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MX2013003506A - Uso de oxido de (poli) butileno para mejorar la durabilidad de espumas de mdi-poliuretano. - Google Patents

Uso de oxido de (poli) butileno para mejorar la durabilidad de espumas de mdi-poliuretano.

Info

Publication number
MX2013003506A
MX2013003506A MX2013003506A MX2013003506A MX2013003506A MX 2013003506 A MX2013003506 A MX 2013003506A MX 2013003506 A MX2013003506 A MX 2013003506A MX 2013003506 A MX2013003506 A MX 2013003506A MX 2013003506 A MX2013003506 A MX 2013003506A
Authority
MX
Mexico
Prior art keywords
rich
isocyanate reactive
reactive component
weight
polyurethane foams
Prior art date
Application number
MX2013003506A
Other languages
English (en)
Other versions
MX338963B (es
Inventor
Rogelio R Gamboa
Bernard E Obi
Kaoru Aou
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2013003506A publication Critical patent/MX2013003506A/es
Publication of MX338963B publication Critical patent/MX338963B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Las modalidades de la presente invención se refieren a espumas de poliuretano teniendo alto flujo de aire, mientras que mantienen propiedades viscoelásticas. En una modalidad, se proporciona un sistema de reacción para preparación de una espuma de poliuretano viscoelástica. El sistema de reacción comprende (a) un componente de poliisocianto y (b) un componente reactivo de isocianato. El componente reactivo de isocianato comprende (i) desde 35 hasta 74% en peso del componente reactivo de isocianato de uno o más polioles ricos en óxido de propileno (PO-ricos) teniendo un peso equivalente promedio de número combinado desde 200 hasta 500, (ii) desde 24 hasta 50% en peso del componente reactivo de isocianato de uno o más polioles ricos en óxido de etileno (EO-ricos) teniendo un peso equivalente promedio de número combinado desde 200 hasta 2,800, y (iii) desde 2 hasta 10% en peso del componente reactivo de isocianato de uno o más poliéteres ricos en óxido de butileno (BO-ricos) teniendo un peso equivalente promedio de número de 2,000 o más.
MX2013003506A 2010-09-29 2011-08-23 Uso de oxido de (poli) butileno para mejorar la durabilidad de espumas de mdi-poliuretano. MX338963B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38789210P 2010-09-29 2010-09-29
PCT/US2011/048856 WO2012044414A1 (en) 2010-09-29 2011-08-23 Use of poly(butylene oxide) polyol to improve durability of mdi-polyurethane foams

Publications (2)

Publication Number Publication Date
MX2013003506A true MX2013003506A (es) 2013-05-20
MX338963B MX338963B (es) 2016-05-06

Family

ID=44545960

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013003506A MX338963B (es) 2010-09-29 2011-08-23 Uso de oxido de (poli) butileno para mejorar la durabilidad de espumas de mdi-poliuretano.

Country Status (9)

