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MX2010008963A - Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato. - Google Patents

Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.

Info

Publication number
MX2010008963A
MX2010008963A MX2010008963A MX2010008963A MX2010008963A MX 2010008963 A MX2010008963 A MX 2010008963A MX 2010008963 A MX2010008963 A MX 2010008963A MX 2010008963 A MX2010008963 A MX 2010008963A MX 2010008963 A MX2010008963 A MX 2010008963A
Authority
MX
Mexico
Prior art keywords
plasticizer
composition
polymers
polymer
phthalate
Prior art date
Application number
MX2010008963A
Other languages
English (en)
Inventor
Robeart Eaton
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40433772&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2010008963(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of MX2010008963A publication Critical patent/MX2010008963A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/08—Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)

Abstract

La presente invención es un sistema de reemplazo de plastificador hecho de o que contiene un plastificador de éster de ácido graso epoxidizado como un plastificador primario y un plastificador secundario. El sistema de reemplazo de colocación es útil con una variedad de polímeros en aplicaciones tales como aislamiento de alambre y cable, fundas de alambre y cable, recubrimientos, adhesivos y fundición.

Description

SISTEMA PLASTIFICANTE DE REEMPLAZO PAR FORMULACIONES PLASTIFICADAS CON FTALAT scripción de la Invención La presente invención se refiere generalmente al c limeros. Específicamente, la presente invención se r n plastificantes usados en polímeros para crear caract icas deseadas en el complejo de polímero/pla ultante, tal como flexibilidad, plegabilidad, y pí rementada en el complejo de polímero resultante.
Por ejemplo, los plastificantes tal como di (2-etilhex EHP" por sus siglas en inglés), di-isononilftalato ("D s siglas en inglés), y otros plastificantes de ftalato rante mucho tiempo plastificantes estándares de la i ados con polímeros tal como homo- y copolímeros de cl I i i n i I o ("PVC" por sus siglas en inglés), dicloruros de " partida a un polímero.
Los plastifícantes de ftalato tal como DEHP y DIN a vez plastifícantes preferidos debido a su capac partí r las características físicas conocidas antes rmanencia en el polímero durante el tiempo, incluso cu puestos relativamente a temperaturas altas y húmed bargo, el sentimiento público ha incitado a muchos fa productos de consumo a continuar con el uso de ftalat stificantes debido a las preocupaciones sobre efectos versos potenciales. Así, composiciones de plastific ucen o eliminan ftalatos, pero funcionan similarmente os plastifícantes de ftalato eficientes, serán ap yormente en la técnica. Por otra parte, los plastific -ftalato alternativos, que muestran una permanencia r , y la alta compatibilidad con, un intervalo amplio de p rán apreciados mayormente en la técnica. sos tal como el metiléter epoxidado de aceite de s masiado volátiles para servir como plastificantes útiles Sin embargo, existe la necesidad de plastificantes l lato que sean compatibles con otros plasti ecuadamente no volátiles, no basados en petróleo, y impartir estabilidad térmica a formulaciones que act lizan plastificantes de ftalato. Es adicionalmente ra ampliar las aplicaciones en las cuales el PV límeros halogenados, polímeros funcionalizados po límeros funcionalizados por anhídrido, y cauchos d eden utilizarse desarrollando nuevas formu stificadas. En algunos casos, podría resultar útil stificante o el sistema de plastificante actuar c minador de ácido.
Para tal fin, se proporciona el sistema de plastifi stitución en la actualidad, que comprende un plastifi teres de mono-alquilo de ácidos grasos de cade rivados de aceites vegetales o aceites a eferiblemente, el biodiesel se deriva de aceites vegetal También, preferiblemente, el éster de ácid oxidado es un epóxido de un metiléter de ácido gra neralmente, el éster de ácido graso epoxidado pu alquier éster de 1 a 14 átomos de carbono del áci oxidado, incluyendo ésteres de etilo, propilo, b etilhexilo.
El éster del ácido graso epoxidado puede prepa a variedad de maneras convencionales. Por eje eites naturales pueden utilizarse como la materia pri e caso, los aceites naturales pueden saponificarse a lo asos y después esterificarse con alcoholes. Des oxidizan los ésteres de peso molecular bajo. aturado puede epoxidizarse con un perácido. ductos de reacción debido a la insolubilidad. Una sol rácido acético en acetato de etilo se utiliza para epoxi aces dobles en los ácidos grasos. El perácido se mant bajo de 35% de perácido y 35 grados centígrados para detonación. Después de la terminación, el acetato d ido acético de producto se eliminan vía extracción al va Cuando se formula con el polímero, el plastificante tá presente en una cantidad de aproximadament roximadamente 60 partes por ciento de caucho.
