acetico.Info
- Publication number
- MX2013006884A MX2013006884A MX2013006884A MX2013006884A MX2013006884A MX 2013006884 A MX2013006884 A MX 2013006884A MX 2013006884 A MX2013006884 A MX 2013006884A MX 2013006884 A MX2013006884 A MX 2013006884A MX 2013006884 A MX2013006884 A MX 2013006884A
- Authority
- MX
- Mexico
- Prior art keywords
- acetic acid
- acetaldehyde
- fed
- separated
- distillation tower
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title abstract 15
- 238000000034 method Methods 0.000 title abstract 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 238000004821 distillation Methods 0.000 abstract 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 2
- 229910000043 hydrogen iodide Inorganic materials 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000000630 rising effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C07C51/46—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation by azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
El ácido acético es producido mientras al mismo tiempo se inhiben las concentraciones aumentadas de yoduro de hidrógeno y ácido acético en una columna de destilación de acetaldehído; un procedimiento de producción de ácido acético comprende un paso para permitir que metanol reaccione con monóxido de carbono; un paso para alimentar a una caldera de evaporación rápida con la mezcla de reacción para separar un componente volátil (2A) y un componente bajo en volátiles (2B); un paso para alimentar una columna de destilación con el componente (2A), y separar un destilado (3A) que contiene yoduro de metilo, ácido acético, acetato de metilo, agua, acetaldehído, y yoduro de hidrógeno, y una corriente (3B) que contiene ácido acético para recolectar ácido acético; y un paso de separación para alimentar una columna de destilación de acetaldehído con por lo menos parte del destilado (3A) y separar un objeto líquido a ser tratado que contiene el destilado (3A) en un componente de menor punto de ebullición (4A) que contiene acetaldehído y un componente de mayor punto de ebullición (4B); en donde, en el paso de separación, el objeto líquido que contiene metanol y/o éter dimetílico en una concentración de 0.1 a 50% en peso se somete a la destilación.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010279799 | 2010-12-15 | ||
| PCT/JP2011/077846 WO2012081418A1 (ja) | 2010-12-15 | 2011-12-01 | 酢酸の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2013006884A true MX2013006884A (es) | 2013-07-05 |
| MX338849B MX338849B (es) | 2016-05-02 |
Family
ID=46244527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013006884A MX338849B (es) | 2010-12-15 | 2011-12-01 | Procedimiento para producir acido acetico. |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | USRE47569E1 (es) |
| EP (1) | EP2653458B2 (es) |
| JP (1) | JP5914358B2 (es) |
| KR (1) | KR101874661B1 (es) |
| CN (1) | CN103402964B (es) |
| BR (1) | BR112013014808B1 (es) |
| ES (1) | ES2646749T5 (es) |
| MX (1) | MX338849B (es) |
| MY (1) | MY161174A (es) |
| SA (1) | SA111330055B1 (es) |
| SG (1) | SG190941A1 (es) |
| TW (1) | TWI511950B (es) |
| WO (1) | WO2012081418A1 (es) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2702766T3 (es) * | 2010-10-06 | 2019-03-05 | Daicel Corp | Proceso de producción de ácido acético |
| WO2012081417A1 (ja) | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
| MY161174A (en) | 2010-12-15 | 2017-04-14 | Daicel Corp | Process for producing acetic acid |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| AR094541A1 (es) * | 2013-01-25 | 2015-08-12 | Daicel Corp | Procedimiento para producir ácido carboxílico |
| US9505691B2 (en) | 2014-10-02 | 2016-11-29 | Celanese International Corporation | Process for producing acetic acid |
| US9233907B1 (en) | 2014-11-14 | 2016-01-12 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| MY182164A (en) | 2014-11-14 | 2021-01-18 | Celanese Int Corp | Process for producing acetic acid by introducing a lithium compound |
