US20130186558A1 - Layer transfusion with heat capacitor belt for additive manufacturing - Google Patents
Layer transfusion with heat capacitor belt for additive manufacturing Download PDFInfo
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- US20130186558A1 US20130186558A1 US13/790,406 US201313790406A US2013186558A1 US 20130186558 A1 US20130186558 A1 US 20130186558A1 US 201313790406 A US201313790406 A US 201313790406A US 2013186558 A1 US2013186558 A1 US 2013186558A1
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Definitions
- the present disclosure relates to additive manufacturing systems for building three-dimensional (3D) parts and support structures.
- the present disclosure relates to additive manufacturing systems and processes for building 3D parts and support structures using an imaging process, such as electrophotography.
- Additive manufacturing systems are used to build 3D parts from digital representations of the 3D parts (e.g., STL format files) using one or more additive manufacturing techniques.
- additive manufacturing techniques include extrusion-based techniques, ink jetting, selective laser sintering, powder/binder jetting, electron-beam melting, and stereolithographic processes.
- the digital representation of the 3D part is initially sliced into multiple horizontal layers.
- a tool path is then generated, which provides instructions for the particular additive manufacturing system to form the given layer.
- a 3D part or model may be printed from a digital representation of the 3D part in a layer-by-layer manner by extruding a flowable part material.
- the part material is extruded through an extrusion tip carried by a print head of the system, and is deposited as a sequence of roads on a substrate in an x-y plane.
- the extruded part material fuses to previously deposited part material, and solidifies upon a drop in temperature.
- the position of the print head relative to the substrate is then incremented along a z-axis (perpendicular to the x-y plane), and the process is then repeated to form a 3D part resembling the digital representation.
- supporting layers or structures are typically built underneath overhanging portions or in cavities of objects under construction, which are not supported by the part material itself.
- a support structure may be built utilizing the same deposition techniques by which the part material is deposited.
- the host computer generates additional geometry acting as a support structure for the overhanging or free-space segments of the 3D part being formed.
- Support material is then deposited from a second nozzle pursuant to the generated geometry during the printing process. The support material adheres to the modeling material during fabrication, and is removable from the completed 3D part when the printing process is complete.
- Electrophotography In two-dimensional (2D) printing, electrophotography (i.e., xerography) is a popular technology for creating 2D images on planar substrates, such as printing paper.
- Electrophotography systems include a conductive support drum coated with a photoconductive material layer, where latent electrostatic images are formed by charging and then image-wise exposing the photoconductive layer by an optical source. The latent electrostatic images are then moved to a developing station where toner is applied to charged areas of the photoconductive insulator to form visible images. The formed toner images are then transferred to substrates (e.g., printing paper) and affixed to the substrates with heat or pressure.
- substrates e.g., printing paper
- An aspect of the present disclosure is directed to an additive manufacturing system for printing a 3D part.
- the additive manufacturing system includes an imaging engine configured to develop an imaged layer, a movable build platform, and a rotatable belt configured to receive the imaged layer from the imaging engine, wherein the rotatable belt has a high average thermal inertia (e.g., of at least about 400 joules/(meter 2 -Kelvin-second 0.5 )).
- the system also includes a first heater configured to heat the rotatable belt and the imaged layer on the rotatable belt, and a nip roller configured to press the heated imaged layer conveyed by the rotatable belt onto a top layer of the 3D part retained by the movable build platform.
- the system further includes a release roller configured to separate the pressed imaged layer from the heated rotatable belt such that the pressed imaged layer remains adhered as a new top layer of the 3D part, wherein the rotatable belt is configured to thermally conduct heat into the three-dimensional part while the pressed imaged layer moves between the nip roller and the release roller.
- Another aspect of the present disclosure is directed to a method for printing a 3D part with an additive manufacturing system.
- the method includes imaging a layer of the 3D part, transferring the imaged layer to a rotatable belt having a high average thermal inertia (e.g., of at least about 400 joules/(meter 2 -Kelvin-second 0.5 )), and heating the rotatable belt and the imaged layer while the imaged layer is retained on the rotating belt.
- a high average thermal inertia e.g., of at least about 400 joules/(meter 2 -Kelvin-second 0.5
- the method also includes pressing the heated imaged layer between the heated rotatable belt and a top surface of the three-dimensional part so that the heated imaged layer fuses to the top surface of the 3D part, and maintaining contact between the rotatable belt and the fused imaged layer so as to conduct thermal energy from the heated rotatable belt to the 3D part.
- the method further includes releasing the pressed layer from the rotatable belt such that the pressed layer defines a new top surface of the three-dimensional part.
- Another aspect of the present disclosure is directed to a method for printing a 3D part with an additive manufacturing system, which includes imaging a layer of the 3D part, rotating a belt having a high average thermal inertia (e.g., of at least about 400 joules/(meter 2 -Kelvin-second 0.5 )), and transferring the imaged layer to the rotating belt.
- the method also includes heating the rotating belt and the imaged layer while the imaged layer is retained on the rotating belt, and engaging the heated rotatable belt with a nip roller, which presses the heated layer to a top surface of the 3D part.
- the method further includes moving the 3D part in a direction and at a rate that is synchronized with a rotation of the belt, conducting thermal energy from the rotating belt to the 3D part while moving the 3D part in the synchronized direction and rate, and releasing the pressed layer from the rotatable belt such that the pressed layer defines a new top surface of the 3D part.
- the additive manufacturing system is configured to print or otherwise produce the layers at a rate that is faster than a passive thermal diffusion rate of the 3D part.
- transfusion refers to the adhesion of layers with the use of heat and pressure, where polymer molecules of the layers at least partially interdiffuse.
- transfusion pressure refers to a pressure applied during a transfusion step, such as when transfusing layers of a 3D part together.
- deformation temperature of a 3D part refers to a temperature at which the 3D part softens enough such that a subsequently-applied transfusion pressure, such as during a subsequent transfusion step, overcomes the structural integrity of the 3D part, thereby deforming the 3D part.
- temperatures referred to herein are based on atmospheric pressure (i.e. one atmosphere).
- Directional orientations such as āaboveā, ābelowā, ātopā, ābottomā, and the like are made with reference to a direction along a printing axis of a 3D part.
- the layer-printing direction is the upward direction along the vertical z-axis.
- the terms āaboveā, ābelowā, ātopā, ābottomā, and the like are based on the vertical z-axis.
- the terms āaboveā, ābelowā, ātopā, ābottomā, and the like are relative to the given axis.
- providing such as for āproviding a materialā and the like, when recited in the claims, is not intended to require any particular delivery or receipt of the provided item. Rather, the term āprovidingā is merely used to recite items that will be referred to in subsequent elements of the claim(s), for purposes of clarity and ease of readability.
- FIG. 1 is a graphical illustration of transfer temperature versus a minimum transfusion duration for a layer transfusion assembly of an additive manufacturing system of the present disclosure.
- FIG. 2A is a schematic illustration of an electrophotography-based additive manufacturing system of the present disclosure having a layer transfusion assembly with a press plate.
- FIG. 2B is a logarithmic graphical illustration of Young's modulus versus temperature at atmospheric pressure for an acrylonitrile-butadiene-styrene (ABS) copolymer.
- ABS acrylonitrile-butadiene-styrene
- FIG. 3A is a top view of a build platform receiving a heated layer, illustrating an air knife arrangement.
- FIG. 3B is a graphical illustration of number of printed layers for a 3D part versus an average part temperature, showing plot lines for a 3D part printed without active cooling and for a 3D part printed with active cooling.
- FIGS. 4A-4D are expanded views of the layer transfusion assembly, illustrating a layer transfer technique of the present disclosure.
- FIGS. 5A-5E are expanded views of a first alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a nip roller, and which illustrate a layer transfer technique.
- FIGS. 6A-6F are expanded views of a second alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and which illustrate a layer transfer technique.
- FIG. 7 is an expanded view of a third alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a nip roller and a post heater, and which illustrates a layer transfer technique.
- FIG. 8 is an expanded view of a fourth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and a post heater, and which illustrates a layer transfer technique.
- FIG. 9 is an expanded view of a fifth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and a belt with a high thermal conductivity and heat capacity, and which illustrates a layer transfer technique.
- FIG. 10 is an expanded view of a sixth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, a belt with a high thermal conductivity and heat capacity, and a contact cooling unit, and which illustrates a layer transfer technique.
- FIGS. 11A , 11 B, and 11 C are expanded views of a seventh alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a closed-loop feedback control.
- FIG. 12 is an expanded view of an eighth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having an enclosable chamber.
- FIG. 13 is a sectional side of a rotatable transfer belt.
- FIG. 14A is a top view of a first embodiment of the rotatable transfer belt, having receiving regions and encoder markings.
- FIG. 14B is a top view of a second embodiment of the rotatable transfer belt, having holes for engagement in a tractor-feed manner.
- FIG. 14C is a bottom view of a third embodiment of the rotatable transfer belt, having rear ribs for engagement in a timing-belt manner.
- FIG. 15 is a flow diagram of an example method for the layer transfer technique of the present disclosure.
- FIG. 16 is a front view of an example electrophotography-based additive manufacturing system of the present disclosure.
- the present disclosure is directed to a layer transfer technique for printing 3D parts and support structures in a layer-by-layer manner, where each layer is printed from a part or support material in a thermally-controlled manner.
- the layer transfer technique is performed with an imaging system, such as an electrophotography-based additive manufacturing system.
- each layer may be developed or otherwise imaged using electrophotography and carried from an electrophotography (EP) engine by a transfer medium (e.g., a rotatable belt or drum).
- EP electrophotography
- the layer is then transferred to a build platform to print the 3D part (or support structure) in a layer-by-layer manner, where the successive layers are transfused together to produce the 3D part (or support structure).
- the multiple printed layers in a 3D environment effectively prevents the electrostatic transfer of part and support materials after a given number of layers are printed (e.g., about 15 layers).
- a layer retained by the transfer medium is heated to an elevated transfer temperature.
- the heated layer is then pressed against a previously-printed layer (or to a build platform) to transfuse the layers together (i.e., a transfusion step). This allows numerous layers of 3D parts and support structures to be built vertically, beyond what is otherwise achievable via electrostatic transfers.
- t transformation This minimum transfusion duration (t transformation ) is believed to be a function of the average time for the polymer molecules to diffuse one molecular radius of gyration ( ā r ), which itself is proportional to the material viscosity ( ā material ), and is inversely proportional in an exponential manner to the transfer temperature (T transfer ), as shown in Equations 1-3:
- the minimum transfusion duration for a given transfer temperature is desirably set to be at least the average time for the polymer molecules to diffuse one molecular radius of gyration ( ā r ), more desirably at least twice the average time for the polymer molecules to diffuse one molecular radius of gyration ( ā 2 ā r ), and even more desirably at least three times the average time for the polymer molecules to diffuse one molecular radius of gyration ( ā 3 ā r ).
- the minimum transfusion duration is Time A , based on the plot line function of f( ā r ), such as 3 ā r .
- the minimum transfusion duration is Time B , which can be exponentially shorter than the minimum transfusion duration for the transfer temperature of Temp A .
- 3D parts may be printed at faster speeds with good layer transfusions by increasing the transfer temperature, such as to at least a āfusion temperatureā of the layer material.
- the fusion temperature is a temperature that sufficiently melts the layer material to a fusable state such that polymer molecules of the layer material readily interdiffuse during the subsequent transfusion steps to promote interlayer or interfacial entanglement.
- ABS acrylonitrile-butadiene-styrene
- the fusion temperature may range from about 180° C. to about 220° C. depending on the particular copolymer composition.
- the minimum transfusion duration for the ABS copolymer is about 0.03 seconds.
- the minimum transfusion duration for the ABS copolymer is about 6 seconds, which is substantially slower.
- Equations 1-3 shown above provide a starting point for selecting a transfer temperature.
- the minimum transfusion duration such as (i) thin layer reheating, (ii) layer adhesion to the transfer medium, and (iii) part heat accumulation.
- the layers being printed are thin.
- the interfaces between one or more of the previously printed layers are reheated with each successive transfusion step, during which further interdiffusion can occur.
- the minimum transfusion duration is not limited to a single transfusion step. Rather, the duration may be divided into multiple successive transfusion steps. For example, the 6 seconds required to transfuse the ABS copolymer at a transfer temperature of 160° C. may be divided into 12 successive cycles of about 0.5 second each.
- the fusion temperature is high enough to promote rapid layer transfusion, it can also be too hot for the transfused layer to cleanly release or otherwise delaminate from the transfer medium (e.g., a rotatable belt or drum). This can potentially result in portions of the transfused layer remaining adhered to the transfer medium, or smear upon release from the transfer medium, which negatively impacts feature detail, dimensional accuracy, and porosity of a printed 3D part.
- the transfer medium e.g., a rotatable belt or drum
- the layer transfer technique may also include a ātransfixing stepā, in which the transfer medium and/or the transfused layer is cooled prior to releasing the transfused layer from the transfer medium.
- this transfixing step cools down the interface between the transfer medium and the transfused layer, thus increasing the adhesive force of the interdiffused polymers in adjacent layers relative to the adhesive force of the transfused layer to the surface of the transfer medium. This keeps the transfused layer adhered to the 3D part in a fixed spatial position, and allows the transfused layer to cleanly release from the transfer medium and remain adhered to the 3D part.
- the layer retained by the transfer medium may be heated to a lower transfer temperature (e.g., Temp A ), such as a temperature between a glass transition temperature and the fusion temperature of the layer material.
- Temp A a transfer temperature between a glass transition temperature and the fusion temperature of the layer material.
- the heated layer is then pressed against a previously-printed layer (or to a build platform) to transfuse the layers together (i.e., a transfusion step), and then released from the transfer medium.
- each layer is imaged (e.g., developed) at an imaging engine, transferred from the imaging engine to a build platform, and thermally treated before and/or after the transfusion step, where any one of these steps may dictate the maximum printing speed attainable.
- the imaging of the layers at the imaging engine may be the slowest step in each layer cycle.
- a longer transfusion duration at a lower transfer temperature may be used.
- the lower transfer temperature allows the heated layer to be hot enough for sufficient polymer interdiffusion over the longer transfusion duration, while also being cool enough to readily release from the transfer medium.
- a lower transfer temperature is also particularly suitable for some embodiments of the present disclosure that incorporate post-fuse or heat-setting steps (e.g., layer transfusion assemblies 333 and 433 , shown below in FIGS. 7 and 8 ).
- the transfused layer and the 3D part may then be further heated to at least the fusion temperature of the layer material in the post-fuse or heat-setting step. This sufficiently melts the transfused layer material to a fusable state such that polymer molecules of the transfused layer material at least partially interdiffuse to promote interfacial entanglement.
- Another factor to consider when balancing the transfer temperature and the minimum transfusion duration involves the bulk temperature of the 3D part. Because the imaging system is capable of printing the layers at speeds that are much faster than the rate at which heat diffuses through the variable thermal resistance of the 3D parts, heat accumulation in the 3D parts has been observed. This heat accumulation is proportional to the transfer temperature and the size of the 3D part.
- heat accumulation can be reduced by slowing down the printing process to allow the passive thermal diffusion to lower the part temperature.
- the transfer temperature may also be lowered since the printing speed is already being slowed down.
- these techniques can substantially increase the time required to print 3D parts, particularly if the layer transfusion step is the rate limiting step in the process, thereby reducing throughput.
- the layer transfer technique may include an āactive cooling stepā to prevent the 3D part from accumulating additional heat, thereby maintaining the 3D part at an āaverage part temperatureā (T part ) that is lower than the deformation temperature (T deform ) of the 3D part, as illustrated in Equation 4:
- T part f ( T transfer +active cooling) ā T deform (Equation 4)
- the heat added to the 3D part from the transfused layer may be substantially removed prior to the transfusion of the next layer.
- system 10 is an example additive manufacturing system for printing 3D parts and support structures using electrophotography, which incorporates the layer transfer technique of the present disclosure.
- system 10 includes EP engine 12 , transfer belt 14 , rollers 16 , build platform 18 , and press plate 20 for printing 3D parts (e.g., 3D part 22 ) and any associated support structures (not shown).
- suitable components and functional operations for system 10 include those disclosed in U.S. patent application Ser. Nos. 13/242,669 and 13/242,841.
- system 10 may include different imaging engines for imaging the layers.
- the layer transfer technique focuses on the transfer of layers from belt 14 (or other transfer medium) to build platform 18 (or to the 3D part 22 being printed on build platform 18 ), and on belt 14 , rather than on the particular imaging engine.
- the layer transfer technique is particularly suitable for use with electrophotography-based additive manufacturing systems (e.g., system 10 ), where the multiple printed layers in a 3D environment effectively prevents electrostatic transfer of part and support materials after a given number of layers are printed, as discussed above.
- System 10 also includes controller 24 , which is one or more control circuits, microprocessor-based engine control systems, and/or digitally-controlled raster imaging processor systems, and which is configured to operate the components of system 10 in a synchronized manner based on printing instructions received from host computer 26 .
- Host computer 26 is one or more computer-based systems configured to communicate with controller 24 to provide the print instructions (and other operating information). For example, host computer 26 may transfer information to controller 24 that relates to the sliced layers of 3D part 22 (and any support structures), thereby allowing system 10 to print 3D part 22 in a layer-by-layer manner.
- EP engine 12 is configured to develop or otherwise image successive layers 28 of a thermoplastic-based powder using electrophotography.
- electrophotography includes ionography.
- the thermoplastic-based powder includes one or more thermoplastic materials (e.g., an acrylonitrile-butadiene-styrene (ABS) copolymer), and may also include one or more additional components for development with EP engine 12 and electrostatic attraction to belt 14 .
- ABS acrylonitrile-butadiene-styrene
- belt 14 is an example transfer medium for transferring or otherwise conveying the imaged layers 28 from EP engine 12 to build platform 18 with the assistance of press plate 20 .
- belt 14 includes front or transfer surface 14 a and rear or contact surface 14 b , where front surface 14 a faces EP engine 12 .
- belt 14 may be a multiple-layer belt with a low-surface-energy film that defines front surface 14 a , and which is disposed over a base portion that defines rear surface 14 b.
- System 10 may also include biasing mechanism 29 , which is configured to induce an electrical potential through belt 14 to electrostatically attract layers 28 of the thermoplastic-based powder from EP engine 12 to belt 14 . Because layers 28 are each only a single layer increment in thickness at this point in the process, electrostatic attraction is suitable for transferring layers 28 from EP engine 12 to belt 14 . However, as mentioned above, the multiple printed layers 28 for 3D part 22 effectively prevents electrostatic transfer of layers 28 from belt 14 to build platform 18 after a given number of layers 28 are printed.
- Rollers 16 are a series of drive and/or idler rollers or pulleys that are configured to maintain tension on belt 14 while belt 14 rotates in the rotational direction of arrows 30 . This allows belt 14 to maintain a substantially planar orientation when engaging build platform 18 and press plate 20 .
- System 10 may also include service loops (not shown), such as those disclosed in U.S. patent application Ser. No. 13/242,841.
- System 10 also includes heater 32 , located upstream from build platform 18 and press plate 20 , based on the rotational direction of belt 14 .
- Heater 32 is one or more heating devices configured to heat layers 28 to a temperature near an intended transfer temperature of the thermoplastic-based powder, such as at least a fusion temperature of the thermoplastic-based powder, prior to reaching press plate 20 .
- suitable devices for heater 32 include non-contact radiant heaters (e.g., infrared heaters or microwave heaters), convection heating devices (e.g., heated air blowers), contact heating devices (e.g., heated rollers and/or platens), combinations thereof, and the like, where non-contact radiant heaters are preferred.
- Each layer 28 desirably passes by (or through) heater 32 for a sufficient residence time to heat the layer 28 to the intended transfer temperature.
- the fusion temperature is a temperature that sufficiently melts the thermoplastic-based powder to a fusable state.
- the fusion temperature will vary depending on the particular layer material used and on the applied pressure.
- the fusion temperature may range from about 180° C. to about 220° C. depending on the particular copolymer composition, as mentioned above. Heating the thermoplastic-based powder to the fusion temperature does not necessarily require every component of the thermoplastic-based powder to melt. Rather, the overall thermoplastic-based powder needs to reach a fusable state for subsequent transfusion. This typically refers to the one or more thermoplastic materials of the thermoplastic-based powder being sufficiently melted to the fusable state.
- Layer transfusion assembly 33 is configured to transfuse the heated layers 28 from the belt 14 to the previously-transfused layers of 3D part 22 (or onto build platform 18 ) in a layer-by-layer manner.
- Build platform 18 is a platform assembly or platen of system 10 that is configured to receive the heated layers 28 for printing 3D part 22 in a layer-by-layer manner.
- Build platform 18 is supported by z-axis gantry 34 , which is a linear guide mechanism configured to incrementally lower build platform 18 along the vertical z-axis relative to belt 14 and press plate 20 after each pressing step.
- the movement of build platform 18 with z-axis gantry 34 is operated by z-axis motor 36 based on commands from controller 24 , where z-axis motor 36 may be an electrical motor, a hydraulic system, a pneumatic system, or the like.
- build platform 18 may include removable film substrates for receiving the printed layers 28 .
- build platform 18 is heatable with heating element 38 (e.g., an electric heater).
- Heating element 38 is configured to heat and maintain build platform 18 at an elevated temperature that is greater than room temperature (25° C.), such as at the desired average part temperature of 3D part 22 . This allows build platform 18 to assist in maintaining 3D part 22 at this average part temperature.
- the average part temperature for 3D part 22 is desirably high enough to promote interlayer adhesion and to reduce the effects of curling, while also being low enough to prevent 3D part 22 from softening too much (i.e., below its deformation temperature).
- Suitable average part temperatures for 3D part 22 range from greater than the average solidification temperature of the thermoplastic material(s) of the thermoplastic-based powder to about the glass transition temperature of the thermoplastic material(s). More desirably, the average part temperature is maintained at about the creep relaxation temperature of the thermoplastic material(s) of the thermoplastic-based powder, or within about 10° C. above or below thereof. Examples of suitable techniques for determining the creep relaxation temperatures of materials are disclosed in Batchelder et al., U.S. Pat. No. 5,866,058.
- the average part temperature is maintained in a range between the creep relaxation temperature of the thermoplastic material(s) of the thermoplastic-based powder and a maximum allowable solidification temperature, where the maximum allowable solidification temperature may be illustrated by the stress relaxation of the thermoplastic-based powder.
- the average part temperature for 3D part 22 may be about 100° C., as may be appreciated by a comparison of the stress relaxation or Young's modulus versus temperature for the composition. As shown in FIG.
- the transfusion interface temperature for transfusing the layers together starts at about 150° C. This temperature is suitable for the polymer molecules of the layers 28 to at least partially interdiffuse to promote interfacial entanglement, pursuant to the plot line function of f( ā r ) in FIG. 1 and Equations 1-3.
- Press plate 20 is an example heateable element or heatable layer transfusion element, which is configured to press belt 14 and a given heated layer 28 downward against 3D part 22 and build platform 18 during each transfusion step.
- Press plate 20 may be actuated with a servo mechanism (not shown) configured to move press plate 20 along the vertical z-axis during each transfusion step.
- the particular pressure applied during each transfusion step is desirably high enough to adhere the heated layer 28 to the previously-transfused layer 28 (or to build platform 18 ), allowing the polymer molecules to at least partially interdiffuse.
- the transfusion pressure is also desirably balanced to prevent press plate 20 from compressing 3D part 22 too much, thereby allowing 3D part 22 to maintain its dimensional integrity.
- press plate 20 is heatable with heating element 40 (e.g., an electric heater).
- Heating element 40 is configured to heat and maintain press plate 20 at an elevated temperature that is greater than room temperature (25° C.). However, in comparison to the elevated temperature of build platform 18 , heating element 40 may heat and maintain press plate 20 at a temperature that is less than the desired average part temperature of 3D part 22 . For example, in situations where the intended average part temperature for 3D part 22 is 100° C., heating element 40 may heat and maintain press plate 20 at about 70° C.
- the lower temperature for press plate 20 will cool belt 14 from the side of rear surface 14 b (i.e., a transfixing step). This is in addition to thermal conduction that occurs by the previously-printed layers of 3D part 22 itself, which draw heat from the transfused layers down into the previously-printed layers. As discussed above, if the transfused layer 28 remains too hot, it may remain adhered to front surface 14 a of belt 14 , rather than cleanly releasing from belt 14 . As such, cooling belt 14 with the contact from press plate 20 (and/or via the previously-printed layers) allows the interface between front surface 14 a of belt 14 and the transfused layer 28 to cool down enough to cleanly release the transfused layer 28 from belt 14 .
- heating element 40 desirably maintains press plate 20 at a temperature that balances these competing thermal effects to facilitate both transfusion and transfixing in a single, combined step.
- System 10 may also include one or more air knives 42 or other cooling units, where air knife 42 is an example cooling unit configured to blow localized cooling air to the top layers of 3D part 22 .
- air knife 42 is located adjacent to the lateral side of build platform 18 to direct the cooling air laterally relative to the direction of movement of belt 14 . This allows air knife 42 to extend along the entire length of 3D part 22 , providing good air flow over the top layers of 3D part 22 , including the fused layer 28 .
- system 10 may also include a second air knife 42 (not shown) located at the opposing lateral side of build platform 18 .
- press plate 20 may be heated to the fusion temperature to promote interdiffusion in the transfusion step. Then, upon release of press plate 20 , a separate transfix step may be performed by cooling the transfused layer before release of the layer from the belt 14 .
- FIG. 3B is a graphical illustration of the number of layers printed versus the average part temperature for a 3D part printed without the active cooling (represented by line 44 ) and for 3D part 22 printed with the active cooling (represented by line 46 ).
- line 44 without the active cooling, the heat added by each layer at its fusion temperature will accumulate in the 3D part, causing the average part temperature to increase until the deformation temperature of the 3D part is reached, as illustrated by threshold line 48 .
- threshold line 48 the temperature in the bulk of the 3D part is high enough such that the part material substantially softens.
- the transfusion pressure applied by press plate 20 during subsequent transfusion steps may overcome the structural integrity of the 3D part, thereby deforming the 3D part.
- Air knife 42 actively cools each layer after the transfusion step to prevent the additional heat from accumulating. As shown by line 46 , the active cooling substantially removes the heat provided by each layer 28 , thereby providing substantially zero heat accumulation after each printed layer 28 . As such, 3D part 22 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation, as illustrated above in Equation 4.
- the average part temperature it can be beneficial for the average part temperature to be high enough such that the bulk of 3D part 22 exhibits a small amount of softening. It has been found that when the bulk of 3D part 22 exhibits a small amount of softening that still maintains its overall structural integrity (i.e., 3D part 22 does not deform), subsequent transfusion steps with press plate 20 may mildly compress the bulk of 3D part 22 , thereby increasing the part density. The increased part density correspondingly reduces brittleness and porosity of the resulting 3D part 22 , and increases its z-axis strength. These properties are beneficial for a variety of applications.
- system 10 may alternatively include a variety of different convective and/or conductive cooling units configured to actively cool each layer after the transfusion step to prevent the additional heat from accumulating, such as refrigeration units, liquid-cooling units, evaporation units, and the like.
- one or more air knives 42 may be located at other locations around build platform 18 and press plate 20 to direct the cooling air towards the top layers of 3D part 22 .
- system 10 may also include additional pre-heaters (e.g., heaters 270 and 272 , shown in FIGS. 6A-6F ) to heat the top layer(s) or surface of 3D part 22 to the transfer temperature (e.g. to the fusion temperature) prior to each subsequent transfusion step.
- FIG. 4A-4D illustrate an example process for printing a layer 28 with system 10 using the layer transfer technique of the present disclosure.
- build platform 18 and press plate 20 may be heated to their desired temperatures.
- build platform 18 may be heated to the desired average part temperature for 3D part 22 (e.g., about 100° C. for an ABS copolymer), and press plate 20 may be heated to a temperature that is lower than the desired average part temperature for 3D part 22 (e.g., about 70° C. for an ABS copolymer).
- the printing operation initially involves imaging (e.g., developing) a powder layer 28 with EP engine 12 (shown in FIG. 1 ) and transferring the imaged powder layer to heater 32 via belt 14 .
- FIG. 4A As the imaged powder layer 28 passes by (or through) heater 32 , heater 32 heats the layer 28 and the associated region of belt 14 to an intended transfer temperature of the thermoplastic-based powder, pursuant to the plot line function of in FIG. 1 and Equations 1-3.
- the following discussion will be made with reference to the fusion temperature of the thermoplastic-based powder or layer material (e.g., about 200° C. for an ABS copolymer).
- the temperature of press plate 20 begins to draw heat from the heated region of belt 14 in a transfixing step.
- the previously-printed layers of 3D part 22 which are at the desired average part temperature, may also conductively draw heat from the transfused layers and the heated region of belt 14 . These assist in releasing the transfused layer 28 by cooling belt 14 from rear side 14 b , as discussed above.
- the minimum transfusion duration for an ABS-copolymer material can be as low as about 0.03 seconds. However, this low duration may be countered by the duration required for the transfixing step to cool the interface between belt 14 and the transfused layer 28 .
- transfusion durations for pressing during the transfusion step range from about 0.1 seconds to about 1.0 second, with particularly suitable transfusion durations ranging from about 0.1 seconds to about 0.5 seconds.
- the transfusion duration is a fixed value for each layer 28 .
- the transfusion duration may be varied based on the dimensions and geometry of 3D part 22 . For example, the transfusion duration may be reduced for layers 28 having smaller cross-sectional areas and/or fine-feature details.
- press plate 20 may then be retracted upward, as illustrated by arrow 52 in FIG. 4C , to release the pressure applied to belt 14 and the transfused layer 28 .
- this releases the layer 28 from belt 14 , allowing the layer 28 to remain transfused to 3D part 22 .
- z-axis gantry 34 may lower build platform 18 downward, such as by a single layer increment or other suitable distance, as illustrated by arrow 54 .
- press plate 20 may be heated to the fusion temperature of the thermoplastic-based powder to assist in the transfusion of layer 28 .
- layer transfusion assembly 33 is desirably configured such that retracting press plate 20 upward does not immediately release the transfused layer 28 from belt 14 . Rather, belt 14 may be maintained in a relatively constant position upon the retraction of press plate 20 by positioning build platform 18 in a higher position relative to that shown in FIG. 4D during the transfusion step. A separate transfixing step may then be utilized.
- air knife 42 may be activated to cool the transfused layer 28 before releasing it from belt 14 . After a duration sufficient to cool the layer material down below the fusion temperature, which maintains the transfused layer 28 in a fixed spatial position and adhered to 3D part 22 , build platform 18 is then lowered to release transfused layer 28 from belt 14 .
- Air knife 42 may also be activated to blow cooling air onto the transfused layer 28 after delamination from belt 14 . This actively cools the transfused layer 28 down to the desired average part temperature. Examples of suitable durations for this active cooling step range from about 1.0 second to about 2.0 seconds, which may correspond with the transfer and alignment of the next layer 28 .
- the transfer of layer 28 from belt 14 to build platform 18 requires a pause during the pressing step. Otherwise, the movement of belt 14 in the rotational direction of arrows 30 during the transfusion step may cause a mis-registration of the pressed layer 28 , potentially resulting in lower part quality. These pauses during each transfusion step may be accommodated with the use of service loops, such as those disclosed in U.S. patent application Ser. No. 13/242,841.
- the next layer 28 a may be positioned at heater 32 . This allows heater 32 to sufficiently heat the next layer 28 a during the required pause while the present layer 28 is transfused to 3D part 22 . After the layer 28 is transfused and cooled, the same process may then be repeated for layer 28 a , and each subsequent layer for 3D part 22 .
- layer transfusion assembly 33 is illustrated with a planar press plate 20
- press plate 20 may be replaced with different pressing mechanisms, such as rollers, partial-cylinder presses (configured to simulate rolling motions, e.g., blotters), and the like.
- the embodiments are beneficial for increasing part density due to their capabilities in expelling any gasses (e.g., air) trapped between the powder particles.
- FIGS. 5A-5E illustrate layer transfusion assembly 133 , which is an alternative to layer transfusion assembly 33 of system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D), and where the reference numbers of the respective components are increased by ā100ā from system 10 .
- layer transfusion assembly 133 includes nip roller 120 in lieu of press plate 20 , where nip roller 120 is another example heateable element or heatable layer transfusion element, and is configured to rotate around a fixed axis with the movement of belt 114 .
- nip roller 120 may roll against rear surface 114 b in the direction of arrow 156 while belt 114 rotates in the direction of arrows 130 .
- nip roller 120 may function as a drive roller for belt 114 .
- belt 114 is illustrated as bending around nip roller 120 at about a 90-degree angle, belt 114 may alternatively bend around nip roller 120 at about 180-degree angle in a U-shaped arrangement as shown below for belt 314 and nip roller 320 (shown below in FIG. 7 ).
- air jets 142 are used in lieu of air knife 42 , and are located downstream from the interface between belt 114 and nip roller 120 . Air jets are configured to blow cooling air towards the top layers of 3D part 122 to actively cool the layers after each transfusion step, as discussed below. Air jets 142 may alternatively be replaced by a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like (e.g., one or more cold belts and/or drums, as discussed below).
- convective and/or conductive cooling units such as refrigeration units, liquid-cooling units, evaporation units, and the like (e.g., one or more cold belts and/or drums, as discussed below).
- build platform 118 is supported by gantry 134 , which is a guide mechanism configured to move build platform 118 along the z-axis and the x-axis to produce a reciprocating rectangular pattern, where the primary motion is back-and-forth along the x-axis.
- Gantry 134 may be operated by motor 136 based on commands from controller 124 , where motor 136 may be an electrical motor, a hydraulic system, a pneumatic system, or the like. Accordingly, the pressure that is applied during each transfusion step is performed by build platform 118 .
- build platform 118 and nip roller 120 may be heated to their desired temperatures, as discussed above for build platform 18 and press plate 20 .