Los plastificantes secundarios adecuados alquier plastificante que tiene una presión de vapor me e la del éster del ácido graso epoxidado. Por ejemplo éster del ácido graso epoxidado es un epóxido de un l ácido graso, un plastificante secundario adec feriblemente aceite de soya epoxidado. Los plast cundarios incluyen aceite de soya epoxidado, aceite oxidado e óxidos de otros aceites ve etales a stificante está presente en una cantidad de aproxima a aproximadamente 60 porciones por ciento de feriblemente, los plastificantes primario y secundar sentes en una relación 1:1.
Los polímeros adecuados para utilizar el sist stificante de reemplazo de la presente invención limeros halogenados, polímeros funcionalizados po limeros funcionalizados por anhídrido, y cauchos d feriblemente, el polímero es un polímero halo feriblemente, el polímero halogenado es un polímero eccionado del grupo que consiste de homopolímeros olímeros de PVC, dicloruros de polivinilo (PVDC), y p vinilcloruro con vinilo, acrílico y otros comonómero mplos de otros polímeros halogenados adecuad liolefinas cloradas y cauchos clorados.
Los polímeros funcionalizados por ácido ad EMPLOS Los siguientes ejemplos no limitadores ilu ención. mplo 1 v Ejemplo Comparativo 2 Una formulación de aislamiento de alambre plificada se produjo con un plastificante primario y se PVC usado fue el homopolímero del cloruro de ychem 240F, que tiene un valor K de 70. El carb lcio se obtuvo de materiales de Huber. El dila utilestaño (DBTDL) se obtuvo de Arkema. El aceite oxidado se obtuvo de Ferro Corp.
El ejemplo comparativo se preparó utilizando ft sodecilo (DIDP), un plastificante convencional, stificante primario y se obtuvo de VWR Internatio mplo de la presente invención se preparó con oxidado como el plastificante primario. mponente Ejemplo Ej. Comp. TDL 4 4 eite de soya epoxidado 2 2 Propiedades Físicas 42 grados centígrados 42 grados centí mplo 3 y Ejemplo Comparativo 4 Una formulación de cubierta de cable eléctrico plificada se produjo. El PVC fue homopolímero del el ivinilo de Oxychem 240F, que tiene un valor K de rbonato de calcio se obtuvo de materiales de Hub abilizador de Zn/Ca se obtuvo como estabilizador de RK™ 6797 de Chemtura Corporation. El antioxid tioxidante fenólico obstaculizado monofuncional de IR 76 disponible de Ciba Corporation. El aceite de soya e obtuvo de Ferro Corp. La cantidad de cada compo estra basada en partes por ciento de caucho (phr). mponente Ejemplo Ej. Comp. eite de soya epoxidado 27.5 4 C03 68 68 tabilizador de Zn/Ca 2.5 2.5 tioxidante 0.05 0.05 Propiedades Físicas ore A 85 75 nsión a rotura (inicial) 260% 400% nsión a rotura (antigua) 180% 200% de alargamiento retenido 73% 50%

Claims (1)

  1. REIVINDICACIONES 1. Una composición del sistema plastifica mprende: (a) un plastificante primario que consiste stificante de éster del ácido graso epoxidado y (b) un plastificante secundario. 2. La composición del sistema plastifica nformidad con la reivindicación 1, caracterizado p stificante primario se selecciona del grupo que co diesel epoxidado y derivados epoxidados de ésteres aso de biodiesel. 3. La composición del sistema plastifica nformidad con la reivindicación 2, caracterizado p diesel se deriva de un aceite vegetal. 4. El sistema del plastificante de conformida ivindicación 2, caracterizado porque el éster del áci vindicación 5, caracterizado porque el sistema está lato. 7. El sistema plastificante de conformidad con C las reivindicaciones 1 a 4, caracterizado po stificante secundario es un ftalato basado en petróleo. 8. Una composición de polímero plastifica mprende: (a) un polímero seleccionado del grupo que con limeros halogenados, polímeros funcionalizados po límeros funcionalizados por anhídrido, y cauchos de nit (b) un sistema plastificante de acuerdo con cualq reivindicaciones 1 a 6. 9. Una composición del polímero libre ftalato pía e comprende: (a) un polímero seleccionado del grupo que con límeros halogenados, polímeros funcionalizados po ímeros funcionalizados or anhídrido, cauchos de nit 11. Un cable que comprende uno o más con ctricos o una base de uno o más conductores eléctr a conductor o base siendo rodeados por una c mprende la composición del polímero plastificado de n cualquiera de las reivindicaciones 8 a 10.
MX2010008963A 2008-02-15 2009-02-12 Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato. MX2010008963A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2903508P 2008-02-15 2008-02-15
PCT/US2009/033935 WO2009102877A1 (en) 2008-02-15 2009-02-12 A replacement plasticizer system for phthalate-plasticized formulations

