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WO2009004950A1 - セルロースを含む材料の加水分解による単糖類および／または水溶性多糖類の製造方法 - Google Patents

セルロースを含む材料の加水分解による単糖類および／または水溶性多糖類の製造方法 Download PDF

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Publication number
WO2009004950A1
WO2009004950A1 PCT/JP2008/061466 JP2008061466W WO2009004950A1 WO 2009004950 A1 WO2009004950 A1 WO 2009004950A1 JP 2008061466 W JP2008061466 W JP 2008061466W WO 2009004950 A1 WO2009004950 A1 WO 2009004950A1
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WIPO (PCT)
Prior art keywords
cellulose
monosaccharide
hydrolysis
water
soluble polysaccharide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/061466
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English (en)
French (fr)
Inventor
Shinichirou Yanagawa
Hidesato Kondo
Michikazu Hara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Institute of Technology NUC
Eneos Corp
Original Assignee
Tokyo Institute of Technology NUC
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Tokyo Institute of Technology NUC, Nippon Oil Corp filed Critical Tokyo Institute of Technology NUC
Priority to JP2009521585A priority Critical patent/JPWO2009004950A1/ja
Publication of WO2009004950A1 publication Critical patent/WO2009004950A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/02—Monosaccharides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
    • C07H3/06—Oligosaccharides, i.e. having three to five saccharide radicals attached to each other by glycosidic linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Emergency Medicine (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

　セルロースを含む材料を、スルホン酸基含有炭素質材料を用いて加水分解することにより効率的に単糖類および／または水溶性多糖類を得るとともに、使用済みのスルホン酸基含有炭素質材料を未反応のセルロースを含む材料と分離することなく再度、炭化およびスルホン化することより再活性化し再利用する。そのことにより、加水分解コストを低減し、廃棄物を低減することにより地球環境の保全に貢献する。
PCT/JP2008/061466 2007-06-29 2008-06-24 セルロースを含む材料の加水分解による単糖類および／または水溶性多糖類の製造方法 Ceased WO2009004950A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009521585A JPWO2009004950A1 (ja) 2007-06-29 2008-06-24 セルロースを含む材料の加水分解による単糖類および／または水溶性多糖類の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007172608 2007-06-29
JP2007-172608 2007-06-29

Publications (1)

Publication Number Publication Date
WO2009004950A1 true WO2009004950A1 (ja) 2009-01-08

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PCT/JP2008/061466 Ceased WO2009004950A1 (ja) 2007-06-29 2008-06-24 セルロースを含む材料の加水分解による単糖類および／または水溶性多糖類の製造方法

Country Status (2)

Country Link
JP (1) JPWO2009004950A1 (ja)
WO (1) WO2009004950A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009296919A (ja) * 2008-06-12 2009-12-24 Tokyo Univ Of Agriculture & Technology セルロース系バイオマスの液化方法
WO2010035832A1 (ja) * 2008-09-29 2010-04-01 株式会社日本触媒 単糖類の製造方法
WO2010137039A2 (en) 2009-05-26 2010-12-02 Arvind Mallinath Lali Method for production of fermentable sugars from biomass
CN104650935A (zh) * 2015-02-11 2015-05-27 中原工学院 一种生物质有效的处理方法
WO2018008546A1 (ja) * 2016-07-04 2018-01-11 国立大学法人東京工業大学 セルロース及びリグニンを含む材料からの単糖又はオリゴ糖の製造方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5925801A (ja) * 1982-06-01 1984-02-09 インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− セルロ−ス含有材料の可溶化および／または加水分解方法
JP2002085100A (ja) * 2000-09-11 2002-03-26 National Institute Of Advanced Industrial & Technology セルロース可溶化方法
JP2004238311A (ja) * 2003-02-05 2004-08-26 Japan Science & Technology Agency 多環式芳香族炭素系固体強酸
WO2005029508A1 (ja) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering スルホン酸基導入無定形炭素、その製造法、及びその用途
JP2006238728A (ja) * 2005-03-01 2006-09-14 Nippon Paper Chemicals Co Ltd 製紙排水からの糖類の製造方法
WO2008001696A1 (en) * 2006-06-26 2008-01-03 Tokyo Institute Of Technology Method for production of polysaccharide and/or monosaccharide by hydrolysis of other polysaccharide