- heating element 140 may heat nip roller 120 to a higher temperature (e.g., to the average part temperature, such as about 100° C. for an ABS copolymer) since there is a relatively short time for the heat to locally flow from nip roller 120 through belt 114 .
- heater 132 heats an imaged powder layer 128 and the associated region of belt 114 to an intended transfer temperature of the thermoplastic-based powder, such as to at least the fusion temperature of the thermoplastic-based powder (e.g., about 200° C. for an ABS copolymer).
- Belt 114 may then move the heated layer 132 to a predetermined registration location along the x-axis, as shown.
- Gantry 134 may then actuate build platform 118 upward to engage belt 114 , which presses the top layer of 3D part 122 against the heated layer 124 , as illustrated by arrow 158 .
- nip roller 120 may be actuated downward to meet the top layer or surface of 3D part 122 .
- gantry 134 may then move build platform 118 (and 3D part 122 ) along the x-axis in the direction of arrow 160 , at a rate that is synchronized with the rotational rate of belt 114 in the direction of arrow 130 (i.e., the same directions and speed). This presses belt 114 and the heated layer 128 between the top layer of 3D part 122 and nip roller 120 .
- this causes rear surface 114 b of belt 114 to roll across nip roller 120 to nip belt 114 and the heated layer 128 against the top layer of 3D part 122 . Because layer 128 is heated to the fusion temperature of the thermoplastic-based powder and 3D part 122 is maintained at the average part temperature, the pressed layer 128 transfuses to the top layer of 3D part 122 in a similar manner to that discussed above for 3D part 22 and layer 28 .
- transfused layer 128 passes the nip of nip roller 120 , belt 114 wraps around nip roller 120 to separate and disengage from build platform 118 . This assists in releasing the transfused layer 128 from belt 114 , allowing the transfused layer 128 to remain adhered to 3D part 122 . Additionally, air jets 142 blow cooling air towards the top layers of 3D part 122 as build platform 118 moves along the x-axis past nip roller 120 to cool down the transfused layer 128 . The transfused layer 128 may be cooled down to the average part temperature (e.g., about 100° C. for an ABS copolymer) by continuing to blow cooling air against the 3D part 122 in between transfusion steps.
- the average part temperature e.g., about 100° C. for an ABS copolymer
- gantry 134 may actuate build platform 118 (and 3D part 122 ) downward, as illustrated by arrow 162 . As shown in FIG. 5D , gantry 134 may then move build platform 118 (and 3D part 122 ) along the x-axis in the direction of arrow 164 , back to a starting position along the x-axis. As shown in FIG. 5E , build platform 118 desirably reaches the starting position as the next heated layer 128 is positioned above 3D part 122 .
- gantry 134 actuates build platform 118 upward to press belt 114 and the next heated layer 128 between the top layer of 3D part 122 and roller 120 , as illustrated by arrow 166 .
- the height of the top surface of 3D part 122 is offset downward, such as by a single layer increment, compared to the previous pressing step.
- moving build platform 118 (and 3D part 122 ) in the reciprocating rectangular pattern allows the transfusion steps to be performed while belt 114 continuously rotates.
- moving build platform 118 at a rate that is synchronized with the rotational rate of belt 114 , along with the use of nip roller 120 , which rotates against rear surface 114 b of belt 114 allows the transfusion and transfixing steps to be performed rapidly (e.g., within about 0.1 to about 0.5 seconds). This allows the active cooling steps to range from about 1.0 second to about 2.0 seconds, which may correspond with the transfer and alignment of the next heated layer 28 .
- gantry 134 may move build platform 118 (and 3D part 122 ) in a reciprocating rectangular pattern having rounded or oval-defining corners, so long as build platform 118 moves linearly along the x-axis during the transfusion steps.
- air jets 142 may direct cooling air towards 3D part 122 in a global manner, where cooling air, while directed at the top layers of 3D part 122 , may also flow around the lateral sides of 3D part 122 .
- this global cooling can cool 3D part 122 down below its desired average part temperature, which can have adverse effects on 3D part 122 in some circumstances (e.g., curling issues).
- air jets 142 may be replaced with one or more localized cooling mechanisms or units, such as one or more cold belts and/or drums, which can contact the top layers of 3D part 122 to selectively cool only the areas of 3D part 122 that are in contact with the cooling unit 642 .
- the cold belts and/or drums only cool the top heated layers of 3D part 122 in a localized manner, rather than a global cooling of 3D part 122 .
- This draws away the additional heat from the transfused layers (and a portion of the previously-printed layers) in an active cooling step without cooling down the entire 3D part 122 .
- suitable cooling units in these embodiments include those discussed below for layer transfusion assembly 633 (e.g., cooling unit 642 , shown below in FIG. 10 ).
- FIGS. 6A-6F illustrate layer transfusion assembly 233 , which is an alternative to layer transfusion assembly 133 (shown in FIGS. 5A-5E ), and where the reference numbers of the respective components are increased by ā200ā from system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D).
- Layer transfusion assembly 233 may function in a similar manner to layer transfusion assembly 133 , where build platform 218 may move in a reciprocating rectangular pattern.
- layer transfusion assembly 233 includes fusion roller 220 and release roller 268 in lieu of a single nip roller 120 , where fusion roller 220 and release roller 268 are each configured to rotate around an axis with the movement of belt 214 .
- the use of separate rollers i.e., fusion roller 220 and release roller 268 ) separates the functions of each roller, allowing them to be optimized for their particular purposes.
- fusion roller 220 may be heated to a high transfer temperature (e.g., the fusion temperature of the thermoplastic-based powder) to accelerate the layer transfusion, and release roller 268 may be maintained at a substantially lower temperature to assist in delaminating the transfused layers 228 from belt 214 .
- layer transfusion assembly 233 also includes heaters 270 and 272 and air jets 274 .
- the separation of fusion roller 220 and release roller 268 creates separate transfusion and release steps, and allows a transfixing step to be performed therebetween via cooling by air jets 274 .
- fusion roller 220 may be heated to a transfer temperature best suited for the transfusion step (e.g., the fusion temperature of the thermoplastic-based powder), rather than a compromise temperature that facilitates both transfusion and release. This can increase the printing speed and/or increase the interlayer adhesion between the transfused layers 228 per transfusion step, while also cleanly releasing the transfused layers 228 from belt 214 .
- build platform 218 and fusion roller 220 may be heated to their desired temperatures.
- build platform 218 may be heated to the average part temperature (e.g., about 100° C. for an ABS copolymer) and fusion roller 220 may be heated to the transfer temperature of the thermoplastic-based powder (e.g., to the fusion temperature, such as about 200° C. for an ABS copolymer).
- belt 214 carries an imaged powder layer 228 past heater 232 , which heats the imaged powder layer 228 and the associated region of belt 214 to the desired transfer temperature.
- platen gantry 234 moves build platform 218 along the x-axis in the direction of arrow 276 below, along, or through heater 270 .
- Heater 270 may function in the same manner as heaters 32 and 232 , and heats the top surface of 3D part 222 to an elevated temperature, such as at the same transfer temperature as the heated layer 228 (or other suitable elevated temperature).
- the continued rotation of belt 214 and the movement of build platform 218 align the heated layer 228 with the heated top surface of 3D part 222 with proper registration along the x-axis.
- the heated layer 228 and the heated top surface of 3D part 222 each pass heater 272 , which may be configured to heat and/or maintain both the heated layer 228 and the heated top surface of 3D part 222 at the transfer temperature of the layer material. This prevents the heated layer 228 from cooling down prior to reaching fusion roller 220 , and brings the temperature of the heated top surface of 3D part 222 to or near the transfer temperature before the next transfusion step is performed.
- one or more of heaters 232 , 270 , and 272 may be provided a single heater configured to direct heat in multiple directions (e.g., towards both the layer 228 and the top surface of 3D part 222 ).
- one or both of heaters 270 and 272 may be omitted if not needed.
- one or both of heaters 270 and 272 may also be utilized with layer transfusion assembly 133 (shown above in FIGS. 5A-5E ) in the same manner as for layer transfusion assembly 233 to direct heat towards the top surface of 3D part 122 prior to the transfusion step.
- Gantry 234 may continue to move build platform 218 (and 3D part 222 ) along the x-axis in the direction of arrow 276 , at a rate that is synchronized with the rotational rate of belt 214 in the direction of arrow 230 (i.e., the same directions and speed). This causes rear surface 214 b of belt 214 to rotate around fusion roller 220 to nip belt 214 and the heated layer 228 against the top surface of 3D part 222 . This engages build platform 218 and belt 214 , and presses the heated layer 228 between the heated top surface of 3D part 222 and belt 214 at the location of fusion roller 220 .
- layer 228 and the heated top layer of 3D part 222 are can each be heated to the fusion temperature of the thermoplastic-based powder, the pressed heated layer 228 transfuses to the heated top surface of 3D part 222 with a high level of interlayer adhesion.
- layer transfusion assembly 233 allows the layers to be heated to an optimal transfusion interface temperature, and to be cooled to a temperature that fixes the layers before release.
- the transfusion interface temperature for transfusing the layers together may be at about the fusion temperature of the thermoplastic-based powder (e.g., about 200° C. for an ABS copolymer). This can substantially increase the printing speed and/or increase the extent to which the polymer molecules of the transfused layers interdiffuse per transfusion step to promote interfacial entanglement, while also maintaining dimensional accuracy of 3D part 222 .
- Air jets 274 may function in the same manner as air jets 142 and 242 for cooling belt 214 the side of rear surface 214 b .
- air jets 274 may be a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like.
- cooling belt 214 with air jets 274 allows the interface between front surface 214 a of belt 214 and the transfused layer 228 to cool so that the transfused layer 228 will remain adhered to 3D part 222 and cleanly release from belt 214 .
- This also partially assists in the active cooling of 3D part 222 to maintain 3D part 222 at the average part temperature below its deformation temperature, as illustrated above in Equation 4.
- belt 214 rotates around release roller 268 to separate and disengage from build platform 218 .
- air jets 242 blow cooling air towards the top layers of 3D part 222 as build platform 218 moves along the x-axis past release roller 268 . This actively cools the transfused layer 228 down to the average part temperature, as also illustrated above in Equation 4.
- gantry 234 may actuate build platform 218 (and 3D part 222 ) downward, as illustrated by arrow 278 .
- build platform 218 may be incrementally offset downward by a single layer increment.
- gantry 234 may then move build platform 218 (and 3D part 222 ) along the x-axis in the direction of arrow 280 , back to a starting position along the x-axis.
- build platform 218 desirably reaches the starting position for proper registration with the next layer 228 .
- gantry 234 may also actuate build platform 218 and 3D part 222 upward for proper registration with the next layer 228 .
- the same process may then be repeated for each remaining layer 228 of 3D part 222 .
- Layer transfusion assembly 233 provides the benefits of transfusing the layers together at the desired transfer temperature (e.g., the fusion temperature of the thermoplastic-based material) to increase interlayer adhesion, while also sufficiently cooling down the interface between front surface 214 a of belt 214 and the transfused layers 228 to transfix the layers 228 in place before release from belt 214 . This promotes a clean release by assisting the delamination from belt 214 .
- the combination of air jets 242 and 274 substantially removes the heat that is added from heating elements 232 , 270 , 272 , and from the heated fusion roller 220 , prior to printing the next layer 228 .
- This active cooling substantially removes the heat provided by each layer 228 , thereby providing substantially zero heat accumulation after each printed layer 228 .
- 3D part 222 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation. Further, the top layer surface temperature of the printed 3D part 222 may be brought back up to the transfer temperature after delamination using heater 270 and/or 272 of layer transfusion assembly 233 for optimal transfusion of the next layer 228 .
- FIGS. 7 and 8 illustrate layer transfusion assemblies 333 and 433 , which are alternatives to layer transfusion assemblies 133 (shown in FIGS. 5A-5E ) and layer transfusion assembly 233 (shown in FIGS. 6A-6F ), and include post-fuse heaters 382 and 482 configured to perform a post-fuse or heat-setting step by heating the part surface to an elevated temperature (e.g., to at least the fusion temperature of the thermoplastic-based powder) after transferring a layer.
- layer transfusion assembly 333 may function in a similar manner to layer transfusion assembly 133 , where the reference numbers of the respective components are increased by ā300ā from system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D).
- this post-fuse step follows the transfusion/transfixing and release steps of the layer transfer process, which may be performed at a transfer temperature that is below the fusion temperature of the thermoplastic-based powder.
- the addition of post heaters 382 and 482 in layer transfusion assemblies 333 and 433 permits transferring of layers to 3D parts 322 and 422 at transfer temperatures optimized for clean and quick transfer of layers, without sacrificing part strength gained through interfacial bonding of the layer material at the fusion temperature of the thermoplastic-based powder. In this manner, part quality may be optimized for dimensional accuracy and porosity (by a clean transfer), and also for strength.
- layer transfusion assembly 333 also includes heaters 370 and 372 (in addition to post-fuse heater 382 ). Heaters 370 and 372 correspond to heaters 270 and 272 of layer transfusion assembly 233 and function in a similar manner for heating the top surface or layer(s) of 3D part 322 prior to the transfusion step.
- Post heater 382 is located downstream from nip roller 320 and upstream from air jets 342 , and is configured to heat the transfused layers to an elevated temperature in the post-fuse or heat-setting step.
- build platform 318 and nip roller 320 may be heated to their desired temperatures.
- build platform 318 may be heated to the average part temperature (e.g., about 100° C. for an ABS copolymer).
- nip roller 320 may be heated to a desired transfer temperature for an imaged layer 328 .
- belt 314 carries the imaged powder layer 328 past heater 332 , which heats the imaged powder layer 328 and the associated region of belt 314 to the transfer temperature.
- the transfer temperature for imaged powder layer 328 is desirably less than its fusion temperature, but high enough to achieve partial entanglement of the polymer molecules between the heated layer 328 and 3D part 322 during the subsequent transfusion step.
- Suitable transfer temperatures for the thermoplastic-based powder include temperatures that exceed the glass transition temperature of the thermoplastic-based powder, where the layer material is softened but not melted, for example, a temperature of ranging from about 140° C. to about 180° C. for an ABS copolymer.
- gantry 334 may move build platform 318 and 3D part 322 in a reciprocating rectangular pattern (depicted by arrows 376 ) in the same manner as gantries 134 and 234 .
- gantry 334 moves build platform 318 along the x-axis below, along, or through heater 370 .
- Heater 370 heats the top surface of 3D part 322 to an elevated temperature, such as the transfer temperature of the thermoplastic-based powder.
- heaters 332 and 370 may heat the imaged powder layers 328 and the top surface of 3D part 322 to about the same temperatures to provide a consistent transfusion interface temperature.
- heaters 332 and 370 may heat the imaged powder layers 328 and the top surface of 3D part 322 to different temperatures to attain a desired transfusion interface temperature.
- the continued rotation of belt 314 and the movement of build platform 318 align the heated layer 328 with the heated top surface of 3D part 322 with proper registration along the x-axis.
- the heated layer 328 and the heated top surface of 3D part 322 may each pass heater 372 , which may be configured to heat and/or maintain both the heated layer 328 and the heated top surface of 3D part 322 at the transfer temperature. This prevents the heated layer 328 from cooling down prior to reaching nip roller 320 , and brings the temperature of the heated top surface of 3D part 322 to or near the transfer temperature before the next transfusion step is performed.
- heater 372 may be omitted.
- Gantry 334 may continue to move build platform 318 (and 3D part 322 ) along the x-axis, at a rate that is synchronized with the rotational rate of belt 314 in the direction of arrow 330 (i.e., the same directions and speed). This causes rear surface 314 b of belt 314 to rotate around nip roller 320 to nip belt 314 and the heated layer 328 against the top surface of 3D part 322 . This engages build platform 318 and belt 314 , and presses the heated layer 328 between the heated top surface of 3D part 322 and belt 314 at the location of nip roller 320 . This at least partially transfuses heated layer 328 to the top layer of 3D part 322 .
- transfused layer 328 passes the nip of nip roller 320 , belt 314 wraps around nip roller 320 to separate and disengage from build platform 318 . This assists in releasing the transfused layer 328 from belt 314 , in an assisted delamination step, allowing the transfused layer 328 to remain adhered to 3D part 322 .
- maintaining the transfusion interface temperature at a transfer temperature that is higher than its glass transition temperature, but lower than its fusion temperature allows the heated layer 328 to be hot enough to adhere to 3D part 322 , while also being cool enough to readily release from belt 314 .
- gantry 334 continues to move build platform 318 (and 3D part 322 ) along the x-axis to post-fuse heater 382 .
- post-fuse heater 382 the transfused layer 328 and 3D part 322 are then heated to at least the fusion temperature of the thermoplastic-based powder in a post-fuse or heat-setting step. This melts the material of the transfused layer 328 to a highly fusable state such that polymer molecules of the transfused layer 328 quickly interdiffuse to achieve a high level of interfacial entanglement with 3D part 322 .
- gantry 334 continues to move build platform 318 (and 3D part 322 ) along the x-axis past post-fuse heater 382 to air jets 342 , air jets 342 blow cooling air towards the top layers of 3D part 322 . This actively cools the transfused layer 328 down to the average part temperature, as discussed above.
- Gantry 334 may then actuate build platform 318 (and 3D part 322 ) downward, and move build platform 318 (and 3D part 322 ) back along the x-axis to a starting position along the x-axis, following the reciprocating rectangular pattern 376 .
- Build platform 318 desirably reaches the starting position for proper registration with the next layer 328 .
- gantry 334 may also actuate build platform 318 and 3D part 322 upward for proper registration with the next layer 328 . The same process may then be repeated for each remaining layer 328 of 3D part 322 .
- Layer transfusion assembly 333 provides an alternative mechanism for transfusing the imaged layers 428 together at 3D part 322 , while also keeping the heated layers 328 cool enough for clean release from belt 314 .
- air jets 342 substantially remove the heat that is added from heating elements 332 , 370 , and 372 , and post-fuse heater 382 prior to printing the next layer 328 .
- This active cooling substantially removes the heat provided by each layer 328 , thereby providing substantially zero heat accumulation after each printed layer 328 .
- 3D part 322 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation. Further, the top layer surface temperature of the printed 3D part 322 may be brought back up to above its glass transition temperature using heaters 370 and/or 372 for transfusion of the next layer 328 .
- layer transfusion assembly 433 is a combination of layer transfusion assemblies 233 and 333 , where the reference numbers of the respective components are increased by ā400ā from system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D).
- Layer transfusion assembly 433 includes post-fuse heater 482 located downstream from release roller 468 and upstream from air jets 442 , which may operate in the same manner as post-fuse heater 382 to heat the transfused layers to at least the fusion temperature of the thermoplastic-based powder in the post-fuse or heat-setting step.
- build platform 418 and fusion roller 420 may be heated to their desired temperatures.
- build platform 418 may be heated to the average part temperature and fusion roller 420 may be heated to an elevated temperature, such as to the fusion temperature of the thermoplastic-based powder, as discussed above for fusion roller 220 , or to a lower transfer temperature.
- belt 414 carries an imaged powder layer 428 past heater 432 , which heats the imaged powder layer 428 and the associated region of belt 414 to an elevated transfer temperature, desirably above the glass transition temperature and typically not exceeding the fusion temperature of the thermoplastic-based powder.
- gantry 434 may move build platform 418 and 3D part 422 in a reciprocating rectangular pattern (depicted by arrows 476 ) in the same manner as gantries 134 , 234 , and 334 .
- Gantry 434 may move build platform 418 along the x-axis below, along, or through heater 470 , which heats the top surface of 3D part 422 to an elevated transfer temperature, likewise above the glass transition temperature and desirably not to exceeding the fusion temperature of the thermoplastic-based powder.
- the continued rotation of belt 414 and the movement of build platform 418 align the heated layer 428 with the heated top surface of 3D part 422 with proper registration along the x-axis.
- the heated layer 428 and the heated top surface of 3D part 422 may each pass heater 472 , which may be configured to heat and/or maintain both the heated layer 428 and the heated top surface of 3D part 422 at the transfer temperature. This prevents the heated layer 428 from cooling down prior to reaching fusion roller 420 , and brings the temperature of the heated top surface of 3D part 422 to the transfer temperature before the next transfusion step is performed.
- Gantry 434 may continue to move build platform 418 (and 3D part 422 ) along the x-axis, at a rate that is synchronized with the rotational rate of belt 414 in the direction of arrow 430 (i.e., the same directions and speed). This causes rear surface 414 b of belt 414 to rotate around fusion roller 420 to nip belt 414 and the heated layer 428 against the heated top surface of 3D part 422 . This engages build platform 418 and belt 414 , and presses the heated layer 428 between the heated top surface of 3D part 422 and belt 414 at the location of fusion roller 420 to perform the transfusion step.
- layer transfusion assembly 433 By separating fusion roller 420 and release roller 468 , with a cooling step therebetween via air jets 474 (or other cooling mechanism), layer transfusion assembly 433 also allows the layers to be heated to a transfusion interface temperature higher than is permitted in using layer transfusion assembly 333 . Where layer 428 and the heated top layer of 3D part 422 are heated to, at, or near the fusion temperature of the thermoplastic-based powder, the pressed heated layer 428 transfuses to the heated top surface of 3D part 422 with a high level of interlayer adhesion.
- air jets 474 After passing fusion roller 420 , and while build platform 418 remains engaged with belt 414 , belt 414 , build platform 418 , and 3D part 422 pass air jets 474 , which cool belt 414 the side of rear surface 414 b , as discussed above for air jets 274 .
- air jets 474 may be a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like. Cooling belt 414 with air jets 474 allows the interface between front surface 414 a of belt 414 and the transfused layer 428 to cool so that the transfused layer 428 will remain adhered to 3D part 422 and cleanly release from belt 414 .
- belt 414 rotates around release roller 468 to separate and disengage from build platform 418 . This assists in releasing the transfused layer 428 from belt 414 , in an assisted delamination step, allowing the transfused layer 428 to remain adhered to 3D part 422 .
- gantry 434 continues to move build platform 418 (and 3D part 422 ) along the x-axis to post-fuse heater 482 .
- post-fuse heater 482 the transfused layer 428 and 3D part 422 are then heated back up to the fusion temperature of the thermoplastic-based powder in a heat-setting step. This melts the material of the transfused layer 428 to a fusable state such that polymer molecules of the transfused layer 428 become highly interdiffused to promote interfacial entanglement with 3D part 422 .
- layer transfusion assembly 433 generates two interdiffusion steps separated by a transfixing step, a process particularly suitable for building very high strength parts.
- gantry 434 continues to move build platform 418 (and 3D part 422 ) along the x-axis past post-fuse heater 482 to air jets 442 , air jets 442 blow cooling air towards the top layers of 3D part 422 . This actively cools the transfused layer 428 down to the average part temperature, as discussed above.
- Gantry 434 may then actuate build platform 418 (and 3D part 422 ) downward, and move build platform 418 (and 3D part 422 ) back along the x-axis to a starting position along the x-axis, following the reciprocating rectangular pattern 476 .
- Build platform 418 desirably reaches the starting position for proper registration with the next layer 428 .
- gantry 434 may also actuate build platform 418 and 3D part 422 upward for proper registration with the next layer 428 . The same process may then be repeated for each remaining layer 428 of 3D part 422 .
- Layer transfusion assembly 433 provides a further alternative mechanism for transfusing the layers together, while also keeping the heated layers 428 cool enough for clean release from belt 414 .
- the separation of fusion roller 420 and release roller 468 , with a cooling or transfixing step therebetween via air jets 474 allows the layers to be heated to an optimal transfusion interface temperature, and to be cooled to a temperature that transfixes the layers 428 before release.
- the heat-setting step via post-fuse heater 482 provides an even greater control over part strength.
- the thermal profile of the layers 428 and 3D part 422 may be tightly controlled to meet a variety of requirements.
- the transfused layer 428 may then be reheated to at least its fusion temperature via post-fuse heater 482 , as discussed above, to further promote interfacial entanglement with 3D part 422 .
- FIGS. 9 and 10 illustrate layer transfusion assemblies 533 and 633 , which are further alternatives layer transfusion assembly 233 (shown in FIGS. 6A-6F ), where air jets 274 are omitted.
- layer transfusion assembly 533 may function in a similar manner to layer transfusion assembly 233 , where the reference numbers of the respective components are increased by ā500ā from system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D), and by ā300ā from layer transfusion assembly 233 .
- belt 514 desirably functions as a heat capacitor for heating the layers 528 and 3D part 522 .
- belt 514 desirably has a high thermal conductivity and high heat capacity, as discussed below.
- Heater 532 as shown is a non-contact radiant heater that directs heat to opposing faces of the belt, so as to heat the belt itself along with heating an imaged powder layer 528 .
- belt 514 may be the sole source of heating for the transfusion step, and nip roller 520 may optionally be unheated or heated to a lower temperature (e.g., the desired average part temperature).
- an alternative or additional heat source may be used in place of heater 532 , such as contact heat source or non-radiant heaters.
- build platform 518 may be heated to its desired temperature (e.g., the average part temperature).
- desired temperature e.g., the average part temperature
- belt 514 carries imaged powder layer 528 past heater 532 , which heats the imaged powder layer 528 and the associated region of belt 514 to an elevated transfer temperature, such as the fusion temperature of the thermoplastic-based powder.
- belt 514 desirably continues to heat the heated layer 528 during transit to build platform 518 .
- gantry 534 may move build platform 518 and 3D part 522 in a reciprocating rectangular pattern (depicted by arrows 576 ) in the same manner as gantries 134 , 234 , 334 , and 434 .
- the continued rotation of belt 514 and the movement of build platform 518 align the heated layer 528 with the top surface of 3D part 522 with proper registration along the x-axis.
- Gantry 534 may continue to move build platform 518 (and 3D part 522 ) along the x-axis, at a rate that is synchronized with the rotational rate of belt 514 in the direction of arrow 530 (i.e., the same directions and speed).
- the conductive heating from belt 514 directly heats only those areas of 3D part 522 that are being fused together (i.e., the areas of 3D part 522 that are in contact with the heated layer 528 or belt 514 . Additionally, belt 514 desirably conducts thermal energy to the transfused layer 528 and 3D part 522 as belt 514 and build platform 518 continue to move in the direction of arrow 530 from nip roller 520 to release roller 568 . While not wishing to be bound by theory, it is believed that the release of thermal energy from belt 514 to the transfused layers of 3D part 522 during this step provides two functions.
- the initial transfusion interface temperature for transfusing the layers together starts at about 150° C.
- the continued conductance of thermal energy from belt 514 to the transfused layers of 3D part 522 while moving from nip roller 520 to release roller 568 increases the transfusion interface temperature. This accordingly increases the extent that the polymer molecules interdiffuse to promote interfacial entanglement, pursuant to the plot line function of f( ā r ) in FIG. 1 and Equations 1-3.
- the conductive heat transfer which draws heat from belt 514 and layer 528 into the top-most layers of 3D part 522 , cools belt 514 and layer 528 down from the fusion temperature to a lower temperature, so that when passing release roller 568 the transfused layer 528 may remain adhered to 3D part 522 and cleanly release from belt 514 .
- drawing heat from belt 514 in this manner cools belt 514 and layer 528 down in a similar manner to air jets 274 and 474 , without employing the jets.
- belt 514 rotates around release roller 568 to separate and disengage from build platform 518 . This assists in releasing the transfused layer 528 from belt 514 , in an assisted delamination step, allowing the transfused layer 528 to remain adhered to 3D part 522 .
- belt 514 may rotate back around to EP engine 12 (shown in FIG. 2A ), and may be cooled down further with additional cooling mechanisms (not shown) or via ambient cooling.
- Gantry 534 may actuate build platform 518 (and 3D part 522 ) downward, and move build platform 518 (and 3D part 522 ) back along the x-axis to a starting position along the x-axis, following the reciprocating rectangular pattern 576 .
- Build platform 518 desirably reaches the starting position for proper registration with the next layer 528 .
- gantry 534 may also actuate build platform 518 and 3D part 522 upward for proper registration with the next layer 528 . The same process may then be repeated for each remaining layer 528 of 3D part 522 .
- Layer transfusion assembly 533 provides a further alternative mechanism for transfusing the layers together, while also keeping the heated layers 528 cool enough for clean release from belt 514 .
- layer transfusion assembly 533 may also optionally include one or more pre-heaters (e.g., heaters 270 and 272 ) to direct heat towards the top surface of 3D part 522 prior to the transfusion step; one or more air jets (e.g., air jets 274 and 474 ) to assist in further cooling belt 514 ; one or more post-fuse heaters (e.g., post-fuse heaters 382 and 482 ) to reheat 3D part 522 ; and/or one or more active cooling air units (e.g., air jets 242 , 342 , and 442 ) to assist in maintaining 3D part 522 at its desired average part temperature.
- pre-heaters e.g., heaters 270 and 272
- air jets e.g., air jets 274 and 474
- post-fuse heaters e.g., post-fuse heaters 382 and 482
- active cooling air units e.g., air jets 242
- the high thermal conductivity and heat capacity of belt 514 allows layer transfusion assembly to selectively transfer heat only to those areas of 3D part 522 that are being fused together.
- This conductive heating reduces the risk of melting melt small part features of 3D part 522 that have been completed and are not being fused with the current layer 528 .
- This is in addition to allowing a reduced number of heating and cooling units in layer transfusion assembly 533 , thereby reducing the number of re-heating and re-cooling steps.
- suitable average thermal conductivities for belt 514 include thermal conductivities of at least about 0.12 watts/meter-Kelvin (W/m-K), with particularly suitable average thermal conductivities ranging from about 0.2 W/m-K to about 0.5 W/m-K, where the average thermal conductivities are measured pursuant to ASTM E1225-09.
- suitable average heat capacities for belt 514 include specific heat capacities of at least about 1,000 joules/(kilogram-Kelvin) (J/kg-K), with particularly suitable average heat capacities ranging from about 2,000 J/kg-K to about 3,000 J/kg-K, where the specific heat capacities are measured pursuant to ASTM E1269-11.
- suitable materials for belt 514 include polymeric and metallic materials, which may be doped with one or more conductive materials to promote the electrostatic charges.
- suitable polymeric materials include polyimide materials, such as those commercially available under the trade designation āKAPTONā from E.I. du Pont de Nemours and Company, Wilmington, Del.
- the thermal conductivity and heat capacity of belt 514 may alternatively be collectively referred to based on its average thermal inertia or effusivity, pursuant to Equation 5:
- I is the thermal inertia or effusivity with units of joules/(meter 2 -Kelvin-seconds 0.5 ) (J/m 2 -K-s 0.5 )
- ā is the thermal conductivity of belt 514
- ā is the density of belt 514 (kilograms/meter 3 )
- c is the specific heat capacity of belt 514 , where the density and specific heat capacity are typically referred to together as the volumetric heat capacity.
- suitable average thermal inertias for belt 514 include thermal inertias of at least about 400 J/m 2 -K-s 0.5 , with particularly suitable average thermal inertias ranging from about 600 J/m 2 -K-s 0.5 to about 800 J/m 2 -K-s 0.5 .
- belt 514 may be also be a multi-layer belt having layers of different materials, as discussed below.
- the above-discussed average thermal conductivities and heat capacities are based on the averages of entirety of belt 514 , which is dependent on the materials of the different layers and the relative cross-sectional thicknesses of the different layers.
- FIG. 10 illustrates layer transfusion assembly 633 , which is an alternative to layer transfusion assembly 533 (shown in FIG. 9 ), where the reference numbers of the respective components are increased by ā600ā from system 10 (shown in FIGS. 2A , 3 A, and 4 A- 4 D), and by ā100ā from layer transfusion assembly 533 .
- layer transfusion assembly 633 also includes cooling unit 642 , which is a conductive cooling unit to actively cool 3D part 622 in a similar manner to air jets 242 , 342 , and 442 to assist in maintaining 3D part 622 at its desired average part temperature.
- cooling unit 642 selectively cools only the areas of 3D part 622 that are in contact with cooling unit 642 .
- cooling unit 642 may include roller 642 a and cooling belt 642 b , where cooling belt 642 b is configured to rotate around roller 642 a (and other idler and/or drive rollers), desirably at a rate that is synchronized with the movement of build platform 618 and 3D part 622 along the x-axis in the direction of arrow 630 .
- Belt 642 b itself desirably has a thermal conductivity and is cooled down (e.g., via a refrigeration unit or other cooling mechanism, not shown) to function as a heat sink.
- cooling unit 642 may include any suitable mechanism for drawing thermal energy from 3D part 622 via thermal conduction (e.g., a rotatable cold drum or a reciprocating cold platform).
- the top surface of 3D part 622 desirably contacts and moves along with belt 642 b for a sufficient duration to actively draw heat from 3D part 622 in an active cooling step. As mentioned above, this selectively cools only the areas of 3D part 622 that are in contact with cooling unit 642 , rather than a global cooling of 3D part 622 .
- the majority of the heat drawn into 3D part 622 resides at the top-most layers of 3D part 622 . As such, selectively drawing heat from these same areas promptly after the transfusion steps prevents the heat from diffusing into the bulk of the part, without globally cooling 3D part 622 .
- the combination of belt 614 and cooling unit 642 allows layer transfusion assembly 633 to directly heat and cool only those areas of 3D part 622 that are being fused. This may eliminate bulk heating and bulk cooling steps that potentially impart undesirable effects such as melting of small features that have been completed, or over cooling of surfaces that are still under construction.
- System 10 with layer transfusion assemblies 33 , 133 , 233 , 333 , 433 , 533 , and 633 is suitable for printing 3D parts (and any support structures) from thermoplastic-based powders at high rates and with good part resolutions.
- system 10 may print layers of a 3D part at a rate of at least about 40 layers per minute (e.g., about 50 layers per minute) with accurate registration, layer thicknesses ranging from about 5 micrometers to about 125 micrometers, and layer dimensions along the y-axis up to at least about 51 centimeters (about 11 inches).