Publications (1)

Publication Number Publication Date
MX2010008963A true MX2010008963A (es) 2011-02-24

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MX2010008963A MX2010008963A (es) 2008-02-15 2009-02-12 Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.

Country Status (10)

Country Link
US (1) US8557139B2 (es)
EP (1) EP2245089B2 (es)
JP (1) JP5261504B2 (es)
KR (2) KR20100127216A (es)
CN (2) CN102007176A (es)
BR (1) BRPI0905919B1 (es)
CA (1) CA2715287C (es)
MX (1) MX2010008963A (es)
TW (1) TW200940609A (es)
WO (1) WO2009102877A1 (es)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2010008963A (es) 2008-02-15 2011-02-24 Union Carbide Chem Plastic Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.
US8552098B2 (en) 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
CA2775975C (en) * 2009-09-30 2016-11-08 Dow Global Technologies Llc Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
US8802988B2 (en) 2009-09-30 2014-08-12 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
JP5693589B2 (ja) 2009-09-30 2015-04-01 ダウ グローバル テクノロジーズ エルエルシー １２−ヒドロキシステアリン酸のアセチル化グリセリドおよびエポキシ化脂肪酸エステルとのブレンド
CN102985481A (zh) * 2010-05-10 2013-03-20 陶氏环球技术有限责任公司 由源自可再生资源的增塑剂制备的挠性pvc组合物
TW201209168A (en) 2010-07-28 2012-03-01 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same
US9034965B2 (en) 2010-08-06 2015-05-19 Arkema Inc. Epoxidized composition and methods for making the same
US20130206450A1 (en) * 2010-11-05 2013-08-15 Dow Global Technologies Llc Plasticizer system with improved electrical properties
EP2452971B1 (de) * 2010-11-12 2013-08-14 Tudapetrol Mineralölerzeugnisse Nils Hansen KG Sauerstoffhaltige Verbindungen als Weichmacher für Kautschuk
US9238728B2 (en) 2011-01-24 2016-01-19 Arkema Inc. Epoxidized fatty acid alkyl esters as flexibilizers for poly(lactic acid)
JP2014534985A (ja) * 2011-09-30 2014-12-25 ダウ グローバル テクノロジーズ エルエルシー 熱老化中の色保持を目的とした可塑剤
US9056965B2 (en) * 2011-09-30 2015-06-16 Dow Global Technologies Llc Process for mixing polyvinyl chloride with a bio-based plasticizer
CA2850429C (en) 2011-09-30 2020-06-02 Dow Global Technologies Llc Plasticizer for low temperature unwind with weight retention during heat aging
JP6151260B2 (ja) * 2011-10-14 2017-06-21 ガラタ ケミカルズ，エルエルシー 再生可能原料から誘導される可塑剤
CN103059441A (zh) * 2011-10-20 2013-04-24 常熟市筑紫机械有限公司 一种改性的聚氯乙烯电线电缆材料
CN102504444A (zh) * 2011-11-22 2012-06-20 浙江嘉澳环保科技股份有限公司 增塑剂及含有该增塑剂的pvc环保型电线电缆护套料
MX357165B (es) * 2012-02-08 2018-06-28 Dow Global Technologies Llc Composiciones de plastificante y metodos para fabricar composiciones de plastificante.
CN104379653B (zh) 2012-06-22 2017-07-18 陶氏环球技术有限责任公司 乙酰化多元醇羟基硬脂酸酯增塑剂和经增塑的聚合物组合物
EP2864406B1 (en) 2012-06-26 2017-03-08 Dow Global Technologies LLC Plasticizers and plasticized polymeric compositions
EP2875069B1 (en) * 2012-07-17 2017-09-20 Italmatch Chemicals S.P.A. Pvc flame retardant compositions
MX370205B (es) * 2012-10-18 2019-12-05 Dow Global Technologies Llc Plastificantes de alquil esteres de acidos grasos epoxidados y metodos para hacer plastificantes de alquil esteres de acidos grasos epoxidados.
KR101570386B1 (ko) 2012-10-25 2015-11-19 애경유화주식회사 에폭시계 에스테르 화합물을 포함한 복합 가소제 조성물 및 이를 이용한 고분자 수지 조성물
JP6189967B2 (ja) * 2012-11-12 2017-08-30 ダウ グローバル テクノロジーズ エルエルシー エポキシ化脂肪酸アルキルエステルを作製するための方法
