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McLeod et al., 2018 - Google Patents

Insights into the Reactivity of Epoxides as Reducing Agents in Low-Catalyst-Concentration ATRP Reactions

McLeod et al., 2018

Document ID
3299359326819083516
Author
McLeod D
Sayala K
Tsarevsky N
Publication year
Publication venue
Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies

External Links

Snippet

Modern atom transfer radical polymerization (ATRP) techniques employ relatively-low concentrations of copper complexes as the polymerization mediators. Typically, the catalyst is initially added in the higher oxidation (deactivating) state, so these systems require a …
Continue reading at pubs.acs.org (other versions)

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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
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    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
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    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
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    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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