MX2009004262A - Proceso para la sulfinilacion de un derivado de pirazol. - Google Patents
Proceso para la sulfinilacion de un derivado de pirazol.Info
- Publication number
- MX2009004262A MX2009004262A MX2009004262A MX2009004262A MX2009004262A MX 2009004262 A MX2009004262 A MX 2009004262A MX 2009004262 A MX2009004262 A MX 2009004262A MX 2009004262 A MX2009004262 A MX 2009004262A MX 2009004262 A MX2009004262 A MX 2009004262A
- Authority
- MX
- Mexico
- Prior art keywords
- acid
- sulfinylation
- pyrazole derivative
- amine
- pyrazole
- Prior art date
Links
- 150000003217 pyrazoles Chemical class 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 3
- QPZYPAMYHBOUTC-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]pyrazole-3-carbonitrile Chemical compound NC1=CC(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl QPZYPAMYHBOUTC-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- SFEBPWPPVGRFOA-UHFFFAOYSA-N trifluoromethanesulfinic acid Chemical compound OS(=O)C(F)(F)F SFEBPWPPVGRFOA-UHFFFAOYSA-N 0.000 abstract 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- -1 alkaline earth metal salt Chemical class 0.000 abstract 1
- 230000002140 halogenating effect Effects 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229940071870 hydroiodic acid Drugs 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- ZAFBCOKFTZISMM-UHFFFAOYSA-N trifluoromethylsulfinyl trifluoromethanesulfinate Chemical compound FC(F)(F)S(=O)OS(=O)C(F)(F)F ZAFBCOKFTZISMM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/41—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having five-membered rings with two or more ring hetero atoms, at least one of which being nitrogen, e.g. tetrazole
- A61K31/415—1,2-Diazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Tropical Medicine & Parasitology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Oncology (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Communicable Diseases (AREA)
- Environmental Sciences (AREA)
- Epidemiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Catalysts (AREA)
Abstract
Un proceso para la sulfinilación de un derivado de pirazol, caracterizado porque se hace reaccionar 5-amino-1-[2,6-dicloro-4-( trifluorometil)fenil]-1H-pirazol-3-carbonitrilo (II) con un agente de sulfinilación seleccionado de ácido trifluorometilsulfínico, anhídrido de ácido trifluorometilsulfínic o y una sal de metal trifluorometilsulfinato alcalino o alcalinotérreo y mezclas del ácido y/o de la(s) sal(es), en presencia de al menos un complejo de amina ácida, en donde la(s) amina(s) es/son seleccionada(s) de aminas terciarias y el/los acido(s) es/son seleccionado(s) de acido fluorhídrico, clorhídrico, bromhídrico y yodhídrico, y derivados del ácido sulfónico, y con la adición de un agente halogenante.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86517806P | 2006-11-10 | 2006-11-10 | |
| US91361707P | 2007-04-24 | 2007-04-24 | |
| PCT/EP2007/061891 WO2008055877A1 (en) | 2006-11-10 | 2007-11-05 | Process for the sulfinylation of a pyrazole derivative |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009004262A true MX2009004262A (es) | 2009-05-05 |