KR102017370B1 (ko) 2012-11-12 2019-09-02 다우 글로벌 테크놀로지스 엘엘씨 에폭시화 지방산 알킬 에스테르 가소제 및 에폭시화 지방산 알킬 에스테르 가소제의 제조 방법
CN110256857B (zh) * 2012-12-29 2022-01-04 美国圣戈班性能塑料公司 柔性管
CA2904869C (en) * 2013-03-15 2021-02-16 Dow Global Technologies Llc Epoxidized-fatty-acid-alkyl-ester plasticizers from natural-oil soap stock and methods for making such epoxidized-fatty-acid-alkyl-ester plasticizers
BR102013010477A2 (pt) 2013-04-29 2015-11-17 Brasil Bio Fuels S A ésteres de acetais produzidos a partir de glicerina purificada para o uso e aplicações como emolientes, lubrificantes, plastificantes, solventes, coalescentes, umectantes, monomeros de polimerização, aditivos para biocombustíveis
WO2014197327A1 (en) 2013-06-03 2014-12-11 Regents Of The University Of Minnesota Epoxy estolide fatty acid alkyl esters useful as biorenewable plasticizers
US9221958B2 (en) 2013-08-23 2015-12-29 Valtris Specialty Chemicals Plasticizer mixture of epoxidized fatty acid glycerin carbonate ester and epoxidized fatty acid esters
EP3186234A1 (en) 2014-08-29 2017-07-05 Iowa State University Research Foundation, Inc. Improved asphalt products and materials and methods of producing them
SE539458C2 (en) * 2014-09-15 2017-09-26 Perstorp Ab A highly stable plasticized polyvinyl halide composition comprising pentaerythritoltetravalerate and an epoxidized unsaturated fatty acid ester.
CN104877170A (zh) * 2015-04-29 2015-09-02 苏州乔布注塑工业有限公司 一种pvc内润滑剂
KR101793383B1 (ko) * 2015-07-24 2017-11-20 주식회사 엘지화학 가소제 조성물, 수지 조성물 및 이들의 제조 방법
KR102019938B1 (ko) 2015-07-24 2019-09-11 주식회사 엘지화학 가소제 조성물, 수지 조성물 및 이들의 제조 방법
WO2017018741A1 (ko) * 2015-07-24 2017-02-02 주식회사 엘지화학 가소제 조성물, 수지 조성물 및 이들의 제조 방법
US10144812B2 (en) * 2015-10-05 2018-12-04 Regents Of The University Of Minnesota Multi-functional fatty acid ester derivatives useful as biorenewable plasticizers
US10407560B2 (en) 2015-10-27 2019-09-10 Lg Chem, Ltd. Plasticizer composition, resin composition, and methods for preparing same
US10577493B2 (en) 2016-01-13 2020-03-03 Arkema Inc. Phthalate-free, epoxidized plasticizer compositions comprising fatty acid esters and bio-based oils, and methods of making the same
US10961395B2 (en) 2016-02-29 2021-03-30 Iowa State University Research Foundation, Inc. Rejuvenation of vacuum tower bottoms through bio-derived materials
US10570286B2 (en) 2016-08-30 2020-02-25 Iowa State University Research Foundation, Inc. Asphalt products and methods of producing them for rejuvenation and softening of asphalt
KR102234147B1 (ko) * 2018-12-28 2021-03-31 엘에스전선 주식회사 케이블 시스용 수지 조성물 및 이를 포함하는 전선
US11773265B2 (en) 2019-09-18 2023-10-03 Iowa State University Research Foundation, Inc. Biosolvents useful for improved asphalt products utilizing recycled asphalt pavement or other brittle asphalt binders such as vacuum tower bottom
US12297150B2 (en) 2020-10-12 2025-05-13 Iowa State University Research Foundation, Inc. Maintenance treatments useful for improving the performance of aged or brittle resinous binders in paving or roofing
JP7784788B2 (ja) * 2022-03-25 2025-12-12 株式会社松風 歯科用研磨材
CN116640555A (zh) * 2023-04-23 2023-08-25 深圳市安伯斯科技有限公司 硅凝胶及其制备方法
WO2025128797A1 (en) 2023-12-13 2025-06-19 Blue Evolution, Inc Ecofriendly, biodegradable biological polysaccharide composition for packaging materials