- system 10 may print a 3D part at a rate of about three inches in height along the vertical z-axis per hour.
- each 3D part may be printed at a āhigh qualityā resolution, in which system 10 operates at a slower rate, but prints with lower layer thicknesses.
- a 3D part may be printed at a ādraft qualityā resolution, in which system 10 operates a faster rate, but prints with greater layer thicknesses.
- a 3D part may be printed in āgray scaleā, in which a lower density of the part material is developed or otherwise imaged. Numerous resolutions and speeds therebetween may also be incorporated. In each of these situations, the controller may adjust the applied pressures, temperatures, and/or contact durations during the transfusion steps to account for the different printing rates.
- System 10 is illustrated as being configured to print 3D parts (e.g., 3D parts 22 , 122 , 222 , 322 , 422 , 522 , and 622 ) from a single thermoplastic-based powder.
- the additive manufacturing systems of the present disclosure may also be configured to print 3D parts and/or support structures from multiple part materials and/or support materials derived from thermoplastic-based powders (e.g., multiple compositions and/or colors). Examples of suitable multiple-material systems include those disclosed in U.S. patent application Ser. Nos. 13/242,669 and 13/242,841.
- controller 24 may monitor the applied pressure, the temperature of the layers, part heights, and the contact durations during the transfusion steps to maximize or otherwise increase the effectiveness in transferring the layers from the front surface of the transfer belt to the build platform.
- one or more of the applied pressure, temperature, and contact durations may be fixed parameters for a given part material and overall printing rate.
- the part height may be self compensated in an open-loop manner where a spring action of the transfer roller may function as a mechanical proportional control system.
- the nip compression is reduced, which reduces the transfer pressures and the layers may not be fully compressed.
- the resulting material would be slightly porous and have a resulting larger layer thickness.
- the nip compression is increased, which increases the transfer pressures and the layers would be more compressed.
- the resulting material would be less porous and have a resulting smaller layer thickness.
- controller 24 may adjust one or more parameters in response to the monitored signals using one or more process control loops.
- layer transfusion assembly 33 may include one or more temperature sensors 784 t and/or one or more height sensors 784 hp and 784 hs , each configured to communicate with controller 24 . While illustrated in use with layer transfusion assembly 33 , sensors 784 t and 784 h are equally suitable for use with layer transfusion assemblies 133 , 233 , 333 , 433 , 533 , and 633 .
- Temperature sensors 784 t are configured to monitor the temperature of 3D part 22 and/or the associated support structure (referred to as support structure 22 s ).
- suitable temperature sensors for temperature sensors 784 t include non-contact sensors, such as infrared pyrometers, which may communicate with controller 24 to transmit signals relating to the monitored temperatures.
- Alternative temperature sensors may include ultrasonic transducers for measuring the part temperatures using acoustic thermometry.
- controller 24 may adjust one or more parameters of system 10 to maintain 3D part 22 /support structure 22 s at a desired temperature (e.g., at its desired average part temperature). For example, controller 24 may adjust operations of one or more of the heating components of system 10 (e.g., heaters, rollers, platforms) and/or one or more of the active cooling mechanisms of system 10 (e.g., cooling air jets). In some aspects, controller 24 may adjust the temperatures and contact durations during the transfusion steps to compensate for changes in the temperatures of layers and/or fluctuations in the monitored applied pressures.
- a desired temperature e.g., at its desired average part temperature
- controller 24 may adjust operations of one or more of the heating components of system 10 (e.g., heaters, rollers, platforms) and/or one or more of the active cooling mechanisms of system 10 (e.g., cooling air jets).
- controller 24 may adjust the temperatures and contact durations during the transfusion steps to compensate for changes in the temperatures of layers and/or fluctuations in the monitored applied pressures.
- the heating components of system 10 may be maintained at set point temperatures, and controller 24 may adjust operations of one or more of the active cooling mechanisms of system 10 (e.g., cooling air knives and air jets).
- the cooling air flow may be adjusted using commercial flow control valves based on feedback from the temperature sensors 784 t to substantially maintain 3D part 22 at the intended average part temperature.
- the layers of 3D part 22 may be laterally encased by the layers of support structure 22 s .
- temperature sensors 784 t may be configured to monitor the temperatures of 3D part 22 and support structure 22 s independently of each other (e.g., with different temperature sensors 784 t ) or together.
- the thermoplastic-based powder for support structure 22 s may have a higher glass transition temperature and/or a higher creep relaxation temperature compared to that of the thermoplastic-based powder of 3D part 22 .
- the layers of 3D part 22 may conform to the dimensions of support structure 22 s during the printing operation.
- Height sensors 784 hp and 784 hs are respectively configured to monitor the heights of 3D part 22 and support structure 22 s during the printing operation.
- suitable height sensors for height sensors 784 hp and 784 hs include non-contact sensors (e.g., laser height sensors), which may communicate with controller 24 to transmit signals relating to the independently monitored heights.
- controller 24 may adjust the pressure applied by press plate 20 or build platforms 118 , 218 , 318 , 418 , 518 , and 618 in response to changes in a monitored nip pressure.
- the cross-sectional locations of 3D part 22 and support structure 22 s may vary in location in the x-y build plane. This can present issues for height sensors 784 hp and 784 hs that have fixed measurement locations. For instance, in a first printing operation support structure 22 s may be positioned below height sensor 784 hs . in a subsequent printing operation 3D part 22 may be positioned below height sensor 784 hs , and in another printing operation neither 3D part 22 nor support structure 22 s may be positioned below height sensor 784 hs.
- system 10 may print layers of part column 22 pc and support column 22 sc along with the layers of 3D part 22 and support structure 22 s , where part column 22 pc may be positioned below height sensor 784 hp , and support column 22 sc may be positioned below height sensor 784 hs .
- This allows height sensors 784 hp and 784 hs to independently measure the heights of 3D part 22 and support structure 22 s , and allow controller 24 to direct height compensation protocols based on the feedback from height sensors 784 hp and 784 hs.
- Height compensation for each of 3D part 22 and support structure 24 can be accomplished, for example, by adjusting bias voltage at the imager (e.g., EP engine 12 ), and by adjusting light-emitting diode (LED) discharge on any organic photo conductor in the part or support material to affect its mass density.
- the imager e.g., EP engine 12
- LED light-emitting diode
- a single height sensor 784 may be configured to map the entire surface of 3D part 22 and support structure 22 s in a two-dimensional image, allowing controller 24 to direct height compensation protocols regardless of the geometries of 3D part 22 and support structure 22 s .
- suitable height sensors for this embodiment include scanning laser line sensors.
- this two-dimensional image data allows controller 24 to account for height changes in the lateral directions along the y-axis well as in the process directions along the x-axis by adjusting the intensity of the LED pixel or grayscale across the light bar in EP engine 12 (for the lateral directions) or in time (for the process directions).
- the height sensor 784 may be configured to also measure layer thickness of each layer 28 on belt 14 prior to the transfusion step.
- system 10 may also include a chamber 785 , which can extend around layer transfusion assembly 33 , and may define an enclosable environment for printing 3D part 22 . While illustrated in use with layer transfusion assembly 33 , chamber 785 is equally suitable for use with layer transfusion assemblies 133 , 233 , 333 , 433 , 533 , and 633 . Chamber 785 is a temperature-controllable chamber, which provides greater control over the active cooling step. For example, chamber 785 may be maintained at the average part temperature of 3D part 22 (e.g., about 100° C. for an ABS copolymer).
- chamber 785 may partially enclose z-axis gantry 34 and belt 14 , allowing z-axis gantry 34 and belt 14 to extend through the walls of chamber 785 .
- deformable baffles may be incorporated to maintain a thermal barrier.
- heater 32 may be located outside and upstream of chamber 784 .
- chamber 785 may be located below press plate 20 , allowing build platform 18 to be lowered down into chamber 785 .
- layer transfusion assembly 33 , 133 , 233 , 333 , 433 , 533 , or 633 may also include pressure sensors (e.g., pressure sensor 786 ) and/or capacitive or resistive sensors (e.g., capacitive sensor 788 ), each of which is configured to communicate with controller 24 over one or more communication lines (not shown).
- pressure sensors e.g., pressure sensor 786
- capacitive or resistive sensors e.g., capacitive sensor 788
- Pressure sensor 786 is one or more sensor assemblies configured to measure the transfusion pressure applied between build platform 18 and press plate 20 (or between build platforms 118 / 218 / 318 / 418 and rollers 120 / 220 / 320 / 420 ), allowing controller 24 to monitor the applied transfusion pressure and adjust the height of build platform 18 and/or press plate 20 using one or more process control loops.
- suitable sensor assemblies for pressure sensor 786 include one or more strain gauges retained on build platform 18 and/or press plate 20 .
- Capacitive or resistive sensor 788 is one or more capacitive/resistive sensor assemblies configured to measure the electrical resistance between build platform 18 and press plate 20 (or between build platforms 118 / 218 / 318 / 418 / 518 / 618 and rollers 120 / 220 / 320 / 420 / 520 / 620 ).
- capacitive sensor 788 may induce an electrical current from platen 18 to press plate 20 (or vice versa), and measure the intensity of the resulting electrical current through the printed layers 28 of 3D part 22 and belt 14 . Since the thickness of belt 14 is constant, the resulting electrical current will reduce as the 3D part 22 grows through the printing of successive layers 28 .
- capacitive sensor 788 is also suitable for monitoring the height of 3D part 22 and the number of layers 28 transferred to build platform 18 . This allows controller 24 to accurately predict the applied pressure during a subsequent pressing step rather than merely relying on the calculated height of a single layer increment. This accurate prediction allows build platform 18 to be quickly raised to an intended height, rather than relying solely on feedback signals from pressure sensor 786 .
- Build platforms 18 , 118 , 218 , 318 , 418 , 518 , and 618 , press plate 20 , and rollers 120 , 220 , 320 , 420 , 520 , and 620 may each also include one or more temperature sensors (not shown) configured to respectively measure the temperatures of the build platforms and press plate/rollers, allowing controller 24 to hold them at the above-discussed temperatures.
- controller 24 and/or host computer 26 may receive operational mode selections for operating system 10 in different modes. For example, a user may select operational modes such as high quality printing, draft quality printing, and gray scale, as discussed above.
- system 10 may receive the operational mode selections as default or system generated modes (e.g., a default of a high quality printing). These received operational mode selections may alternatively (or additionally) be set based on the geometry of the 3D part, such as if the 3D part has a small cross-sectional area and/or fine-feature details, as discussed above.
- controller 24 and/or host computer 26 may set transfusion parameters for performing the transfusion steps, based on the received operational mode selections. For example, the transfusion pressure, temperature(s), and or duration for each transfusion step may be set or adjusted based on the received operational mode select. This provides greater control over the transfusion steps when operating system 10 to improve printing accuracies and/or printing rates.
- System 10 may then image a powder layer of the 3D part from a thermoplastic-based powder (e.g., develop a powder layer with EP engine 12 ), transfer the imaged powder layer to a transfer medium, heat the imaged powder layer while the imaged layer is retained on the transfer medium, and transfuse the heated layer to a surface of the three-dimensional part based on the set transfusion parameters.
- a thermoplastic-based powder e.g., develop a powder layer with EP engine 12
- transfer the imaged powder layer to a transfer medium heat the imaged powder layer while the imaged layer is retained on the transfer medium, and transfuse the heated layer to a surface of the three-dimensional part based on the set transfusion parameters.
- the set transfusion parameters allow the transfusion pressure, temperature(s), and or duration for each transfusion steps to vary between different transfusion steps. For example, if a first portion of a 3D part contains a simple block geometry and a second portion of the 3D part contains a fine-feature geometry, controller 24 and/or host computer 26 may set the transfusion parameters such that the layers used to form the simple block geometry are transfused differently (e.g., higher transfusion pressure) from those used to form the fine-feature geometry (e.g., lower transfusion pressure).
- FIGS. 13 and 14 A- 14 C illustrate a suitable embodiment for belt 14 (shown in FIGS. 2A , 3 A, and 4 A- 4 D), and is equally suitable for belt 114 (shown in FIGS. 5A-5E ), belt 214 (shown in FIGS. 6A-6F ), belt 314 (shown in FIG. 7 ), belt 414 (shown in FIG. 8 ), belt 514 (shown in FIG. 9 ), and belt 614 (shown in FIG. 10 ).
- belt 14 is a multiple-layer belt that includes layer or film 790 (defining front surface 14 a ) and base portion 792 (defining rear surface 14 b ).
- Film 790 and base portion 792 are desirably derived from materials that are suitable for transferring the layers 28 of part (or support) materials from EP engine 12 to build platform 18 , that are thermally stable at the fusion temperatures T (f) of the part and support materials, and that are robust for continued operation at high rotational speeds while being repeatedly heated and cooled during the heating and active cooling steps. Furthermore, for use as belts 514 and 614 , film 790 and/or base portion 792 also desirably have high thermal conductivities and heat capacities for selectively heating the 3D parts.
- Film 790 has a film thickness 790 t , and is derived from one or more low-surface energy materials, thereby allowing the received layers 28 to effectively release from front surface 14 a to build platform 18 .
- suitable materials for film 790 include one or more fluorinated polymers, such as polytetrafluoroethylenes (PTFE), fluorinated ethylene propylenes, and perfluoroalkoxy polymers.
- PTFE polytetrafluoroethylenes
- fluorinated ethylene propylenes fluorinated ethylene propylenes
- perfluoroalkoxy polymers examples of suitable commercially available fluorinated polymers include PTFE available under the trade designation āTEFLONā from E.I. du Pont de Nemours and Company, Wilmington, Del.
- Base portion 792 has a thickness 792 t , and is derived from one or more materials that promote good electrostatic attraction for the thermoplastic-based powders to front surface 14 a via electrostatic charges.
- suitable materials for base portion 792 include one or more polyimide materials, such as those commercially available under the trade designation āKAPTONā from E.I. du Pont de Nemours and Company, Wilmington, Del., which may be doped with one or more conductive materials to promote the electrostatic charges.
- belt 14 may also include one or more additional layers between film 790 and base portion 792 , such as one or more tie layers.
- base portion 792 For use as belts 514 and 614 , examples of suitable materials for base portion 792 include those discussed above for belts 514 and 614 .
- base portion 792 may constitute the bulk of belt 14 , where thickness 792 t is substantially greater than film thickness 790 t . This allows film 790 to be derived from a low-surface energy material that may have a lower thermal conductivity and/or heat capacity, while still retaining an overall high thermal conductivity and high heat capacity.
- FIGS. 13A-13C illustrate alternative embodiments for belt 14 for engaging with various drive rollers of system 10 .
- front surface 14 a of belt 14 may include receiving region 794 and edge regions 796 on opposing lateral sides of receiving region 794 .
- Receiving region 794 is the region of front surface 14 a on which layers 28 are retained for transfer between EP engine 12 and build platform 18 .
- Edges regions 796 are the regions at which one or more drive mechanisms may engage drive belt 14 .
- one or more rollers may engage front surface 14 a and/or rear surface 14 b at edge regions 796 to ensure the rollers to not interfere with the imaged layers 28 .
- pairs of opposing rollers may simultaneously engage front surface 14 a and rear surface 14 b at edge regions 796 to nip and drive belt 14 in the direction of arrow 30 .
- Encoder markings 798 may be pre-marked on front surface 14 a and/or rear surface 14 b at preset increments along the x-axis, or may be printed with the imaged layers 28 to identify relative locations of the imaged layers 28 along the x-axis.
- System 10 may also include one or more optical readers (e.g., optical reader 800 ) to locate encoder markings 798 as belt 14 rotates in the direction of arrow 30 .
- belt 14 may include an array of holes 802 or other openings that extend through film 790 and base portion 792 adjacent to the lateral edges of belt 14 .
- Holes 802 are configured to engage with gear teeth (not shown) of one or more rollers (e.g., rollers 16 , nip roller 120 , fusion roller 220 , release roller 268 , nip roller 320 , fusion roller 420 , release roller 468 , nip roller 520 , release roller 568 , nip roller 620 , release roller 668 , and/or any service-loop roller) to drive belt 14 in a tractor-feed manner.
- rollers e.g., rollers 16 , nip roller 120 , fusion roller 220 , release roller 268 , nip roller 320 , fusion roller 420 , release roller 468 , nip roller 520 , release roller 568 , nip roller 620 , release roller 668 , and
- System 10 may also include one or more optical readers (e.g., optical reader 799 ) to locate encoder markings 798 and/or holes 802 as belt 14 rotates in the direction of arrow 30 .
- optical readers e.g., optical reader 799
- FIG. 14C shows yet another alternative embodiment in which belt 14 includes rear ribs 804 that extend laterally along rear surface 14 b .
- Ribs 804 are configured to engage with reciprocating gear teeth (not shown) of one or more rollers (e.g., rollers 16 , nip roller 120 , fusion roller 220 , release roller 268 , nip roller 320 , fusion roller 420 , release roller 468 , nip roller 520 , release roller 568 , nip roller 620 , release roller 668 , and/or any service-loop roller) to drive belt 14 in a timing-belt manner.
- rollers e.g., rollers 16 , nip roller 120 , fusion roller 220 , release roller 268 , nip roller 320 , fusion roller 420 , release roller 468 , nip roller 520 , release roller 568 , nip roller 620 , release roller 668 , and
- System 10 may also include one or more optical readers (e.g., optical reader 800 ) to locate the encoder markings and/or holes ribs as belt 14 rotates in the direction of arrow 30 .
- optical readers e.g., optical reader 800
- FIGS. 14A-14C illustrate example engagement mechanisms for belt 14 , allowing belt 14 to engage with one or more drive mechanisms of system 10 .
- belt 14 may alternatively include different engagement mechanisms as particular designs may require.
- FIG. 15 is a flow diagram of method 810 , which is an example method for the layer transfer technique of the present disclosure, and may be performed with system 10 having layer transfusion assemblies 33 , 133 , 233 , 333 , 433 , 533 , and 633 .
- method 810 includes step 812 - 826 , where steps 818 , 820 a , 820 b , 824 , and 826 are optional steps depending on the particular embodied layer transfusion assembly utilized (e.g., layer transfusion assemblies 33 , 133 , 233 , 333 , 433 , 533 , and 633 ).
- Method 810 initially involves developing or otherwise imaging a powder layer (step 812 ), such as with EP engine 12 .
- the imaged powder layer may then be transferred on a transfer medium from a first location at EP engine 12 to a second location at the layer transfusion assembly (e.g., layer transfusion assemblies 33 , 133 , 233 , 333 , 433 , 533 , and 633 ) (step 814 ).
- the powder layer Prior to reaching the second location at the layer transfusion assembly, the powder layer is heated to a transfer temperature, such as the fusion temperature of the thermoplastic-based powder (e.g., at heaters 32 , 132 , 232 , 332 , 432 , 532 , and 632 ) (step 816 ).
- the top surface or layer(s) of the 3D part may also be pre-heated prior to the transfusion/transfixing steps (step 818 ).
- heaters 270 and 272 may heat the top surface or layer(s) of 3D part 222 to the fusion temperature of the thermoplastic-based powder, or other suitable transfer temperature. Because layer 228 and the heated top surface/layer of 3D part 222 can each be heated to the fusion temperature of the thermoplastic-based powder, the pressed heated layer 228 transfuses to the heated top surface/layer of 3D part 222 with a high level of interlayer adhesion (during transfusion step 520 ).
- the heated layer may then be directly transfused and transfixed with the layer transfusion assembly, as illustrated by arrow 828 .
- the heated layer may then be transfused and transfixed (step 820 ).
- the transfusion and transfixing may be performed in a single step.
- press plate 20 may engage build platform 18 to transfuse the heated layer 28 to the top surface of 3D part 22 .
- press plate 20 may be heated to a temperature that is lower than the fusion temperature, the contact between press plate 20 and rear surface 14 b of belt 14 cools down the interface between belt 14 and the transfused layer 28 , increasing the adhesive force of the interdiffused polymers in the transfused layer 28 and 3D part 22 relative to the adhesive force of the transfused layer 28 to surface 14 a of belt 14 , thereby maintaining the transfused layer adhered to the 3D part in a fixed spatial position.
- the transfused and transfixed layer may then be released from the transfer medium (step 822 ), such as by retracting press plate 20 and/or build platform 18 , or by the separation of belts 114 / 333 from build platforms 118 / 318 by belts 114 / 318 winding around nip rollers 120 / 320 .
- the transfixing step discussed above allows the transfused layer to cleanly release from the transfer medium and remain adhered to the 3D part.
- method 510 may include a transfusion step 820 a and transfixing step 820 b , which are separate.
- layer transfusion assembly 233 includes a heated fusion roller 220 (for transfusion step 820 a ) and release roller 268 (for release step 822 ), which are separated by air jets 274 (for a cooling or transfixing step 820 b ).
- belts 514 and 614 which have high thermal conductivities and heat capacities, may be utilized instead of (or in addition to) air jets 274 for the cooling or transfixing step 820 b.
- This allows the layers to be heated to an optimal transfusion interface temperature at the heating steps 816 and/or 818 , and during the transfusion step 820 a , and then to be cooled to a temperature that fixes the layers (at transfixing step 820 b ) before release at release step 822 .
- This substantially increases the extent to which the polymer molecules of the transfused layers interdiffuse to promote interfacial entanglement, while also maintaining dimensional accuracy of the 3D part.
- release roller 268 may assist in releasing transfused layer 228 from belt 214 by increasing the angle of separation between belt 214 and build platform 218 , which increases the ease at which transfused layer 228 delaminates from belt 214 .
- the 3D part may then optionally (depending on the particular embodiment) undergo one or more post-fuse or heat-setting steps (step 824 ), such as discussed above for layer transfusion assembly 333 (shown in FIG. 7 ) and layer transfusion assembly 433 (shown in FIG. 8 ).
- the 3D part may be heated to at least the fusion temperature of the thermoplastic-based powder, such as with post-fuse heaters 382 and 482 . This sufficiently melts the material of the transfused layer to a fusable state such that polymer molecules of the transfused layer further interdiffuse to promote interfacial entanglement with 3D part.
- the 3D part may then be actively cooled (e.g., with air knives 42 and air jets 142 , 242 , 342 , 442 , or other convective and/or conductive cooling units, such as cooling unit 642 ) (step 826 ).
- the imaging system e.g., system 10
- the imaging system is capable of printing the layers at speeds that are much faster than the rate at which heat diffuses through the variable thermal resistance of the 3D parts
- heat can accumulate in the 3D parts, which, if not accounted for, can exceed a deformation temperature of the 3D part, causing the bulk of the 3D part to soften enough reduces its structural integrity.
- Such a soft part may deform under a subsequently-applied transfusion pressure during a subsequent transfusion step.
- the 3D part may be actively cooled between each transfusion step 818 to maintain the 3D part at an average part temperature that is lower than the deformation temperature of the 3D part.
- the active cooling step 826 may also be an optional step of method 810 .
- system 10 may instead operate at a lower printing speed to allow heat to diffuse from the 3D part.
- the active cooling step 826 is desirable for maintaining the structural integrity of the 3D part while printing at high speeds.
- Steps 812 - 826 may then be repeated for each layer of the 3D part until the printing operation is completed (as indicated by arrow 830 ).
- By heating each layer to at least the fusion temperature of the thermoplastic-based powder, followed by transfusing, transfixing, and optional active cooling allows system 10 to print 3D parts with good part quality and strengths (e.g., z-strengths).
- 3D parts were printed with an additive manufacturing system corresponding to the system shown in FIGS. 1 , 2 , and 4 A- 4 D, having a moveable press plate and a vertically-actuatable build platform, each of which were heated.
- the 3D parts were printed from an ABS part material, where each layer was developed with an electrophotography engine and transferred to a rotatable transfer belt looped around a service loop design.
- the developed layer was carried by the transfer belt to an infrared heater to heat the layer to a fusion temperature of ABS part material.
- the heated layer was then transferred to and aligned over the build platform.
- the press plate was actuated downward to transfuse the heated layer against a previously-transfused layer of the 3D part (or to the build platform for the initial layer).
- the press plate was then retracted, which cleanly delaminated the layer from the transfer belt, allowing the layer to remain transfused to the 3D part.
- Cooling air from an air knife was also directed to the top layers of the 3D part. This removed the additional heat from the transfused layer to provide an average part temperature of that maintained the structural integrity of the 3D part, where the 3D part did not slump or melt due to heat accumulation. This process was repeated for each layer of the 3D part.
- the air knife and the press plate successfully maintained the average part temperature below the deformation temperature of the 3D part during the entire printing operation.
- the resulting 3D parts exhibited good part resolution, dense fill, and good dimensional integrity.
- Example 2 3D parts were printed with an additive manufacturing system corresponding to system 10 having a layer transfusion assembly 333 as shown in FIG. 7 (without pre-heaters 370 or 372 ), and as further depicted in FIG. 16 (using the same reference numbers as for system 10 and layer transfusion assembly 333 ).
- the system 10 included two EP engines 12 , a belt 314 , two belt drive mechanisms 16 a , three belt drag mechanisms 16 b , three loop limit sensors 16 c , idler rollers 16 d , belt cleaner 16 e , and layer transfusion assembly 333 .
- Belt drive mechanisms 16 a , belt drag mechanisms 16 b , loop limit sensors 16 c , idler rollers 16 d , and belt cleaner 16 e maintained tension on belt 314 while belt 314 rotated in the rotational direction of arrows 330 .
- belt drive mechanisms 16 a engaged and drove belt, and belt drag mechanisms 16 b functioned as brakes to provide a service loop design for protecting belt 314 against tension stress, based on monitored readings via loop limit sensors 16 c.
- the 3D parts were printed from an ABS part material, where each layer was developed with an EP engine 12 and transferred to belt 314 looped in the service loop design.
- the developed layer was carried by belt 314 to an infrared heater 332 to heat the layer and belt 314 to a fusion temperature of the ABS part material.
- the heated layer was then transferred to and aligned over the build platform 318 (not shown in FIG. 16 ).
- the build platform 315 was actuated upward by gantry 934 to transfuse the heated layer against a previously-transfused layer of the 3D part (or to the build platform 318 for the initial layer).
- actuating the build platform 318 upward pressed the heated layer and transfer belt between the build platform 318 (or against a previously-transfused layer of the 3D part) and the nip roller 320 .
- the build platform 318 was then moved at a synchronized rate with belt 314 , and then released at a downstream location. This cleanly delaminated the layer from the transfer belt, allowing the layer to remain transfused to the 3D part.
- the 3D part was then re-heated with post-fuse infrared heater 382 to further increase adhesion of the transfused layers. Cooling air from air jets 342 was also directed to the top layers of the 3D part. This removed the additional heat from the transfused layers to provide an average part temperature of that maintained the structural integrity of the 3D part, where the 3D part did not slump or melt due to heat accumulation.
- the build platform 318 was then moved back to its starting position via gantry 934 , and the process was repeated for each layer of the 3D part.
- the air jets 342 successfully maintained the average part temperature below the deformation temperature of the 3D part during the entire printing operation.
- the resulting 3D parts also exhibited good part resolution, dense fill, and good dimensional integrity.
- Comparative Examples A and B 3D parts were printed with the same additive manufacturing systems respectively used for Examples 1 and 2. However, for Comparative Examples A and B, the air knife or jet cooling was omitted. Otherwise, the processes were performed in the same manner as discussed above for Examples 1 and 2.
- the layer transfer technique of the present disclosure including the active cooling is beneficial for printing 3D parts at high rates using electrophotography.
- the active cooling was successfully implemented to remove the added heat from each fused layer prior to the transfusion of the next layer. This allowed the 3D parts printed with the systems in Examples 1 and 2 to be maintained at average part temperatures below their deformation temperatures, but high enough to promote good interlayer adhesion and reduced curl.
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Abstract
Description
- The present application is a continuation-in-part of U.S. patent application Ser. No. 13/624,495, entitled āLAYER TRANSFUSION FOR ADDITIVE MANUFACTURINGā; of U.S. patent application Ser. No. 13/624,507, entitled āLAYER TRANSFUSION WITH TRANSFIXING FOR ADDITIVE MANUFACTURINGā; of U.S. patent application Ser. No. 13/624,513, entitled āLAYER TRANSFUSION WITH PART HEATING FOR ADDITIVE MANUFACTURINGā; of U.S. patent application Ser. No. 13/624,519, entitled āLAYER TRANSFUSION WITH ROTATABLE BELT FOR ADDITIVE MANUFACTURINGā; each of which was filed on Sep. 21, 2012; and each of which claims priority to U.S. Provisional Application No. 61/538,491, entitled āLAYER TRANSFUSION FOR ELECTROPHOTOGRAPHY-BASED ADDITIVE MANUFACTURINGā, filed on Sep. 23, 2011.
- Reference is also made to co-filed U.S. patent application Ser. No. ______, entitled āLAYER TRANSFUSION FOR ADDITIVE MANUFACTURINGā (attorney docket no. S697.12-0241).
- The present disclosure relates to additive manufacturing systems for building three-dimensional (3D) parts and support structures. In particular, the present disclosure relates to additive manufacturing systems and processes for building 3D parts and support structures using an imaging process, such as electrophotography.
- Additive manufacturing systems are used to build 3D parts from digital representations of the 3D parts (e.g., STL format files) using one or more additive manufacturing techniques. Examples of commercially available additive manufacturing techniques include extrusion-based techniques, ink jetting, selective laser sintering, powder/binder jetting, electron-beam melting, and stereolithographic processes. For each of these techniques, the digital representation of the 3D part is initially sliced into multiple horizontal layers. For each sliced layer, a tool path is then generated, which provides instructions for the particular additive manufacturing system to form the given layer.
- For example, in an extrusion-based additive manufacturing system, a 3D part or model may be printed from a digital representation of the 3D part in a layer-by-layer manner by extruding a flowable part material. The part material is extruded through an extrusion tip carried by a print head of the system, and is deposited as a sequence of roads on a substrate in an x-y plane. The extruded part material fuses to previously deposited part material, and solidifies upon a drop in temperature. The position of the print head relative to the substrate is then incremented along a z-axis (perpendicular to the x-y plane), and the process is then repeated to form a 3D part resembling the digital representation.
- In fabricating 3D parts by depositing layers of a part material, supporting layers or structures are typically built underneath overhanging portions or in cavities of objects under construction, which are not supported by the part material itself. A support structure may be built utilizing the same deposition techniques by which the part material is deposited. The host computer generates additional geometry acting as a support structure for the overhanging or free-space segments of the 3D part being formed. Support material is then deposited from a second nozzle pursuant to the generated geometry during the printing process. The support material adheres to the modeling material during fabrication, and is removable from the completed 3D part when the printing process is complete.
- In two-dimensional (2D) printing, electrophotography (i.e., xerography) is a popular technology for creating 2D images on planar substrates, such as printing paper. Electrophotography systems include a conductive support drum coated with a photoconductive material layer, where latent electrostatic images are formed by charging and then image-wise exposing the photoconductive layer by an optical source. The latent electrostatic images are then moved to a developing station where toner is applied to charged areas of the photoconductive insulator to form visible images. The formed toner images are then transferred to substrates (e.g., printing paper) and affixed to the substrates with heat or pressure.
- An aspect of the present disclosure is directed to an additive manufacturing system for printing a 3D part. The additive manufacturing system includes an imaging engine configured to develop an imaged layer, a movable build platform, and a rotatable belt configured to receive the imaged layer from the imaging engine, wherein the rotatable belt has a high average thermal inertia (e.g., of at least about 400 joules/(meter2-Kelvin-second0.5)). The system also includes a first heater configured to heat the rotatable belt and the imaged layer on the rotatable belt, and a nip roller configured to press the heated imaged layer conveyed by the rotatable belt onto a top layer of the 3D part retained by the movable build platform. The system further includes a release roller configured to separate the pressed imaged layer from the heated rotatable belt such that the pressed imaged layer remains adhered as a new top layer of the 3D part, wherein the rotatable belt is configured to thermally conduct heat into the three-dimensional part while the pressed imaged layer moves between the nip roller and the release roller.
- Another aspect of the present disclosure is directed to a method for printing a 3D part with an additive manufacturing system. The method includes imaging a layer of the 3D part, transferring the imaged layer to a rotatable belt having a high average thermal inertia (e.g., of at least about 400 joules/(meter2-Kelvin-second0.5)), and heating the rotatable belt and the imaged layer while the imaged layer is retained on the rotating belt. The method also includes pressing the heated imaged layer between the heated rotatable belt and a top surface of the three-dimensional part so that the heated imaged layer fuses to the top surface of the 3D part, and maintaining contact between the rotatable belt and the fused imaged layer so as to conduct thermal energy from the heated rotatable belt to the 3D part. The method further includes releasing the pressed layer from the rotatable belt such that the pressed layer defines a new top surface of the three-dimensional part.
- Another aspect of the present disclosure is directed to a method for printing a 3D part with an additive manufacturing system, which includes imaging a layer of the 3D part, rotating a belt having a high average thermal inertia (e.g., of at least about 400 joules/(meter2-Kelvin-second0.5)), and transferring the imaged layer to the rotating belt. The method also includes heating the rotating belt and the imaged layer while the imaged layer is retained on the rotating belt, and engaging the heated rotatable belt with a nip roller, which presses the heated layer to a top surface of the 3D part. The method further includes moving the 3D part in a direction and at a rate that is synchronized with a rotation of the belt, conducting thermal energy from the rotating belt to the 3D part while moving the 3D part in the synchronized direction and rate, and releasing the pressed layer from the rotatable belt such that the pressed layer defines a new top surface of the 3D part.
- In some embodiments, the additive manufacturing system is configured to print or otherwise produce the layers at a rate that is faster than a passive thermal diffusion rate of the 3D part.
- Unless otherwise specified, the following terms as used herein have the meanings provided below:
- The terms ātransfusionā, ātransfuseā, ātransfusingā, and the like refer to the adhesion of layers with the use of heat and pressure, where polymer molecules of the layers at least partially interdiffuse.