Country Link
US (1) US9255174B2 (es)
EP (1) EP2621984B1 (es)
JP (2) JP2013538916A (es)
CN (1) CN103180358B (es)
AU (1) AU2011307525B2 (es)
BR (1) BR112013006991B1 (es)
ES (1) ES2534299T3 (es)
MX (1) MX338963B (es)
WO (1) WO2012044414A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9029432B2 (en) 2010-09-29 2015-05-12 Dow Global Technologies Llc Process for making high airflow and low compression set viscoelastic polyurethane foam
MX370742B (es) * 2013-05-29 2019-12-20 Dow Quim Mexicana S A De C V Una formulacion para preparar una espuma de poliuretano.
US9951174B2 (en) 2015-05-20 2018-04-24 Covestro Llc Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow
CN106243304A (zh) 2015-06-11 2016-12-21 科思创聚合物（中国）有限公司 粘弹性网状聚氨酯泡沫及其制备方法
WO2017104649A1 (ja) * 2015-12-16 2017-06-22 株式会社ブリヂストン 軟質ポリウレタンフォーム、及びシート用パッド
JP7162609B2 (ja) 2017-03-15 2022-10-28 コベストロ・エルエルシー 温度感度が低減した改良粘弾性フォーム用ポリオール
US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
MX2020009420A (es) * 2018-03-13 2020-11-06 Dow Global Technologies Llc Espuma de poliuretano flexible con tiempo de recuperación prolongado.
CN112424249B (zh) * 2018-07-25 2023-08-25 巴斯夫欧洲公司 用于制备聚氨酯泡沫的不含硅酮的泡沫稳定剂
US10793692B2 (en) 2018-10-24 2020-10-06 Covestro Llc Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers
WO2020137679A1 (ja) * 2018-12-25 2020-07-02 株式会社Adeka ウレタンポリマー及びこれを含む油類組成物
US12351675B2 (en) * 2020-01-06 2025-07-08 Dow Global Technologies Llc Soft, washable polyurethane foam with slow recovery time
JP2023543145A (ja) * 2020-09-21 2023-10-13 サン－ゴバン パフォーマンス プラスティックス コーポレイション ポリウレタンフォーム及びその形成方法
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams
EP4437024A4 (en) * 2021-11-25 2025-08-06 Dow Global Technologies Llc POLYURETHANE COMPOSITIONS AND VISCOELASTIC POLYURETHANE FOAMS HAVING REDUCED SURFACE DEFECT PREPARED THEREFROM

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4596665A (en) 1984-11-23 1986-06-24 The Dow Chemical Company Flexible polymer foams prepared with C4 or higher polyethers as cell openers
US4950694A (en) 1989-06-29 1990-08-21 Union Carbide Chemicals And Plastics Company Inc. Preparation of polyurethane foams without using inert blowing agents
US5137934A (en) * 1989-09-29 1992-08-11 The Dow Chemical Company Alkylene oxide adducts and polyurethane foams prepared therefrom
AU3413195A (en) 1994-08-26 1996-03-22 Dow Chemical Company, The Reduced density flexible polyurethane foam from methylene diphenylisocyanate
JP4856360B2 (ja) * 2001-11-29 2012-01-18 ハンツマン・インターナショナル・エルエルシー 粘弾性ポリウレタン
US20040116594A1 (en) * 2002-12-11 2004-06-17 Debkumar Bhattacharjee Polyurethane prepolymer, stable aqueous dispersions with high solids containing the same and method of using and preparing the aqueous dispersions
KR20090047460A (ko) 2006-08-10 2009-05-12 다우 글로벌 테크놀로지스 인크. 점탄성 폴리우레탄 발포체의 제조 방법
WO2009029621A1 (en) * 2007-08-27 2009-03-05 Dow Global Technologies Inc. Catalysis of natural oil based flexible polyurethane foams with bismuth compounds
JP2011528726A (ja) 2008-07-18 2011-11-24 ダウ グローバル テクノロジーズ エルエルシー 気泡構造物及び粘弾性ポリウレタンフォーム

Also Published As

Publication number Publication date
BR112013006991B1 (pt) 2021-08-31
CN103180358A (zh) 2013-06-26
MX338963B (es) 2016-05-06
AU2011307525A1 (en) 2013-03-21
JP6046842B2 (ja) 2016-12-21
AU2011307525B2 (en) 2015-02-05
JP2013538916A (ja) 2013-10-17
ES2534299T3 (es) 2015-04-21
WO2012044414A1 (en) 2012-04-05
EP2621984A1 (en) 2013-08-07
US20130178548A1 (en) 2013-07-11
EP2621984B1 (en) 2015-02-25
BR112013006991A2 (pt) 2020-11-24
JP2016166328A (ja) 2016-09-15
CN103180358B (zh) 2015-01-21
US9255174B2 (en) 2016-02-09

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