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Dolzine et al., 1974 - Google Patents

Intramolecular metal—double bond interactions: VII. Intramolecular cyclization of alkenyl derivatives of lithium, aluminum, gallium and indium

Dolzine et al., 1974

Document ID
2178786756068600836
Author
Dolzine T
Oliver J
Publication year
Publication venue
Journal of Organometallic Chemistry

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Snippet

The intramolecular cyclization reactions of tri-1-hex-5-enyl Group III derivatives and of 1-hex- 5-enyllithium have been investigated and it is proposed that the reactions may be depicted as internal addition across the terminal double bonds of the alkenyl species. The cyclization …
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C07F7/0814—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring said ring is substituted at a C ring atom by Si
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    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
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