| US9540304B2 (en) | 2014-11-14 | 2017-01-10 | Celanese International Corporation | Processes for producing an acetic acid product having low butyl acetate content |
| MY181883A (en) * | 2014-11-14 | 2021-01-12 | Celanese Int Corp | Processes for producing acetic acid with decanter control |
| US9688600B2 (en) | 2014-11-14 | 2017-06-27 | Celanese International Corporation | Processes for improving acetic acid yield by removing iron |
| US9340481B1 (en) | 2014-11-14 | 2016-05-17 | Celanese International Corporation | Process for flashing a reaction medium comprising lithium acetate |
| ES2807618T3 (es) | 2014-11-14 | 2021-02-23 | Celanese Int Corp | Procesos para producir ácido acético a partir de un medio de reacción que tiene bajo contenido de yoduro de etilo |
| US9458077B2 (en) | 2014-11-14 | 2016-10-04 | Celanese International Corporation | Reducing hydrogen iodide content in carbonylation processes |
| US9260369B1 (en) | 2014-11-14 | 2016-02-16 | Celanese International Corporation | Processes for producing acetic acid product having low butyl acetate content |
| US9302975B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9540302B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9487464B2 (en) | 2015-01-30 | 2016-11-08 | Celanese International Corporation | Processes for producing acetic acid |
| WO2016122727A1 (en) | 2015-01-30 | 2016-08-04 | Celanese International Corporation | Processes for producing acetic acid |
| US9561994B2 (en) | 2015-01-30 | 2017-02-07 | Celanese International Corporation | Processes for producing acetic acid |
| CN107207392B (zh) | 2015-01-30 | 2021-06-08 | 国际人造丝公司 | 生产乙酸的方法 |
| US10413840B2 (en) | 2015-02-04 | 2019-09-17 | Celanese International Coporation | Process to control HI concentration in residuum stream |
| US9512056B2 (en) * | 2015-02-04 | 2016-12-06 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9505696B2 (en) | 2015-02-04 | 2016-11-29 | Celanese International Corporation | Process to control HI concentration in residuum stream |
| US9540303B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9382183B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for flashing a reaction medium |
| US9302974B1 (en) | 2015-07-01 | 2016-04-05 | Celanese International Corporation | Process for producing acetic acid |
| US9382186B1 (en) | 2015-07-01 | 2016-07-05 | Celanese International Corporation | Process for producing acetic acid |
| US9416088B1 (en) | 2015-10-02 | 2016-08-16 | Celanese International Corporation | Process to produce acetic acid with recycle of water |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| US9908835B2 (en) | 2015-11-13 | 2018-03-06 | Celanese International Corporation | Processes for purifying acetic and hydrating anhydride |
| BR112018074026A2 (pt) * | 2016-07-07 | 2019-02-26 | Daicel Corporation | processos para separação ou remoção de compostos redutores de permanganato (prc?s) de uma primeira mistura e para produção de ácido acético |
| KR102255683B1 (ko) * | 2017-01-18 | 2021-05-26 | 주식회사 다이셀 | 아세트산의 제조 방법 |
| EP3369721B1 (en) | 2017-01-18 | 2019-10-16 | Daicel Corporation | Method for producing acetic acid |
| US10308581B2 (en) | 2017-03-28 | 2019-06-04 | Daicel Corporation | Method for producing acetic acid |
| CN110191874A (zh) * | 2017-03-28 | 2019-08-30 | 株式会社大赛璐 | 乙酸的制备方法 |
| US11840050B2 (en) | 2018-05-24 | 2023-12-12 | Vkr Holding A/S | VIG unit lamination |
| US10759730B2 (en) * | 2018-07-02 | 2020-09-01 | Daicel Corporation | Method for producing acetic acid |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3335179A (en) | 1964-02-12 | 1967-08-08 | Monsanto Co | Production of acetic acid and recovery by plural stage distillation |
| US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
| US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
| US5625095A (en) | 1994-06-15 | 1997-04-29 | Daicel Chemical Industries, Ltd. | Process for producing high purity acetic acid |
| JP3244385B2 (ja) | 1994-06-15 | 2002-01-07 | ダイセル化学工業株式会社 | 高純度酢酸の製造方法 |