Family Cites Families (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR499931A (fr) 1917-12-08 1920-02-26 Twitchell Process C Sulfonate de métaux alcalins et son procédé de fabrication
US2397592A (en) 1940-08-02 1946-04-02 Gen Cable Corp Resinous compositions for wire coatings and the like
US2403215A (en) 1943-10-14 1946-07-02 Du Pont Resinous compositions and electrical conductors insulated therewith
US2500918A (en) 1945-08-10 1950-03-14 Goodrich Co B F Acylation of hydroxylated esters
US2458484A (en) 1946-06-17 1949-01-04 Gen Mills Inc Process of preparing epoxy derivatives from unsaturated aliphatic compounds
US2618622A (en) 1950-01-17 1952-11-18 Sherwin Williams Co Plasticizer for vinyl halides
US2666752A (en) 1950-01-17 1954-01-19 Sherwin Williams Co Stabilizer for halogen-containing polymers
GB790314A (en) 1955-02-23 1958-02-05 Lankro Chem Ltd New derivatives or acetylated castor oil and esters of acetylated ricinoleic acid, and polymers plasticised therewith
US3281382A (en) * 1956-08-27 1966-10-25 Swift & Co Halogenated polymers containing complex epoxy fatty esters
GB934689A (en) 1959-04-22 1963-08-21 Swift & Co Epoxy fatty acid esters and polyvinyl resin compositions containing them
NL131832C (es) 1959-11-12
US3138566A (en) 1960-01-08 1964-06-23 Gen Mills Inc Fluid resins prepared from epoxidized unsaturated fatty acids or esters
BE647338A (es) 1963-05-01 1964-10-30
FR1437722A (fr) 1964-04-03 1966-05-06 Allied Chem Compositions à base de polymères vinyliques servant de revêtement du sol
US3409580A (en) 1964-05-01 1968-11-05 Ethyl Corp Polyvinyl halide plastisols containing cyclohexyl amines and cellular products therefrom
NL127901C (es) 1966-02-10
US3639318A (en) * 1968-05-29 1972-02-01 Union Carbide Corp Plasticized polyvinyl chloride film
DE2009047C2 (de) 1970-02-26 1982-04-08 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von Epoxystearinsäureestern
DE2021530A1 (de) 1970-05-02 1971-11-25 Henkel & Cie Gmbh Verfahren zur Herstellung von Oxyfettsaeureestern
US3891694A (en) 1970-05-18 1975-06-24 Monsanto Co Plasticizer purification
US3668091A (en) 1971-02-02 1972-06-06 Ashland Oil Inc Ultraviolet light bleaching of carboxylic acid esters and epoxy compounds
US3712875A (en) * 1971-02-22 1973-01-23 Union Carbide Corp Synergistic additive system for anti-fog vinyl film
US3780140A (en) 1971-08-06 1973-12-18 Du Pont Ethylene/carbon monoxide polymer compositions
US3868341A (en) † 1972-06-02 1975-02-25 Western Electric Co Clear flame retardant composition
US3872187A (en) 1972-09-18 1975-03-18 Tenneco Chem Aryloxyalkyl haloalkyl phosphates
US4083816A (en) 1976-06-25 1978-04-11 The United States Of America As Represented By The Secretary Of Agriculture Acetoxymethyl derivatives of polyunsaturated fatty triglycerides as primary plasticizers for polyvinylchloride
DE2652328A1 (de) 1976-11-17 1978-05-18 Neynaber Chemie Gmbh Bleiverbindungen enthaltende stabilisator-gleitmittel-kombination fuer formmassen auf basis von polyvinylchlorid
US4346145A (en) 1981-01-05 1982-08-24 Western Electric Co., Inc. Coating composition and coated articles
