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Wetherby Jr et al., 2008 - Google Patents

Metal-Dependent Reactions of Bulky Metal (II) Amides M [N (SiMe3) 2] 2 with 3, 3′-Disubstituted Binaphthols (HO) 2C20H10 (SiR3) 2-3, 3′: Selective Conversion of …

Wetherby Jr et al., 2008

Document ID
525290047138117053
Author
Wetherby Jr A
Goeller L
DiPasquale A
Rheingold A
Weinert C
Publication year
Publication venue
Inorganic chemistry

External Links

Snippet

The outcome of the reaction of the bulky metal (II) amides M [N (SiMe3) 2] 2· n THF (M= Be, Zn, Ge, Sn, n= 0; M= Mg, Ca, n= 2) with (R)-3, 3′-bis (trimethylsilyl)-1, 1′-bi-2, 2′- naphthol ((R)-1) or (S)-3, 3′-bis (dimethylphenylsilyl)-1, 1′-bi-2, 2′-naphthol ((S)-9) …
Continue reading at pubs.acs.org (other versions)

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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1812—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
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    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
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