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MX2008016485A - Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros. - Google Patents

Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros.

Info

Publication number
MX2008016485A
MX2008016485A MX2008016485A MX2008016485A MX2008016485A MX 2008016485 A MX2008016485 A MX 2008016485A MX 2008016485 A MX2008016485 A MX 2008016485A MX 2008016485 A MX2008016485 A MX 2008016485A MX 2008016485 A MX2008016485 A MX 2008016485A
Authority
MX
Mexico
Prior art keywords
derivatives
free
preparation
aqueous dispersion
radical polymerization
Prior art date
Application number
MX2008016485A
Other languages
English (en)
Inventor
Patrick Lacroix-Desmazes
Jeff Tonnar
Original Assignee
Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv filed Critical Cid Ct Investigacion Desarrollo Tecnologico Sa De Cv
Publication of MX2008016485A publication Critical patent/MX2008016485A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros que utiliza: (A) al menos un monómero etilénicamente insaturado en donde uno de ellos se utiliza como monómero principal y se selecciona entre el estireno y sus derivados, ácido acrílico y sus derivados, ácido metacrílico y sus derivados, los diénicos, los ésteres vinílicos, éteres vinílicos, derivados vinílicos de piridina, ácido vinilsulfónico y sus derivados, ácido vinilfosfónico y sus derivados y los monómeros N-vinílicos; (B) al menos un agente generador de radicales seleccionados entre los compuestos diazo, los peróxidos y los dialquildifenilalcanos; (C) yodo molecular; y (D) al menos un oxidante cuya solubilidad en agua es de al menos 10 g/l en donde al menos uno puede ser uno de (B); que comprende las etapas de: (1) introducir en un reactor al menos una fracción de cada uno de los compuestos (A), (B), (C) y CD); y (2) hacer reaccionar el contenido del reactor, introduciendo el posible residuo de cada uno de los compuestos (A), (B), (C) y (D). Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de copolímeros en bloques partiendo de los polímeros preparados por el procedimiento mencionado anteriormente.
MX2008016485A 2006-07-04 2007-07-04 Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros. MX2008016485A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0606079A FR2903409A1 (fr) 2006-07-04 2006-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
US81827606P 2006-07-05 2006-07-05
PCT/EP2007/056779 WO2008003729A2 (fr) 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres

Publications (1)

Publication Number Publication Date
MX2008016485A true MX2008016485A (es) 2009-02-25

Family

ID=37719193

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2008016485A MX2008016485A (es) 2006-07-04 2007-07-04 Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros.

Country Status (6)

Country Link
US (2) US8541524B2 (es)
EP (2) EP2049573A2 (es)
JP (1) JP5201419B2 (es)
FR (1) FR2903409A1 (es)
MX (1) MX2008016485A (es)
WO (2) WO2008003729A2 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7741524B2 (en) 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
DE102008054482A1 (de) * 2008-12-10 2010-06-17 Wacker Chemie Ag Pfropfcopolymere und deren Verwendung als Low-Profile-Additive
JP2013018953A (ja) * 2011-06-15 2013-01-31 Canon Inc 高分子粒子の製造方法
KR101507999B1 (ko) 2011-08-03 2015-04-07 인하대학교 산학협력단 Ｒｉｔｐ 중합법과 용액 재결정법을 이용한 안정화된 단분산 구형 고분자 입자의 제조 방법
CN104271621B (zh) * 2011-12-21 2017-09-05 索尔维公司 用于制备偏二氯乙烯聚合物的方法
US9394394B2 (en) * 2013-09-30 2016-07-19 Honeywell International Inc. Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization
FR3053970A1 (fr) 2016-07-13 2018-01-19 Centre National De La Recherche Scientifique (Cnrs) Procede de synthese d'une polyolefine par romp en presence d'un catalyseur a base de ruthenium
US11180665B2 (en) 2020-02-21 2021-11-23 Swimc Llc Stain-blocking polymers, primers, kits, and methods
US20240309124A1 (en) 2021-07-30 2024-09-19 Basf Se A composition and its application in controlled living water-based emulsion polymerization
CN119463072B (zh) * 2024-11-11 2025-12-09 苏州大学 一种基于光控原位溴-碘转换可逆-失活自由基聚合法制备星形嵌段共聚物的方法

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US3467636A (en) 1967-02-24 1969-09-16 Du Pont Redox catalyst system for preparing vinylidene fluoride interpolymers
LU73211A1 (es) 1975-08-18 1977-04-15
JPS5386787A (en) * 1977-09-30 1978-07-31 Daikin Ind Ltd Polymer having fluorine-containing segment and its production
JPS63260914A (ja) * 1987-04-17 1988-10-27 Nippon Mektron Ltd ブロツク共重合体の製造方法
BE1007648A3 (fr) 1993-10-21 1995-09-05 Solvay Procede pour la polymerisation radicalaire du chlorure de vinyle a ph acide en dispersion aqueuse.
DE69835366T2 (de) * 1997-03-31 2007-07-19 Daikin Industries, Ltd. Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
EP0947527A1 (en) 1998-04-03 1999-10-06 The B.F. Goodrich Company Waterborne block copolymers and process for making the same
US6911515B2 (en) 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
FR2826658B1 (fr) * 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2839724B1 (fr) 2002-05-17 2005-08-05 Solvay Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes
FR2839725A1 (fr) * 2002-05-17 2003-11-21 Solvay Polymeres alpha-fluoroacryliques a faible indice de polydispersite, procede pour les synthetiser et procede de fabrication d'articles les mettant en oeuvre
US7034085B2 (en) * 2002-07-23 2006-04-25 Nuplex Resins, B.V. Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer
US7741524B2 (en) 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
FR2858319B1 (fr) * 2003-08-01 2005-09-23 Solvay Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire
WO2004094356A1 (en) 2003-04-22 2004-11-04 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
FR2896505B1 (fr) * 2006-01-26 2008-03-07 Rhodia Recherches & Tech Procede de preparation par polymerisation par transfert d'iode d'un copolymere a architecture controlee de type telomere ou de copolymere a bloc issu de monomeres vinyl phosphonate
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
WO2008155324A1 (en) * 2007-06-21 2008-12-24 Dsm Ip Assets B.V. Process for obtaining low free monomer levels in a block copolymer emulsion prepared with (reverse) iodine transfer polymerisation

Also Published As

Publication number Publication date
US8541524B2 (en) 2013-09-24
EP2041185B1 (en) 2019-01-09
WO2008003729A3 (fr) 2008-05-08
WO2008003729A2 (fr) 2008-01-10
EP2049573A2 (fr) 2009-04-22
EP2041185A1 (en) 2009-04-01
JP2009541567A (ja) 2009-11-26
WO2008003728A1 (en) 2008-01-10
FR2903409A1 (fr) 2008-01-11
JP5201419B2 (ja) 2013-06-05
US20090292071A1 (en) 2009-11-26
US20090306302A1 (en) 2009-12-10

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