DE3125376A1 (de) 1981-06-27 1983-01-13 Hoechst Ag, 6000 Frankfurt Thermoplastische formmassen auf der basis von vinylchloridpolymerisaten und schlagzaehmodifizierungspolymeren
JPS5832647A (ja) 1981-08-21 1983-02-25 Riken Vitamin Co Ltd 熱可塑性樹脂組成物
US4613533A (en) 1982-07-01 1986-09-23 E. I. Du Pont De Nemours And Company Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
US4627993A (en) 1982-07-01 1986-12-09 E. I. Du Pont De Nemours And Company Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
DE3326455A1 (de) 1983-07-22 1985-01-31 Henkel Kgaa Kosmetisch-pharmazeutische oelkomponenten
JPS6133661A (ja) 1984-02-02 1986-02-17 テルモ株式会社 医療用器具
JPS6116950A (ja) * 1984-07-02 1986-01-24 Mitsubishi Kasei Vinyl Co 農業用塩化ビニル系樹脂フイルム
US4556694A (en) 1984-07-26 1985-12-03 E. I. Du Pont De Nemours And Company Low temperature flexible PVC blends
DE3503383A1 (de) 1985-02-01 1986-08-07 Hoechst Ag, 6230 Frankfurt Folie auf basis von vinylchloridpolymerisat und ihre verwendung zur herstellung steifer rohrfoermiger koerper
US4670494A (en) † 1985-07-30 1987-06-02 Gary Chemical Corp. Flame retardant low smoke poly(vinyl chloride) thermoplastic composition
US4605694A (en) 1985-10-31 1986-08-12 Hercules Incorporated Plasticizing compositions for polyvinylchloride
US4857600A (en) 1988-05-23 1989-08-15 Union Carbide Corporation Process for grafting diacid anhydrides
US5036121A (en) 1988-09-06 1991-07-30 The B. F. Goodrich Company Flame and smoke retardant cable insulation and jacketing compositions
AU610013B2 (en) 1988-09-09 1991-05-09 B.F. Goodrich Company, The Flexible blend compositions based on overpolymers of vinyl chloride polymers on ethylene copolymers
JPH0354233A (ja) 1989-04-19 1991-03-08 Furukawa Electric Co Ltd:The 複合難燃剤およびそれを含有する難燃性樹脂組成物
HU209937B (en) 1989-05-04 1994-12-28 Du Pont Polyvinyl chloride composition and calendered sheet prepared from it
US5225108A (en) 1990-05-18 1993-07-06 Witco Corporation Polymer stabilizer and polymer composition stabililzed therewith
AU8025991A (en) 1990-07-20 1992-01-23 B.F. Goodrich Company, The Improved barrier pvc resins, compounds and articles derived therefrom
JPH0485354A (ja) * 1990-07-27 1992-03-18 Asahi Denka Kogyo Kk 農業用塩化ビニル系樹脂組成物
JPH04261452A (ja) 1991-02-15 1992-09-17 Asahi Denka Kogyo Kk 農業用塩化ビニル系樹脂組成物
US5246783A (en) 1991-08-15 1993-09-21 Exxon Chemical Patents Inc. Electrical devices comprising polymeric insulating or semiconducting members
US5227417A (en) * 1992-01-24 1993-07-13 Cooper Industries, Inc. Polyvinyl chloride based plenum cable
US5484844A (en) 1992-04-14 1996-01-16 Mitsubishi Chemical Mkv Company Vinyl chloride resin elastomer composition
JPH07508066A (ja) † 1992-05-19 1995-09-07 クロンプトン・コーポレーション 鉛ではない安定剤を用いて安定化した電気絶縁用の塩化ビニル樹脂組成物
US5466267A (en) 1992-09-17 1995-11-14 Mobil Oil Corporation Oligomeric/polymeric multifunctional additives to improve the low-temperature properties of distillate fuels
US5454806A (en) 1992-11-06 1995-10-03 Terumo Kabushiki Kaisha Medical device
US5270366A (en) 1992-12-16 1993-12-14 Vista Chemical Company Lead stabilized, flexible polymeric blends containing polyvinylchloride
US5886072A (en) 1993-05-24 1999-03-23 Teknor Apex Company Flame retardant composition
