Trommer et al., 2001 - Google Patents
Disproportionation of chlorodisilanes containing vinyl, diethylamino or phenyl substituentsTrommer et al., 2001
- Document ID
- 4501496081182136878
- Author
- Trommer K
- Herzog U
- Schulze
- Roewer G
- Publication year
- Publication venue
- Main Group Metal Chemistry
External Links
Snippet
The base catalyzed disproportionation of the disilanes CUMeSi-SiMeCIR, CIMeRSi- SiMeClR, MeR-> Si-SiMeClR (R=(CH= CH2), NEt2) and CUPhSi-SiCLPh was investigated. The formation of the observed mono-as well as oligosilanes with up to five silicon atoms is …
- 238000007323 disproportionation reaction 0 title description 33
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- C07F7/02—Silicon compounds
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- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
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- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1812—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
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- C07F7/02—Silicon compounds
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- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
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