- The term ātransfusion pressureā refers to a pressure applied during a transfusion step, such as when transfusing layers of a 3D part together.
- The term ādeformation temperatureā of a 3D part refers to a temperature at which the 3D part softens enough such that a subsequently-applied transfusion pressure, such as during a subsequent transfusion step, overcomes the structural integrity of the 3D part, thereby deforming the 3D part.
- Unless otherwise specified, temperatures referred to herein are based on atmospheric pressure (i.e. one atmosphere).
- Directional orientations such as āaboveā, ābelowā, ātopā, ābottomā, and the like are made with reference to a direction along a printing axis of a 3D part. In the embodiments in which the printing axis is a vertical z-axis, the layer-printing direction is the upward direction along the vertical z-axis. In these embodiments, the terms āaboveā, ābelowā, ātopā, ābottomā, and the like are based on the vertical z-axis. However, in embodiments in which the layers of 3D parts are printed along a different axis, the terms āaboveā, ābelowā, ātopā, ābottomā, and the like are relative to the given axis.
- The term āprovidingā, such as for āproviding a materialā and the like, when recited in the claims, is not intended to require any particular delivery or receipt of the provided item. Rather, the term āprovidingā is merely used to recite items that will be referred to in subsequent elements of the claim(s), for purposes of clarity and ease of readability.
- The terms āaboutā and āsubstantiallyā are used herein with respect to measurable values and ranges due to expected variations known to those skilled in the art (e.g., limitations and variabilities in measurements).
-
FIG. 1 is a graphical illustration of transfer temperature versus a minimum transfusion duration for a layer transfusion assembly of an additive manufacturing system of the present disclosure. -
FIG. 2A is a schematic illustration of an electrophotography-based additive manufacturing system of the present disclosure having a layer transfusion assembly with a press plate. -
FIG. 2B is a logarithmic graphical illustration of Young's modulus versus temperature at atmospheric pressure for an acrylonitrile-butadiene-styrene (ABS) copolymer. -
FIG. 3A is a top view of a build platform receiving a heated layer, illustrating an air knife arrangement. -
FIG. 3B is a graphical illustration of number of printed layers for a 3D part versus an average part temperature, showing plot lines for a 3D part printed without active cooling and for a 3D part printed with active cooling. -
FIGS. 4A-4D are expanded views of the layer transfusion assembly, illustrating a layer transfer technique of the present disclosure. -
FIGS. 5A-5E are expanded views of a first alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a nip roller, and which illustrate a layer transfer technique. -
FIGS. 6A-6F are expanded views of a second alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and which illustrate a layer transfer technique. -
FIG. 7 is an expanded view of a third alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a nip roller and a post heater, and which illustrates a layer transfer technique. -
FIG. 8 is an expanded view of a fourth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and a post heater, and which illustrates a layer transfer technique. -
FIG. 9 is an expanded view of a fifth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, and a belt with a high thermal conductivity and heat capacity, and which illustrates a layer transfer technique. -
FIG. 10 is an expanded view of a sixth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having separate transfusion and release rollers, a belt with a high thermal conductivity and heat capacity, and a contact cooling unit, and which illustrates a layer transfer technique. -
FIGS. 11A , 11B, and 11C are expanded views of a seventh alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having a closed-loop feedback control. -
FIG. 12 is an expanded view of an eighth alternative layer transfusion assembly of the electrophotography-based additive manufacturing system, having an enclosable chamber. -
FIG. 13 is a sectional side of a rotatable transfer belt. -
FIG. 14A is a top view of a first embodiment of the rotatable transfer belt, having receiving regions and encoder markings. -
FIG. 14B is a top view of a second embodiment of the rotatable transfer belt, having holes for engagement in a tractor-feed manner. -
FIG. 14C is a bottom view of a third embodiment of the rotatable transfer belt, having rear ribs for engagement in a timing-belt manner. -
FIG. 15 is a flow diagram of an example method for the layer transfer technique of the present disclosure. -
FIG. 16 is a front view of an example electrophotography-based additive manufacturing system of the present disclosure. - The present disclosure is directed to a layer transfer technique for printing 3D parts and support structures in a layer-by-layer manner, where each layer is printed from a part or support material in a thermally-controlled manner. The layer transfer technique is performed with an imaging system, such as an electrophotography-based additive manufacturing system. For example, each layer may be developed or otherwise imaged using electrophotography and carried from an electrophotography (EP) engine by a transfer medium (e.g., a rotatable belt or drum). The layer is then transferred to a build platform to print the 3D part (or support structure) in a layer-by-layer manner, where the successive layers are transfused together to produce the 3D part (or support structure).
- In comparison to 2D printing, in which developed toner particles can be electrostatically transferred to printing paper by placing an electrical potential through the printing paper, the multiple printed layers in a 3D environment effectively prevents the electrostatic transfer of part and support materials after a given number of layers are printed (e.g., about 15 layers). Instead, in the present disclosure, a layer retained by the transfer medium is heated to an elevated transfer temperature. The heated layer is then pressed against a previously-printed layer (or to a build platform) to transfuse the layers together (i.e., a transfusion step). This allows numerous layers of 3D parts and support structures to be built vertically, beyond what is otherwise achievable via electrostatic transfers.
- For transfusion to occur, the interfaces between the heated layers need to be pressed for at least a minimum duration to allow molecular interdiffusion to occur between the layers. This minimum transfusion duration (ttransformation) is believed to be a function of the average time for the polymer molecules to diffuse one molecular radius of gyration (Ļr), which itself is proportional to the material viscosity (μmaterial), and is inversely proportional in an exponential manner to the transfer temperature (Ttransfer), as shown in Equations 1-3:
-
- In other words, as illustrated in
FIG. 1 , if the transfer temperature is increased, the minimum duration required for the polymer molecules to diffuse one molecular radius of gyration decreases exponentially, and vice versa. - The particular inverse exponential relationship between the transfer temperature and the minimum transfusion duration varies depending on the particular compositions of the layer materials. However, to obtain good part strengths, the minimum transfusion duration for a given transfer temperature is desirably set to be at least the average time for the polymer molecules to diffuse one molecular radius of gyration (ā§Ļr), more desirably at least twice the average time for the polymer molecules to diffuse one molecular radius of gyration (ā§2Ļr), and even more desirably at least three times the average time for the polymer molecules to diffuse one molecular radius of gyration (ā§3Ļr).
- For example, as shown in
FIG. 1 , when transfusing layers heated to a transfer temperature TempA, the minimum transfusion duration is TimeA, based on the plot line function of f(Ļr), such as 3Ļr. Alternatively, if the transfer temperature is increased to TempB, the minimum transfusion duration is TimeB, which can be exponentially shorter than the minimum transfusion duration for the transfer temperature of TempA. Thus, 3D parts may be printed at faster speeds with good layer transfusions by increasing the transfer temperature, such as to at least a āfusion temperatureā of the layer material. - As discussed below, the fusion temperature is a temperature that sufficiently melts the layer material to a fusable state such that polymer molecules of the layer material readily interdiffuse during the subsequent transfusion steps to promote interlayer or interfacial entanglement. For example, for an acrylonitrile-butadiene-styrene (ABS) copolymer, the fusion temperature may range from about 180° C. to about 220° C. depending on the particular copolymer composition. At a transfer temperature of about 220° C. and a plot line function of f(Ļr)=3Ļr, the minimum transfusion duration for the ABS copolymer is about 0.03 seconds. In comparison, at a transfer temperature of about 160° C. and the same plot line function, the minimum transfusion duration for the ABS copolymer is about 6 seconds, which is substantially slower.
- Equations 1-3 shown above provide a starting point for selecting a transfer temperature. However, it has been found that several additional factors balance the correlation between the transfer temperature and the minimum transfusion duration, such as (i) thin layer reheating, (ii) layer adhesion to the transfer medium, and (iii) part heat accumulation. First, the layers being printed are thin. As such, the interfaces between one or more of the previously printed layers are reheated with each successive transfusion step, during which further interdiffusion can occur. As such, the minimum transfusion duration is not limited to a single transfusion step. Rather, the duration may be divided into multiple successive transfusion steps. For example, the 6 seconds required to transfuse the ABS copolymer at a transfer temperature of 160° C. may be divided into 12 successive cycles of about 0.5 second each.
- Additionally, while the fusion temperature is high enough to promote rapid layer transfusion, it can also be too hot for the transfused layer to cleanly release or otherwise delaminate from the transfer medium (e.g., a rotatable belt or drum). This can potentially result in portions of the transfused layer remaining adhered to the transfer medium, or smear upon release from the transfer medium, which negatively impacts feature detail, dimensional accuracy, and porosity of a printed 3D part.
- Accordingly, in some embodiments, the layer transfer technique may also include a ātransfixing stepā, in which the transfer medium and/or the transfused layer is cooled prior to releasing the transfused layer from the transfer medium. While not wishing to be bound by theory, it is believed that this transfixing step cools down the interface between the transfer medium and the transfused layer, thus increasing the adhesive force of the interdiffused polymers in adjacent layers relative to the adhesive force of the transfused layer to the surface of the transfer medium. This keeps the transfused layer adhered to the 3D part in a fixed spatial position, and allows the transfused layer to cleanly release from the transfer medium and remain adhered to the 3D part.
- Alternatively, the layer retained by the transfer medium (and optionally, the top surface of the 3D part) may be heated to a lower transfer temperature (e.g., TempA), such as a temperature between a glass transition temperature and the fusion temperature of the layer material. In this embodiment, the heated layer is then pressed against a previously-printed layer (or to a build platform) to transfuse the layers together (i.e., a transfusion step), and then released from the transfer medium.
- However, as discussed above, a lower transfer temperature increases the minimum transfusion duration, which can potentially slow down printing speeds. Nonetheless, depending on the particular additive manufacturing system, the transfusion step may not necessarily be the rate limiting step for printing speeds. As discussed below, each layer is imaged (e.g., developed) at an imaging engine, transferred from the imaging engine to a build platform, and thermally treated before and/or after the transfusion step, where any one of these steps may dictate the maximum printing speed attainable.
- For example, due to the layers being thin, the imaging of the layers at the imaging engine may be the slowest step in each layer cycle. In this situation, a longer transfusion duration at a lower transfer temperature may be used. The lower transfer temperature allows the heated layer to be hot enough for sufficient polymer interdiffusion over the longer transfusion duration, while also being cool enough to readily release from the transfer medium.
- The use of a lower transfer temperature is also particularly suitable for some embodiments of the present disclosure that incorporate post-fuse or heat-setting steps (e.g.,
333 and 433, shown below inlayer transfusion assemblies FIGS. 7 and 8 ). In these embodiments, after release, the transfused layer and the 3D part may then be further heated to at least the fusion temperature of the layer material in the post-fuse or heat-setting step. This sufficiently melts the transfused layer material to a fusable state such that polymer molecules of the transfused layer material at least partially interdiffuse to promote interfacial entanglement. - Another factor to consider when balancing the transfer temperature and the minimum transfusion duration involves the bulk temperature of the 3D part. Because the imaging system is capable of printing the layers at speeds that are much faster than the rate at which heat diffuses through the variable thermal resistance of the 3D parts, heat accumulation in the 3D parts has been observed. This heat accumulation is proportional to the transfer temperature and the size of the 3D part.
- As such, as the height of a given 3D part grows, heat dissipation from passive thermal diffusion can become insufficient to cool the heated layers. The faster the layer speed, the faster the heat accumulation in the bulk of the 3D part. As successive layers are continuously printed, this heat accumulation may exceed the ādeformation temperatureā of the 3D part, causing the bulk of the 3D part to soften enough to reduce its structural integrity. Such a soft part may deform under a subsequently-applied transfusion pressure during a subsequent transfusion step.
- In some embodiments, heat accumulation can be reduced by slowing down the printing process to allow the passive thermal diffusion to lower the part temperature. As mentioned above, the transfer temperature may also be lowered since the printing speed is already being slowed down. However, as can be appreciated, these techniques can substantially increase the time required to print 3D parts, particularly if the layer transfusion step is the rate limiting step in the process, thereby reducing throughput. Instead, to overcome this issue while maintaining fast printing rates, the layer transfer technique may include an āactive cooling stepā to prevent the 3D part from accumulating additional heat, thereby maintaining the 3D part at an āaverage part temperatureā (Tpart) that is lower than the deformation temperature (Tdeform) of the 3D part, as illustrated in Equation 4:
-
T part =f(T transfer+active cooling)<T deformāā(Equation 4) - In particular, after each layer of the 3D part is transfused, the heat added to the 3D part from the transfused layer may be substantially removed prior to the transfusion of the next layer. This holds the 3D part at an average part temperature that is desirably balanced to promote interlayer adhesion and reduce the effects of curling, while also being low enough to prevent the 3D part from softening too much (i.e., below its deformation temperature).
- The following embodiments illustrate example additive manufacturing systems of the present disclosure that are configured to balance the thermal effects described by one or more of Equations 1-4. For example as shown in
FIG. 2A ,system 10 is an example additive manufacturing system for printing 3D parts and support structures using electrophotography, which incorporates the layer transfer technique of the present disclosure. In the shown embodiment,system 10 includesEP engine 12,transfer belt 14,rollers 16,build platform 18, andpress plate 20 for printing 3D parts (e.g., 3D part 22) and any associated support structures (not shown). Examples of suitable components and functional operations forsystem 10 include those disclosed in U.S. patent application Ser. Nos. 13/242,669 and 13/242,841. - In alternative embodiments,
system 10 may include different imaging engines for imaging the layers. As discussed below, the layer transfer technique focuses on the transfer of layers from belt 14 (or other transfer medium) to build platform 18 (or to the3D part 22 being printed on build platform 18), and onbelt 14, rather than on the particular imaging engine. However, the layer transfer technique is particularly suitable for use with electrophotography-based additive manufacturing systems (e.g., system 10), where the multiple printed layers in a 3D environment effectively prevents electrostatic transfer of part and support materials after a given number of layers are printed, as discussed above. -
System 10 also includescontroller 24, which is one or more control circuits, microprocessor-based engine control systems, and/or digitally-controlled raster imaging processor systems, and which is configured to operate the components ofsystem 10 in a synchronized manner based on printing instructions received fromhost computer 26.Host computer 26 is one or more computer-based systems configured to communicate withcontroller 24 to provide the print instructions (and other operating information). For example,host computer 26 may transfer information tocontroller 24 that relates to the sliced layers of 3D part 22 (and any support structures), thereby allowingsystem 10 to print3D part 22 in a layer-by-layer manner. - As discussed in the U.S. patent application Ser. Nos. 13/242,669 and 13/242,841,
EP engine 12 is configured to develop or otherwise imagesuccessive layers 28 of a thermoplastic-based powder using electrophotography. As used herein, the term āelectrophotographyā includes ionography. The thermoplastic-based powder includes one or more thermoplastic materials (e.g., an acrylonitrile-butadiene-styrene (ABS) copolymer), and may also include one or more additional components for development withEP engine 12 and electrostatic attraction to belt 14. - The imaged layers 28 of the thermoplastic-based powder are then rotated to a first transfer region in which layers 28 are transferred from
EP engine 12 to belt 14.Belt 14 is an example transfer medium for transferring or otherwise conveying the imaged layers 28 fromEP engine 12 to buildplatform 18 with the assistance ofpress plate 20. In the shown embodiment,belt 14 includes front ortransfer surface 14 a and rear orcontact surface 14 b, wherefront surface 14 afaces EP engine 12. As discussed below, in some embodiments,belt 14 may be a multiple-layer belt with a low-surface-energy film that definesfront surface 14 a, and which is disposed over a base portion that definesrear surface 14 b. -
System 10 may also include biasingmechanism 29, which is configured to induce an electrical potential throughbelt 14 to electrostatically attractlayers 28 of the thermoplastic-based powder fromEP engine 12 to belt 14. Becauselayers 28 are each only a single layer increment in thickness at this point in the process, electrostatic attraction is suitable for transferringlayers 28 fromEP engine 12 to belt 14. However, as mentioned above, the multiple printedlayers 28 for3D part 22 effectively prevents electrostatic transfer oflayers 28 frombelt 14 to buildplatform 18 after a given number oflayers 28 are printed. -
Rollers 16 are a series of drive and/or idler rollers or pulleys that are configured to maintain tension onbelt 14 whilebelt 14 rotates in the rotational direction ofarrows 30. This allowsbelt 14 to maintain a substantially planar orientation when engagingbuild platform 18 andpress plate 20.System 10 may also include service loops (not shown), such as those disclosed in U.S. patent application Ser. No. 13/242,841. -
System 10 also includesheater 32, located upstream frombuild platform 18 andpress plate 20, based on the rotational direction ofbelt 14.Heater 32 is one or more heating devices configured to heatlayers 28 to a temperature near an intended transfer temperature of the thermoplastic-based powder, such as at least a fusion temperature of the thermoplastic-based powder, prior to reachingpress plate 20. Examples of suitable devices forheater 32 include non-contact radiant heaters (e.g., infrared heaters or microwave heaters), convection heating devices (e.g., heated air blowers), contact heating devices (e.g., heated rollers and/or platens), combinations thereof, and the like, where non-contact radiant heaters are preferred. Eachlayer 28 desirably passes by (or through)heater 32 for a sufficient residence time to heat thelayer 28 to the intended transfer temperature. - As defined above, the fusion temperature is a temperature that sufficiently melts the thermoplastic-based powder to a fusable state. Thus, the fusion temperature will vary depending on the particular layer material used and on the applied pressure. For example, for an ABS copolymer material, the fusion temperature may range from about 180° C. to about 220° C. depending on the particular copolymer composition, as mentioned above. Heating the thermoplastic-based powder to the fusion temperature does not necessarily require every component of the thermoplastic-based powder to melt. Rather, the overall thermoplastic-based powder needs to reach a fusable state for subsequent transfusion. This typically refers to the one or more thermoplastic materials of the thermoplastic-based powder being sufficiently melted to the fusable state.
-
Build platform 18,press plate 20, andheater 32 may collectively be referred to aslayer transfusion assembly 33.Layer transfusion assembly 33 is configured to transfuse theheated layers 28 from thebelt 14 to the previously-transfused layers of 3D part 22 (or onto build platform 18) in a layer-by-layer manner. -
Build platform 18 is a platform assembly or platen ofsystem 10 that is configured to receive theheated layers 28 for 22 in a layer-by-layer manner.printing 3D partBuild platform 18 is supported by z-axis gantry 34, which is a linear guide mechanism configured to incrementallylower build platform 18 along the vertical z-axis relative to belt 14 andpress plate 20 after each pressing step. The movement ofbuild platform 18 with z-axis gantry 34 is operated by z-axis motor 36 based on commands fromcontroller 24, where z-axis motor 36 may be an electrical motor, a hydraulic system, a pneumatic system, or the like. In some embodiments, buildplatform 18 may include removable film substrates for receiving the printed layers 28. - In the shown embodiment, build
platform 18 is heatable with heating element 38 (e.g., an electric heater).Heating element 38 is configured to heat and maintainbuild platform 18 at an elevated temperature that is greater than room temperature (25° C.), such as at the desired average part temperature of3D part 22. This allowsbuild platform 18 to assist in maintaining3D part 22 at this average part temperature. - As mentioned above, the average part temperature for
3D part 22 is desirably high enough to promote interlayer adhesion and to reduce the effects of curling, while also being low enough to prevent3D part 22 from softening too much (i.e., below its deformation temperature). Suitable average part temperatures for3D part 22 range from greater than the average solidification temperature of the thermoplastic material(s) of the thermoplastic-based powder to about the glass transition temperature of the thermoplastic material(s). More desirably, the average part temperature is maintained at about the creep relaxation temperature of the thermoplastic material(s) of the thermoplastic-based powder, or within about 10° C. above or below thereof. Examples of suitable techniques for determining the creep relaxation temperatures of materials are disclosed in Batchelder et al., U.S. Pat. No. 5,866,058. - In some preferred embodiments, the average part temperature is maintained in a range between the creep relaxation temperature of the thermoplastic material(s) of the thermoplastic-based powder and a maximum allowable solidification temperature, where the maximum allowable solidification temperature may be illustrated by the stress relaxation of the thermoplastic-based powder. For example, when printing layers 28 of an ABS copolymer-based powder, the average part temperature for
3D part 22 may be about 100° C., as may be appreciated by a comparison of the stress relaxation or Young's modulus versus temperature for the composition. As shown inFIG. 2B , which is a logarithmic graphical illustration of Young's modulus versus temperature at atmospheric pressure for a particular ABS copolymer, as the temperature increases by a small amount above about 100° C., the elastic modulus of the ABS copolymer significantly drop (illustrated by the shoulder in the plot). At this Young's modulus drop, the ABS copolymer significantly softens, which reduces its structural integrity. - As such, maintaining
3D part 22 at an average part temperature below the Young's modulus drop for its composition allows3D part 22 to maintain its structural integrity when pressed betweenbuild platform 18 andpress plate 20 during subsequent transfusion steps. Furthermore, when the top-most layer of3D part 22 is maintained at this temperature and receives aheated layer 28 at a fusion temperature of about 200° C., the transfusion interface temperature for transfusing the layers together starts at about 150° C. This temperature is suitable for the polymer molecules of thelayers 28 to at least partially interdiffuse to promote interfacial entanglement, pursuant to the plot line function of f(Ļr) inFIG. 1 and Equations 1-3. -
Press plate 20 is an example heateable element or heatable layer transfusion element, which is configured to pressbelt 14 and a givenheated layer 28 downward against3D part 22 and buildplatform 18 during each transfusion step.Press plate 20 may be actuated with a servo mechanism (not shown) configured to movepress plate 20 along the vertical z-axis during each transfusion step. - As mentioned above, the particular pressure applied during each transfusion step is desirably high enough to adhere the
heated layer 28 to the previously-transfused layer 28 (or to build platform 18), allowing the polymer molecules to at least partially interdiffuse. However, the transfusion pressure is also desirably balanced to preventpress plate 20 from compressing3D part 22 too much, thereby allowing3D part 22 to maintain its dimensional integrity. - In the shown embodiment,
press plate 20 is heatable with heating element 40 (e.g., an electric heater).Heating element 40 is configured to heat and maintainpress plate 20 at an elevated temperature that is greater than room temperature (25° C.). However, in comparison to the elevated temperature ofbuild platform 18,heating element 40 may heat and maintainpress plate 20 at a temperature that is less than the desired average part temperature of3D part 22. For example, in situations where the intended average part temperature for3D part 22 is 100° C.,heating element 40 may heat and maintainpress plate 20 at about 70° C. - The lower temperature for
press plate 20 will cool belt 14 from the side ofrear surface 14 b (i.e., a transfixing step). This is in addition to thermal conduction that occurs by the previously-printed layers of3D part 22 itself, which draw heat from the transfused layers down into the previously-printed layers. As discussed above, if the transfusedlayer 28 remains too hot, it may remain adhered tofront surface 14 a ofbelt 14, rather than cleanly releasing frombelt 14. As such, coolingbelt 14 with the contact from press plate 20 (and/or via the previously-printed layers) allows the interface betweenfront surface 14 a ofbelt 14 and the transfusedlayer 28 to cool down enough to cleanly release the transfusedlayer 28 frombelt 14. - On the other hand, due to the large contact surface area between
belt 14 andpress plate 20, ifpress plate 20 is maintained at a temperature that is too low, the contact duration betweenpress plate 20 andbelt 14 during the transfusion step may cool the transfusedlayer 28 down too much, thereby lowering the transfusion interface temperature, which can reduce the interlayer adhesion. As such, in some embodiments,heating element 40 desirably maintainspress plate 20 at a temperature that balances these competing thermal effects to facilitate both transfusion and transfixing in a single, combined step. -
System 10 may also include one ormore air knives 42 or other cooling units, whereair knife 42 is an example cooling unit configured to blow localized cooling air to the top layers of3D part 22. As best shown inFIG. 3A ,air knife 42 is located adjacent to the lateral side ofbuild platform 18 to direct the cooling air laterally relative to the direction of movement ofbelt 14. This allowsair knife 42 to extend along the entire length of3D part 22, providing good air flow over the top layers of3D part 22, including the fusedlayer 28. - In an alternative embodiment,
system 10 may also include a second air knife 42 (not shown) located at the opposing lateral side ofbuild platform 18. In embodiments havingair knives 42 or other cooling units,press plate 20 may be heated to the fusion temperature to promote interdiffusion in the transfusion step. Then, upon release ofpress plate 20, a separate transfix step may be performed by cooling the transfused layer before release of the layer from thebelt 14. - As also stated above, when
system 10 prints layers 28 at high speeds, the printedlayers 28 do not have sufficient time to cool down to the desired average part temperature beforesuccessive layers 28 are printed. As such, as the height of3D part 22 grows, heat dissipation from passive thermal diffusion becomes insufficient to cool the heated layers. - This is depicted in
FIG. 3B , which is a graphical illustration of the number of layers printed versus the average part temperature for a 3D part printed without the active cooling (represented by line 44) and for3D part 22 printed with the active cooling (represented by line 46). As shown byline 44, without the active cooling, the heat added by each layer at its fusion temperature will accumulate in the 3D part, causing the average part temperature to increase until the deformation temperature of the 3D part is reached, as illustrated bythreshold line 48. Atthreshold line 48, the temperature in the bulk of the 3D part is high enough such that the part material substantially softens. When the 3D part reaches this point, the transfusion pressure applied bypress plate 20 during subsequent transfusion steps may overcome the structural integrity of the 3D part, thereby deforming the 3D part. -
Air knife 42, however, actively cools each layer after the transfusion step to prevent the additional heat from accumulating. As shown by line 46, the active cooling substantially removes the heat provided by eachlayer 28, thereby providing substantially zero heat accumulation after each printedlayer 28. As such,3D part 22 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation, as illustrated above in Equation 4. - In some embodiments, it can be beneficial for the average part temperature to be high enough such that the bulk of
3D part 22 exhibits a small amount of softening. It has been found that when the bulk of3D part 22 exhibits a small amount of softening that still maintains its overall structural integrity (i.e.,3D part 22 does not deform), subsequent transfusion steps withpress plate 20 may mildly compress the bulk of3D part 22, thereby increasing the part density. The increased part density correspondingly reduces brittleness and porosity of the resulting3D part 22, and increases its z-axis strength. These properties are beneficial for a variety of applications. - While illustrated with
air knife 42,system 10 may alternatively include a variety of different convective and/or conductive cooling units configured to actively cool each layer after the transfusion step to prevent the additional heat from accumulating, such as refrigeration units, liquid-cooling units, evaporation units, and the like. Furthermore, one or more air knives 42 (or other cooling units) may be located at other locations aroundbuild platform 18 andpress plate 20 to direct the cooling air towards the top layers of3D part 22. Optionally,system 10 may also include additional pre-heaters (e.g., 270 and 272, shown inheaters FIGS. 6A-6F ) to heat the top layer(s) or surface of3D part 22 to the transfer temperature (e.g. to the fusion temperature) prior to each subsequent transfusion step. -
FIG. 4A-4D illustrate an example process for printing alayer 28 withsystem 10 using the layer transfer technique of the present disclosure. At the start of the printing operation, buildplatform 18 andpress plate 20 may be heated to their desired temperatures. For example, buildplatform 18 may be heated to the desired average part temperature for 3D part 22 (e.g., about 100° C. for an ABS copolymer), andpress plate 20 may be heated to a temperature that is lower than the desired average part temperature for 3D part 22 (e.g., about 70° C. for an ABS copolymer). - The printing operation initially involves imaging (e.g., developing) a
powder layer 28 with EP engine 12 (shown inFIG. 1 ) and transferring the imaged powder layer toheater 32 viabelt 14. As shown inFIG. 4A , as the imagedpowder layer 28 passes by (or through)heater 32,heater 32 heats thelayer 28 and the associated region ofbelt 14 to an intended transfer temperature of the thermoplastic-based powder, pursuant to the plot line function of inFIG. 1 and Equations 1-3. For simplification, the following discussion will be made with reference to the fusion temperature of the thermoplastic-based powder or layer material (e.g., about 200° C. for an ABS copolymer). - As shown in
FIG. 4B , the continued rotation ofbelt 14 in the direction ofarrow 30 aligns theheated layer 28 abovebuild platform 18 with proper registration location along the x-axis.Press plate 20 may then actuate downward, as illustrated byarrow 50, to press theheated layer 28 onto the previously-printed layer of3D part 22. As shown inFIG. 4C , becauselayer 28 is heated to the fusion temperature of the thermoplastic-based powder, the pressedlayer 28 transfuses to the top surface of3D part 22. - The temperature of
press plate 20, being lower than the desired average part temperature, and substantially lower than the fusion temperature, begins to draw heat from the heated region ofbelt 14 in a transfixing step. Additionally, the previously-printed layers of3D part 22, which are at the desired average part temperature, may also conductively draw heat from the transfused layers and the heated region ofbelt 14. These assist in releasing the transfusedlayer 28 by coolingbelt 14 fromrear side 14 b, as discussed above. As also mentioned above, at its fusion temperature, the minimum transfusion duration for an ABS-copolymer material can be as low as about 0.03 seconds. However, this low duration may be countered by the duration required for the transfixing step to cool the interface betweenbelt 14 and the transfusedlayer 28. - As such, examples of suitable transfusion durations for pressing during the transfusion step range from about 0.1 seconds to about 1.0 second, with particularly suitable transfusion durations ranging from about 0.1 seconds to about 0.5 seconds. In some embodiments, the transfusion duration is a fixed value for each
layer 28. In alternative embodiments, the transfusion duration may be varied based on the dimensions and geometry of3D part 22. For example, the transfusion duration may be reduced forlayers 28 having smaller cross-sectional areas and/or fine-feature details. - After the transfusion/transfixing step is completed,
press plate 20 may then be retracted upward, as illustrated byarrow 52 inFIG. 4C , to release the pressure applied to belt 14 and the transfusedlayer 28. In the embodiment shown inFIG. 4D , this releases thelayer 28 frombelt 14, allowing thelayer 28 to remain transfused to3D part 22. Additionally, z-axis gantry 34 may lower buildplatform 18 downward, such as by a single layer increment or other suitable distance, as illustrated byarrow 54. - In an alternate embodiment,
press plate 20 may be heated to the fusion temperature of the thermoplastic-based powder to assist in the transfusion oflayer 28. In this embodiment,layer transfusion assembly 33 is desirably configured such that retractingpress plate 20 upward does not immediately release the transfusedlayer 28 frombelt 14. Rather, belt 14 may be maintained in a relatively constant position upon the retraction ofpress plate 20 by positioningbuild platform 18 in a higher position relative to that shown inFIG. 4D during the transfusion step. A separate transfixing step may then be utilized. - In this transfixing step,
air knife 42 may be activated to cool the transfusedlayer 28 before releasing it frombelt 14. After a duration sufficient to cool the layer material down below the fusion temperature, which maintains the transfusedlayer 28 in a fixed spatial position and adhered to3D part 22,build platform 18 is then lowered to release transfusedlayer 28 frombelt 14. -
Air knife 42 may also be activated to blow cooling air onto the transfusedlayer 28 after delamination frombelt 14. This actively cools the transfusedlayer 28 down to the desired average part temperature. Examples of suitable durations for this active cooling step range from about 1.0 second to about 2.0 seconds, which may correspond with the transfer and alignment of thenext layer 28. - As can be appreciated, the transfer of
layer 28 frombelt 14 to buildplatform 18 requires a pause during the pressing step. Otherwise, the movement ofbelt 14 in the rotational direction ofarrows 30 during the transfusion step may cause a mis-registration of the pressedlayer 28, potentially resulting in lower part quality. These pauses during each transfusion step may be accommodated with the use of service loops, such as those disclosed in U.S. patent application Ser. No. 13/242,841. - As further shown in
FIGS. 4B-4D , as apresent layer 28 is being transfused, thenext layer 28 a may be positioned atheater 32. This allowsheater 32 to sufficiently heat thenext layer 28 a during the required pause while thepresent layer 28 is transfused to3D part 22. After thelayer 28 is transfused and cooled, the same process may then be repeated forlayer 28 a, and each subsequent layer for3D part 22. - While
layer transfusion assembly 33 is illustrated with aplanar press plate 20, in alternative embodiments,press plate 20 may be replaced with different pressing mechanisms, such as rollers, partial-cylinder presses (configured to simulate rolling motions, e.g., blotters), and the like. The embodiments are beneficial for increasing part density due to their capabilities in expelling any gasses (e.g., air) trapped between the powder particles. For example,FIGS. 5A-5E illustratelayer transfusion assembly 133, which is an alternative to layertransfusion assembly 33 of system 10 (shown inFIGS. 2A , 3A, and 4A-4D), and where the reference numbers of the respective components are increased by ā100ā fromsystem 10. - As shown in
FIG. 5A ,layer transfusion assembly 133 includes niproller 120 in lieu ofpress plate 20, where niproller 120 is another example heateable element or heatable layer transfusion element, and is configured to rotate around a fixed axis with the movement ofbelt 114. In particular, niproller 120 may roll againstrear surface 114 b in the direction ofarrow 156 whilebelt 114 rotates in the direction ofarrows 130. In some embodiments, niproller 120 may function as a drive roller forbelt 114. Whilebelt 114 is illustrated as bending around niproller 120 at about a 90-degree angle,belt 114 may alternatively bend around niproller 120 at about 180-degree angle in a U-shaped arrangement as shown below forbelt 314 and nip roller 320 (shown below inFIG. 7 ). - As further shown, air jets 142 (or other suitable cooling units) are used in lieu of
air knife 42, and are located downstream from the interface betweenbelt 114 and niproller 120. Air jets are configured to blow cooling air towards the top layers of3D part 122 to actively cool the layers after each transfusion step, as discussed below.Air jets 142 may alternatively be replaced by a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like (e.g., one or more cold belts and/or drums, as discussed below). - In this embodiment,
build platform 118 is supported bygantry 134, which is a guide mechanism configured to movebuild platform 118 along the z-axis and the x-axis to produce a reciprocating rectangular pattern, where the primary motion is back-and-forth along the x-axis.Gantry 134 may be operated bymotor 136 based on commands from controller 124, wheremotor 136 may be an electrical motor, a hydraulic system, a pneumatic system, or the like. Accordingly, the pressure that is applied during each transfusion step is performed bybuild platform 118. - Prior to
122,printing 3D partbuild platform 118 and niproller 120 may be heated to their desired temperatures, as discussed above forbuild platform 18 andpress plate 20. In comparison to pressplate 20,heating element 140 may heat niproller 120 to a higher temperature (e.g., to the average part temperature, such as about 100° C. for an ABS copolymer) since there is a relatively short time for the heat to locally flow from niproller 120 throughbelt 114. - During the printing operation,
heater 132 heats an imagedpowder layer 128 and the associated region ofbelt 114 to an intended transfer temperature of the thermoplastic-based powder, such as to at least the fusion temperature of the thermoplastic-based powder (e.g., about 200° C. for an ABS copolymer).Belt 114 may then move theheated layer 132 to a predetermined registration location along the x-axis, as shown.Gantry 134 may then actuatebuild platform 118 upward to engagebelt 114, which presses the top layer of3D part 122 against the heated layer 124, as illustrated byarrow 158. Alternatively, niproller 120 may be actuated downward to meet the top layer or surface of3D part 122. - As shown in
FIG. 5B , this presses theheated layer 128 between the top layer of3D part 122 andbelt 114 at the location of niproller 120. Whilebuild platform 118 remains engaged withbelt 114,gantry 134 may then move build platform 118 (and 3D part 122) along the x-axis in the direction ofarrow 160, at a rate that is synchronized with the rotational rate ofbelt 114 in the direction of arrow 130 (i.e., the same directions and speed). This pressesbelt 114 and theheated layer 128 between the top layer of3D part 122 and niproller 120. - As shown in
FIG. 5C , this causesrear surface 114 b ofbelt 114 to roll across niproller 120 to nipbelt 114 and theheated layer 128 against the top layer of3D part 122. Becauselayer 128 is heated to the fusion temperature of the thermoplastic-based powder and3D part 122 is maintained at the average part temperature, the pressedlayer 128 transfuses to the top layer of3D part 122 in a similar manner to that discussed above for3D part 22 andlayer 28. - As further shown, as the transfused
layer 128 passes the nip of niproller 120,belt 114 wraps around niproller 120 to separate and disengage frombuild platform 118. This assists in releasing the transfusedlayer 128 frombelt 114, allowing the transfusedlayer 128 to remain adhered to3D part 122. Additionally,air jets 142 blow cooling air towards the top layers of3D part 122 asbuild platform 118 moves along the x-axis past niproller 120 to cool down the transfusedlayer 128. The transfusedlayer 128 may be cooled down to the average part temperature (e.g., about 100° C. for an ABS copolymer) by continuing to blow cooling air against the3D part 122 in between transfusion steps. - When
