[go: up one dir, main page]

Berding et al., 2011 - Google Patents

[NiX2 (NHC) 2] complexes in the hydrosilylation of internal alkynes

Berding et al., 2011

Document ID
8327471276055813970
Author
Berding J
van Paridon J
van Rixel V
Bouwman E
Publication year
Publication venue
European Journal of Inorganic Chemistry

External Links

Snippet

A number of nickel (II) dihalide complexes with small monodentate N‐heterocyclic carbene ligands was synthesized and tested for their catalytic activity in the hydrosilylation of internal alkynes. The nickel (0) active species was obtained from the starting nickel (II) complex by …
Continue reading at chemistry-europe.onlinelibrary.wiley.com (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System

Similar Documents

Publication Publication Date Title
Poyatos et al. Synthesis, Reactivity, Crystal Structures and Catalytic Activity of New Chelating Bisimidazolium‐Carbene Complexes of Rh
Steiman et al. Reversible substrate activation and catalysis at an intact metal–metal bond using a redox-active supporting ligand
Iglesias et al. An Alternative Mechanistic Paradigm for the β‐Z Hydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle
Alshakova et al. Ru‐catalyzed transfer hydrogenation of nitriles, aromatics, olefins, alkynes and esters
Werner et al. Alkynes and Diynes as Precursors for Organoiridium Complexes Containing Iridium− Carbon Single and Double Bonds
Saravanakumar et al. Anellated N‐Heterocyclic Carbenes: 1, 3‐Dineopentylnaphtho [2, 3‐d] imidazol‐2‐ylidene: Synthesis, KOH Addition Product, Transition‐Metal Complexes, and Anellation Effects
Berding et al. [NiX2 (NHC) 2] complexes in the hydrosilylation of internal alkynes
Huckaba et al. Synthesis and characterization of a 1, 3-phenylene-bridged N-alkyl bis (benzimidazole) CCC-NHC pincer ligand precursor: homobimetallic silver and rhodium complexes and the catalytic hydrosilylation of phenylacetylene
Rubio-Pérez et al. A well-defined NHC–Ir (III) catalyst for the silylation of aromatic C–H bonds: substrate survey and mechanistic insights
Muñoz III et al. Tris (carbene) borate ligands featuring imidazole-2-ylidene, benzimidazol-2-ylidene, and 1, 3, 4-triazol-2-ylidene donors. Evaluation of donor properties in four-coordinate {NiNO} 10 complexes
Chay et al. Platinum complexes with chelating acyclic aminocarbene ligands work as catalysts for hydrosilylation of alkynes
Zhao et al. Reactivity of dialumane and “dialumene” compounds toward alkenes
Lu et al. Platinum (II) complexes with polydentate N-heterocyclic carbenes: synthesis, structural characterization and hydrosilylation catalysis
Liao et al. Robust and Electron‐Rich cis‐Palladium (II) Complexes with Phosphine and Carbene Ligands as Catalytic Precursors in Suzuki Coupling Reactions
Vicenzi et al. Platinum (II) complexes with novel diisocyanide ligands: Catalysts in alkyne hydroarylation
Warsink et al. Intramolecularly Stabilised Group 10 Metal Stannyl and Stannylene Complexes: Multi‐pathway Synthesis and Observation of Platinum‐to‐Tin Alkyl Transfer
Fuchigami et al. Mononuclear rhodium (II) and iridium (II) complexes supported by tetradentate pyridinophane ligands
Park et al. Use of Rhodium N‐Heterocyclic Carbene Complexes in Catalytic Cyclization and Hydrosilylation of 1, 6‐Enynes to 2‐Methyl‐1‐silylmethylidene‐2‐cyclopentane
Zhang et al. Synthesis, characterization and electrochemical properties of stable osmabenzenes containing PPh3 substituents
Dai et al. Cobalt bis (2‐ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins
Siggelkow et al. Synthesis, Structures and Catalytic Properties of Bis (2‐pyridylimino)‐isoindolatopalladium Complexes
Garcés et al. Rhodium‐Catalyzed Dehydrogenative Silylation of Acetophenone Derivatives: Formation of Silyl Enol Ethers versus Silyl Ethers
Marciniec et al. Synthesis of Functionalized Vinylgermanes through a New Ruthenium‐Catalyzed Coupling Reaction
Winkelmann et al. Bimacrocyclic NHC transition metal complexes
Molotkov et al. Iridium Halide Complexes [1, 1‐X2‐8‐SMe2‐1, 2, 8‐IrC2B9H10] 2 (X= Cl, Br, I): Synthesis, Reactivity and Catalytic Activity