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Harger et al., 1999 - Google Patents

Base induced rearrangement reactions of N-phosphinoyl-O-sulfonylhydroxylamines. Observation of a phosphonamidic–sulfonic anhydride intermediate by NMR …

Harger et al., 1999

Document ID
17766226658788360987
Author
Harger M
et al.
Publication year
Publication venue
Journal of the Chemical Society, Perkin Transactions 2

External Links

Snippet

The hydroxylamine derivative PhRP (O) NHOSO2Me (R= PhMeCH) reacts with ButNH2 to give the rearrangement product RP (O)(NHPh) NHBut by way of a reactive but non-transient intermediate. At low amine concentrations the intermediate can be observed by 31P NMR …
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P-C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/30—Phosphinic acids R2P(=O)(OH); Thiophosphinic acids, i.e. R2P(=X)(XH) (X = S, Se)
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