build platform 118 moves3D part 122 past niproller 120,gantry 134 may actuate build platform 118 (and 3D part 122) downward, as illustrated byarrow 162. As shown inFIG. 5D ,gantry 134 may then move build platform 118 (and 3D part 122) along the x-axis in the direction ofarrow 164, back to a starting position along the x-axis. As shown inFIG. 5E ,build platform 118 desirably reaches the starting position as the nextheated layer 128 is positioned above3D part 122. The same process may then be repeated, wheregantry 134 actuatesbuild platform 118 upward to pressbelt 114 and the nextheated layer 128 between the top layer of3D part 122 androller 120, as illustrated byarrow 166. In this step, however, the height of the top surface of3D part 122 is offset downward, such as by a single layer increment, compared to the previous pressing step. - As can be appreciated, moving build platform 118 (and 3D part 122) in the reciprocating rectangular pattern allows the transfusion steps to be performed while
belt 114 continuously rotates. In particular, movingbuild platform 118 at a rate that is synchronized with the rotational rate ofbelt 114, along with the use of niproller 120, which rotates againstrear surface 114 b ofbelt 114, allows the transfusion and transfixing steps to be performed rapidly (e.g., within about 0.1 to about 0.5 seconds). This allows the active cooling steps to range from about 1.0 second to about 2.0 seconds, which may correspond with the transfer and alignment of the nextheated layer 28. - While the reciprocating rectangular pattern is described as a rectangular pattern with sharp axial corners (defined by
160, 162, 164, and 166),arrows gantry 134 may move build platform 118 (and 3D part 122) in a reciprocating rectangular pattern having rounded or oval-defining corners, so long asbuild platform 118 moves linearly along the x-axis during the transfusion steps. - As can be appreciated from the depictions in
FIGS. 5C and 5D ,air jets 142 may direct cooling air towards3D part 122 in a global manner, where cooling air, while directed at the top layers of3D part 122, may also flow around the lateral sides of3D part 122. Depending on the geometry of3D part 122, this global cooling can cool3D part 122 down below its desired average part temperature, which can have adverse effects on3D part 122 in some circumstances (e.g., curling issues). - As such, in some embodiments,
air jets 142 may be replaced with one or more localized cooling mechanisms or units, such as one or more cold belts and/or drums, which can contact the top layers of3D part 122 to selectively cool only the areas of3D part 122 that are in contact with thecooling unit 642. In other words, the cold belts and/or drums only cool the top heated layers of3D part 122 in a localized manner, rather than a global cooling of3D part 122. This draws away the additional heat from the transfused layers (and a portion of the previously-printed layers) in an active cooling step without cooling down theentire 3D part 122. This accordingly precludes the need to heat the bulk of3D part 122 back up to its desired average part temperature. Examples of suitable cooling units in these embodiments include those discussed below for layer transfusion assembly 633 (e.g., coolingunit 642, shown below inFIG. 10 ). -
FIGS. 6A-6F illustratelayer transfusion assembly 233, which is an alternative to layer transfusion assembly 133 (shown inFIGS. 5A-5E ), and where the reference numbers of the respective components are increased by ā200ā from system 10 (shown inFIGS. 2A , 3A, and 4A-4D).Layer transfusion assembly 233 may function in a similar manner to layertransfusion assembly 133, wherebuild platform 218 may move in a reciprocating rectangular pattern. - However, as shown in
FIG. 6A ,layer transfusion assembly 233 includesfusion roller 220 andrelease roller 268 in lieu of asingle nip roller 120, wherefusion roller 220 andrelease roller 268 are each configured to rotate around an axis with the movement ofbelt 214. The use of separate rollers (i.e.,fusion roller 220 and release roller 268) separates the functions of each roller, allowing them to be optimized for their particular purposes. For example,fusion roller 220 may be heated to a high transfer temperature (e.g., the fusion temperature of the thermoplastic-based powder) to accelerate the layer transfusion, andrelease roller 268 may be maintained at a substantially lower temperature to assist in delaminating the transfusedlayers 228 frombelt 214. - As further shown,
layer transfusion assembly 233 also includes 270 and 272 andheaters air jets 274. The separation offusion roller 220 andrelease roller 268 creates separate transfusion and release steps, and allows a transfixing step to be performed therebetween via cooling byair jets 274. By postponing the release step,fusion roller 220 may be heated to a transfer temperature best suited for the transfusion step (e.g., the fusion temperature of the thermoplastic-based powder), rather than a compromise temperature that facilitates both transfusion and release. This can increase the printing speed and/or increase the interlayer adhesion between the transfusedlayers 228 per transfusion step, while also cleanly releasing the transfusedlayers 228 frombelt 214. - Prior to
222,printing 3D partbuild platform 218 andfusion roller 220 may be heated to their desired temperatures. For example, buildplatform 218 may be heated to the average part temperature (e.g., about 100° C. for an ABS copolymer) andfusion roller 220 may be heated to the transfer temperature of the thermoplastic-based powder (e.g., to the fusion temperature, such as about 200° C. for an ABS copolymer). During the printing operation, belt 214 carries an imagedpowder layer 228past heater 232, which heats the imagedpowder layer 228 and the associated region ofbelt 214 to the desired transfer temperature. - Additionally,
platen gantry 234 movesbuild platform 218 along the x-axis in the direction ofarrow 276 below, along, or throughheater 270.Heater 270 may function in the same manner as 32 and 232, and heats the top surface ofheaters 3D part 222 to an elevated temperature, such as at the same transfer temperature as the heated layer 228 (or other suitable elevated temperature). - As shown in
FIG. 6B , the continued rotation ofbelt 214 and the movement ofbuild platform 218 align theheated layer 228 with the heated top surface of3D part 222 with proper registration along the x-axis. Furthermore, theheated layer 228 and the heated top surface of3D part 222 eachpass heater 272, which may be configured to heat and/or maintain both theheated layer 228 and the heated top surface of3D part 222 at the transfer temperature of the layer material. This prevents theheated layer 228 from cooling down prior to reachingfusion roller 220, and brings the temperature of the heated top surface of3D part 222 to or near the transfer temperature before the next transfusion step is performed. In alternative embodiments, one or more of 232, 270, and 272 may be provided a single heater configured to direct heat in multiple directions (e.g., towards both theheaters layer 228 and the top surface of 3D part 222). - In further alternative embodiments, one or both of
270 and 272 may be omitted if not needed. Correspondingly, one or both ofheaters 270 and 272 may also be utilized with layer transfusion assembly 133 (shown above inheaters FIGS. 5A-5E ) in the same manner as forlayer transfusion assembly 233 to direct heat towards the top surface of3D part 122 prior to the transfusion step. -
Gantry 234 may continue to move build platform 218 (and 3D part 222) along the x-axis in the direction ofarrow 276, at a rate that is synchronized with the rotational rate ofbelt 214 in the direction of arrow 230 (i.e., the same directions and speed). This causesrear surface 214 b ofbelt 214 to rotate aroundfusion roller 220 to nipbelt 214 and theheated layer 228 against the top surface of3D part 222. This engagesbuild platform 218 andbelt 214, and presses theheated layer 228 between the heated top surface of3D part 222 andbelt 214 at the location offusion roller 220. - Because
layer 228 and the heated top layer of3D part 222 are can each be heated to the fusion temperature of the thermoplastic-based powder, the pressedheated layer 228 transfuses to the heated top surface of3D part 222 with a high level of interlayer adhesion. By separatingfusion roller 220 andrelease roller 268, with a cooling step therebetween viaair jets 274,layer transfusion assembly 233 allows the layers to be heated to an optimal transfusion interface temperature, and to be cooled to a temperature that fixes the layers before release. - For example, the transfusion interface temperature for transfusing the layers together may be at about the fusion temperature of the thermoplastic-based powder (e.g., about 200° C. for an ABS copolymer). This can substantially increase the printing speed and/or increase the extent to which the polymer molecules of the transfused layers interdiffuse per transfusion step to promote interfacial entanglement, while also maintaining dimensional accuracy of
3D part 222. - As shown in
FIG. 6C , after passingfusion roller 220, and whilebuild platform 218 remains engaged withbelt 214,belt 214, 218, andbuild platform 3D part 222pass air jets 274.Air jets 274 may function in the same manner as 142 and 242 for coolingair jets belt 214 the side ofrear surface 214 b. In alternative embodiments,air jets 274 may be a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like. - As discussed above, if the transfused
layer 228 remains too hot, portions of it may remain adhered tofront surface 214 a ofbelt 214, rather than cleanly releasing frombelt 214. As such,cooling belt 214 withair jets 274 allows the interface betweenfront surface 214 a ofbelt 214 and the transfusedlayer 228 to cool so that the transfusedlayer 228 will remain adhered to3D part 222 and cleanly release frombelt 214. This also partially assists in the active cooling of3D part 222 to maintain3D part 222 at the average part temperature below its deformation temperature, as illustrated above in Equation 4. - As further shown in
FIG. 6D , as the transfusedlayer 228 passes the nip ofrelease roller 268,belt 214 rotates aroundrelease roller 268 to separate and disengage frombuild platform 218. This assists in releasing the transfusedlayer 228 frombelt 214, in an āassisted delaminationā step, allowing the transfusedlayer 228 to remain adhered to3D part 222. Additionally,air jets 242 blow cooling air towards the top layers of3D part 222 asbuild platform 218 moves along the x-axis pastrelease roller 268. This actively cools the transfusedlayer 228 down to the average part temperature, as also illustrated above in Equation 4. - When
build platform 218 moves3D part 222past release roller 268,gantry 234 may actuate build platform 218 (and 3D part 222) downward, as illustrated byarrow 278. For example, buildplatform 218 may be incrementally offset downward by a single layer increment. As shown inFIG. 6E ,gantry 234 may then move build platform 218 (and 3D part 222) along the x-axis in the direction ofarrow 280, back to a starting position along the x-axis. - As shown in
FIG. 6F , buildplatform 218 desirably reaches the starting position for proper registration with thenext layer 228. In some embodiments,gantry 234 may also actuate 218 andbuild platform 3D part 222 upward for proper registration with thenext layer 228. The same process may then be repeated for each remaininglayer 228 of3D part 222.Layer transfusion assembly 233 provides the benefits of transfusing the layers together at the desired transfer temperature (e.g., the fusion temperature of the thermoplastic-based material) to increase interlayer adhesion, while also sufficiently cooling down the interface betweenfront surface 214 a ofbelt 214 and the transfusedlayers 228 to transfix thelayers 228 in place before release frombelt 214. This promotes a clean release by assisting the delamination frombelt 214. - In addition, for each printed
layer 228, the combination ofair jets 242 and 274 (or other cooling units) substantially removes the heat that is added from 232, 270, 272, and from theheating elements heated fusion roller 220, prior to printing thenext layer 228. This active cooling substantially removes the heat provided by eachlayer 228, thereby providing substantially zero heat accumulation after each printedlayer 228. As such,3D part 222 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation. Further, the top layer surface temperature of the printed3D part 222 may be brought back up to the transfer temperature afterdelamination using heater 270 and/or 272 oflayer transfusion assembly 233 for optimal transfusion of thenext layer 228. -
FIGS. 7 and 8 illustrate 333 and 433, which are alternatives to layer transfusion assemblies 133 (shown inlayer transfusion assemblies FIGS. 5A-5E ) and layer transfusion assembly 233 (shown inFIGS. 6A-6F ), and include 382 and 482 configured to perform a post-fuse or heat-setting step by heating the part surface to an elevated temperature (e.g., to at least the fusion temperature of the thermoplastic-based powder) after transferring a layer. As shown inpost-fuse heaters FIG. 7 ,layer transfusion assembly 333 may function in a similar manner to layertransfusion assembly 133, where the reference numbers of the respective components are increased by ā300ā from system 10 (shown inFIGS. 2A , 3A, and 4A-4D). - As shown in
FIGS. 7 and 8 , this post-fuse step follows the transfusion/transfixing and release steps of the layer transfer process, which may be performed at a transfer temperature that is below the fusion temperature of the thermoplastic-based powder. The addition of 382 and 482 inpost heaters 333 and 433 permits transferring of layers tolayer transfusion assemblies 322 and 422 at transfer temperatures optimized for clean and quick transfer of layers, without sacrificing part strength gained through interfacial bonding of the layer material at the fusion temperature of the thermoplastic-based powder. In this manner, part quality may be optimized for dimensional accuracy and porosity (by a clean transfer), and also for strength.3D parts - As shown in
FIG. 7 ,layer transfusion assembly 333 also includesheaters 370 and 372 (in addition to post-fuse heater 382). 370 and 372 correspond toHeaters 270 and 272 ofheaters layer transfusion assembly 233 and function in a similar manner for heating the top surface or layer(s) of3D part 322 prior to the transfusion step.Post heater 382 is located downstream from niproller 320 and upstream fromair jets 342, and is configured to heat the transfused layers to an elevated temperature in the post-fuse or heat-setting step. - Prior to
322,printing 3D partbuild platform 318 and niproller 320 may be heated to their desired temperatures. For example, buildplatform 318 may be heated to the average part temperature (e.g., about 100° C. for an ABS copolymer). However, niproller 320 may be heated to a desired transfer temperature for an imagedlayer 328. - During the printing operation, belt 314 carries the imaged
powder layer 328past heater 332, which heats the imagedpowder layer 328 and the associated region ofbelt 314 to the transfer temperature. In comparison to layer 133 and 233, in which the imaged powder layers may be heated to at least the fusion temperature of the thermoplastic-based powder, the transfer temperature for imagedtransfusion assemblies powder layer 328 is desirably less than its fusion temperature, but high enough to achieve partial entanglement of the polymer molecules between the 328 andheated layer 3D part 322 during the subsequent transfusion step. Suitable transfer temperatures for the thermoplastic-based powder include temperatures that exceed the glass transition temperature of the thermoplastic-based powder, where the layer material is softened but not melted, for example, a temperature of ranging from about 140° C. to about 180° C. for an ABS copolymer. - As further shown in
FIG. 7 , during operation,gantry 334 may move 318 andbuild platform 3D part 322 in a reciprocating rectangular pattern (depicted by arrows 376) in the same manner as 134 and 234. In particular,gantries gantry 334 movesbuild platform 318 along the x-axis below, along, or throughheater 370.Heater 370 heats the top surface of3D part 322 to an elevated temperature, such as the transfer temperature of the thermoplastic-based powder. As with the above-discussed embodiments, 332 and 370 may heat the imagedheaters powder layers 328 and the top surface of3D part 322 to about the same temperatures to provide a consistent transfusion interface temperature. Alternatively, 332 and 370 may heat the imagedheaters powder layers 328 and the top surface of3D part 322 to different temperatures to attain a desired transfusion interface temperature. - The continued rotation of
belt 314 and the movement ofbuild platform 318 align theheated layer 328 with the heated top surface of3D part 322 with proper registration along the x-axis. Furthermore, theheated layer 328 and the heated top surface of3D part 322 may each passheater 372, which may be configured to heat and/or maintain both theheated layer 328 and the heated top surface of3D part 322 at the transfer temperature. This prevents theheated layer 328 from cooling down prior to reaching niproller 320, and brings the temperature of the heated top surface of3D part 322 to or near the transfer temperature before the next transfusion step is performed. In alternative embodiments,heater 372 may be omitted. -
Gantry 334 may continue to move build platform 318 (and 3D part 322) along the x-axis, at a rate that is synchronized with the rotational rate ofbelt 314 in the direction of arrow 330 (i.e., the same directions and speed). This causesrear surface 314 b ofbelt 314 to rotate around niproller 320 to nipbelt 314 and theheated layer 328 against the top surface of3D part 322. This engagesbuild platform 318 andbelt 314, and presses theheated layer 328 between the heated top surface of3D part 322 andbelt 314 at the location of niproller 320. This at least partially transfusesheated layer 328 to the top layer of3D part 322. - As the transfused
layer 328 passes the nip of niproller 320,belt 314 wraps around niproller 320 to separate and disengage frombuild platform 318. This assists in releasing the transfusedlayer 328 frombelt 314, in an assisted delamination step, allowing the transfusedlayer 328 to remain adhered to3D part 322. As discussed above, maintaining the transfusion interface temperature at a transfer temperature that is higher than its glass transition temperature, but lower than its fusion temperature, allows theheated layer 328 to be hot enough to adhere to3D part 322, while also being cool enough to readily release frombelt 314. - After release,
gantry 334 continues to move build platform 318 (and 3D part 322) along the x-axis topost-fuse heater 382. Atpost-fuse heater 382, the transfused 328 andlayer 3D part 322 are then heated to at least the fusion temperature of the thermoplastic-based powder in a post-fuse or heat-setting step. This melts the material of the transfusedlayer 328 to a highly fusable state such that polymer molecules of the transfusedlayer 328 quickly interdiffuse to achieve a high level of interfacial entanglement with3D part 322. - Additionally, as
gantry 334 continues to move build platform 318 (and 3D part 322) along the x-axis pastpost-fuse heater 382 toair jets 342,air jets 342 blow cooling air towards the top layers of3D part 322. This actively cools the transfusedlayer 328 down to the average part temperature, as discussed above. -
Gantry 334 may then actuate build platform 318 (and 3D part 322) downward, and move build platform 318 (and 3D part 322) back along the x-axis to a starting position along the x-axis, following the reciprocatingrectangular pattern 376.Build platform 318 desirably reaches the starting position for proper registration with thenext layer 328. In some embodiments,gantry 334 may also actuate 318 andbuild platform 3D part 322 upward for proper registration with thenext layer 328. The same process may then be repeated for each remaininglayer 328 of3D part 322. -
Layer transfusion assembly 333 provides an alternative mechanism for transfusing the imagedlayers 428 together at3D part 322, while also keeping theheated layers 328 cool enough for clean release frombelt 314. The heat-setting step performed after releasing each transfusedlayer 328 frombelt 314 accordingly increase interlayer adhesion to promote good part strengths. - Additionally, air jets 342 (or other cooling units) substantially remove the heat that is added from
332, 370, and 372, andheating elements post-fuse heater 382 prior to printing thenext layer 328. This active cooling substantially removes the heat provided by eachlayer 328, thereby providing substantially zero heat accumulation after each printedlayer 328. As such,3D part 322 may be substantially maintained at an average part temperature that is below its deformation temperature during the entire printing operation. Further, the top layer surface temperature of the printed3D part 322 may be brought back up to above its glass transitiontemperature using heaters 370 and/or 372 for transfusion of thenext layer 328. - As shown in
FIG. 8 ,layer transfusion assembly 433 is a combination of 233 and 333, where the reference numbers of the respective components are increased by ā400ā from system 10 (shown inlayer transfusion assemblies FIGS. 2A , 3A, and 4A-4D).Layer transfusion assembly 433 includespost-fuse heater 482 located downstream fromrelease roller 468 and upstream fromair jets 442, which may operate in the same manner aspost-fuse heater 382 to heat the transfused layers to at least the fusion temperature of the thermoplastic-based powder in the post-fuse or heat-setting step. - Prior to
422,printing 3D partbuild platform 418 andfusion roller 420 may be heated to their desired temperatures. For example, buildplatform 418 may be heated to the average part temperature andfusion roller 420 may be heated to an elevated temperature, such as to the fusion temperature of the thermoplastic-based powder, as discussed above forfusion roller 220, or to a lower transfer temperature. During the printing operation, belt 414 carries an imagedpowder layer 428past heater 432, which heats the imagedpowder layer 428 and the associated region ofbelt 414 to an elevated transfer temperature, desirably above the glass transition temperature and typically not exceeding the fusion temperature of the thermoplastic-based powder. - During operation,
gantry 434 may move 418 andbuild platform 3D part 422 in a reciprocating rectangular pattern (depicted by arrows 476) in the same manner as 134, 234, and 334.gantries Gantry 434 may movebuild platform 418 along the x-axis below, along, or throughheater 470, which heats the top surface of3D part 422 to an elevated transfer temperature, likewise above the glass transition temperature and desirably not to exceeding the fusion temperature of the thermoplastic-based powder. - The continued rotation of
belt 414 and the movement ofbuild platform 418 align theheated layer 428 with the heated top surface of3D part 422 with proper registration along the x-axis. Furthermore, theheated layer 428 and the heated top surface of3D part 422 may each passheater 472, which may be configured to heat and/or maintain both theheated layer 428 and the heated top surface of3D part 422 at the transfer temperature. This prevents theheated layer 428 from cooling down prior to reachingfusion roller 420, and brings the temperature of the heated top surface of3D part 422 to the transfer temperature before the next transfusion step is performed. -
Gantry 434 may continue to move build platform 418 (and 3D part 422) along the x-axis, at a rate that is synchronized with the rotational rate ofbelt 414 in the direction of arrow 430 (i.e., the same directions and speed). This causesrear surface 414 b ofbelt 414 to rotate aroundfusion roller 420 to nipbelt 414 and theheated layer 428 against the heated top surface of3D part 422. This engagesbuild platform 418 andbelt 414, and presses theheated layer 428 between the heated top surface of3D part 422 andbelt 414 at the location offusion roller 420 to perform the transfusion step. - By separating
fusion roller 420 andrelease roller 468, with a cooling step therebetween via air jets 474 (or other cooling mechanism),layer transfusion assembly 433 also allows the layers to be heated to a transfusion interface temperature higher than is permitted in usinglayer transfusion assembly 333. Wherelayer 428 and the heated top layer of3D part 422 are heated to, at, or near the fusion temperature of the thermoplastic-based powder, the pressedheated layer 428 transfuses to the heated top surface of3D part 422 with a high level of interlayer adhesion. - After passing
fusion roller 420, and whilebuild platform 418 remains engaged withbelt 414,belt 414, 418, andbuild platform 3D part 422pass air jets 474, which coolbelt 414 the side ofrear surface 414 b, as discussed above forair jets 274. In alternative embodiments,air jets 474 may be a variety of different convective and/or conductive cooling units, such as refrigeration units, liquid-cooling units, evaporation units, and the like. Coolingbelt 414 withair jets 474 allows the interface betweenfront surface 414 a ofbelt 414 and the transfusedlayer 428 to cool so that the transfusedlayer 428 will remain adhered to3D part 422 and cleanly release frombelt 414. - In particular, as the transfused
layer 428 passes the nip ofrelease roller 468,belt 414 rotates aroundrelease roller 468 to separate and disengage frombuild platform 418. This assists in releasing the transfusedlayer 428 frombelt 414, in an assisted delamination step, allowing the transfusedlayer 428 to remain adhered to3D part 422. - After release,
gantry 434 continues to move build platform 418 (and 3D part 422) along the x-axis topost-fuse heater 482. Atpost-fuse heater 482, the transfused 428 andlayer 3D part 422 are then heated back up to the fusion temperature of the thermoplastic-based powder in a heat-setting step. This melts the material of the transfusedlayer 428 to a fusable state such that polymer molecules of the transfusedlayer 428 become highly interdiffused to promote interfacial entanglement with3D part 422. In effect,layer transfusion assembly 433 generates two interdiffusion steps separated by a transfixing step, a process particularly suitable for building very high strength parts. - Additionally, as
gantry 434 continues to move build platform 418 (and 3D part 422) along the x-axis pastpost-fuse heater 482 toair jets 442,air jets 442 blow cooling air towards the top layers of3D part 422. This actively cools the transfusedlayer 428 down to the average part temperature, as discussed above. -
Gantry 434 may then actuate build platform 418 (and 3D part 422) downward, and move build platform 418 (and 3D part 422) back along the x-axis to a starting position along the x-axis, following the reciprocatingrectangular pattern 476.Build platform 418 desirably reaches the starting position for proper registration with thenext layer 428. In some embodiments,gantry 434 may also actuate 418 andbuild platform 3D part 422 upward for proper registration with thenext layer 428. The same process may then be repeated for each remaininglayer 428 of3D part 422. -
Layer transfusion assembly 433 provides a further alternative mechanism for transfusing the layers together, while also keeping theheated layers 428 cool enough for clean release frombelt 414. The separation offusion roller 420 andrelease roller 468, with a cooling or transfixing step therebetween viaair jets 474, allows the layers to be heated to an optimal transfusion interface temperature, and to be cooled to a temperature that transfixes thelayers 428 before release. Furthermore, the heat-setting step viapost-fuse heater 482 provides an even greater control over part strength. - Accordingly, the thermal profile of the
428 andlayers 3D part 422 may be tightly controlled to meet a variety of requirements. After release frombelt 414, the transfusedlayer 428 may then be reheated to at least its fusion temperature viapost-fuse heater 482, as discussed above, to further promote interfacial entanglement with3D part 422. -
FIGS. 9 and 10 illustrate 533 and 633, which are further alternatives layer transfusion assembly 233 (shown inlayer transfusion assemblies FIGS. 6A-6F ), whereair jets 274 are omitted. For example, as shown inFIG. 9 ,layer transfusion assembly 533 may function in a similar manner to layertransfusion assembly 233, where the reference numbers of the respective components are increased by ā500ā from system 10 (shown inFIGS. 2A , 3A, and 4A-4D), and by ā300ā fromlayer transfusion assembly 233. - In this embodiment,
belt 514 desirably functions as a heat capacitor for heating the 528 andlayers 3D part 522. In particular,belt 514 desirably has a high thermal conductivity and high heat capacity, as discussed below.Heater 532 as shown is a non-contact radiant heater that directs heat to opposing faces of the belt, so as to heat the belt itself along with heating an imagedpowder layer 528. As such, after being heated withheater 532,belt 514 may be the sole source of heating for the transfusion step, and niproller 520 may optionally be unheated or heated to a lower temperature (e.g., the desired average part temperature). In other embodiments, an alternative or additional heat source may be used in place ofheater 532, such as contact heat source or non-radiant heaters. - Accordingly, prior to
522,printing 3D partbuild platform 518 may be heated to its desired temperature (e.g., the average part temperature). During the printing operation, belt 514 carries imagedpowder layer 528past heater 532, which heats the imagedpowder layer 528 and the associated region ofbelt 514 to an elevated transfer temperature, such as the fusion temperature of the thermoplastic-based powder. In this embodiment, due to its higher thermal conductivity and heat capacity,belt 514 desirably continues to heat theheated layer 528 during transit to buildplatform 518. - During operation,
gantry 534 may move 518 andbuild platform 3D part 522 in a reciprocating rectangular pattern (depicted by arrows 576) in the same manner as 134, 234, 334, and 434. The continued rotation ofgantries belt 514 and the movement ofbuild platform 518 align theheated layer 528 with the top surface of3D part 522 with proper registration along the x-axis.Gantry 534 may continue to move build platform 518 (and 3D part 522) along the x-axis, at a rate that is synchronized with the rotational rate ofbelt 514 in the direction of arrow 530 (i.e., the same directions and speed). This causesrear surface 514 b ofbelt 514 to rotate around niproller 520 to nipbelt 514 and theheated layer 528 against the heated top surface of3D part 522. This engagesbuild platform 518 andbelt 514, and presses theheated layer 528 between the top surface of3D part 522 andbelt 514 at the location of niproller 520 to perform the transfusion step. - The conductive heating from
belt 514 directly heats only those areas of3D part 522 that are being fused together (i.e., the areas of3D part 522 that are in contact with theheated layer 528 orbelt 514. Additionally,belt 514 desirably conducts thermal energy to the transfused 528 andlayer 3D part 522 asbelt 514 and buildplatform 518 continue to move in the direction ofarrow 530 from niproller 520 to releaseroller 568. While not wishing to be bound by theory, it is believed that the release of thermal energy frombelt 514 to the transfused layers of3D part 522 during this step provides two functions. - First, it continues to heat the transfused layers of
3D part 522, thereby increasing the interlayer adhesion. For example, ifbelt 514 andlayer 528 are heated to a fusion temperature of about 200° C., and3D part 522 is maintained at an average part temperature of about 100° C., the initial transfusion interface temperature for transfusing the layers together starts at about 150° C. However, the continued conductance of thermal energy frombelt 514 to the transfused layers of3D part 522 while moving from niproller 520 to releaseroller 568 increases the transfusion interface temperature. This accordingly increases the extent that the polymer molecules interdiffuse to promote interfacial entanglement, pursuant to the plot line function of f(Ļr) inFIG. 1 and Equations 1-3. - Second, the conductive heat transfer, which draws heat from
belt 514 andlayer 528 into the top-most layers of3D part 522, coolsbelt 514 andlayer 528 down from the fusion temperature to a lower temperature, so that when passingrelease roller 568 the transfusedlayer 528 may remain adhered to3D part 522 and cleanly release frombelt 514. Thus, drawing heat frombelt 514 in this manner coolsbelt 514 andlayer 528 down in a similar manner to air 274 and 474, without employing the jets.jets - In particular, as the transfused
layer 528 passes the nip ofrelease roller 568,belt 514 rotates aroundrelease roller 568 to separate and disengage frombuild platform 518. This assists in releasing the transfusedlayer 528 frombelt 514, in an assisted delamination step, allowing the transfusedlayer 528 to remain adhered to3D part 522. - After release,
belt 514 may rotate back around to EP engine 12 (shown inFIG. 2A ), and may be cooled down further with additional cooling mechanisms (not shown) or via ambient cooling.Gantry 534 may actuate build platform 518 (and 3D part 522) downward, and move build platform 518 (and 3D part 522) back along the x-axis to a starting position along the x-axis, following the reciprocatingrectangular pattern 576.Build platform 518 desirably reaches the starting position for proper registration with thenext layer 528. In some embodiments,gantry 534 may also actuate 518 andbuild platform 3D part 522 upward for proper registration with thenext layer 528. The same process may then be repeated for each remaininglayer 528 of3D part 522. -
Layer transfusion assembly 533 provides a further alternative mechanism for transfusing the layers together, while also keeping theheated layers 528 cool enough for clean release frombelt 514. The separation offusion roller 520 andrelease roller 568, with a cooling or transfixing step therebetween via the thermal conductance frombelt 514 to3D part 522, allows the layers to be heated to an optimal transfusion interface temperature, and to be cooled to a temperature that transfixes thelayers 528 before release. - In some embodiments,
layer transfusion assembly 533 may also optionally include one or more pre-heaters (e.g.,heaters 270 and 272) to direct heat towards the top surface of3D part 522 prior to the transfusion step; one or more air jets (e.g.,air jets 274 and 474) to assist infurther cooling belt 514; one or more post-fuse heaters (e.g.,post-fuse heaters 382 and 482) to reheat3D part 522; and/or one or more active cooling air units (e.g., 242, 342, and 442) to assist in maintainingair jets 3D part 522 at its desired average part temperature. - However, the high thermal conductivity and heat capacity of
belt 514 allows layer transfusion assembly to selectively transfer heat only to those areas of3D part 522 that are being fused together. This conductive heating reduces the risk of melting melt small part features of3D part 522 that have been completed and are not being fused with thecurrent layer 528. This is in addition to allowing a reduced number of heating and cooling units inlayer transfusion assembly 533, thereby reducing the number of re-heating and re-cooling steps. - Examples of suitable average thermal conductivities for
belt 514 include thermal conductivities of at least about 0.12 watts/meter-Kelvin (W/m-K), with particularly suitable average thermal conductivities ranging from about 0.2 W/m-K to about 0.5 W/m-K, where the average thermal conductivities are measured pursuant to ASTM E1225-09. Furthermore, examples of suitable average heat capacities forbelt 514 include specific heat capacities of at least about 1,000 joules/(kilogram-Kelvin) (J/kg-K), with particularly suitable average heat capacities ranging from about 2,000 J/kg-K to about 3,000 J/kg-K, where the specific heat capacities are measured pursuant to ASTM E1269-11. - Examples of suitable materials for
belt 514 include polymeric and metallic materials, which may be doped with one or more conductive materials to promote the electrostatic charges. Examples of suitable polymeric materials include polyimide materials, such as those commercially available under the trade designation āKAPTONā from E.I. du Pont de Nemours and Company, Wilmington, Del. - The thermal conductivity and heat capacity of
belt 514 may alternatively be collectively referred to based on its average thermal inertia or effusivity, pursuant to Equation 5: -
I=ā{square root over (()}ĪŗĀ·ĻĀ·c)āā(Equation 5) - where āIā is the thermal inertia or effusivity with units of joules/(meter2-Kelvin-seconds0.5) (J/m2-K-s0.5), āĪŗā is the thermal conductivity of
belt 514, āĻā is the density of belt 514 (kilograms/meter3), and ācā is the specific heat capacity ofbelt 514, where the density and specific heat capacity are typically referred to together as the volumetric heat capacity. Accordingly, examples of suitable average thermal inertias forbelt 514 include thermal inertias of at least about 400 J/m2-K-s0.5, with particularly suitable average thermal inertias ranging from about 600 J/m2-K-s0.5 to about 800 J/m2-K-s0.5. - In some embodiments,
belt 514 may be also be a multi-layer belt having layers of different materials, as discussed below. In these embodiments, the above-discussed average thermal conductivities and heat capacities are based on the averages of entirety ofbelt 514, which is dependent on the materials of the different layers and the relative cross-sectional thicknesses of the different layers. -
FIG. 10 illustrateslayer transfusion assembly 633, which is an alternative to layer transfusion assembly 533 (shown inFIG. 9 ), where the reference numbers of the respective components are increased by ā600ā from system 10 (shown inFIGS. 2A , 3A, and 4A-4D), and by ā100ā fromlayer transfusion assembly 533. As shown inFIG. 10 ,layer transfusion assembly 633 also includes coolingunit 642, which is a conductive cooling unit to activelycool 3D part 622 in a similar manner to air 242, 342, and 442 to assist in maintainingjets 3D part 622 at its desired average part temperature. - However, in comparison to non-contact cooling units (e.g.,
242, 342, and 442), coolingair jets unit 642 selectively cools only the areas of3D part 622 that are in contact withcooling unit 642. In particular, coolingunit 642 may include roller 642 a and cooling belt 642 b, where cooling belt 642 b is configured to rotate around roller 642 a (and other idler and/or drive rollers), desirably at a rate that is synchronized with the movement of 618 andbuild platform 3D part 622 along the x-axis in the direction ofarrow 630. Belt 642 b itself desirably has a thermal conductivity and is cooled down (e.g., via a refrigeration unit or other cooling mechanism, not shown) to function as a heat sink. In alternative embodiments, coolingunit 642 may include any suitable mechanism for drawing thermal energy from3D part 622 via thermal conduction (e.g., a rotatable cold drum or a reciprocating cold platform). - In this embodiment, after moving
past release roller 668, the top surface of3D part 622 desirably contacts and moves along with belt 642 b for a sufficient duration to actively draw heat from3D part 622 in an active cooling step. As mentioned above, this selectively cools only the areas of3D part 622 that are in contact withcooling unit 642, rather than a global cooling of3D part 622. As can be appreciated, during each transfusion step withbelt 614, which selectively heats only those areas of3D part 622 that are being fused together, the majority of the heat drawn into3D part 622 resides at the top-most layers of3D part 622. As such, selectively drawing heat from these same areas promptly after the transfusion steps prevents the heat from diffusing into the bulk of the part, without globally cooling3D part 622. - Accordingly, the combination of
belt 614 andcooling unit 642 allowslayer transfusion assembly 633 to directly heat and cool only those areas of3D part 622 that are being fused. This may eliminate bulk heating and bulk cooling steps that potentially impart undesirable effects such as melting of small features that have been completed, or over cooling of surfaces that are still under construction. -
System 10 with 33, 133, 233, 333, 433, 533, and 633 is suitable for printing 3D parts (and any support structures) from thermoplastic-based powders at high rates and with good part resolutions. In some embodiments,layer transfusion assemblies system 10 may print layers of a 3D part at a rate of at least about 40 layers per minute (e.g., about 50 layers per minute) with accurate registration, layer thicknesses ranging from about 5 micrometers to about 125 micrometers, and layer dimensions along the y-axis up to at least about 51 centimeters (about 11 inches). For example,system 10 may print a 3D part at a rate of about three inches in height along the vertical z-axis per hour. - The resolutions of the 3D parts may also be varied based on the printing rate. For example, each 3D part may be printed at a āhigh qualityā resolution, in which
system 10 operates at a slower rate, but prints with lower layer thicknesses. Alternatively, a 3D part may be printed at a ādraft qualityā resolution, in whichsystem 10 operates a faster rate, but prints with greater layer thicknesses. Furthermore, a 3D part may be printed in āgray scaleā, in which a lower density of the part material is developed or otherwise imaged. Numerous resolutions and speeds therebetween may also be incorporated. In each of these situations, the controller may adjust the applied pressures, temperatures, and/or contact durations during the transfusion steps to account for the different printing rates. -
System 10 is illustrated as being configured to print 3D parts (e.g., 22, 122, 222, 322, 422, 522, and 622) from a single thermoplastic-based powder. However, the additive manufacturing systems of the present disclosure may also be configured to print 3D parts and/or support structures from multiple part materials and/or support materials derived from thermoplastic-based powders (e.g., multiple compositions and/or colors). Examples of suitable multiple-material systems include those disclosed in U.S. patent application Ser. Nos. 13/242,669 and 13/242,841.3D parts - In some embodiments,
controller 24 may monitor the applied pressure, the temperature of the layers, part heights, and the contact durations during the transfusion steps to maximize or otherwise increase the effectiveness in transferring the layers from the front surface of the transfer belt to the build platform. In an open-loop embodiment, one or more of the applied pressure, temperature, and contact durations may be fixed parameters for a given part material and overall printing rate. For example, in embodiments in which the 3D part 22 (and any associated support structure) is printed with partially porous structures, the part height may be self compensated in an open-loop manner where a spring action of the transfer roller may function as a mechanical proportional control system. - If the printed layers begin to fall behind in height relative to the ideal nip height, the nip compression is reduced, which reduces the transfer pressures and the layers may not be fully compressed. The resulting material would be slightly porous and have a resulting larger layer thickness. Alternatively, if the height of the printed layers grows too large, the nip compression is increased, which increases the transfer pressures and the layers would be more compressed. The resulting material would be less porous and have a resulting smaller layer thickness.
