MX2011009379A - Uso de polimeros tipo peine para mejorar la capacidad de soporte de carga. - Google Patents
Uso de polimeros tipo peine para mejorar la capacidad de soporte de carga.Info
- Publication number
- MX2011009379A MX2011009379A MX2011009379A MX2011009379A MX2011009379A MX 2011009379 A MX2011009379 A MX 2011009379A MX 2011009379 A MX2011009379 A MX 2011009379A MX 2011009379 A MX2011009379 A MX 2011009379A MX 2011009379 A MX2011009379 A MX 2011009379A
- Authority
- MX
- Mexico
- Prior art keywords
- load capacity
- comb polymers
- scuffing load
- improving
- repeats
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/04—Molecular weight; Molecular weight distribution
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Lubricants (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invención trata sobre el uso de polímeros tipo peine que constan de unidades repetidas, en la cadena principal, derivadas de macro monómeros con base en poliolefina con peso molecular de al menos 500 g/mol, y unidades repetidas derivadas de monómeros con bajo peso molecular con un peso molecular menor a 500 g/mol, para mejorar la capacidad de carga de los fluidos hidráulicos. Además, la presente invención describe nuevos fluidos hidráulicos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009001447A DE102009001447A1 (de) | 2009-03-10 | 2009-03-10 | Verwendung von Kammpolymeren zur Verbesserung des Lasttragevermögens |
| PCT/EP2010/051564 WO2010102871A1 (de) | 2009-03-10 | 2010-02-09 | Verwendung von kammpolymeren zur verbesserung des lasttragevermögens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2011009379A true MX2011009379A (es) | 2011-12-14 |
Family
ID=42115508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011009379A MX2011009379A (es) | 2009-03-10 | 2010-02-09 | Uso de polimeros tipo peine para mejorar la capacidad de soporte de carga. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20110319305A1 (es) |
| EP (1) | EP2406359A1 (es) |
| JP (1) | JP5675660B2 (es) |
| KR (1) | KR101643440B1 (es) |
| CN (1) | CN102395664B (es) |
| BR (1) | BRPI1009437A8 (es) |
| CA (1) | CA2755054A1 (es) |
| DE (1) | DE102009001447A1 (es) |
| MX (1) | MX2011009379A (es) |
| SG (1) | SG174234A1 (es) |
| WO (1) | WO2010102871A1 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011117262A1 (de) | 2011-10-27 | 2013-05-02 | Li-Tec Battery Gmbh | Verwendung von Kammpolymeren in Lithiumionen-Batterien |
| EP2864459A1 (en) * | 2012-06-21 | 2015-04-29 | Shell Internationale Research Maatschappij B.V. | Lubricating composition |
| CN105246928B (zh) * | 2013-04-18 | 2018-02-13 | 赢创油品添加剂有限公司 | 用于降低燃料消耗的传动油制剂 |
| US10913916B2 (en) * | 2014-11-04 | 2021-02-09 | Shell Oil Company | Lubricating composition |
| FR3031744B1 (fr) * | 2015-01-15 | 2017-02-10 | Total Marketing Services | Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant |
| MX374432B (es) * | 2016-08-31 | 2025-03-06 | Evonik Oil Additives Gmbh | Polímeros de tipo peine para mejorar la pérdida de evaporación de noack de formulaciones de aceite para motor. |
| US10544241B2 (en) | 2016-09-15 | 2020-01-28 | Fina Technology, Inc. | Farnesene-based macromonomers and methods of making and using the same |
| WO2018056316A1 (ja) | 2016-09-21 | 2018-03-29 | 株式会社日本触媒 | 粘度指数向上剤および潤滑油組成物 |
| US20190300808A1 (en) * | 2016-11-02 | 2019-10-03 | Evonik Oil Additives Gmbh | Lubricant composition with an improved viscosity characteristic at low operating temperature |
| EP3555245B1 (en) | 2016-12-19 | 2020-10-28 | Evonik Operations GmbH | Lubricating oil composition comprising dispersant comb polymers |