US5430108A (en) 1994-01-14 1995-07-04 Exxon Chemical Patents Inc. Polyol ester PVC plasticizers
US5464903A (en) 1994-10-31 1995-11-07 E. I. Du Pont De Nemours And Company Process for preparing ethylene copolymer plasticized PVC
US5575965A (en) 1995-05-19 1996-11-19 Union Carbide Chemicals & Plastics Technology Corporation Process for extrusion
JP3036405B2 (ja) 1995-06-14 2000-04-24 三菱化学エムケーブイ株式会社 塩化ビニル系樹脂組成物
US5929133A (en) 1996-02-16 1999-07-27 Hitachi Chemical Filtec, Inc. Anti-bacterial film suitable for food packaging
US6063846A (en) 1997-05-30 2000-05-16 Teknor Apex Company Polyvinyl chloride compositions
US6114425A (en) 1997-07-17 2000-09-05 Unitex Chemical Corporation Plasticized polyvinyl chloride compound
BE1011906A3 (nl) 1998-05-12 2000-02-01 Atlas Copco Airpower Nv Inrichting voor het scheiden van twee onmengbare vloeistoffen met verschillend soortelijk gewicht.
US6274750B1 (en) 1998-07-21 2001-08-14 Cognis Corporation Dimer and trimer acid esters from epoxidized compounds and methods for their preparation
BR9917230A (pt) 1999-04-21 2002-01-08 Basf Ag Mistura de diésteres de nonanol isomérico de um ácido dicarboxìlico, e, uso da mesma
JP2000319468A (ja) * 1999-05-07 2000-11-21 Asahi Denka Kogyo Kk 塩化ビニル系樹脂用安定剤組成物
US6496629B2 (en) 1999-05-28 2002-12-17 Tycom (Us) Inc. Undersea telecommunications cable
US6949597B2 (en) 1999-08-19 2005-09-27 Danisco A/S Composition
DK1624014T3 (da) 1999-08-19 2010-01-11 Danisco Specifikke acylerede glycerolforbindelser som blödgöringsmidler i polymerer og fremgangsmåde til deres fremstilling
US6608142B1 (en) 2000-05-08 2003-08-19 Teknor Apex Company Polyvinyl chloride compositions
US6797753B2 (en) * 2000-06-20 2004-09-28 Battelle Memorial Institute Plasticizers derived from vegetable oils
CN1341681A (zh) * 2000-09-07 2002-03-27 苏州德威实业有限公司 用于电线电缆的软聚氯乙烯塑料
US6451958B1 (en) 2001-04-06 2002-09-17 Sartomer Technology Company Inc. Radiation curable acrylate-terminated polymers having polycarbonate repeating units
JP2003064233A (ja) 2001-08-27 2003-03-05 C I Kasei Co Ltd 農業用塩化ビニル系樹脂フィルム及び塩化ビニル系樹脂組成物
US6706815B2 (en) 2001-09-06 2004-03-16 Dupont Dow Elastomers L.L.C. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US6849694B2 (en) 2002-01-17 2005-02-01 Dupont Dow Elastomers, Llc Impact modifier compositions for rigid PVC compositions of hydrocarbon rubbers and chlorinated polyethylene
US6714707B2 (en) 2002-01-24 2004-03-30 Alcatel Optical cable housing an optical unit surrounded by a plurality of gel layers
JP2003297149A (ja) 2002-04-04 2003-10-17 Fujikura Ltd 電気絶縁性ポリ塩化ビニル樹脂組成物
US6869985B2 (en) 2002-05-10 2005-03-22 Awi Licensing Company Environmentally friendly polylactide-based composite formulations
JP4204305B2 (ja) 2002-11-08 2009-01-07 株式会社Ａｄｅｋａ ポリエステル系可塑剤及び塩素含有樹脂組成物
WO2004052977A1 (en) 2002-12-06 2004-06-24 Cognis Brasil Ltda. Plasticized poly vinyl chloride compositions
US7015285B2 (en) 2002-12-18 2006-03-21 General Electric Composition and method for improving the adhesion of polyphenylene ether moldings to polyurethane foam
US20040122149A1 (en) 2002-12-19 2004-06-24 Kadakia Vishal S. Flame-retardant polyvinyl chloride compositions