- More preferably, in a closed-loop embodiment,
controller 24 may adjust one or more parameters in response to the monitored signals using one or more process control loops. For example, as shown inFIG. 11A ,layer transfusion assembly 33 may include one or more temperature sensors 784 t and/or one ormore height sensors 784 hp and 784 hs, each configured to communicate withcontroller 24. While illustrated in use withlayer transfusion assembly 33, sensors 784 t and 784 h are equally suitable for use with 133, 233, 333, 433, 533, and 633.layer transfusion assemblies - Temperature sensors 784 t are configured to monitor the temperature of
3D part 22 and/or the associated support structure (referred to assupport structure 22 s). Examples of suitable temperature sensors for temperature sensors 784 t include non-contact sensors, such as infrared pyrometers, which may communicate withcontroller 24 to transmit signals relating to the monitored temperatures. Alternative temperature sensors may include ultrasonic transducers for measuring the part temperatures using acoustic thermometry. - Based on the received signals of the monitored temperatures,
controller 24 may adjust one or more parameters ofsystem 10 to maintain3D part 22/support structure 22 s at a desired temperature (e.g., at its desired average part temperature). For example,controller 24 may adjust operations of one or more of the heating components of system 10 (e.g., heaters, rollers, platforms) and/or one or more of the active cooling mechanisms of system 10 (e.g., cooling air jets). In some aspects,controller 24 may adjust the temperatures and contact durations during the transfusion steps to compensate for changes in the temperatures of layers and/or fluctuations in the monitored applied pressures. - Alternatively, and more preferably, the heating components of system 10 (e.g., heaters, rollers, platforms) may be maintained at set point temperatures, and
controller 24 may adjust operations of one or more of the active cooling mechanisms of system 10 (e.g., cooling air knives and air jets). In particular, the cooling air flow may be adjusted using commercial flow control valves based on feedback from the temperature sensors 784 t to substantially maintain3D part 22 at the intended average part temperature. - As further shown in
FIG. 11A , the layers of3D part 22 may be laterally encased by the layers ofsupport structure 22 s. In these embodiments, temperature sensors 784 t may be configured to monitor the temperatures of3D part 22 andsupport structure 22 s independently of each other (e.g., with different temperature sensors 784 t) or together. In some aspects, the thermoplastic-based powder forsupport structure 22 s may have a higher glass transition temperature and/or a higher creep relaxation temperature compared to that of the thermoplastic-based powder of3D part 22. As such, the layers of3D part 22 may conform to the dimensions ofsupport structure 22 s during the printing operation. -
Height sensors 784 hp and 784 hs are respectively configured to monitor the heights of3D part 22 andsupport structure 22 s during the printing operation. Examples of suitable height sensors forheight sensors 784 hp and 784 hs include non-contact sensors (e.g., laser height sensors), which may communicate withcontroller 24 to transmit signals relating to the independently monitored heights. - Maintaining an intended part height during the printing operation is beneficial for good part accuracy, and also controls the amount of nip compression at the transfer rollers, which have small working nip interference ranges (e.g., from about 0.002 inches to about 0.012 inches). Accordingly, in some aspects,
controller 24 may adjust the pressure applied bypress plate 20 or build 118, 218, 318, 418, 518, and 618 in response to changes in a monitored nip pressure.platforms - However, this can present issues when printing with part and support materials at the same time. If the printed
3D part 22 is too high relative to the printedsupport structure 22 s, the transfer roller pressure will be high due to thehigher 3D part 22 and completely mask any feedback from the lower height ofsupport structure 22 s. As such, the use ofseparate height sensors 784 hp and 784 hs allowscontroller 24 to compensate for height variations in each of3D part 22 andsupport structure 22 s, as well as when using multiple part materials and/or multiple support materials. - Due to the variety of 3D part and support structure geometries that
system 10 can print, the cross-sectional locations of3D part 22 andsupport structure 22 s may vary in location in the x-y build plane. This can present issues forheight sensors 784 hp and 784 hs that have fixed measurement locations. For instance, in a first printingoperation support structure 22 s may be positioned belowheight sensor 784 hs. in asubsequent printing 22 may be positioned belowoperation 3D partheight sensor 784 hs, and in another printing operation neither3D part 22 norsupport structure 22 s may be positioned belowheight sensor 784 hs. - As such, as shown in
FIG. 11B , in some embodiments,system 10 may print layers ofpart column 22 pc andsupport column 22 sc along with the layers of3D part 22 andsupport structure 22 s, wherepart column 22 pc may be positioned belowheight sensor 784 hp, andsupport column 22 sc may be positioned belowheight sensor 784 hs. This allowsheight sensors 784 hp and 784 hs to independently measure the heights of3D part 22 andsupport structure 22 s, and allowcontroller 24 to direct height compensation protocols based on the feedback fromheight sensors 784 hp and 784 hs. - Height compensation for each of
3D part 22 andsupport structure 24 can be accomplished, for example, by adjusting bias voltage at the imager (e.g., EP engine 12), and by adjusting light-emitting diode (LED) discharge on any organic photo conductor in the part or support material to affect its mass density. - As shown in
FIG. 11C , in some embodiments, asingle height sensor 784 may be configured to map the entire surface of3D part 22 andsupport structure 22 s in a two-dimensional image, allowingcontroller 24 to direct height compensation protocols regardless of the geometries of3D part 22 andsupport structure 22 s. Examples of suitable height sensors for this embodiment include scanning laser line sensors. - Moreover, this two-dimensional image data allows
controller 24 to account for height changes in the lateral directions along the y-axis well as in the process directions along the x-axis by adjusting the intensity of the LED pixel or grayscale across the light bar in EP engine 12 (for the lateral directions) or in time (for the process directions). In further embodiments, theheight sensor 784 may be configured to also measure layer thickness of eachlayer 28 onbelt 14 prior to the transfusion step. - As shown in
FIG. 12 , in some embodiments,system 10 may also include achamber 785, which can extend aroundlayer transfusion assembly 33, and may define an enclosable environment for printing3D part 22. While illustrated in use withlayer transfusion assembly 33,chamber 785 is equally suitable for use with 133, 233, 333, 433, 533, and 633.layer transfusion assemblies Chamber 785 is a temperature-controllable chamber, which provides greater control over the active cooling step. For example,chamber 785 may be maintained at the average part temperature of 3D part 22 (e.g., about 100° C. for an ABS copolymer). - In these embodiments,
chamber 785 may partially enclose z-axis gantry 34 andbelt 14, allowing z-axis gantry 34 andbelt 14 to extend through the walls ofchamber 785. In some embodiments, deformable baffles may be incorporated to maintain a thermal barrier. In alternative embodiments,heater 32 may be located outside and upstream ofchamber 784. In further alternative embodiments,chamber 785 may be located belowpress plate 20, allowingbuild platform 18 to be lowered down intochamber 785. These embodiments further assist in maintaining3D part 22 at an average part temperature that is below its deformation temperature, as illustrated above in Equation 4. - As further shown in
FIG. 11 , 33, 133, 233, 333, 433, 533, or 633 may also include pressure sensors (e.g., pressure sensor 786) and/or capacitive or resistive sensors (e.g., capacitive sensor 788), each of which is configured to communicate withlayer transfusion assembly controller 24 over one or more communication lines (not shown).Pressure sensor 786 is one or more sensor assemblies configured to measure the transfusion pressure applied betweenbuild platform 18 and press plate 20 (or betweenbuild platforms 118/218/318/418 androllers 120/220/320/420), allowingcontroller 24 to monitor the applied transfusion pressure and adjust the height ofbuild platform 18 and/orpress plate 20 using one or more process control loops. Examples of suitable sensor assemblies forpressure sensor 786 include one or more strain gauges retained onbuild platform 18 and/orpress plate 20. - Capacitive or
resistive sensor 788 is one or more capacitive/resistive sensor assemblies configured to measure the electrical resistance betweenbuild platform 18 and press plate 20 (or betweenbuild platforms 118/218/318/418/518/618 androllers 120/220/320/420/520/620). For example, during a transfusion step,capacitive sensor 788 may induce an electrical current from platen 18 to press plate 20 (or vice versa), and measure the intensity of the resulting electrical current through the printedlayers 28 of3D part 22 andbelt 14. Since the thickness ofbelt 14 is constant, the resulting electrical current will reduce as the3D part 22 grows through the printing ofsuccessive layers 28. - Thus,
capacitive sensor 788 is also suitable for monitoring the height of3D part 22 and the number oflayers 28 transferred to buildplatform 18. This allowscontroller 24 to accurately predict the applied pressure during a subsequent pressing step rather than merely relying on the calculated height of a single layer increment. This accurate prediction allowsbuild platform 18 to be quickly raised to an intended height, rather than relying solely on feedback signals frompressure sensor 786. Build 18, 118, 218, 318, 418, 518, and 618,platforms press plate 20, and 120, 220, 320, 420, 520, and 620 may each also include one or more temperature sensors (not shown) configured to respectively measure the temperatures of the build platforms and press plate/rollers, allowingrollers controller 24 to hold them at the above-discussed temperatures. - In some embodiments,
controller 24 and/orhost computer 26 may receive operational mode selections for operatingsystem 10 in different modes. For example, a user may select operational modes such as high quality printing, draft quality printing, and gray scale, as discussed above. Alternatively,system 10 may receive the operational mode selections as default or system generated modes (e.g., a default of a high quality printing). These received operational mode selections may alternatively (or additionally) be set based on the geometry of the 3D part, such as if the 3D part has a small cross-sectional area and/or fine-feature details, as discussed above. - Upon receipt of these operational mode selections,
controller 24 and/orhost computer 26 may set transfusion parameters for performing the transfusion steps, based on the received operational mode selections. For example, the transfusion pressure, temperature(s), and or duration for each transfusion step may be set or adjusted based on the received operational mode select. This provides greater control over the transfusion steps when operatingsystem 10 to improve printing accuracies and/or printing rates. -
System 10 may then image a powder layer of the 3D part from a thermoplastic-based powder (e.g., develop a powder layer with EP engine 12), transfer the imaged powder layer to a transfer medium, heat the imaged powder layer while the imaged layer is retained on the transfer medium, and transfuse the heated layer to a surface of the three-dimensional part based on the set transfusion parameters. - In some embodiments, the set transfusion parameters allow the transfusion pressure, temperature(s), and or duration for each transfusion steps to vary between different transfusion steps. For example, if a first portion of a 3D part contains a simple block geometry and a second portion of the 3D part contains a fine-feature geometry,
controller 24 and/orhost computer 26 may set the transfusion parameters such that the layers used to form the simple block geometry are transfused differently (e.g., higher transfusion pressure) from those used to form the fine-feature geometry (e.g., lower transfusion pressure). - FIGS. 13 and 14A-14C illustrate a suitable embodiment for belt 14 (shown in
FIGS. 2A , 3A, and 4A-4D), and is equally suitable for belt 114 (shown inFIGS. 5A-5E ), belt 214 (shown inFIGS. 6A-6F ), belt 314 (shown inFIG. 7 ), belt 414 (shown inFIG. 8 ), belt 514 (shown inFIG. 9 ), and belt 614 (shown inFIG. 10 ). In the embodiment shown inFIG. 13 ,belt 14 is a multiple-layer belt that includes layer or film 790 (definingfront surface 14 a) and base portion 792 (definingrear surface 14 b). -
Film 790 andbase portion 792 are desirably derived from materials that are suitable for transferring thelayers 28 of part (or support) materials fromEP engine 12 to buildplatform 18, that are thermally stable at the fusion temperatures T(f) of the part and support materials, and that are robust for continued operation at high rotational speeds while being repeatedly heated and cooled during the heating and active cooling steps. Furthermore, for use as 514 and 614,belts film 790 and/orbase portion 792 also desirably have high thermal conductivities and heat capacities for selectively heating the 3D parts. -
Film 790 has afilm thickness 790 t, and is derived from one or more low-surface energy materials, thereby allowing the received layers 28 to effectively release fromfront surface 14 a to buildplatform 18. Examples of suitable materials forfilm 790 include one or more fluorinated polymers, such as polytetrafluoroethylenes (PTFE), fluorinated ethylene propylenes, and perfluoroalkoxy polymers. Examples of suitable commercially available fluorinated polymers include PTFE available under the trade designation āTEFLONā from E.I. du Pont de Nemours and Company, Wilmington, Del. -
Base portion 792 has a thickness 792 t, and is derived from one or more materials that promote good electrostatic attraction for the thermoplastic-based powders tofront surface 14 a via electrostatic charges. Examples of suitable materials forbase portion 792 include one or more polyimide materials, such as those commercially available under the trade designation āKAPTONā from E.I. du Pont de Nemours and Company, Wilmington, Del., which may be doped with one or more conductive materials to promote the electrostatic charges. In some embodiments,belt 14 may also include one or more additional layers betweenfilm 790 andbase portion 792, such as one or more tie layers. - For use as
514 and 614, examples of suitable materials forbelts base portion 792 include those discussed above for 514 and 614. In these embodiments,belts base portion 792 may constitute the bulk ofbelt 14, where thickness 792 t is substantially greater thanfilm thickness 790 t. This allowsfilm 790 to be derived from a low-surface energy material that may have a lower thermal conductivity and/or heat capacity, while still retaining an overall high thermal conductivity and high heat capacity. -
FIGS. 13A-13C illustrate alternative embodiments forbelt 14 for engaging with various drive rollers ofsystem 10. As shown inFIG. 14A ,front surface 14 a ofbelt 14 may include receivingregion 794 andedge regions 796 on opposing lateral sides of receivingregion 794. Receivingregion 794 is the region offront surface 14 a on which layers 28 are retained for transfer betweenEP engine 12 and buildplatform 18.Edges regions 796 are the regions at which one or more drive mechanisms may engagedrive belt 14. - For example, one or more rollers (e.g.,
rollers 16, niproller 120,fusion roller 220,release roller 268, niproller 320,fusion roller 420,release roller 468, niproller 520,release roller 568, niproller 620,release roller 668, and/or any service-loop roller) may engagefront surface 14 a and/orrear surface 14 b atedge regions 796 to ensure the rollers to not interfere with the imaged layers 28. In some embodiments, pairs of opposing rollers (not shown) may simultaneously engagefront surface 14 a andrear surface 14 b atedge regions 796 to nip anddrive belt 14 in the direction ofarrow 30. - Registration along the x-axis may be maintained with the use of
encoder markings 798.Encoder markings 798 may be pre-marked onfront surface 14 a and/orrear surface 14 b at preset increments along the x-axis, or may be printed with the imaged layers 28 to identify relative locations of the imaged layers 28 along the x-axis.System 10 may also include one or more optical readers (e.g., optical reader 800) to locateencoder markings 798 asbelt 14 rotates in the direction ofarrow 30. - Alternatively, as shown in
FIG. 14B ,belt 14 may include an array ofholes 802 or other openings that extend throughfilm 790 andbase portion 792 adjacent to the lateral edges ofbelt 14.Holes 802 are configured to engage with gear teeth (not shown) of one or more rollers (e.g.,rollers 16, niproller 120,fusion roller 220,release roller 268, niproller 320,fusion roller 420,release roller 468, niproller 520,release roller 568, niproller 620,release roller 668, and/or any service-loop roller) to drivebelt 14 in a tractor-feed manner. In this embodiment, registration along the x-axis may also be maintained with the use ofencoder markings 798, if desired. Alternatively, holes 802 may themselves function as encoder markings in the same manner.System 10 may also include one or more optical readers (e.g., optical reader 799) to locateencoder markings 798 and/orholes 802 asbelt 14 rotates in the direction ofarrow 30. -
FIG. 14C shows yet another alternative embodiment in whichbelt 14 includesrear ribs 804 that extend laterally alongrear surface 14 b.Ribs 804 are configured to engage with reciprocating gear teeth (not shown) of one or more rollers (e.g.,rollers 16, niproller 120,fusion roller 220,release roller 268, niproller 320,fusion roller 420,release roller 468, niproller 520,release roller 568, niproller 620,release roller 668, and/or any service-loop roller) to drivebelt 14 in a timing-belt manner. In this embodiment, registration along the x-axis may also be maintained with the use of encoder markings corresponding to encodermarkings 798, if desired. Alternatively,ribs 804 may themselves function as encoder markings in the same manner.System 10 may also include one or more optical readers (e.g., optical reader 800) to locate the encoder markings and/or holes ribs asbelt 14 rotates in the direction ofarrow 30. -
FIGS. 14A-14C illustrate example engagement mechanisms forbelt 14, allowingbelt 14 to engage with one or more drive mechanisms ofsystem 10. However,belt 14 may alternatively include different engagement mechanisms as particular designs may require. -
FIG. 15 is a flow diagram ofmethod 810, which is an example method for the layer transfer technique of the present disclosure, and may be performed withsystem 10 having 33, 133, 233, 333, 433, 533, and 633. As shown,layer transfusion assemblies method 810 includes step 812-826, where 818, 820 a, 820 b, 824, and 826 are optional steps depending on the particular embodied layer transfusion assembly utilized (e.g.,steps 33, 133, 233, 333, 433, 533, and 633).layer transfusion assemblies -
Method 810 initially involves developing or otherwise imaging a powder layer (step 812), such as withEP engine 12. The imaged powder layer may then be transferred on a transfer medium from a first location atEP engine 12 to a second location at the layer transfusion assembly (e.g., 33, 133, 233, 333, 433, 533, and 633) (step 814). Prior to reaching the second location at the layer transfusion assembly, the powder layer is heated to a transfer temperature, such as the fusion temperature of the thermoplastic-based powder (e.g., atlayer transfusion assemblies 32, 132, 232, 332, 432, 532, and 632) (step 816).heaters - In some embodiments, the top surface or layer(s) of the 3D part may also be pre-heated prior to the transfusion/transfixing steps (step 818). For example, with
layer transfusion assembly 233, 270 and 272 may heat the top surface or layer(s) ofheaters 3D part 222 to the fusion temperature of the thermoplastic-based powder, or other suitable transfer temperature. Becauselayer 228 and the heated top surface/layer of3D part 222 can each be heated to the fusion temperature of the thermoplastic-based powder, the pressedheated layer 228 transfuses to the heated top surface/layer of3D part 222 with a high level of interlayer adhesion (during transfusion step 520). - If the particular embodiment does not incorporate heating of the top surface or layer(s) of the 3D part, the heated layer may then be directly transfused and transfixed with the layer transfusion assembly, as illustrated by
arrow 828. Upon reaching the layer transfusion assembly, after either step 816 or step 818, the heated layer may then be transfused and transfixed (step 820). - In some embodiments, such as for
33, 133, and 333, the transfusion and transfixing may be performed in a single step. For example, forlayer transfusion assemblies layer transfusion assembly 33,press plate 20 may engagebuild platform 18 to transfuse theheated layer 28 to the top surface of3D part 22. Becausepress plate 20 may be heated to a temperature that is lower than the fusion temperature, the contact betweenpress plate 20 andrear surface 14 b ofbelt 14 cools down the interface betweenbelt 14 and the transfusedlayer 28, increasing the adhesive force of the interdiffused polymers in the transfused 28 andlayer 3D part 22 relative to the adhesive force of the transfusedlayer 28 to surface 14 a ofbelt 14, thereby maintaining the transfused layer adhered to the 3D part in a fixed spatial position. - The transfused and transfixed layer may then be released from the transfer medium (step 822), such as by retracting
press plate 20 and/or buildplatform 18, or by the separation ofbelts 114/333 frombuild platforms 118/318 bybelts 114/318 winding around niprollers 120/320. The transfixing step discussed above allows the transfused layer to cleanly release from the transfer medium and remain adhered to the 3D part. - Alternatively, such as for
233,433, 533, and 633, instead of a combined transfusion and transfixinglayer transfusion assemblies step 820, method 510 may include atransfusion step 820 a and transfixingstep 820 b, which are separate. For example,layer transfusion assembly 233 includes a heated fusion roller 220 (fortransfusion step 820 a) and release roller 268 (for release step 822), which are separated by air jets 274 (for a cooling or transfixingstep 820 b). Correspondingly, 514 and 614, which have high thermal conductivities and heat capacities, may be utilized instead of (or in addition to)belts air jets 274 for the cooling or transfixingstep 820 b. - This allows the layers to be heated to an optimal transfusion interface temperature at the heating steps 816 and/or 818, and during the
transfusion step 820 a, and then to be cooled to a temperature that fixes the layers (at transfixingstep 820 b) before release atrelease step 822. This substantially increases the extent to which the polymer molecules of the transfused layers interdiffuse to promote interfacial entanglement, while also maintaining dimensional accuracy of the 3D part. - Moreover, the release of the transfused layer from the transfer medium may be assisted during the
release step 822. For example,release roller 268 may assist in releasing transfusedlayer 228 frombelt 214 by increasing the angle of separation betweenbelt 214 and buildplatform 218, which increases the ease at which transfusedlayer 228 delaminates frombelt 214. - After release, the 3D part may then optionally (depending on the particular embodiment) undergo one or more post-fuse or heat-setting steps (step 824), such as discussed above for layer transfusion assembly 333 (shown in
FIG. 7 ) and layer transfusion assembly 433 (shown inFIG. 8 ). At heat-settingstep 824, the 3D part may be heated to at least the fusion temperature of the thermoplastic-based powder, such as with 382 and 482. This sufficiently melts the material of the transfused layer to a fusable state such that polymer molecules of the transfused layer further interdiffuse to promote interfacial entanglement with 3D part.post-fuse heaters - The 3D part may then be actively cooled (e.g., with
air knives 42 and 142, 242, 342, 442, or other convective and/or conductive cooling units, such as cooling unit 642) (step 826). As discussed above, because the imaging system (e.g., system 10) is capable of printing the layers at speeds that are much faster than the rate at which heat diffuses through the variable thermal resistance of the 3D parts, heat can accumulate in the 3D parts, which, if not accounted for, can exceed a deformation temperature of the 3D part, causing the bulk of the 3D part to soften enough reduces its structural integrity. Such a soft part may deform under a subsequently-applied transfusion pressure during a subsequent transfusion step.air jets - To overcome this issue while maintaining fast printing rates, the 3D part may be actively cooled between each
transfusion step 818 to maintain the 3D part at an average part temperature that is lower than the deformation temperature of the 3D part. In some embodiments, theactive cooling step 826 may also be an optional step ofmethod 810. For example,system 10 may instead operate at a lower printing speed to allow heat to diffuse from the 3D part. However, as discussed above, theactive cooling step 826 is desirable for maintaining the structural integrity of the 3D part while printing at high speeds. - Steps 812-826 may then be repeated for each layer of the 3D part until the printing operation is completed (as indicated by arrow 830). By heating each layer to at least the fusion temperature of the thermoplastic-based powder, followed by transfusing, transfixing, and optional active cooling allows
system 10 to print 3D parts with good part quality and strengths (e.g., z-strengths). - The present disclosure is more particularly described in the following examples that are intended as illustrations only, since numerous modifications and variations within the scope of the present disclosure will be apparent to those skilled in the art.
- For the printing operations of Example 1, 3D parts were printed with an additive manufacturing system corresponding to the system shown in
FIGS. 1 , 2, and 4A-4D, having a moveable press plate and a vertically-actuatable build platform, each of which were heated. The 3D parts were printed from an ABS part material, where each layer was developed with an electrophotography engine and transferred to a rotatable transfer belt looped around a service loop design. The developed layer was carried by the transfer belt to an infrared heater to heat the layer to a fusion temperature of ABS part material. - The heated layer was then transferred to and aligned over the build platform. The press plate was actuated downward to transfuse the heated layer against a previously-transfused layer of the 3D part (or to the build platform for the initial layer). The press plate was then retracted, which cleanly delaminated the layer from the transfer belt, allowing the layer to remain transfused to the 3D part.
- Cooling air from an air knife was also directed to the top layers of the 3D part. This removed the additional heat from the transfused layer to provide an average part temperature of that maintained the structural integrity of the 3D part, where the 3D part did not slump or melt due to heat accumulation. This process was repeated for each layer of the 3D part. The air knife and the press plate successfully maintained the average part temperature below the deformation temperature of the 3D part during the entire printing operation. The resulting 3D parts exhibited good part resolution, dense fill, and good dimensional integrity.
- For the printing operations of Example 2, 3D parts were printed with an additive manufacturing system corresponding to
system 10 having alayer transfusion assembly 333 as shown inFIG. 7 (without pre-heaters 370 or 372), and as further depicted inFIG. 16 (using the same reference numbers as forsystem 10 and layer transfusion assembly 333). As shown inFIG. 16 , thesystem 10 included twoEP engines 12, abelt 314, twobelt drive mechanisms 16 a, threebelt drag mechanisms 16 b, threeloop limit sensors 16 c,idler rollers 16 d, belt cleaner 16 e, andlayer transfusion assembly 333. -
Belt drive mechanisms 16 a,belt drag mechanisms 16 b,loop limit sensors 16 c,idler rollers 16 d, and belt cleaner 16 e maintained tension onbelt 314 whilebelt 314 rotated in the rotational direction ofarrows 330. In particular,belt drive mechanisms 16 a engaged and drove belt, andbelt drag mechanisms 16 b functioned as brakes to provide a service loop design for protectingbelt 314 against tension stress, based on monitored readings vialoop limit sensors 16 c. - The 3D parts were printed from an ABS part material, where each layer was developed with an
EP engine 12 and transferred to belt 314 looped in the service loop design. The developed layer was carried bybelt 314 to aninfrared heater 332 to heat the layer andbelt 314 to a fusion temperature of the ABS part material. - The heated layer was then transferred to and aligned over the build platform 318 (not shown in
FIG. 16 ). The build platform 315 was actuated upward by gantry 934 to transfuse the heated layer against a previously-transfused layer of the 3D part (or to thebuild platform 318 for the initial layer). In particular, actuating thebuild platform 318 upward pressed the heated layer and transfer belt between the build platform 318 (or against a previously-transfused layer of the 3D part) and thenip roller 320. Thebuild platform 318 was then moved at a synchronized rate withbelt 314, and then released at a downstream location. This cleanly delaminated the layer from the transfer belt, allowing the layer to remain transfused to the 3D part. - The 3D part was then re-heated with post-fuse
infrared heater 382 to further increase adhesion of the transfused layers. Cooling air fromair jets 342 was also directed to the top layers of the 3D part. This removed the additional heat from the transfused layers to provide an average part temperature of that maintained the structural integrity of the 3D part, where the 3D part did not slump or melt due to heat accumulation. Thebuild platform 318 was then moved back to its starting position via gantry 934, and the process was repeated for each layer of the 3D part. In these Examples, theair jets 342 successfully maintained the average part temperature below the deformation temperature of the 3D part during the entire printing operation. The resulting 3D parts also exhibited good part resolution, dense fill, and good dimensional integrity. - For the printing operations of Comparative Examples A and B, 3D parts were printed with the same additive manufacturing systems respectively used for Examples 1 and 2. However, for Comparative Examples A and B, the air knife or jet cooling was omitted. Otherwise, the processes were performed in the same manner as discussed above for Examples 1 and 2.