Family
ID=39167843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009004262A MX2009004262A (es) | 2006-11-10 | 2007-11-05 | Proceso para la sulfinilacion de un derivado de pirazol. |
Country Status (22)
| Country | Link |
|---|---|
| US (2) | US8263783B2 (es) |
| EP (1) | EP2081908B1 (es) |
| JP (1) | JP5450077B2 (es) |
| KR (1) | KR20090083453A (es) |
| CN (1) | CN102746233A (es) |
| AR (1) | AR063646A1 (es) |
| AU (1) | AU2007316718B2 (es) |
| BR (1) | BRPI0718774A2 (es) |
| CA (1) | CA2667559A1 (es) |
| DK (1) | DK2081908T3 (es) |
| EA (1) | EA200900629A1 (es) |
| ES (1) | ES2422296T3 (es) |
| HR (1) | HRP20130582T1 (es) |
| IL (1) | IL198259A (es) |
| MA (1) | MA30917B1 (es) |
| MX (1) | MX2009004262A (es) |
| NZ (1) | NZ576594A (es) |
| PL (1) | PL2081908T3 (es) |
| PT (1) | PT2081908E (es) |
| TW (1) | TWI413498B (es) |
| WO (1) | WO2008055877A1 (es) |
| ZA (1) | ZA200903968B (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5396085B2 (ja) | 2005-12-14 | 2014-01-22 | マクテシム・ケミカル・ワークス・リミテツド | ５−アミノ−１−［２，６−ジクロロ−４−（トリフルオロメチル）フェニル］−４−［（トリフルオロメチル）スルフィニル］−１ｈ−ピラゾール−３−カルボニトリルの多形および非晶形 |
| EA018047B1 (ru) | 2006-11-10 | 2013-05-30 | Басф Се | Способ сульфинилирования производной пиразола |
| CN102171182B (zh) * | 2008-10-02 | 2015-07-22 | 巴斯夫欧洲公司 | 生产和提纯三氟甲烷亚磺酸的方法 |
| EP3412658A1 (en) * | 2017-06-09 | 2018-12-12 | Solvay Sa | Processes for the manufacture of sulfur-substitued pyrazole derivatives |
| EP3412659A1 (en) * | 2017-06-09 | 2018-12-12 | Solvay Sa | Processes for the manufacture of sulfur-substituted pyrazole derivatives |
| EP3941907A4 (en) * | 2019-03-19 | 2023-01-04 | Gharda Chemicals Limited | FIPRONIL SYNTHESIS METHOD |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2716453B1 (fr) | 1994-02-22 | 1996-03-29 | Rhone Poulenc Agrochimie | Procédé de sulfinylation de composés hétérocycliques. |
| EP0165136B1 (fr) * | 1984-05-23 | 1989-03-01 | Rhone-Poulenc Chimie | Compositions détergentes comprenant des copolymères à base de polyoxyéthylène et de polyoxyalkylène utilisés comme agents antiredéposants , et leur procédé de preparation |
| GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
| AU728097B2 (en) * | 1996-08-01 | 2001-01-04 | Rhodia Chimie | Process for grafting a substituted difluoromethyle group |
| JPH11246555A (ja) * | 1997-10-31 | 1999-09-14 | Sumitomo Chem Co Ltd | フッ素置換ベンゾヘテロ環化合物 |
| EP1042281B1 (en) | 1997-12-22 | 2003-03-19 | Minnesota Mining And Manufacturing Company | Process for preparation of fluorinated sulfinates |
| DE19853560A1 (de) | 1998-11-20 | 2000-05-25 | Bayer Ag | Verfahren zur Herstellung von 5-Amino-3-(thio)carbamoylpyrazolen |
| IN2005MU00818A (es) | 1999-10-22 | 2005-11-11 | Bayer Cropscience Sa | |
| JP2001220386A (ja) * | 1999-11-30 | 2001-08-14 | Takeda Chem Ind Ltd | オキサジアゾリン誘導体の製造方法 |
| JP2002020364A (ja) * | 2000-07-06 | 2002-01-23 | Konica Corp | スルフィン酸ナトリウム、スルフィン酸カリウムの製造方法およびそれらを用いた写真用カプラーの製造方法 |
| EP1331222A1 (en) | 2002-01-28 | 2003-07-30 | Virbac S.A. | Environment friendly reagents and process for halogenoalkylsulfinylation of organic compounds |
| CN1176078C (zh) | 2002-03-27 | 2004-11-17 | 江苏省农药研究所 | 带三氟甲基亚磺酰基的吡唑类化合物的亚磺酰化方法 |