| JP2019014802A (ja) * | 2017-07-05 | 2019-01-31 | 株式会社日本触媒 | 粘度指数向上剤および潤滑油組成物 |
| US11326120B2 (en) | 2017-08-10 | 2022-05-10 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition, internal combustion engine, and lubrication method for internal combustion engine |
| EP3450527B1 (en) * | 2017-09-04 | 2020-12-02 | Evonik Operations GmbH | New viscosity index improvers with defined molecular weight distributions |
| EP3743490B1 (en) * | 2018-01-23 | 2021-08-18 | Evonik Operations GmbH | Polymeric-inorganic nanoparticle compositions, manufacturing process thereof and their use as lubricant additives |
| KR102587269B1 (ko) * | 2018-01-23 | 2023-10-11 | 에보닉 오퍼레이션스 게엠베하 | 중합체성-무기 나노입자 조성물, 이의 제조 방법 및 윤활제 첨가제로서의 이들의 용도 |
| FR3078706B1 (fr) * | 2018-03-07 | 2020-12-18 | Total Marketing Services | Copolymeres thermoassociatifs et echangeables, composition les comprenant |
| FR3078710B1 (fr) * | 2018-03-07 | 2020-10-30 | Total Marketing Services | Composition comprenant des copolymeres thermoassociatifs et echangeables |
| KR102883633B1 (ko) | 2019-03-20 | 2025-11-11 | 에보니크 오퍼레이션즈 게엠베하 | 연비, 분산력 및 침착 성능을 개선시키기 위한 폴리알킬(메트)아크릴레이트 |
| JP7481814B2 (ja) * | 2019-08-13 | 2024-05-13 | エボニック オペレーションズ ゲーエムベーハー | せん断抵抗性の改善を示す粘度指数向上剤 |
| CN115485354B (zh) | 2020-04-30 | 2023-08-25 | 赢创运营有限公司 | 分散剂聚(甲基)丙烯酸烷基酯聚合物的制备方法 |
| US12065526B2 (en) | 2020-04-30 | 2024-08-20 | Evonik Operations Gmbh | Process for the preparation of polyalkyl (meth)acrylate polymers |
| EP4060009B1 (en) | 2021-03-19 | 2023-05-03 | Evonik Operations GmbH | Viscosity index improver and lubricant compositions thereof |
| EP4119640B1 (en) | 2021-07-16 | 2023-06-14 | Evonik Operations GmbH | Lubricant additive composition containing polyalkylmethacrylates |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US3772196A (en) | 1971-12-03 | 1973-11-13 | Shell Oil Co | Lubricating compositions |
| GB1575507A (en) | 1976-02-10 | 1980-09-24 | Shell Int Research | Hydrogenated star-shaped polymers and oil compositions thereof |
| GB8531392D0 (en) | 1985-12-20 | 1986-02-05 | Unilever Plc | Sulphonated aromated esters |
| DE3611230A1 (de) | 1986-04-04 | 1987-10-08 | Basf Ag | Polybutyl- und polyisobutylamine, verfahren zu deren herstellung und diese enthaltende kraft- und schmierstoffzusammensetzungen |
| DE3700363A1 (de) | 1987-01-08 | 1988-07-21 | Basf Ag | Kraft- oder schmierstoffzusammensetzung und verwendung von polybutyl- oder polyisobutylderivaten in denselben |
| US4965005A (en) * | 1987-09-17 | 1990-10-23 | Ciba-Geigy Corporation | Aminomethyl derivatives of monothiocarbamates and dithiocarbamates as additives for lubricants |
| DE3930142A1 (de) * | 1989-09-09 | 1991-03-21 | Roehm Gmbh | Dispergierwirksame viskositaets-index-verbesserer |
| US5310814A (en) * | 1991-03-15 | 1994-05-10 | Exxon Chemical Patents Inc. | Viscosity modifier polybutadiene polymers |
| BE1006694A5 (fr) | 1991-06-22 | 1994-11-22 | Basf Ag | Procede de preparation de polyisobutenes extremement reactifs. |
| US5393843A (en) | 1992-08-31 | 1995-02-28 | Shell Oil Company | Butadiene polymers having terminal functional groups |
| DE4312715A1 (de) * | 1993-04-20 | 1994-10-27 | Roehm Gmbh | Kammpolymere |
| DE4431302A1 (de) | 1994-09-02 | 1996-03-07 | Roehm Gmbh | Kammpolymere |
| US6156228A (en) * | 1994-11-16 | 2000-12-05 | Houghton International, Inc. | Trialkoxyalkylphosphate-based fire resistant fluid containing triglyceride |
| US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
| US6127481A (en) | 1995-08-04 | 2000-10-03 | Dsm Copolymer, Inc. | Branched polyolefin polymers as additives in fuel and lubricating oil compositions |