JP2004311064A (ja) 2003-04-02 2004-11-04 Fujikura Ltd 直流電力ケーブル
JP4640753B2 (ja) 2003-12-08 2011-03-02 株式会社Adeka 塩化ビニル系樹脂組成物
FR2880892B1 (fr) 2005-01-17 2008-03-21 Gerflor Sa Utilisation d'acides gras esterifies comme plastifiants du pvc
JP2006335874A (ja) 2005-06-02 2006-12-14 Kao Corp 生分解性樹脂用可塑剤
DE102005031945A1 (de) * 2005-07-08 2007-01-11 Construction Research & Technology Gmbh Verwendung von entfärbtem Biodiesel als Weichmacher
DE102005059143A1 (de) * 2005-12-08 2007-06-14 J. S. Staedtler Gmbh & Co. Kg Modelliermasse sowie deren Verwendung
CN101108982A (zh) * 2006-07-21 2008-01-23 时代环保能源集团（香港）投资有限公司 一种用生物柴油制取的塑料环保增塑剂
JP5094109B2 (ja) 2006-12-22 2012-12-12 株式会社Ａｄｅｋａ 塩化ビニル系樹脂組成物
GB0700076D0 (en) 2007-01-03 2007-02-07 Danisco Compound
GB0700074D0 (en) 2007-01-03 2007-02-07 Danisco process
US20080227993A1 (en) 2007-03-17 2008-09-18 Matthew Mark Zuckerman Synthesizing and compounding molecules from and with plant oils to improve low temperature behavior of plant oils as fuels, oils and lubricants
EP1978013A1 (en) 2007-04-04 2008-10-08 Cognis IP Management GmbH Diols and polyols
CN100590188C (zh) * 2007-05-22 2010-02-17 江阴市向阳科技有限公司 利用废弃油脂生产环氧增塑剂的方法
EP2223970B1 (en) 2007-11-28 2014-03-26 Adeka Corporation Stabilizer for chlorine-containing resins and chlorine -containing resin compositions
BRPI0705276A2 (pt) 2007-12-10 2009-08-11 Nexoleum Bioderivados Ltda plastificantes primários de pvc derivados de óleos vegetais, processo de obtenção de plastificantes primários de pvc derivados de oléos vegetais e composição de pvc plastificado
BRPI0705621B1 (pt) 2007-12-10 2019-04-09 Nexoleum Bioderivados Ltda. Composição plastificte de pvc
MX2010008963A (es) 2008-02-15 2011-02-24 Union Carbide Chem Plastic Sistema plastificante de reemplazo para formulaciones plastificadas con ftalato.
MX341364B (es) 2008-06-17 2016-08-18 Resinas Y Mat S A De C V Bioplastificantes o plastificantes oleoquimicos primarios, que a su vez actuan como estabilizadores termicos y de radiacion ultravioleta en resinas moldeables de pvc y proceso para obtencion de los mismos.
JP2010042669A (ja) 2008-07-16 2010-02-25 Daikin Ind Ltd フッ素ゴム積層体およびその製造方法
CN101591588A (zh) 2009-06-24 2009-12-02 江南大学 有机铼氧化物-过氧化脲催化制备环氧大豆油或环氧脂肪酸甲(乙)酯的方法
FR2950051B1 (fr) 2009-09-11 2012-08-03 Centre Nat Rech Scient Nouveau procede de preparation de polyols et produits tels qu'obtenus
CN102666697B (zh) 2009-09-30 2015-01-07 陶氏环球技术有限责任公司 乙酰基化的聚甘油脂肪酸酯以及用其增塑的聚氯乙烯绝缘材料
US8802988B2 (en) 2009-09-30 2014-08-12 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
US8552098B2 (en) 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
JP5693589B2 (ja) 2009-09-30 2015-04-01 ダウ グローバル テクノロジーズ エルエルシー １２−ヒドロキシステアリン酸のアセチル化グリセリドおよびエポキシ化脂肪酸エステルとのブレンド
CN101824193B (zh) 2010-02-24 2013-01-30 杭州高新橡塑材料股份有限公司 一种耐寒pvc电缆料及制备方法
CN102985481A (zh) 2010-05-10 2013-03-20 陶氏环球技术有限责任公司 由源自可再生资源的增塑剂制备的挠性pvc组合物
CN101914219B (zh) 2010-07-26 2012-09-05 江阴市向阳科技有限公司 一种复合环氧增塑剂的制备方法
WO2013003225A2 (en) 2011-06-29 2013-01-03 Dow Global Technologies Llc Vegetable-oil derived plasticizer

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