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5925801A (ja) * 1982-06-01 1984-02-09 インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− セルロ−ス含有材料の可溶化および／または加水分解方法
JP2002085100A (ja) * 2000-09-11 2002-03-26 National Institute Of Advanced Industrial & Technology セルロース可溶化方法
JP2004238311A (ja) * 2003-02-05 2004-08-26 Japan Science & Technology Agency 多環式芳香族炭素系固体強酸
WO2005029508A1 (ja) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering スルホン酸基導入無定形炭素、その製造法、及びその用途
JP2006238728A (ja) * 2005-03-01 2006-09-14 Nippon Paper Chemicals Co Ltd 製紙排水からの糖類の製造方法
WO2008001696A1 (en) * 2006-06-26 2008-01-03 Tokyo Institute Of Technology Method for production of polysaccharide and/or monosaccharide by hydrolysis of other polysaccharide

Non-Patent Citations (11)

* Cited by examiner, † Cited by third party
Title
ABBADI A. ET AL.: "Study on solid acid catalyzed hydrolysis of maltose and related polysaccharides.", STARCH, vol. 50, 1998, pages 23 - 28, XP000739810, DOI: doi:10.1002/(SICI)1521-379X(199801)50:1<23::AID-STAR23>3.3.CO;2-K *
ATSUSHI FUKUOKA ET AL.: "Sulfonated Mesoporous Silica ni yoru Torui no Henkan Hanno", THE 48TH THE JAPAN PETROLEUM INSTITUTE NENKAI KOEN YOSHI, 2005, pages 67 - 68 *
ATSUSHI FUKUOKA: "Sulfonated Mesoporous Silica ni yoru To no Kasui Bunkai Hanno", FINE CHEMICAL, vol. 34, no. 5, 2005, pages 11 - 18 *
DHEPE P.L. ET AL.: "Hydrolysis of sugars by sulfonated mesoporous silicas.", SHOKUBAI, vol. 47, 2005, pages 122 - 124 *
DHEPE P.L. ET AL.: "Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas.", CATAL. LETT., vol. 102, 2005, pages 163 - 169, XP019275199 *
DHEPE, PARESH ET AL.: "Sulfonated Mesoporous Silica ni yoru Suichu deno Torui Kasui Bunkai Hanno", THE 85TH ANNUAL MEETING ON CHEMICAL SOCIETY OF JAPAN IN SPRING - KOEN YOKOSHU I, 2005, pages 53, 4 B4 - 06 *
KEIKO ICHIKAWA ET AL.: "Biomass Zairyo o Genryo to shita Kotaisan Shokubai no San Shokubai Kassei to Characterization", T HE 86TH ANNUAL MEETING ON CHEMICAL SOCIETY OF JAPAN IN SPRING - KOEN YOKOSHU I, 2006, pages 131, 2 Dl - 38 *
MICHIKAZU HARA: "Kankyo · Energy Mondai no Kaiketsu o Mezashita Kotaisan Shokubai no Kaihatsu", ENEOS TECHNICAL REVIEW, vol. 48, 2006, pages 142 - 146 *
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009296919A (ja) * 2008-06-12 2009-12-24 Tokyo Univ Of Agriculture & Technology セルロース系バイオマスの液化方法
WO2010035832A1 (ja) * 2008-09-29 2010-04-01 株式会社日本触媒 単糖類の製造方法
WO2010137039A2 (en) 2009-05-26 2010-12-02 Arvind Mallinath Lali Method for production of fermentable sugars from biomass
US8338139B2 (en) 2009-05-26 2012-12-25 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
US8673596B2 (en) 2009-05-26 2014-03-18 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
US8709763B2 (en) 2009-05-26 2014-04-29 Chemical Engineering Department, Institute Of Chemical Technology (Deemed University) Method for production of fermentable sugars from biomass
CN104650935A (zh) * 2015-02-11 2015-05-27 中原工学院 一种生物质有效的处理方法
CN104650935B (zh) * 2015-02-11 2017-02-01 中原工学院 一种生物质有效的处理方法
WO2018008546A1 (ja) * 2016-07-04 2018-01-11 国立大学法人東京工業大学 セルロース及びリグニンを含む材料からの単糖又はオリゴ糖の製造方法

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