| JP3581725B2 (ja) | 1994-06-30 | 2004-10-27 | ダイセル化学工業株式会社 | アセトアルデヒドとヨウ化メチルの分離方法 |
| IN192600B (es) | 1996-10-18 | 2004-05-08 | Hoechst Celanese Corp | |
| US6339171B1 (en) | 1996-10-18 | 2002-01-15 | Celanese International Corporation | Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream |
| JP4242952B2 (ja) * | 1998-08-31 | 2009-03-25 | ダイセル化学工業株式会社 | 酢酸の製造方法 |
| US7115772B2 (en) | 2002-01-11 | 2006-10-03 | Celanese International Corporation | Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream |
| US7208624B2 (en) | 2004-03-02 | 2007-04-24 | Celanese International Corporation | Process for producing acetic acid |
| US7271293B2 (en) * | 2004-03-02 | 2007-09-18 | Celanese International Corporation | Control method for process of removing permanganate reducing compounds from methanol carbonylation process |
| JP4489487B2 (ja) * | 2004-04-02 | 2010-06-23 | ダイセル化学工業株式会社 | ヨウ化水素の分離方法 |
| US7855306B2 (en) | 2005-04-28 | 2010-12-21 | Celanese International Corporation | Process for the production of acetic acid |
| EP1912926A2 (en) | 2005-07-14 | 2008-04-23 | Daicel Chemical Industries, Ltd. | Process for producing carboxylic acid |
| US7524988B2 (en) | 2006-08-01 | 2009-04-28 | Lyondell Chemical Technology, L.P. | Preparation of acetic acid |
| US7820855B2 (en) | 2008-04-29 | 2010-10-26 | Celanese International Corporation | Method and apparatus for carbonylating methanol with acetic acid enriched flash stream |
| JP5933168B2 (ja) | 2010-09-24 | 2016-06-08 | 株式会社三共 | 遊技機 |
| ES2702766T3 (es) * | 2010-10-06 | 2019-03-05 | Daicel Corp | Proceso de producción de ácido acético |
| WO2012081417A1 (ja) * | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
| WO2012081416A1 (ja) * | 2010-12-15 | 2012-06-21 | 株式会社ダイセル | 酢酸の製造方法 |
| MY161174A (en) | 2010-12-15 | 2017-04-14 | Daicel Corp | Process for producing acetic acid |
-
2011
- 2011-12-01 MY MYPI2013002221A patent/MY161174A/en unknown
- 2011-12-01 BR BR112013014808-0A patent/BR112013014808B1/pt not_active IP Right Cessation
- 2011-12-01 CN CN201180067677.1A patent/CN103402964B/zh not_active Ceased
- 2011-12-01 US US16/026,736 patent/USRE47569E1/en active Active
- 2011-12-01 US US13/995,102 patent/US9162958B2/en not_active Ceased
- 2011-12-01 US US15/664,076 patent/USRE46999E1/en active Active
- 2011-12-01 EP EP11848683.6A patent/EP2653458B2/en active Active
- 2011-12-01 MX MX2013006884A patent/MX338849B/es active IP Right Grant
- 2011-12-01 SG SG2013042031A patent/SG190941A1/en unknown
- 2011-12-01 JP JP2012548728A patent/JP5914358B2/ja active Active
- 2011-12-01 KR KR1020137018273A patent/KR101874661B1/ko active Active
- 2011-12-01 WO PCT/JP2011/077846 patent/WO2012081418A1/ja not_active Ceased
- 2011-12-01 ES ES11848683T patent/ES2646749T5/es active Active
- 2011-12-14 SA SA111330055A patent/SA111330055B1/ar unknown
- 2011-12-14 TW TW100146096A patent/TWI511950B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| TW201231450A (en) | 2012-08-01 |
| WO2012081418A1 (ja) | 2012-06-21 |
| USRE46999E1 (en) | 2018-08-21 |
| KR101874661B1 (ko) | 2018-07-04 |
| MX338849B (es) | 2016-05-02 |
| BR112013014808A2 (pt) | 2020-08-11 |
| USRE47569E1 (en) | 2019-08-13 |
| EP2653458B1 (en) | 2017-09-13 |
| KR20140032367A (ko) | 2014-03-14 |
| EP2653458A1 (en) | 2013-10-23 |
| CN103402964A (zh) | 2013-11-20 |
| ES2646749T3 (es) | 2017-12-15 |
| SG190941A1 (en) | 2013-08-30 |
| CN103402964B (zh) | 2015-09-02 |
| JP5914358B2 (ja) | 2016-05-11 |
| MY161174A (en) | 2017-04-14 |
| EP2653458B2 (en) | 2021-03-17 |
| US20130281735A1 (en) | 2013-10-24 |
| ES2646749T5 (es) | 2021-10-21 |
| BR112013014808B1 (pt) | 2021-03-02 |
| EP2653458A4 (en) | 2015-12-09 |
| SA111330055B1 (ar) | 2015-03-31 |
| US9162958B2 (en) | 2015-10-20 |
| JPWO2012081418A1 (ja) | 2014-05-22 |
| TWI511950B (zh) | 2015-12-11 |
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| Date | Code | Title | Description |
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| FG | Grant or registration |