- For the printing operations of Comparative Examples A and B, prior to the completion of each printed 3D part, the printed layers began to compress and flatten. As discussed above, this is believed to be due to heat accumulating in the printed layers, which was unable to diffuse sufficiently between each printed layer. The accumulated heat softened the bulk of the 3D part, causing it to compress during subsequent transfusion steps. This resulted in deformed 3D parts.
- As such, the layer transfer technique of the present disclosure including the active cooling is beneficial for printing 3D parts at high rates using electrophotography. The active cooling was successfully implemented to remove the added heat from each fused layer prior to the transfusion of the next layer. This allowed the 3D parts printed with the systems in Examples 1 and 2 to be maintained at average part temperatures below their deformation temperatures, but high enough to promote good interlayer adhesion and reduced curl.
- Although the present disclosure has been described with reference to preferred embodiments, workers skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the disclosure.
Claims (20)
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| US13/624,519 US9720363B2 (en) | 2011-09-23 | 2012-09-21 | Layer transfusion with rotatable belt for additive manufacturing |
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Cited By (138)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104504190A (en) * | 2014-12-17 | 2015-04-08 | å±ē¦å®äøļ¼ę±éØļ¼č“µéå±ęéå ¬åø | 3D printing method and device |
| WO2015081009A1 (en) | 2013-11-27 | 2015-06-04 | Stratasys, Inc. | Method for printing three-dimensional parts wtih crystallization kinetics control |
| US20150183166A1 (en) * | 2012-09-05 | 2015-07-02 | Aprecia Pharmaceuticals Company | Three-dimensional Printing System and Equipment Assembly |
| CN104827155A (en) * | 2015-05-22 | 2015-08-12 | åäøē§ęå¤§å¦ | Solidifying and melting composite material increase forming method suitable for complex parts |
| WO2015142495A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys. Inc. | Electrophotography-based additive manufacturing with solvent-assisted planarization |
| WO2015142493A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Eletrophotography-based additive manufacturing with pre-sintering |
| WO2015142492A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Additive manufacturing with virtual planarization control |
| WO2015142494A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Eletrophotography-based additive manufacturing with powder density detection and utilization |
| WO2015153030A1 (en) | 2014-04-01 | 2015-10-08 | Stratasys, Inc. | Electrophotography-based additive manufacturing with overlay control |
| WO2015175682A1 (en) | 2014-05-16 | 2015-11-19 | Stratasys, Inc. | High-temperature soluble support material for additive manufacturing |
| CN105150537A (en) * | 2015-09-24 | 2015-12-16 | 蓵å·ēæ°åÆęÆęŗč½ęęÆęéå ¬åø | Intelligent manufacturing system consisting of 3D printing device and mechanical arms |
| US20160059308A1 (en) * | 2014-08-28 | 2016-03-03 | Incodema3D, LLC | Additive manufacturing device |
| WO2016073409A1 (en) | 2014-11-04 | 2016-05-12 | Stratasys, Inc. | Break-away support material for additive manufacturing |
| US20160129528A1 (en) * | 2014-11-11 | 2016-05-12 | DMG Mori USA | Machine tool system and method for additive manufacturing |
| WO2016084367A1 (en) * | 2014-11-28 | 2016-06-02 | Canon Kabushiki Kaisha | Three-dimensional shaping apparatus and three-dimensional shaped article manufacturing method |
| WO2016084351A1 (en) * | 2014-11-28 | 2016-06-02 | Canon Kabushiki Kaisha | Method and apparatus for forming stereoscopic object |
| CN105904732A (en) * | 2016-05-26 | 2016-08-31 | ę¹ę½å¤§å¦ | Guiding device and implementation method for fiber orientation in selective laser sintering of fiber composite powder |
| WO2016184994A1 (en) * | 2015-05-19 | 2016-11-24 | Addifab Aps | Apparatus and method for release of additively manufactured products and build platform |
| US9523934B2 (en) | 2013-07-17 | 2016-12-20 | Stratasys, Inc. | Engineering-grade consumable materials for electrophotography-based additive manufacturing |
| WO2016205690A1 (en) | 2015-06-19 | 2016-12-22 | Stratasys, Inc. | Water dispersible polymer for use in additive manufacturing |
| US20170028629A1 (en) * | 2015-07-29 | 2017-02-02 | Canon Kabushiki Kaisha | Shaping apparatus and shaping method |
| US9592660B2 (en) * | 2014-12-17 | 2017-03-14 | Arevo Inc. | Heated build platform and system for three dimensional printing methods |
| WO2017015217A3 (en) * | 2015-07-20 | 2017-03-16 | Velo3D, Inc. | Transfer of particulate material |
| US20170106590A1 (en) * | 2015-10-19 | 2017-04-20 | Mimaki Engineering Co., Ltd. | Shaping apparatus and shaping method |
| WO2017063640A3 (en) * | 2015-10-13 | 2017-06-08 | M & R Beteiligungsgesellschaft mbH | Method and device for producing a workpiece |
| WO2017098968A1 (en) * | 2015-12-10 | 2017-06-15 | Canon Kabushiki Kaisha | Shaping apparatus |
| US20170173696A1 (en) * | 2014-05-08 | 2017-06-22 | Stratasys Ltd. | Method and apparatus for 3d printing by selective sintering |
| WO2017112687A1 (en) | 2015-12-24 | 2017-06-29 | Stratasys, Inc. | Water soluble support material for high temperature additive manufacturing applications |
| WO2017112689A1 (en) | 2015-12-24 | 2017-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| US20170192377A1 (en) * | 2015-12-31 | 2017-07-06 | Stratasys, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts |
| US9744730B2 (en) | 2013-11-22 | 2017-08-29 | Stratasys, Inc. | Magnetic platen assembly for additive manufacturing system |
| WO2017147412A1 (en) | 2016-02-25 | 2017-08-31 | Stratasys Ltd. | Gpu material assignment for 3d printing using 3d distance fields |
| US9785064B2 (en) | 2013-07-17 | 2017-10-10 | Stratasys, Inc. | Semi-crystalline consumable materials for electrophotography-based additive manufacturing system |
| CN107336439A (en) * | 2016-04-28 | 2017-11-10 | ę½ä¹å ¬åø | The D printers of mixing electrostatic 3 being fixed using laser |
| CN107364123A (en) * | 2016-05-12 | 2017-11-21 | ę½ä¹å ¬åø | The D printers of electrostatic 3 being crosslinked using addressable UV |
| KR20170128082A (en) * | 2016-05-12 | 2017-11-22 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | 3-d printing using intermediate transfer belt and curable polymers |
| US9833944B1 (en) * | 2014-05-23 | 2017-12-05 | Robert Wayne Huthmaker | Printer plates for three dimensional printing |
| US20170348909A1 (en) * | 2016-06-07 | 2017-12-07 | Xerox Corporation | Electrostatic 3-d printer using layer and mechanical planer |
| CN107457987A (en) * | 2016-06-06 | 2017-12-12 | ę½ä¹å ¬åø | Use the D printers of electrostatic 3 of aerosol applicator key-course pattern |
| US9919479B2 (en) | 2014-04-01 | 2018-03-20 | Stratasys, Inc. | Registration and overlay error correction of electrophotographically formed elements in an additive manufacturing system |
| US9925714B2 (en) | 2012-11-21 | 2018-03-27 | Stratasys, Inc. | Method for printing three-dimensional items wtih semi-crystalline build materials |
| US20180126649A1 (en) | 2016-11-07 | 2018-05-10 | Velo3D, Inc. | Gas flow in three-dimensional printing |
| US10000010B2 (en) * | 2016-06-29 | 2018-06-19 | Xerox Corporation | 3-D electrostatic printer using rack and pinion registration system |
| US10005230B2 (en) * | 2016-05-10 | 2018-06-26 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to transfer device |
| US10005228B2 (en) | 2016-05-10 | 2018-06-26 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to exposure device |
| US10011071B2 (en) | 2014-03-18 | 2018-07-03 | Evolve Additive Solutions, Inc. | Additive manufacturing using density feedback control |
| US10023739B2 (en) | 2012-11-21 | 2018-07-17 | Stratasys, Inc. | Semi-crystalline build materials |
| US10040250B2 (en) * | 2016-04-14 | 2018-08-07 | Xerox Corporation | Electro-photographic 3-D printing using collapsible substrate |
| US10046512B2 (en) * | 2016-04-14 | 2018-08-14 | Xerox Corporation | Electro-photographic 3-D printing using dissolvable paper |
| US10058920B2 (en) | 2015-12-10 | 2018-08-28 | Velo3D, Inc. | Skillful three-dimensional printing |
| US10076869B2 (en) | 2016-06-07 | 2018-09-18 | Xerox Corporation | Electrostatic 3-D printer using leveling material and mechanical planer |
| US10086558B2 (en) * | 2016-06-29 | 2018-10-02 | Xerox Corporation | 3-D electrostatic printer using track bound platens and registration system |
| US10105902B2 (en) | 2016-04-18 | 2018-10-23 | Evolve Additive Solutions, Inc. | Electrophotography-based additive manufacturing with part molding |
| US10112379B2 (en) | 2016-01-25 | 2018-10-30 | Eastman Kodak Company | Large format electrophotographic 3D printer |
| US10144828B2 (en) | 2012-11-21 | 2018-12-04 | Stratasys, Inc. | Semi-crystalline build materials |
| US10144176B1 (en) | 2018-01-15 | 2018-12-04 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| WO2018236859A1 (en) | 2017-06-22 | 2018-12-27 | Evolve Additive Solutions, Inc. | ADDITIVE FABRICATION BASED ON ELECTROPHOTOGRAPHY USING A SUPPORT STRUCTURE AND REMOVING SUPPORT STRUCTURE |
| EP3388221A3 (en) * | 2017-03-24 | 2019-01-09 | Korea Institute of Machinery & Materials | 3d printing device for multiple materials and 3d printing method for multiple materials |
| US10183443B2 (en) | 2016-05-10 | 2019-01-22 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to development device |
| US10195787B2 (en) | 2016-05-12 | 2019-02-05 | Xerox Corporation | Electrostatic 3-D development apparatus using different melting point materials |
| US10195693B2 (en) | 2014-06-20 | 2019-02-05 | Vel03D, Inc. | Apparatuses, systems and methods for three-dimensional printing |
| WO2019028030A1 (en) | 2017-07-31 | 2019-02-07 | Evolve Additive Solutions, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts utilizing multiple printing paths |
| US10201930B2 (en) | 2016-05-06 | 2019-02-12 | Xerox Corporation | Acoustic transfude 3-D printing |
| US10213958B2 (en) | 2016-05-06 | 2019-02-26 | Xerox Corporation | Electrostatic 3-D printing system having acoustic transfer and corotron |
| WO2019060537A1 (en) | 2017-09-20 | 2019-03-28 | Evolve Additive Solutions, Inc. | Thermoplastic polyurethane material for selective deposition-based additive manufacturing and method of making same |
| EP3467592A1 (en) | 2013-07-17 | 2019-04-10 | Stratasys, Inc. | Abs part material for electrophotography-based additive manufacturing |
| WO2019075107A1 (en) | 2017-10-10 | 2019-04-18 | Stratasys, Inc. | Water-dispersible thermoplastic material comprising sulfonated copolymer for use in additive manufacturing |
| US10272525B1 (en) | 2017-12-27 | 2019-04-30 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| US10279577B2 (en) | 2016-04-22 | 2019-05-07 | Xerox Corporation | Electrostatic 3-D printer having rotating magnetic cores within developer rolls |
| US20190171155A1 (en) * | 2017-12-04 | 2019-06-06 | Konica Minolta, Inc. | Image post-processing method, image post-processing apparatus and image forming apparatus |
| US10315252B2 (en) | 2017-03-02 | 2019-06-11 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| WO2019133850A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Method of thermally transferring images in a selective deposition based additive manufacturing system |
| WO2019133835A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Sacrificial layers in selective deposition-based additive manufacturing of parts |
| US20190204769A1 (en) * | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Height control in selective deposition based additive manufacturing of parts |
| WO2019133840A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Compliant transfusion roller for selective deposition based additive manufacturing system |
| US10357957B2 (en) | 2015-11-06 | 2019-07-23 | Velo3D, Inc. | Adept three-dimensional printing |
| US10369744B2 (en) | 2016-04-14 | 2019-08-06 | Xerox Corporation | Electrostatic 3-D development apparatus using cold fusing |
| WO2019152797A1 (en) | 2018-02-02 | 2019-08-08 | Evolve Additive Solutions, Inc. | Method of thermally transferring layers in a selective deposition-based additive manufacturing system using conductive heat |
| WO2019133846A3 (en) * | 2017-12-29 | 2019-08-15 | Evolve Additive Solutions, Inc. | Building layers with unsupported portions through selective deposition-based additive manufacturing |
| US10384265B2 (en) * | 2015-06-19 | 2019-08-20 | Applied Materials, Inc. | Selective depositing of powder in additive manufacturing |
| US20190293049A1 (en) * | 2018-03-26 | 2019-09-26 | General Electric Company | Methods for Joining Blade Components of Rotor Blades Using Printed Grid Structures |
| US10434573B2 (en) | 2016-02-18 | 2019-10-08 | Velo3D, Inc. | Accurate three-dimensional printing |
| US10449696B2 (en) | 2017-03-28 | 2019-10-22 | Velo3D, Inc. | Material manipulation in three-dimensional printing |
| US10457833B2 (en) | 2015-12-22 | 2019-10-29 | Stratasys, Inc. | Materials containing fluoropolymers for additive manufacturing applications |
| US10557056B2 (en) | 2015-12-31 | 2020-02-11 | Evolve Additive Solutions, Inc. | ABS/polycarbonate/poly(styrene-co-maleimide) part material for electrophotography-based additive manufacturing |
| WO2020051412A1 (en) | 2018-09-06 | 2020-03-12 | Evolve Additive Solutions, Inc. | Thermal partitioning in an electrostatographic additive manufacturing system |
| US10611092B2 (en) | 2017-01-05 | 2020-04-07 | Velo3D, Inc. | Optics in three-dimensional printing |
| WO2020077127A1 (en) | 2018-10-10 | 2020-04-16 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| US10632670B2 (en) | 2015-02-23 | 2020-04-28 | Xactiv, Inc. | Fabrication of 3D objects via electrostatic powder deposition |
| WO2020096787A1 (en) | 2018-11-09 | 2020-05-14 | Eastman Kodak Company | Electrophotography-based 3d printing with improved layer uniformity |
| WO2020112381A1 (en) | 2018-11-29 | 2020-06-04 | Eastman Kodak Company | Electrophotography-based 3d printing with improved layer registration |
| US10675858B2 (en) | 2015-12-18 | 2020-06-09 | Evolve Additive Solutons, Inc. | Electrophotography-based additive manufacturing with support structure and boundary |
| US10723075B2 (en) | 2016-11-02 | 2020-07-28 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US10723072B1 (en) * | 2016-12-30 | 2020-07-28 | Xactiv, Inc. | Electrophotographic additive manufacturing process |
| US10730109B2 (en) | 2016-04-11 | 2020-08-04 | Stratasys Ltd. | Method and apparatus for additive manufacturing with powder material |
| US10737442B2 (en) | 2018-11-29 | 2020-08-11 | Eastman Kodak Company | Electrophotography-based 3D printing with improved layer registration |
| US10773464B2 (en) | 2017-11-21 | 2020-09-15 | General Electric Company | Method for manufacturing composite airfoils |
| US10821696B2 (en) | 2018-03-26 | 2020-11-03 | General Electric Company | Methods for manufacturing flatback airfoils for wind turbine rotor blades |
| US10821652B2 (en) | 2017-11-21 | 2020-11-03 | General Electric Company | Vacuum forming mold assembly and method for creating a vacuum forming mold assembly |
| US10830206B2 (en) | 2017-02-03 | 2020-11-10 | General Electric Company | Methods for manufacturing wind turbine rotor blades and components thereof |
| WO2020236610A1 (en) | 2019-05-17 | 2020-11-26 | Evolve Additive Solutions, Inc. | Layer transfusion sequencing for selective deposition-based additive manufacturing |
| WO2020243522A1 (en) | 2019-05-31 | 2020-12-03 | Evolve Additive Solutions, Inc. | Selective deposition-based additive manufacturing device and method of printing 3d parts with semi-crystalline materials |
| US10865769B2 (en) | 2017-11-21 | 2020-12-15 | General Electric Company | Methods for manufacturing wind turbine rotor blade panels having printed grid structures |
| US10882301B2 (en) | 2015-12-31 | 2021-01-05 | Evolve Additive Solutions, Inc. | Electrophotographic additive manufacturing with moving platen and environmental chamber |
| US10913216B2 (en) | 2017-11-21 | 2021-02-09 | General Electric Company | Methods for manufacturing wind turbine rotor blade panels having printed grid structures |
| US10920745B2 (en) | 2017-11-21 | 2021-02-16 | General Electric Company | Wind turbine rotor blade components and methods of manufacturing the same |
| US10967573B2 (en) | 2019-04-02 | 2021-04-06 | NEXA3D Inc. | Tank assembly and components thereof for a 3D printing system |
| WO2021067450A1 (en) | 2019-09-30 | 2021-04-08 | Evolve Additive Solutions, Inc. | Additive manufacturing system and method with improved surface finish |
| WO2021081320A1 (en) | 2019-10-25 | 2021-04-29 | Evolve Additive Solutions, Inc. | Cooling apparatus and method for additive manufacture |
| US11035339B2 (en) | 2018-03-26 | 2021-06-15 | General Electric Company | Shear web assembly interconnected with additive manufactured components |
| US11040503B2 (en) | 2017-11-21 | 2021-06-22 | General Electric Company | Apparatus for manufacturing composite airfoils |
| WO2021130661A1 (en) * | 2019-12-23 | 2021-07-01 | Cubicure Gmbh | System for the lithography-based additive manufacturing of three-dimensional (3d) structures |
| US11098691B2 (en) | 2017-02-03 | 2021-08-24 | General Electric Company | Methods for manufacturing wind turbine rotor blades and components thereof |
| US11150570B2 (en) | 2013-07-17 | 2021-10-19 | Evolve Additive Solutions, Inc. | Method of printing parts with a high-performance consumable materials with electrophotography based additive manufacturing system |
| US20210339469A1 (en) * | 2019-03-08 | 2021-11-04 | Ricoh Company, Ltd. | Apparatus configured to model three-dimensional modeled object, apparatus configured to fly particles, and method of modeling three-dimensional modeled object |
| US11167473B2 (en) | 2019-03-18 | 2021-11-09 | NEXA3D Inc. | System for additive manufacture |
| US11167477B1 (en) | 2017-01-06 | 2021-11-09 | Xactiv, Inc. | Fabrication of 3D objects via direct powder deposition |
| US11179808B1 (en) * | 2018-07-11 | 2021-11-23 | Rosemount Aerospace Inc. | System and method of additive manufacturing |
| US11203150B2 (en) | 2017-12-29 | 2021-12-21 | Evolve Additive Solutions, Inc. | Layer orientation in selective deposition based additive manufacturing of parts |
| US11203156B2 (en) | 2018-08-20 | 2021-12-21 | NEXA3D Inc. | Methods and systems for photo-curing photo-sensitive material for printing and other applications |
| US11220055B2 (en) | 2018-11-09 | 2022-01-11 | NEXA3D Inc. | Three-dimensional printing system |
| US20220040912A1 (en) * | 2020-08-05 | 2022-02-10 | Io Tech Group Ltd. | Systems and methods for 3d printing with vacuum assisted laser printing machine |
| US11248582B2 (en) | 2017-11-21 | 2022-02-15 | General Electric Company | Multiple material combinations for printed reinforcement structures of rotor blades |
| US11383440B2 (en) | 2015-08-21 | 2022-07-12 | Aprecia Pharmaceuticals LLC | Three-dimensional printing system and equipment assembly |
| US11390013B2 (en) | 2017-11-21 | 2022-07-19 | General Electric Company | Vacuum forming mold assembly and associated methods |
| US11400516B2 (en) | 2017-03-20 | 2022-08-02 | Stratasys Ltd. | Method and system for additive manufacturing with powder material |
| US20230039713A1 (en) * | 2018-06-07 | 2023-02-09 | Sakuu Corporation | Multi-material three-dimensional printer |
| US11660819B2 (en) | 2016-11-02 | 2023-05-30 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US11668275B2 (en) | 2017-11-21 | 2023-06-06 | General Electric Company | Methods for manufacturing an outer skin of a rotor blade |
| US11691343B2 (en) | 2016-06-29 | 2023-07-04 | Velo3D, Inc. | Three-dimensional printing and three-dimensional printers |
| US11697166B2 (en) | 2020-02-03 | 2023-07-11 | Io Tech Group Ltd. | Methods for printing solder paste and other viscous materials at high resolution |
| US11785722B2 (en) | 2020-06-09 | 2023-10-10 | Io Tech Group Ltd. | Systems for printing conformal materials on component edges at high resolution |
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| US12064917B2 (en) | 2012-11-21 | 2024-08-20 | Stratasys, Inc. | Method for printing three-dimensional parts with cyrstallization kinetics control |
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| US12168713B2 (en) | 2020-06-10 | 2024-12-17 | Inkbit, LLC | Materials for photoinitiated cationic ring-opening polymerization and uses thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5234784A (en) * | 1992-04-01 | 1993-08-10 | Eastman Kodak Company | Method of making a projection viewable transparency comprising an electrostatographic toner image |
| JPH08281808A (en) * | 1995-04-17 | 1996-10-29 | Ricoh Co Ltd | 3D shape manufacturing method |
| JPH10207194A (en) * | 1997-01-24 | 1998-08-07 | Fuji Xerox Co Ltd | Laminate molding method and device |
| JP2002347129A (en) * | 2001-05-25 | 2002-12-04 | Konica Corp | Apparatus and method for three-dimensional shaping |
| WO2004037469A1 (en) * | 2002-10-23 | 2004-05-06 | Sintef | Method and apparatus for rapid manufacturing of metal, ceramic and metal-ceramic products |
| US20090304952A1 (en) * | 2008-06-05 | 2009-12-10 | Kritchman Eliahu M | Apparatus and method for solid freeform fabrication |
Family Cites Families (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2297691A (en) | 1939-04-04 | 1942-10-06 | Chester F Carlson | Electrophotography |
| WO1990003893A1 (en) | 1988-10-05 | 1990-04-19 | Michael Feygin | An improved apparatus and method for forming an integral object from laminations |
| DE68917128T2 (en) | 1989-06-28 | 1994-12-08 | Agfa Gevaert Nv | Toner-receiving printing plate. |
| US5088047A (en) | 1989-10-16 | 1992-02-11 | Bynum David K | Automated manufacturing system using thin sections |
| US4988602A (en) | 1990-04-18 | 1991-01-29 | Minnesota Mining And Manufacturing Co. | Liquid electrophotographic toner with acid containing polyester resins |
| US5099288A (en) | 1990-11-19 | 1992-03-24 | Lexmark International, Inc. | Fixing device with selectable finish |
| US5594652A (en) | 1991-01-31 | 1997-01-14 | Texas Instruments Incorporated | Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data |
| US6175422B1 (en) | 1991-01-31 | 2001-01-16 | Texas Instruments Incorporated | Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data |
| JPH05165350A (en) | 1991-12-17 | 1993-07-02 | Konica Corp | Fixing device |
| US5990268A (en) | 1992-11-23 | 1999-11-23 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
| US5514232A (en) | 1993-11-24 | 1996-05-07 | Burns; Marshall | Method and apparatus for automatic fabrication of three-dimensional objects |
| US6206672B1 (en) | 1994-03-31 | 2001-03-27 | Edward P. Grenda | Apparatus of fabricating 3 dimensional objects by means of electrophotography, ionography or a similar process |
| US6887640B2 (en) | 2002-02-28 | 2005-05-03 | Sukun Zhang | Energy activated electrographic printing process |
| US5593531A (en) | 1994-11-09 | 1997-01-14 | Texas Instruments Incorporated | System, method and process for fabrication of 3-dimensional objects by a static electrostatic imaging and lamination device |
| EP0712051A3 (en) | 1994-11-09 | 1997-06-18 | Texas Instruments Inc | Improvements in or relating to the manufacture of three-dimensional objects |
| US6270335B2 (en) | 1995-09-27 | 2001-08-07 | 3D Systems, Inc. | Selective deposition modeling method and apparatus for forming three-dimensional objects and supports |
| JP4068191B2 (en) | 1996-09-11 | 2008-03-26 | ę Ŗå¼ä¼ē¤¾ćŖć³ć¼ | Toner for electrophotography and method for producing the same |
| JP3765896B2 (en) | 1996-12-13 | 2006-04-12 | ļ¼Ŗļ½ļ½ę Ŗå¼ä¼ē¤¾ | Photocurable resin composition for optical three-dimensional modeling |
| DE69738664D1 (en) | 1997-04-07 | 2008-06-19 | Punch Graphix Int Nv | Electrostatographic printing device and method |
| SE509088C2 (en) | 1997-04-30 | 1998-12-07 | Ralf Larsson | Methods and apparatus for the production of volume bodies |
| US5866058A (en) | 1997-05-29 | 1999-02-02 | Stratasys Inc. | Method for rapid prototyping of solid models |
| US6066285A (en) | 1997-12-12 | 2000-05-23 | University Of Florida | Solid freeform fabrication using power deposition |
| JP2001075376A (en) | 1999-09-06 | 2001-03-23 | Canon Inc | Image forming device |
| JP2001150556A (en) | 1999-09-14 | 2001-06-05 | Minolta Co Ltd | Three-dimensional printing apparatus and three-dimensional printing method |
| US6509128B1 (en) | 2000-10-25 | 2003-01-21 | 3M Innovative Properties Company | Imagewise printing of adhesives and limited coalescence polymerization method |
| US20020093115A1 (en) | 2001-01-12 | 2002-07-18 | Jang B. Z. | Layer manufacturing method and apparatus using a programmable planar light source |
| US6376148B1 (en) | 2001-01-17 | 2002-04-23 | Nanotek Instruments, Inc. | Layer manufacturing using electrostatic imaging and lamination |
| US6780368B2 (en) | 2001-04-10 | 2004-08-24 | Nanotek Instruments, Inc. | Layer manufacturing of a multi-material or multi-color 3-D object using electrostatic imaging and lamination |
| JP2003053849A (en) | 2001-08-16 | 2003-02-26 | Konica Corp | Laminate shaping apparatus and laminate shaping method |
| JP2003071940A (en) | 2001-09-03 | 2003-03-12 | Konica Corp | Apparatus for lamination shaping and method for lamination shaping |
| US7011783B2 (en) | 2001-10-24 | 2006-03-14 | 3D Systems, Inc. | Cooling techniques in solid freeform fabrication |
| RU2302945C2 (en) | 2002-12-20 | 2007-07-20 | ЮнивеŃŃŠøŃŠø ŠŃ ДаŃŃŠµŃн ŠŠ°Š»ŠøŃŠ¾ŃŠ½ŠøŃ | Method and device for manufacturing a three-dimensional object (variants) |
| EP1459871B1 (en) | 2003-03-15 | 2011-04-06 | Evonik Degussa GmbH | Method and apparatus for manufacturing three dimensional objects using microwave radiation and shaped body produced according to this method |
| US6815636B2 (en) | 2003-04-09 | 2004-11-09 | 3D Systems, Inc. | Sintering using thermal image feedback |
| JP2005062860A (en) | 2003-07-31 | 2005-03-10 | Tokai Rubber Ind Ltd | Production method of endless belt for electrophotography |
| US7261542B2 (en) | 2004-03-18 | 2007-08-28 | Desktop Factory, Inc. | Apparatus for three dimensional printing using image layers |
| JP4368711B2 (en) | 2004-03-18 | 2009-11-18 | ę Ŗå¼ä¼ē¤¾ćŖć³ć¼ | Transfer fixing device, image forming apparatus including the same, and transfer fixing method |
| US8119053B1 (en) | 2004-03-18 | 2012-02-21 | 3D Systems, Inc. | Apparatus for three dimensional printing using imaged layers |
| US7435763B2 (en) | 2004-04-02 | 2008-10-14 | Hewlett-Packard Development Company, L.P. | Solid freeform compositions, methods of application thereof, and systems for use thereof |
| DE102004020453A1 (en) | 2004-04-27 | 2005-11-24 | Degussa Ag | Polymer powder with polyamide, use in a molding process and molding, made from this polymer powder |
| EP1763703A4 (en) | 2004-05-12 | 2010-12-08 | Massachusetts Inst Technology | FABRICATION PROCESS, FOR EXAMPLE THREE-DIMENSIONAL PRESSURE WITH SOLVENT VAPOR FILMING AND THE SAME |
| US7208257B2 (en) | 2004-06-25 | 2007-04-24 | Xerox Corporation | Electron beam curable toners and processes thereof |
| DE102004047876A1 (en) | 2004-10-01 | 2006-04-06 | Degussa Ag | Powder with improved recycling properties, process for its preparation and use of the powder in a process for producing three-dimensional objects |
| JP2006182813A (en) | 2004-12-24 | 2006-07-13 | Sumitomo Rubber Ind Ltd | Electroconductive seamless belt, manufacturing method of electroconductive seamless belt, and image-forming apparatus equipped with electroconductive seamless belt |
| DE102005033379A1 (en) | 2005-07-16 | 2007-01-18 | Degussa Ag | Use of cyclic oligomers in a molding process and molding made by this process |
| WO2007114895A2 (en) | 2006-04-06 | 2007-10-11 | Z Corporation | Production of three-dimensional objects by use of electromagnetic radiation |
| US7706910B2 (en) | 2007-01-17 | 2010-04-27 | 3D Systems, Inc. | Imager assembly and method for solid imaging |
| US7731887B2 (en) | 2007-01-17 | 2010-06-08 | 3D Systems, Inc. | Method for removing excess uncured build material in solid imaging |
| US20080226346A1 (en) | 2007-01-17 | 2008-09-18 | 3D Systems, Inc. | Inkjet Solid Imaging System and Method for Solid Imaging |
| US7614866B2 (en) | 2007-01-17 | 2009-11-10 | 3D Systems, Inc. | Solid imaging apparatus and method |
| US8221671B2 (en) | 2007-01-17 | 2012-07-17 | 3D Systems, Inc. | Imager and method for consistent repeatable alignment in a solid imaging apparatus |
| GB2446386A (en) | 2007-02-06 | 2008-08-13 | Univ Montfort | Electrostatic printing method and its use in rapid prototyping |
| DE102007029142A1 (en) | 2007-06-25 | 2009-01-02 | 3D-Micromac Ag | Layer application device for electrostatic layer application of a powdery material and apparatus and method for producing a three-dimensional object |
| SE0701934L (en) | 2007-08-27 | 2009-02-28 | Sintermask Technologies Ab | Toner composition, developer comprising the toner composition and process for preparing a volume body |
| JP4404136B2 (en) | 2007-12-17 | 2010-01-27 | åÆå£«ć¼ćććÆć¹ę Ŗå¼ä¼ē¤¾ | Toner for developing electrostatic image, method for producing the same, electrostatic image developer, toner cartridge, process cartridge, and image forming apparatus |
| DE102008000755B4 (en) | 2008-03-19 | 2019-12-12 | Evonik Degussa Gmbh | Copolyamide powder and its preparation, use of copolyamide powder in a molding process and molding, made from this copolyamide powder |
| CN101310964B (en) | 2008-07-10 | 2010-08-11 | ååēå·„å¤§å¦ | Selective laser fusion rapid molding method and device of medical implantation material wax mould |
| US8147910B2 (en) | 2009-02-24 | 2012-04-03 | Objet Ltd. | Method and apparatus for three-dimensional printing |
| US8249480B2 (en) | 2009-06-25 | 2012-08-21 | Eastman Kodak Company | Fusing apparatus for high speed electrophotography system |
| DE102009037815B4 (en) | 2009-08-18 | 2016-06-09 | Sintermask Gmbh | Method and device for producing a three-dimensional object |
| GB0917936D0 (en) | 2009-10-13 | 2009-11-25 | 3D Printer Aps | Three-dimensional printer |
| WO2011065920A1 (en) | 2009-11-26 | 2011-06-03 | Yu En Tan | Process for building three-dimensional objects |
| DE102010045679A1 (en) | 2010-09-17 | 2012-03-22 | Fraunhofer-Gesellschaft zur Fƶrderung der angewandten Forschung e.V. | Method for chemical toner fixation |
| DE102011003610A1 (en) | 2011-02-03 | 2012-08-09 | Evonik Degussa Gmbh | Device for better inertization of laser sintering systems |
| US8568951B2 (en) | 2011-03-16 | 2013-10-29 | Ricoh Company, Ltd. | Toner, method of manufacturing toner, image forming method, image forming apparatus, and process cartridge |
| US9017591B2 (en) | 2011-04-27 | 2015-04-28 | Canon Kabushiki Kaisha | Method for manufacturing seamless belt for electrophotography |
| GB201109045D0 (en) | 2011-05-31 | 2011-07-13 | Warwick Ventures | Additive building |
| US20140004462A1 (en) | 2012-06-29 | 2014-01-02 | Mark Cameron Zaretsky | Making article with desired profile |
-
2013
- 2013-03-08 US US13/790,406 patent/US20130186558A1/en not_active Abandoned
-
2018
- 2018-08-06 US US16/055,894 patent/US11241824B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5234784A (en) * | 1992-04-01 | 1993-08-10 | Eastman Kodak Company | Method of making a projection viewable transparency comprising an electrostatographic toner image |
| JPH08281808A (en) * | 1995-04-17 | 1996-10-29 | Ricoh Co Ltd | 3D shape manufacturing method |
| JPH10207194A (en) * | 1997-01-24 | 1998-08-07 | Fuji Xerox Co Ltd | Laminate molding method and device |
| JP2002347129A (en) * | 2001-05-25 | 2002-12-04 | Konica Corp | Apparatus and method for three-dimensional shaping |
