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MX2009011209A - Polimeros aromaticos de monovinilideno mejorados que comprenden polimeros elastomericos funcionalizados con sulfanilsilano. - Google Patents

Polimeros aromaticos de monovinilideno mejorados que comprenden polimeros elastomericos funcionalizados con sulfanilsilano.

Info

Publication number
MX2009011209A
MX2009011209A MX2009011209A MX2009011209A MX2009011209A MX 2009011209 A MX2009011209 A MX 2009011209A MX 2009011209 A MX2009011209 A MX 2009011209A MX 2009011209 A MX2009011209 A MX 2009011209A MX 2009011209 A MX2009011209 A MX 2009011209A
Authority
MX
Mexico
Prior art keywords
rubber
monovinylidene aromatic
polymers
modified
present
Prior art date
Application number
MX2009011209A
Other languages
English (en)
Inventor
Jose M Rego
Sven K H Thiele
Amaia Montoya-Goni
Evemarie Hamann
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MX2009011209A publication Critical patent/MX2009011209A/es

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L19/00—Compositions of rubbers not provided for in groups C08L7/00 - C08L17/00
    • C08L19/006—Rubber characterised by functional groups, e.g. telechelic diene polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/548—Silicon-containing compounds containing sulfur

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención es una composición de polímero aromático de monovinilideno modificado con goma, donde la goma es un polímero elastomérico modificado en extremo de cadena de sulfanilsilano. En la presente invención, la goma funcionalizada proporciona niveles de injertado suficientes en tecnologías de proceso de polimerización de injerto estándar para preparar distribuciones de tamaño de partícula de goma y morfologías deseadas. A través de un rango de polímeros aromáticos de monovinilideno modificados con goma, se ha encontrado que el uso de los polimeros elastoméricos modificados de acuerdo con la presente invención pueden mejorar las combinaciones de propiedades de resina, en particular claridad, superficie y propiedades físicas, incluyendo tanto homopolímeros aromáticos de monovinilideno modificados con goma (por ejemplo, poliestireno de alto impacto y copolímeros (por ejemplo, ABS). Las gomas funcionalizadas tienen grupos funcionales de sulfanilo que proporcionan un sitio de injertado reactivo optimizado. Esto asegura que bajo condiciones de polimerización de injerto, un bloque de polímero aromático de monovinilideno es formado injertado al bloque de polímero de butadieno. Esto es particularmente deseable para permitir el uso de gomas de homopolimero de polibutadieno, las cuales son usadas más efectivamente en cuanto a costo en polímeros aromáticos de monovinilideno modificados con goma.
MX2009011209A 2007-04-18 2008-03-27 Polimeros aromaticos de monovinilideno mejorados que comprenden polimeros elastomericos funcionalizados con sulfanilsilano. MX2009011209A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US92500607P 2007-04-18 2007-04-18
US3217108P 2008-02-28 2008-02-28
PCT/US2008/058336 WO2008130782A1 (en) 2007-04-18 2008-03-27 Improved monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers

Publications (1)

Publication Number Publication Date
MX2009011209A true MX2009011209A (es) 2009-10-30

Family

ID=39433875

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009011209A MX2009011209A (es) 2007-04-18 2008-03-27 Polimeros aromaticos de monovinilideno mejorados que comprenden polimeros elastomericos funcionalizados con sulfanilsilano.

Country Status (9)

Country Link
US (1) US8048960B2 (es)
EP (1) EP2139946A1 (es)
JP (1) JP2010525110A (es)
KR (1) KR20090130070A (es)
CN (1) CN101784604A (es)
BR (1) BRPI0809726A8 (es)
MX (1) MX2009011209A (es)
RU (1) RU2009142420A (es)
WO (1) WO2008130782A1 (es)

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BRPI0909921A2 (pt) * 2008-06-18 2015-10-20 Styron Europe Gmbh composição compreendendo um interpolímero acoplado compreendendo uma ou mais unidades monoméricas derivadas de um dieno e composição de poliestireno de alto impacto
IT1391109B1 (it) * 2008-08-20 2011-11-18 Polimeri Europa Spa Procedimento per la sintesi di poli(1,3-alcadieni) funzionalizzati e loro impiego nella preparazione di polimeri vinilaromatici ad alta resistenza all'urto
CN102933613B (zh) 2009-12-21 2015-03-11 斯泰隆欧洲有限责任公司 改性聚合物组合物
ES2439669T3 (es) * 2009-12-21 2014-01-24 Styron Europe Gmbh Composiciones poliméricas modificadas
JP2013119529A (ja) * 2011-12-07 2013-06-17 Shin-Etsu Chemical Co Ltd 有機ケイ素化合物及びその製造方法、ゴム用配合剤並びにゴム組成物
RU2599723C2 (ru) 2012-03-20 2016-10-10 ТРИНСЕО ЮРОП ГмбХ Модифицированные полимерные композиции
US8993669B2 (en) 2012-03-28 2015-03-31 The Goodyear Tire & Rubber Company Functionalized polymer, rubber composition and pneumatic tire
RU2661220C2 (ru) * 2013-09-27 2018-07-13 ТРИНСЕО ЮРОП ГмбХ Модифицированные эластомерные сополимеры с низким содержанием виниловых связей
FR3017388B1 (fr) * 2014-02-11 2016-02-12 Michelin & Cie Procede de preparation d'elastomeres dieniques porteurs de fonctions phosphorees, produits issus de ce procede et composition les contenant.
KR101633996B1 (ko) 2014-10-21 2016-06-27 곽주완 음식물 조리장치
CN105219012B (zh) * 2015-11-09 2017-12-01 沈阳化工大学 一种接枝改性abs抗静电材料及其制备方法

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US4409369A (en) 1980-03-03 1983-10-11 The Dow Chemical Company Transparent impact resin and process for the preparation thereof
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Also Published As

Publication number Publication date
EP2139946A1 (en) 2010-01-06
CN101784604A (zh) 2010-07-21
BRPI0809726A2 (pt) 2016-10-25
RU2009142420A (ru) 2011-05-27
US20100087612A1 (en) 2010-04-08
US8048960B2 (en) 2011-11-01
BRPI0809726A8 (pt) 2017-03-21
KR20090130070A (ko) 2009-12-17
WO2008130782A1 (en) 2008-10-30
JP2010525110A (ja) 2010-07-22

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