| US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
| AU735085B2 (en) | 1996-06-12 | 2001-06-28 | Warwick Effect Polymers Limited | Polymerisation catalyst and process |
| US7714075B1 (en) | 1996-07-10 | 2010-05-11 | Commonwealth Scientific And Industrial Research Organisation | Polymerization with living characteristics |
| TW593347B (en) | 1997-03-11 | 2004-06-21 | Univ Carnegie Mellon | Improvements in atom or group transfer radical polymerization |
| US6071980A (en) | 1997-08-27 | 2000-06-06 | E. I. Du Pont De Nemours And Company | Atom transfer radical polymerization |
| DE10303275A1 (de) | 2003-01-28 | 2004-07-29 | Basf Ag | Funktionalisierung von ungesättigten Isobutenpolymeren durch Hydroborierung |
| US6841695B2 (en) | 2003-03-18 | 2005-01-11 | Rohmax Additives Gmbh | Process for preparing dithioesters |
| DE10314776A1 (de) * | 2003-03-31 | 2004-10-14 | Rohmax Additives Gmbh | Schmierölzusammensetzung mit guten Reibeigenschaften |
| DE102004021778A1 (de) | 2004-04-30 | 2005-12-08 | Rohmax Additives Gmbh | Verwendung von Polyalkyl(meth)acrylaten in Schmierölzusammensetzungen |
| DE102005031244A1 (de) * | 2005-07-01 | 2007-02-15 | Rohmax Additives Gmbh | Öllösliche Kammpolymere |
| DE102005041528A1 (de) | 2005-08-31 | 2007-03-01 | Rohmax Additives Gmbh | Öllösliche Polymere |
| US20070066495A1 (en) * | 2005-09-21 | 2007-03-22 | Ian Macpherson | Lubricant compositions including gas to liquid base oils |
| US20070197410A1 (en) * | 2006-02-21 | 2007-08-23 | Rohmax Additives Gmbh | Energy efficiency in hydraulic systems |
| CN101687963B (zh) * | 2007-07-09 | 2015-05-06 | 赢创罗麦斯添加剂有限责任公司 | 梳形聚合物用于降低燃料消耗的用途 |
| DE102007032120A1 (de) * | 2007-07-09 | 2009-01-15 | Evonik Rohmax Additives Gmbh | Verwendung von Kammpolymeren zur Verringerung des Kraftstoffverbrauchs |
| DE102007036856A1 (de) * | 2007-08-06 | 2009-02-26 | Evonik Rohmax Additives Gmbh | Verwendung von Estergruppen-umfassenden Polymeren als Antifatigue-Additive |
-
2009
- 2009-03-10 DE DE102009001447A patent/DE102009001447A1/de not_active Withdrawn
-
2010
- 2010-02-09 US US13/255,218 patent/US20110319305A1/en not_active Abandoned
- 2010-02-09 BR BRPI1009437A patent/BRPI1009437A8/pt not_active IP Right Cessation
- 2010-02-09 JP JP2011553377A patent/JP5675660B2/ja not_active Expired - Fee Related
- 2010-02-09 CA CA2755054A patent/CA2755054A1/en not_active Abandoned
- 2010-02-09 MX MX2011009379A patent/MX2011009379A/es unknown
- 2010-02-09 EP EP10704537A patent/EP2406359A1/de not_active Withdrawn
- 2010-02-09 KR KR1020117023618A patent/KR101643440B1/ko not_active Expired - Fee Related
- 2010-02-09 SG SG2011063567A patent/SG174234A1/en unknown
- 2010-02-09 WO PCT/EP2010/051564 patent/WO2010102871A1/de not_active Ceased
- 2010-02-09 CN CN201080017003.6A patent/CN102395664B/zh not_active Expired - Fee Related
-
2012
- 2012-06-20 US US13/528,510 patent/US20120258899A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2755054A1 (en) | 2010-09-16 |
| JP5675660B2 (ja) | 2015-02-25 |
| DE102009001447A1 (de) | 2010-09-16 |
| US20110319305A1 (en) | 2011-12-29 |
| US20120258899A1 (en) | 2012-10-11 |
| EP2406359A1 (de) | 2012-01-18 |
| CN102395664A (zh) | 2012-03-28 |
| BRPI1009437A2 (pt) | 2016-03-01 |
| JP2012520358A (ja) | 2012-09-06 |
| BRPI1009437A8 (pt) | 2018-05-08 |
| WO2010102871A1 (de) | 2010-09-16 |
| CN102395664B (zh) | 2017-02-08 |
| SG174234A1 (en) | 2011-10-28 |
| KR101643440B1 (ko) | 2016-07-27 |
| KR20110139254A (ko) | 2011-12-28 |
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