| WO2004037469A1 (en) * | 2002-10-23 | 2004-05-06 | Sintef | Method and apparatus for rapid manufacturing of metal, ceramic and metal-ceramic products |
| US20090304952A1 (en) * | 2008-06-05 | 2009-12-10 | Kritchman Eliahu M | Apparatus and method for solid freeform fabrication |
Non-Patent Citations (5)
| Title |
|---|
| Dupont Kapton Technical Information. http://www.dupont.com/content/dam/assets/products-and-services/membranes-films/assets/DEC-Kapton-summary-of-properties.pdf. Date of Publication Unknown. * |
| Dupont Teflon Properties Handbook. http://rjchase.com/ptfe_handbook.pdf. Date of Publication Unknown. * |
| USPTO Scientific & Technical Information Center Full Translation of Koseko, JP 08-281808 A. August 2016. * |
| USPTO Scientific & Technical Information Center Full Translation of Nishida, JP 2002-347129 A. August 2016. * |
| USPTO Scientific & Technical Information Center Full Translation of Yamada, JP 10-207194 A. August 2016. * |
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| US10807302B2 (en) | 2012-11-21 | 2020-10-20 | Stratasys, Inc. | Semi-crystalline build materials |
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| US10144828B2 (en) | 2012-11-21 | 2018-12-04 | Stratasys, Inc. | Semi-crystalline build materials |
| US11150570B2 (en) | 2013-07-17 | 2021-10-19 | Evolve Additive Solutions, Inc. | Method of printing parts with a high-performance consumable materials with electrophotography based additive manufacturing system |
| EP3467592A1 (en) | 2013-07-17 | 2019-04-10 | Stratasys, Inc. | Abs part material for electrophotography-based additive manufacturing |
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| US9785064B2 (en) | 2013-07-17 | 2017-10-10 | Stratasys, Inc. | Semi-crystalline consumable materials for electrophotography-based additive manufacturing system |
| US9744730B2 (en) | 2013-11-22 | 2017-08-29 | Stratasys, Inc. | Magnetic platen assembly for additive manufacturing system |
| WO2015081009A1 (en) | 2013-11-27 | 2015-06-04 | Stratasys, Inc. | Method for printing three-dimensional parts wtih crystallization kinetics control |
| US9643357B2 (en) | 2014-03-18 | 2017-05-09 | Stratasys, Inc. | Electrophotography-based additive manufacturing with powder density detection and utilization |
| US10011071B2 (en) | 2014-03-18 | 2018-07-03 | Evolve Additive Solutions, Inc. | Additive manufacturing using density feedback control |
| CN106104390A (en) * | 2014-03-18 | 2016-11-09 | ęÆē¹ęå”脿ęÆå ¬åø | Electrophotography-based additive manufacturing with pre-sintering |
| WO2015142492A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Additive manufacturing with virtual planarization control |
| US9868255B2 (en) | 2014-03-18 | 2018-01-16 | Stratasys, Inc. | Electrophotography-based additive manufacturing with pre-sintering |
| KR101848073B1 (en) * | 2014-03-18 | 2018-05-24 | ģ¤ķøėķ°ģģ¤,ģøģ½ķ¬ė ģ“ķ°ė | Eletrophotography-based additive manufacturing with pre-sintering |
| US10144175B2 (en) | 2014-03-18 | 2018-12-04 | Evolve Additive Solutions, Inc. | Electrophotography-based additive manufacturing with solvent-assisted planarization |
| WO2015142493A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Eletrophotography-based additive manufacturing with pre-sintering |
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| WO2015142494A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys, Inc. | Eletrophotography-based additive manufacturing with powder density detection and utilization |
| WO2015142495A1 (en) | 2014-03-18 | 2015-09-24 | Stratasys. Inc. | Electrophotography-based additive manufacturing with solvent-assisted planarization |
| US9688027B2 (en) | 2014-04-01 | 2017-06-27 | Stratasys, Inc. | Electrophotography-based additive manufacturing with overlay control |
| US9919479B2 (en) | 2014-04-01 | 2018-03-20 | Stratasys, Inc. | Registration and overlay error correction of electrophotographically formed elements in an additive manufacturing system |
| WO2015153030A1 (en) | 2014-04-01 | 2015-10-08 | Stratasys, Inc. | Electrophotography-based additive manufacturing with overlay control |
| CN106133617A (en) * | 2014-04-01 | 2016-11-16 | ęÆē¹ęå”脿ęÆå ¬åø | There is the increasing material manufacture based on electrophotography of Overlapped control |
| US20170173696A1 (en) * | 2014-05-08 | 2017-06-22 | Stratasys Ltd. | Method and apparatus for 3d printing by selective sintering |
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| US10675853B2 (en) | 2014-05-16 | 2020-06-09 | Stratasys, Inc. | High-temperature soluble support material for additive manufacturing |
| WO2015175682A1 (en) | 2014-05-16 | 2015-11-19 | Stratasys, Inc. | High-temperature soluble support material for additive manufacturing |
| US9833944B1 (en) * | 2014-05-23 | 2017-12-05 | Robert Wayne Huthmaker | Printer plates for three dimensional printing |
| US10493564B2 (en) | 2014-06-20 | 2019-12-03 | Velo3D, Inc. | Apparatuses, systems and methods for three-dimensional printing |
| US10195693B2 (en) | 2014-06-20 | 2019-02-05 | Vel03D, Inc. | Apparatuses, systems and methods for three-dimensional printing |
| US20160059308A1 (en) * | 2014-08-28 | 2016-03-03 | Incodema3D, LLC | Additive manufacturing device |
| US9597731B2 (en) * | 2014-08-28 | 2017-03-21 | Incodema3D, LLC | Additive manufacturing device |
| US10059053B2 (en) | 2014-11-04 | 2018-08-28 | Stratasys, Inc. | Break-away support material for additive manufacturing |
| WO2016073409A1 (en) | 2014-11-04 | 2016-05-12 | Stratasys, Inc. | Break-away support material for additive manufacturing |
| US11046014B2 (en) | 2014-11-04 | 2021-06-29 | Stratasys, Inc. | Break-away support material for additive manufacturing |
| US10960493B2 (en) * | 2014-11-11 | 2021-03-30 | DMG Mori USA | Machine tool system and method for additive manufacturing |
| US20160129528A1 (en) * | 2014-11-11 | 2016-05-12 | DMG Mori USA | Machine tool system and method for additive manufacturing |
| WO2016084367A1 (en) * | 2014-11-28 | 2016-06-02 | Canon Kabushiki Kaisha | Three-dimensional shaping apparatus and three-dimensional shaped article manufacturing method |
| WO2016084351A1 (en) * | 2014-11-28 | 2016-06-02 | Canon Kabushiki Kaisha | Method and apparatus for forming stereoscopic object |
| US9592660B2 (en) * | 2014-12-17 | 2017-03-14 | Arevo Inc. | Heated build platform and system for three dimensional printing methods |
| CN104504190A (en) * | 2014-12-17 | 2015-04-08 | å±ē¦å®äøļ¼ę±éØļ¼č“µéå±ęéå ¬åø | 3D printing method and device |
| US10632670B2 (en) | 2015-02-23 | 2020-04-28 | Xactiv, Inc. | Fabrication of 3D objects via electrostatic powder deposition |
| WO2016184994A1 (en) * | 2015-05-19 | 2016-11-24 | Addifab Aps | Apparatus and method for release of additively manufactured products and build platform |
| CN104827155A (en) * | 2015-05-22 | 2015-08-12 | åäøē§ęå¤§å¦ | Solidifying and melting composite material increase forming method suitable for complex parts |
| WO2016205690A1 (en) | 2015-06-19 | 2016-12-22 | Stratasys, Inc. | Water dispersible polymer for use in additive manufacturing |
| US11186679B2 (en) | 2015-06-19 | 2021-11-30 | Stratasys, Inc. | Water dispersible polymer for use in additive manufacturing |
| US10384265B2 (en) * | 2015-06-19 | 2019-08-20 | Applied Materials, Inc. | Selective depositing of powder in additive manufacturing |
| US10982043B2 (en) | 2015-06-19 | 2021-04-20 | Stratasys, Inc. | Recycling and reuse of sulfonated polymer material in additive manufacturing |
| WO2017015217A3 (en) * | 2015-07-20 | 2017-03-16 | Velo3D, Inc. | Transfer of particulate material |
| US10486411B2 (en) * | 2015-07-29 | 2019-11-26 | Canon Kabushiki Kaisha | Shaping apparatus and shaping method |
| US20170028629A1 (en) * | 2015-07-29 | 2017-02-02 | Canon Kabushiki Kaisha | Shaping apparatus and shaping method |
| US11383440B2 (en) | 2015-08-21 | 2022-07-12 | Aprecia Pharmaceuticals LLC | Three-dimensional printing system and equipment assembly |
| CN105150537A (en) * | 2015-09-24 | 2015-12-16 | 蓵å·ēæ°åÆęÆęŗč½ęęÆęéå ¬åø | Intelligent manufacturing system consisting of 3D printing device and mechanical arms |
| US20190054685A1 (en) * | 2015-10-13 | 2019-02-21 | M & R Beteiligungsgesellschaft mbH | Method and device for producing a workpiece |
| US11458674B2 (en) * | 2015-10-13 | 2022-10-04 | M & R Beteiligungsgesellschaft mbH | Method and device for producing a workpiece |
| WO2017063640A3 (en) * | 2015-10-13 | 2017-06-08 | M & R Beteiligungsgesellschaft mbH | Method and device for producing a workpiece |
| US11376784B2 (en) * | 2015-10-19 | 2022-07-05 | Mimaki Engineering Co., Ltd. | Three-dimensional object shaping system |
| US20170106590A1 (en) * | 2015-10-19 | 2017-04-20 | Mimaki Engineering Co., Ltd. | Shaping apparatus and shaping method |
| US10357957B2 (en) | 2015-11-06 | 2019-07-23 | Velo3D, Inc. | Adept three-dimensional printing |
| WO2017098968A1 (en) * | 2015-12-10 | 2017-06-15 | Canon Kabushiki Kaisha | Shaping apparatus |
| US10058920B2 (en) | 2015-12-10 | 2018-08-28 | Velo3D, Inc. | Skillful three-dimensional printing |
| US10675858B2 (en) | 2015-12-18 | 2020-06-09 | Evolve Additive Solutons, Inc. | Electrophotography-based additive manufacturing with support structure and boundary |
| US10457833B2 (en) | 2015-12-22 | 2019-10-29 | Stratasys, Inc. | Materials containing fluoropolymers for additive manufacturing applications |
| US10953595B2 (en) | 2015-12-24 | 2021-03-23 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| WO2017112689A1 (en) | 2015-12-24 | 2017-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| WO2017112687A1 (en) | 2015-12-24 | 2017-06-29 | Stratasys, Inc. | Water soluble support material for high temperature additive manufacturing applications |
| US11045997B2 (en) | 2015-12-24 | 2021-06-29 | Stratasys, Inc. | Water soluble support materials for high temperature additive manufacturing applications |
| US10557056B2 (en) | 2015-12-31 | 2020-02-11 | Evolve Additive Solutions, Inc. | ABS/polycarbonate/poly(styrene-co-maleimide) part material for electrophotography-based additive manufacturing |
| US10792908B2 (en) * | 2015-12-31 | 2020-10-06 | Evolve Additive Solutions, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts |
| US10882301B2 (en) | 2015-12-31 | 2021-01-05 | Evolve Additive Solutions, Inc. | Electrophotographic additive manufacturing with moving platen and environmental chamber |
| US20170192377A1 (en) * | 2015-12-31 | 2017-07-06 | Stratasys, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts |
| US10112379B2 (en) | 2016-01-25 | 2018-10-30 | Eastman Kodak Company | Large format electrophotographic 3D printer |
| US10434573B2 (en) | 2016-02-18 | 2019-10-08 | Velo3D, Inc. | Accurate three-dimensional printing |
| US11024075B2 (en) | 2016-02-25 | 2021-06-01 | Stratasys Ltd. | GPU material assignment for 3D printing using 3D distance fields |
| US11625889B2 (en) | 2016-02-25 | 2023-04-11 | Stratasys Ltd. | GPU material assignment for 3D printing using 3D distance fields |
| US12125134B2 (en) | 2016-02-25 | 2024-10-22 | Stratasys Ltd. | GPU material assignment for 3D printing using 3D distance fields |
| WO2017147412A1 (en) | 2016-02-25 | 2017-08-31 | Stratasys Ltd. | Gpu material assignment for 3d printing using 3d distance fields |
| US10730109B2 (en) | 2016-04-11 | 2020-08-04 | Stratasys Ltd. | Method and apparatus for additive manufacturing with powder material |
| US11059100B2 (en) | 2016-04-11 | 2021-07-13 | Stratasys Ltd. | Method and apparatus for additive manufacturing with powder material |
| US11980941B2 (en) | 2016-04-11 | 2024-05-14 | Stratasys Ltd. | Method and apparatus for additive manufacturing with powder material |
| US11691196B2 (en) | 2016-04-11 | 2023-07-04 | Stratasys Ltd. | Method and apparatus for additive manufacturing with powder material |
| US10046512B2 (en) * | 2016-04-14 | 2018-08-14 | Xerox Corporation | Electro-photographic 3-D printing using dissolvable paper |
| US11130282B2 (en) | 2016-04-14 | 2021-09-28 | Xerox Corporation | Electrostatic 3-D development apparatus using cold fusing |
| US10040250B2 (en) * | 2016-04-14 | 2018-08-07 | Xerox Corporation | Electro-photographic 3-D printing using collapsible substrate |
| US10369744B2 (en) | 2016-04-14 | 2019-08-06 | Xerox Corporation | Electrostatic 3-D development apparatus using cold fusing |
| US10105902B2 (en) | 2016-04-18 | 2018-10-23 | Evolve Additive Solutions, Inc. | Electrophotography-based additive manufacturing with part molding |
| US10279577B2 (en) | 2016-04-22 | 2019-05-07 | Xerox Corporation | Electrostatic 3-D printer having rotating magnetic cores within developer rolls |
| US10137634B2 (en) * | 2016-04-28 | 2018-11-27 | Xerox Corporation | Hybrid electrostatic 3-D printer using laser fusing |
| CN107336439A (en) * | 2016-04-28 | 2017-11-10 | ę½ä¹å ¬åø | The D printers of mixing electrostatic 3 being fixed using laser |
| US10201930B2 (en) | 2016-05-06 | 2019-02-12 | Xerox Corporation | Acoustic transfude 3-D printing |
| US10213958B2 (en) | 2016-05-06 | 2019-02-26 | Xerox Corporation | Electrostatic 3-D printing system having acoustic transfer and corotron |
| US10005228B2 (en) | 2016-05-10 | 2018-06-26 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to exposure device |
| US10183443B2 (en) | 2016-05-10 | 2019-01-22 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to development device |
| US10005230B2 (en) * | 2016-05-10 | 2018-06-26 | Xerox Corporation | Electrostatic 3-D printer controlling layer thickness using feedback loop to transfer device |
| KR20170128083A (en) * | 2016-05-12 | 2017-11-22 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer using addressable uv crosslinking |
| US10195787B2 (en) | 2016-05-12 | 2019-02-05 | Xerox Corporation | Electrostatic 3-D development apparatus using different melting point materials |
| KR102208285B1 (en) | 2016-05-12 | 2021-01-26 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | 3-d printing using intermediate transfer belt and curable polymers |
| US10350828B2 (en) | 2016-05-12 | 2019-07-16 | Xerox Corporation | 3-D printing using intermediate transfer belt and curable polymers |
| KR102142833B1 (en) | 2016-05-12 | 2020-08-10 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer using addressable uv crosslinking |
| CN107364123A (en) * | 2016-05-12 | 2017-11-21 | ę½ä¹å ¬åø | The D printers of electrostatic 3 being crosslinked using addressable UV |
| US10005227B2 (en) * | 2016-05-12 | 2018-06-26 | Xerox Corporation | Electrostatic 3-D printer using addressable UV crosslinking |
| US10099421B2 (en) * | 2016-05-12 | 2018-10-16 | Xerox Corporation | 3-D printing using intermediate transfer belt and curable polymers |
| KR20170128082A (en) * | 2016-05-12 | 2017-11-22 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | 3-d printing using intermediate transfer belt and curable polymers |
| CN105904732A (en) * | 2016-05-26 | 2016-08-31 | ę¹ę½å¤§å¦ | Guiding device and implementation method for fiber orientation in selective laser sintering of fiber composite powder |
| KR102159479B1 (en) | 2016-06-06 | 2020-09-25 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer controlling layer topography using aerosol applicator |
| US10688717B2 (en) * | 2016-06-06 | 2020-06-23 | Xerox Corporation | Electrostatic 3-D printer controlling layer topography using aerosol applicator |
| CN107457987A (en) * | 2016-06-06 | 2017-12-12 | ę½ä¹å ¬åø | Use the D printers of electrostatic 3 of aerosol applicator key-course pattern |
| US10118337B2 (en) * | 2016-06-06 | 2018-11-06 | Xerox Corporation | Electrostatic 3-D printer controlling layer topography using aerosol applicator |
| KR20170138038A (en) * | 2016-06-06 | 2017-12-14 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer controlling layer topography using aerosol applicator |
| KR20170138343A (en) * | 2016-06-07 | 2017-12-15 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer using layer and mechanical planer |
| US10875241B2 (en) * | 2016-06-07 | 2020-12-29 | Xerox Corporation | Electrostatic 3-D printer using layer and mechanical planer |
| KR102159481B1 (en) | 2016-06-07 | 2020-09-25 | ģ ė”ģ¤ ģ½ķ¬ė ģ“ģ | Electrostatic 3-d printer using layer and mechanical planer |
| US10076869B2 (en) | 2016-06-07 | 2018-09-18 | Xerox Corporation | Electrostatic 3-D printer using leveling material and mechanical planer |
| US20170348909A1 (en) * | 2016-06-07 | 2017-12-07 | Xerox Corporation | Electrostatic 3-d printer using layer and mechanical planer |
| US10293547B2 (en) * | 2016-06-07 | 2019-05-21 | Xerox Corporation | Electrostatic 3-D printer using layer and mechanical planer |
| US10086558B2 (en) * | 2016-06-29 | 2018-10-02 | Xerox Corporation | 3-D electrostatic printer using track bound platens and registration system |
| US11691343B2 (en) | 2016-06-29 | 2023-07-04 | Velo3D, Inc. | Three-dimensional printing and three-dimensional printers |
| US10000010B2 (en) * | 2016-06-29 | 2018-06-19 | Xerox Corporation | 3-D electrostatic printer using rack and pinion registration system |
| US12070907B2 (en) | 2016-09-30 | 2024-08-27 | Velo3D | Three-dimensional objects and their formation |
| US11110658B2 (en) | 2016-11-02 | 2021-09-07 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US11167489B2 (en) | 2016-11-02 | 2021-11-09 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US10723075B2 (en) | 2016-11-02 | 2020-07-28 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US12325188B2 (en) | 2016-11-02 | 2025-06-10 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US11760017B2 (en) | 2016-11-02 | 2023-09-19 | R3 Printing, Inc. | System for automated successive three-dimensional printing |
| US12337539B2 (en) | 2016-11-02 | 2025-06-24 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US11660819B2 (en) | 2016-11-02 | 2023-05-30 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US11731355B2 (en) | 2016-11-02 | 2023-08-22 | R3 Printing, Inc. | System and method for automated successive three-dimensional printing |
| US10661341B2 (en) | 2016-11-07 | 2020-05-26 | Velo3D, Inc. | Gas flow in three-dimensional printing |
| US20180126649A1 (en) | 2016-11-07 | 2018-05-10 | Velo3D, Inc. | Gas flow in three-dimensional printing |
| US10723072B1 (en) * | 2016-12-30 | 2020-07-28 | Xactiv, Inc. | Electrophotographic additive manufacturing process |
| US10611092B2 (en) | 2017-01-05 | 2020-04-07 | Velo3D, Inc. | Optics in three-dimensional printing |
| US11167477B1 (en) | 2017-01-06 | 2021-11-09 | Xactiv, Inc. | Fabrication of 3D objects via direct powder deposition |
| US10830206B2 (en) | 2017-02-03 | 2020-11-10 | General Electric Company | Methods for manufacturing wind turbine rotor blades and components thereof |
| US11098691B2 (en) | 2017-02-03 | 2021-08-24 | General Electric Company | Methods for manufacturing wind turbine rotor blades and components thereof |
| US10315252B2 (en) | 2017-03-02 | 2019-06-11 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US10888925B2 (en) | 2017-03-02 | 2021-01-12 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US10369629B2 (en) | 2017-03-02 | 2019-08-06 | Veo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US10442003B2 (en) | 2017-03-02 | 2019-10-15 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US10357829B2 (en) | 2017-03-02 | 2019-07-23 | Velo3D, Inc. | Three-dimensional printing of three-dimensional objects |
| US11400516B2 (en) | 2017-03-20 | 2022-08-02 | Stratasys Ltd. | Method and system for additive manufacturing with powder material |
| EP3388221A3 (en) * | 2017-03-24 | 2019-01-09 | Korea Institute of Machinery & Materials | 3d printing device for multiple materials and 3d printing method for multiple materials |
| US10800104B2 (en) | 2017-03-24 | 2020-10-13 | Korea Institute Of Machinery & Materials | 3D printing device for multiple materials and 3D printing method for multiple materials |
| US10449696B2 (en) | 2017-03-28 | 2019-10-22 | Velo3D, Inc. | Material manipulation in three-dimensional printing |
| WO2018236859A1 (en) | 2017-06-22 | 2018-12-27 | Evolve Additive Solutions, Inc. | ADDITIVE FABRICATION BASED ON ELECTROPHOTOGRAPHY USING A SUPPORT STRUCTURE AND REMOVING SUPPORT STRUCTURE |
| US10518486B2 (en) | 2017-06-22 | 2019-12-31 | Evolve Additive Solutions, Inc. | Electrophotography-based additive manufacturing with support structure and support structure removal |
| US11396127B2 (en) | 2017-07-31 | 2022-07-26 | Evolve Additive Solutions, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts utilizing multiple printing paths |
| WO2019028030A1 (en) | 2017-07-31 | 2019-02-07 | Evolve Additive Solutions, Inc. | Systems and methods for electrophotography-based additive manufacturing of parts utilizing multiple printing paths |
| WO2019060537A1 (en) | 2017-09-20 | 2019-03-28 | Evolve Additive Solutions, Inc. | Thermoplastic polyurethane material for selective deposition-based additive manufacturing and method of making same |
| US11220062B2 (en) | 2017-10-10 | 2022-01-11 | Stratasys, Inc. | Water-dispersible thermoplastic material comprising sulfonated copolymer for use in additive manufacturing |
| WO2019075107A1 (en) | 2017-10-10 | 2019-04-18 | Stratasys, Inc. | Water-dispersible thermoplastic material comprising sulfonated copolymer for use in additive manufacturing |
| US10913216B2 (en) | 2017-11-21 | 2021-02-09 | General Electric Company | Methods for manufacturing wind turbine rotor blade panels having printed grid structures |
| US11248582B2 (en) | 2017-11-21 | 2022-02-15 | General Electric Company | Multiple material combinations for printed reinforcement structures of rotor blades |
| US10920745B2 (en) | 2017-11-21 | 2021-02-16 | General Electric Company | Wind turbine rotor blade components and methods of manufacturing the same |
| US11548246B2 (en) | 2017-11-21 | 2023-01-10 | General Electric Company | Apparatus for manufacturing composite airfoils |
| US11390013B2 (en) | 2017-11-21 | 2022-07-19 | General Electric Company | Vacuum forming mold assembly and associated methods |
| US10865769B2 (en) | 2017-11-21 | 2020-12-15 | General Electric Company | Methods for manufacturing wind turbine rotor blade panels having printed grid structures |
| US11668275B2 (en) | 2017-11-21 | 2023-06-06 | General Electric Company | Methods for manufacturing an outer skin of a rotor blade |
| US11040503B2 (en) | 2017-11-21 | 2021-06-22 | General Electric Company | Apparatus for manufacturing composite airfoils |
| US10821652B2 (en) | 2017-11-21 | 2020-11-03 | General Electric Company | Vacuum forming mold assembly and method for creating a vacuum forming mold assembly |
| US10773464B2 (en) | 2017-11-21 | 2020-09-15 | General Electric Company | Method for manufacturing composite airfoils |
| US10754287B2 (en) * | 2017-12-04 | 2020-08-25 | Konica Minolta, Inc. | Image post-processing method, image post-processing apparatus and image forming apparatus |
| US20190171155A1 (en) * | 2017-12-04 | 2019-06-06 | Konica Minolta, Inc. | Image post-processing method, image post-processing apparatus and image forming apparatus |
| US10272525B1 (en) | 2017-12-27 | 2019-04-30 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| WO2019133850A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Method of thermally transferring images in a selective deposition based additive manufacturing system |
| US11654624B2 (en) | 2017-12-29 | 2023-05-23 | Evolve Additive Solutions, Inc. | Building layers with unsupported portions through selective deposition-based additive manufacturing |
| US10996602B2 (en) * | 2017-12-29 | 2021-05-04 | Evolve Additive Solutions, Inc. | Height control in selective deposition based additive manufacturing of parts |
| WO2019133846A3 (en) * | 2017-12-29 | 2019-08-15 | Evolve Additive Solutions, Inc. | Building layers with unsupported portions through selective deposition-based additive manufacturing |
| US11203150B2 (en) | 2017-12-29 | 2021-12-21 | Evolve Additive Solutions, Inc. | Layer orientation in selective deposition based additive manufacturing of parts |
| WO2019133835A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Sacrificial layers in selective deposition-based additive manufacturing of parts |
| US20190204769A1 (en) * | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Height control in selective deposition based additive manufacturing of parts |
| US11904531B2 (en) | 2017-12-29 | 2024-02-20 | Evolve Additive Solutions, Inc. | Method of thermally transferring images in a selective deposition based additive manufacturing system |
| WO2019133840A1 (en) | 2017-12-29 | 2019-07-04 | Evolve Additive Solutions, Inc. | Compliant transfusion roller for selective deposition based additive manufacturing system |
| US11446862B2 (en) | 2017-12-29 | 2022-09-20 | Evolve Additive Solutions, Inc. | Sacrificial layers in selective deposition-based additive manufacturing of parts |
| US10144176B1 (en) | 2018-01-15 | 2018-12-04 | Velo3D, Inc. | Three-dimensional printing systems and methods of their use |
| WO2019152797A1 (en) | 2018-02-02 | 2019-08-08 | Evolve Additive Solutions, Inc. | Method of thermally transferring layers in a selective deposition-based additive manufacturing system using conductive heat |
| US11845221B2 (en) | 2018-02-02 | 2023-12-19 | Evolve Additive Solutions, Inc. | Method of thermally transferring layers in a selective deposition-based additive manufacturing system using conductive heat |
| US10821696B2 (en) | 2018-03-26 | 2020-11-03 | General Electric Company | Methods for manufacturing flatback airfoils for wind turbine rotor blades |
| US20190293049A1 (en) * | 2018-03-26 | 2019-09-26 | General Electric Company | Methods for Joining Blade Components of Rotor Blades Using Printed Grid Structures |
| US11035339B2 (en) | 2018-03-26 | 2021-06-15 | General Electric Company | Shear web assembly interconnected with additive manufactured components |
| US20230039713A1 (en) * | 2018-06-07 | 2023-02-09 | Sakuu Corporation | Multi-material three-dimensional printer |
| US11806937B2 (en) * | 2018-06-07 | 2023-11-07 | Sakuu Corporation | Method for creating structures of two or more materials using a multi-material three-dimensional printer |
| US11179808B1 (en) * | 2018-07-11 | 2021-11-23 | Rosemount Aerospace Inc. | System and method of additive manufacturing |
| US11890697B1 (en) * | 2018-07-11 | 2024-02-06 | Rosemount Aerospace Inc. | System and method of additive manufacturing |
| US11203156B2 (en) | 2018-08-20 | 2021-12-21 | NEXA3D Inc. | Methods and systems for photo-curing photo-sensitive material for printing and other applications |
| US11865768B2 (en) | 2018-08-20 | 2024-01-09 | NEXA3D Inc. | Methods for photo-curing photo-sensitive material for printing and other applications |
| US12036727B2 (en) * | 2018-09-06 | 2024-07-16 | Evolve Additive Solutions, Inc. | Thermal partitioning in an electrostatographic additive manufacturing system |
| WO2020051412A1 (en) | 2018-09-06 | 2020-03-12 | Evolve Additive Solutions, Inc. | Thermal partitioning in an electrostatographic additive manufacturing system |
| US11939480B2 (en) | 2018-10-10 | 2024-03-26 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| WO2020077127A1 (en) | 2018-10-10 | 2020-04-16 | Stratasys, Inc. | Water dispersible sulfonated thermoplastic copolymer for use in additive manufacturing |
| US11220055B2 (en) | 2018-11-09 | 2022-01-11 | NEXA3D Inc. | Three-dimensional printing system |
| US11161309B2 (en) | 2018-11-09 | 2021-11-02 | Eastman Kodak Company | Electrophotography-based 3D printing with improved layer uniformity |
| WO2020096787A1 (en) | 2018-11-09 | 2020-05-14 | Eastman Kodak Company | Electrophotography-based 3d printing with improved layer uniformity |
| WO2020112381A1 (en) | 2018-11-29 | 2020-06-04 | Eastman Kodak Company | Electrophotography-based 3d printing with improved layer registration |
| US10737442B2 (en) | 2018-11-29 | 2020-08-11 | Eastman Kodak Company | Electrophotography-based 3D printing with improved layer registration |
| US20210339469A1 (en) * | 2019-03-08 | 2021-11-04 | Ricoh Company, Ltd. | Apparatus configured to model three-dimensional modeled object, apparatus configured to fly particles, and method of modeling three-dimensional modeled object |
| US11167473B2 (en) | 2019-03-18 | 2021-11-09 | NEXA3D Inc. | System for additive manufacture |
| US11559945B2 (en) | 2019-04-02 | 2023-01-24 | NEXA3D Inc. | Membrane assembly for a 3D printing system |
| US10967573B2 (en) | 2019-04-02 | 2021-04-06 | NEXA3D Inc. | Tank assembly and components thereof for a 3D printing system |
| US12046575B2 (en) | 2019-05-01 | 2024-07-23 | Io Tech Group Ltd. | Method to electrically connect chip with top connectors using 3D printing |
| US12083747B2 (en) | 2019-05-17 | 2024-09-10 | Evolve Additive Solutions, Inc. | Layer transfusion sequencing for selective deposition-based additive manufacturing |
| WO2020236610A1 (en) | 2019-05-17 | 2020-11-26 | Evolve Additive Solutions, Inc. | Layer transfusion sequencing for selective deposition-based additive manufacturing |
| WO2020243522A1 (en) | 2019-05-31 | 2020-12-03 | Evolve Additive Solutions, Inc. | Selective deposition-based additive manufacturing device and method of printing 3d parts with semi-crystalline materials |
| US11993006B2 (en) | 2019-05-31 | 2024-05-28 | Evolve Additive Solutions, Inc | Selective deposition-based additive manufacturing device and method of printing 3D parts with semi-crystalline materials |
| US11999110B2 (en) | 2019-07-26 | 2024-06-04 | Velo3D, Inc. | Quality assurance in formation of three-dimensional objects |
| US11934129B2 (en) | 2019-09-30 | 2024-03-19 | Evolve Additive Solutions, Inc. | Additive manufacturing system and method with improved surface finish |
| WO2021067450A1 (en) | 2019-09-30 | 2021-04-08 | Evolve Additive Solutions, Inc. | Additive manufacturing system and method with improved surface finish |
| WO2021081320A1 (en) | 2019-10-25 | 2021-04-29 | Evolve Additive Solutions, Inc. | Cooling apparatus and method for additive manufacture |
| US11904550B2 (en) | 2019-12-23 | 2024-02-20 | Cubicure Gmbh | System for the lithography-based additive manufacturing of three-dimensional (3D) structures |
| WO2021130661A1 (en) * | 2019-12-23 | 2021-07-01 | Cubicure Gmbh | System for the lithography-based additive manufacturing of three-dimensional (3d) structures |
| US12280548B2 (en) | 2019-12-23 | 2025-04-22 | Cubicure Gmbh | System for the lithography-based additive manufacturing of three-dimensional (3D) structures |
| US11697166B2 (en) | 2020-02-03 | 2023-07-11 | Io Tech Group Ltd. | Methods for printing solder paste and other viscous materials at high resolution |
| US11785722B2 (en) | 2020-06-09 | 2023-10-10 | Io Tech Group Ltd. | Systems for printing conformal materials on component edges at high resolution |
| US12168713B2 (en) | 2020-06-10 | 2024-12-17 | Inkbit, LLC | Materials for photoinitiated cationic ring-opening polymerization and uses thereof |
| US11865767B2 (en) | 2020-08-05 | 2024-01-09 | Io Tech Group Ltd. | Systems and methods for 3D printing with vacuum assisted laser printing machine |
| US12109754B2 (en) | 2020-08-05 | 2024-10-08 | Io Tech Group Ltd. | Systems and methods for 3D printing with vacuum assisted laser printing machine |
| US11691332B2 (en) * | 2020-08-05 | 2023-07-04 | Io Tech Group Ltd. | Systems and methods for 3D printing with vacuum assisted laser printing machine |
| US20220040912A1 (en) * | 2020-08-05 | 2022-02-10 | Io Tech Group Ltd. | Systems and methods for 3d printing with vacuum assisted laser printing machine |
| US12157800B2 (en) | 2021-04-12 | 2024-12-03 | Stratasys, Inc. | Method for underwater processing of water-dispersible materials |
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| US11241824B2 (en) | 2022-02-08 |
| US20180370214A1 (en) | 2018-12-27 |
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