| NZ576638A (en) | 2006-11-10 | 2011-12-22 | Basf Se | Process for the sulfinylation of a pyrazole derivative |
| EA018047B1 (ru) | 2006-11-10 | 2013-05-30 | Басф Се | Способ сульфинилирования производной пиразола |
| FR2924115B1 (fr) | 2007-11-27 | 2010-02-26 | Rhodia Operations | Procede de preparation d'un acide trifluoromethanesulfinique |
| CN102171182B (zh) | 2008-10-02 | 2015-07-22 | 巴斯夫欧洲公司 | 生产和提纯三氟甲烷亚磺酸的方法 |
-
2007
- 2007-11-05 ES ES07822220T patent/ES2422296T3/es active Active
- 2007-11-05 CN CN2012102449529A patent/CN102746233A/zh active Pending
- 2007-11-05 JP JP2009535702A patent/JP5450077B2/ja not_active Expired - Fee Related
- 2007-11-05 DK DK07822220.5T patent/DK2081908T3/da active
- 2007-11-05 BR BRPI0718774-2A patent/BRPI0718774A2/pt not_active Application Discontinuation
- 2007-11-05 US US12/514,098 patent/US8263783B2/en active Active
- 2007-11-05 HR HRP20130582TT patent/HRP20130582T1/hr unknown
- 2007-11-05 EA EA200900629A patent/EA200900629A1/ru unknown
- 2007-11-05 EP EP07822220.5A patent/EP2081908B1/en active Active
- 2007-11-05 WO PCT/EP2007/061891 patent/WO2008055877A1/en not_active Ceased
- 2007-11-05 NZ NZ576594A patent/NZ576594A/en not_active IP Right Cessation
- 2007-11-05 CA CA002667559A patent/CA2667559A1/en not_active Abandoned
- 2007-11-05 KR KR1020097011871A patent/KR20090083453A/ko not_active Ceased
- 2007-11-05 MX MX2009004262A patent/MX2009004262A/es active IP Right Grant
- 2007-11-05 AU AU2007316718A patent/AU2007316718B2/en active Active
- 2007-11-05 PL PL07822220T patent/PL2081908T3/pl unknown
- 2007-11-05 PT PT78222205T patent/PT2081908E/pt unknown
- 2007-11-09 AR ARP070105012A patent/AR063646A1/es not_active Application Discontinuation
- 2007-11-09 TW TW096142570A patent/TWI413498B/zh not_active IP Right Cessation
-
2009
- 2009-04-21 IL IL198259A patent/IL198259A/en not_active IP Right Cessation
- 2009-05-25 MA MA31913A patent/MA30917B1/fr unknown
- 2009-06-08 ZA ZA2009/03968A patent/ZA200903968B/en unknown
-
2012
- 2012-08-14 US US13/585,233 patent/US20120309806A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007316718A1 (en) | 2008-05-15 |
| HRP20130582T1 (en) | 2013-08-31 |
| EA200900629A1 (ru) | 2009-10-30 |
| PT2081908E (pt) | 2013-06-28 |
| JP5450077B2 (ja) | 2014-03-26 |
| AR063646A1 (es) | 2009-02-04 |
| IL198259A0 (en) | 2009-12-24 |
| US20120309806A1 (en) | 2012-12-06 |
| EP2081908B1 (en) | 2013-04-24 |
| NZ576594A (en) | 2011-12-22 |
| US20100137395A1 (en) | 2010-06-03 |
| ES2422296T3 (es) | 2013-09-10 |
| PL2081908T3 (pl) | 2013-09-30 |
| DK2081908T3 (da) | 2013-07-29 |
| TWI413498B (zh) | 2013-11-01 |
| CA2667559A1 (en) | 2008-05-15 |
| EP2081908A1 (en) | 2009-07-29 |
| ZA200903968B (en) | 2012-02-29 |
| BRPI0718774A2 (pt) | 2013-12-03 |
| JP2010509271A (ja) | 2010-03-25 |
| WO2008055877A1 (en) | 2008-05-15 |
| US8263783B2 (en) | 2012-09-11 |
| TW200829169A (en) | 2008-07-16 |
| MA30917B1 (fr) | 2009-11-02 |
| KR20090083453A (ko) | 2009-08-03 |
| CN102746233A (zh) | 2012-10-24 |
| IL198259A (en) | 2013-10-31 |
| AU2007316718B2 (en) | 2013-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |